arXiv subjects

Anita Guarino

Publications and source records attributed to Anita Guarino.

11 recordsLinked to original sources

arXiv2026

Giant geometric nonlinear transport in inhomogeneously strained Bi$_2$Se$_3$ single crystalline slabs

Electrical transport in non-centrosymmetric materials exhibits a nonlinear conductivity tensor component that generates second-harmonic voltages in response to applied electric fields. Harnessing this effect is essential for developing zero-threshold electromagnetic energy harvesters and broadband frequency upconverters, both of which require maximizing the nonlinear responsivity. Here, we demonstrate that inhomogeneously strained macroscopic slabs of the topological insulator Bi$_2$Se$_3$ achieve a record-high nonlinear responsivity of $10^4\,μ$m/V: a six orders of magnitude boost compared to its thin-film counterparts. We attribute this giant enhancement to a classical geometric nonlinear transport effect, which is driven by complex strain gradients within the bulk material. Notably, a similar geometric mechanism known as geometric nonlinear Hall was previously observed only in microscale-patterned structures. Our findings establish macroscopic strain engineering as a powerful route to enhance nonlinear transport, with immediate relevance to a broad class of layered systems, including transition metal dichalcogenides and moiré heterostructures.

cond-mat.mes-hall↗

arXiv2026

Raman signatures of a non-reciprocal magnetic phase transition in Ca$_2$RuO$_4$

The magnetic behavior of Ca$_2$RuO$_4$ represents a unique puzzle due to the interplay of strong electronic correlations, magneto-elastic interactions, and large spin-orbit coupling. At low temperatures, an anomalous Mott insulating state emerges, characterized by a complex antiferromagnetic order with a collective amplitude excitation of the magnetic moment which has been discussed in analogy with the Higgs mode. We report here evidence of a magnetic first-order phase transition driven by an out-of-plane magnetic field along the crystallographic $c$-axis of Ca$_2$RuO$_4$. Raman measurements in magnetic field reveal the emergence of mode of magnetic origin and a concomitant modification of the coupling between a phonon and the Higgs amplitude mode. Both the Raman features are characterized by a non-reciprocal hysteresis in magnetic field. Surprisingly, the observed phase transition does not affect the Raman scattering from the in-plane magnons, indicating that the dipolar antiferromagnetic order is preserved. This is consistent with the onset of a new quadrupolar field-controlled state, whose fluctuations structure can trigger an hybridization between the lattice and the magnetic Higgs mode resulting in the observed Raman features.

cond-mat.str-el↗

arXiv2026

Unveiling Hidden Magnons with Anomalous Rotational Symmetry

Correlated materials with competing spin-orbit and crystal-field interactions can host composite spin-orbital magnons that are highly susceptible to structural and electronic perturbations, enabling the control of magnetic dynamics beyond spin-only physics. Using Raman spectroscopy on Ca$_2$RuO$_4$, we show that the partial substitution of Ru with Mn reconstructs the magnon spectrum and reveals one-magnon modes that are hidden in the undoped state. We demonstrate that the transition-metal substitution activates otherwise symmetry-forbidden magnon modes through mirror-symmetry breaking of the underlying spin-orbital configuration. This effect can be theoretically explained by the local structural distortions induced in the RuO$_6$ octahedra near the dopant, that enable the observation of mixed-parity one-magnon modes. These excitations display a distinctive polarization dependence, with a lowering from fourfold to twofold rotational symmetry arising from the mixed-parity character of the coupled magnons and interference between resonant and nonresonant scattering channels. Our results show that spin-orbit-lattice entanglement provides a route to tailoring collective magnetic excitations and their polarization response in spin-orbit-coupled correlated systems.

cond-mat.str-el↗

arXiv2024

Probing disorder-induced time-reversal symmetry breaking in Josephson junctions

The relation between superconductivity and time-reversal symmetry (TRS) is one of the most fascinating problems in condensed matter physics. Although most superconductors inherently possess TRS, nonmagnetic disorder can induce states that demonstrate the breaking of this symmetry. Yet, the identification of experimental signatures of superconductivity with broken TRS remains a challenge. Here, we fabricate vertical Josephson junctions using metallic superconductor (Al) and ion bombarded Sr2RuO4 to study disorder-driven TRS breaking effects. We observe persistent magnetoresistive hysteresis behavior dependent on the disorder deposition time that provides evidence of TRS breaking below the superconducting transition temperature. Field and temperature dependent measurements suggest that the observed effects arise from disorder-induced anomalous flux in Sr2RuO4 which can be sensitively detected by superconducting Al. Our experimental results can be accounted within a physical framework of disorder-induced reconstruction of the superconducting order parameter as described within a multiband Ginzburg-Landau approach.

cond-mat.supr-con↗

arXiv2024

Signatures of a surface spin-orbital chiral metal

The relation between crystal symmetries, electron correlations, and electronic structure steers the formation of a large array of unconventional phases of matter, including magneto-electric loop currents and chiral magnetism. Detection of such hidden orders is a major goal in condensed matter physics. However, to date, nonstandard forms of magnetism with chiral electronic ordering have been experimentally elusive. Here, we develop a theory for symmetry-broken chiral ground states and propose a methodology based on circularly polarized spin-selective angular-resolved photoelectron spectroscopy to probe them. We exploit the archetypal quantum material Sr2RuO4 and reveal spectroscopic signatures which, even though subtle, may be reconciled with the formation of spin-orbital chiral currents at the material surface. As we shed light on these chiral regimes, our findings pave the way for a deeper understanding of ordering phenomena and unconventional magnetism.

cond-mat.str-el↗

arXiv2022

Superconductivity induced by structural reorganization in the electron-doped cuprate Nd$_{2-x}$Ce$_x$CuO$_4$

Electron-doped and hole-doped superconducting cuprates exhibit a symmetric phase diagram as a function of doping. This symmetry is however only approximate. Indeed, electron-doped cuprates become superconductors only after a specific annealing process: This annealing affects the oxygen content by only a tiny amount, but has a dramatic impact on the electronic properties of the sample. Here we report the occurrence of superconductivity in oxygen-deficient Nd$_{2-x}$Ce$_x$CuO$_4$ thin films grown in an oxygen-free environment, after annealing in pure argon flow. As verified by x-ray diffraction, annealing induces an increase of the interlayer distance between CuO$_2$ planes in the crystal structure. Since this distance is correlated to the concentration of oxygens in apical positions, and since oxygen content cannot substantially increase during annealing, our experiments indicate that the superconducting phase transition has to be ascribed to a migration of oxygen ions to apical positions during annealing. Moreover, as we confirm via first-principles density functional theory calculations, the changes in the structural and transport properties of the films can be theoretically described by a specific redistribution of the existing oxygen ions at apical positions with respect to CuO$_2$ planes, which remodulates the electronic band structure and suppresses the antiferromagnetic order, allowing the emergence of hole superconductivity.

cond-mat.supr-con↗

arXiv2020

Self-formed $LaAlO_3/SrTiO_3$ Micro-Membranes

Oxide heterostructures represent a unique playground for triggering the emergence of novel electronic states and for implementing new device concepts. The discovery of 2D conductivity at the $LaAlO_3/SrTiO_3$ interface has been linking for over a decade two of the major current research fields in Materials Science: correlated transition-metal-oxide systems and low-dimensional systems. A full merging of these two fields requires nevertheless the realization of $LaAlO_3/SrTiO_3$ heterostructures in the form of freestanding membranes. Here we show a completely new method for obtaining oxide hetero-membranes with micrometer lateral dimensions. Unlike traditional thin-film-based techniques developed for semiconductors and recently extended to oxides, the concept we demonstrate does not rely on any sacrificial layer and is based instead on pure strain engineering. We monitor through both real-time and post-deposition analyses, performed at different stages of growth, the strain relaxation mechanism leading to the spontaneous formation of curved hetero-membranes. Detailed transmission electron microscopy investigations show that the membranes are fully epitaxial and that their curvature results in a huge strain gradient, each of the layers showing a mixed compressive/tensile strain state. Electronic devices are fabricated by realizing ad hoc circuits for individual micro-membranes transferred on silicon chips. Our samples exhibit metallic conductivity and electrostatic field effect similar to 2D-electron systems in bulk heterostructures. Our results open a new path for adding oxide functionality into semiconductor electronics, potentially allowing for ultra-low voltage gating of a superconducting transistors, micromechanical control of the 2D electron gas mediated by ferroelectricity and flexoelectricity, and on-chip straintronics.

cond-mat.mtrl-sci↗

arXiv2017

Quenching current by flux-flow instability in iron-chalcogenides thin films

The stability against quench is one of the main issue to be pursued in a superconducting material which should be able to perform at very high levels of current densities. Here we focus on the connection between the critical current $I_c$ and the quenching current $I^*$ associated to the so-called flux-flow instability phenomenon, which sets in as an abrupt transition from the flux flow state to the normal state. To this purpose, we analyze several current-voltage characteristics of three types of iron-based thin films, acquired at different temperature and applied magnetic field values. For these samples, we discuss the impact of a possible coexistence of intrinsic electronic mechanisms and extrinsic thermal effects on the quenching current dependence upon the applied magnetic field. The differences between the quenching current and the critical current are reported also in the case of predominant intrinsic mechanisms. Carrying out a comparison with high-temperature cuprate superconductors, we suggest which material can be the best trade-off between maximum operating temperature, higher upper critical field and stability under high current bias.

cond-mat.supr-con↗

arXiv2016

Disorder-sensitive pump-probe measurements on Nd$_{1.83}$Ce$_{0.17}$CuO$_{4\pmδ}$ films

We find an unambiguous relationship between disorder-driven features in the temperature dependence of the resistance and the behavior, as functions of the temperature, of the parameters necessary to describe some of the relaxation processes in the photoinduced differential time-resolved reflectivity of three samples of Nd$_{1.83}$Ce$_{0.17}$CuO$_{4\pmδ}$. The latter, sharing the same Ce content, have been fabricated and annealed ad-hoc in order to differ only for the degree of disorder, mainly related to oxygen content and location, and, consequently, for the temperature dependence of the resistance: two of them present a minimum in the resistance and behave as a superconductor and as a metal, respectively, the third behaves as an insulator. The systematic coherence between the resistance and the relaxation parameters behaviors in temperature for all three samples is absolutely remarkable and shows that pump-probe measurements can be extremely sensitive to disorder as it drives the emergence of new excitations and of the related relaxation channels as in this paradigmatic case.

cond-mat.supr-con↗

arXiv2016

Magneto-transport measurements on Nd$_{1.83}$Ce$_{0.17}$CuO$_{4\pmδ}$ thin films

Nd$_{2-x}$Ce$_x$CuO$_{4\pmδ}$ (NCCO) epitaxial thin films have been deposited on (100) SrTiO$_3$ substrates by DC sputtering technique in different atmosphere. The as-grown samples show different dependence of the in-plane resistivity at low temperature, when they are grown in pure argon atmosphere or in oxygen. Moreover, an unusual behaviour is also found when transport takes place in the presence of an external magnetic field. It is commonly accepted that the higher anisotropic properties of NCCO crystalline cell with respect to the hole doped YBCO and LSCO and the electric conduction mainly confined in the CuO$_2$ plane, strongly support the two-dimensional (2D) character of the current transport in this system. Results on the temperature dependence of the resistance, as well as on the magnetoresistance and the Hall coefficient, obtained on epitaxial NCCO thin films in the over-doped region ($x\ge0.15$) of the phase diagram are presented and discussed.

cond-mat.supr-con↗

arXiv2016

Stability mechanisms of high current transport in iron-chalcogenides superconducting films

The improvement in the fabrication techniques of iron-based superconductors have made these materials real competitors of high temperature superconductors and MgB$_2$. In particular, iron-chalcogenides have proved to be the most promising for the realization of high current carrying tapes. But their use on a large scale cannot be achieved without the understanding of the current stability mechanisms in these compounds. Indeed, we have recently observed the presence of flux flow instabilities features in Fe(Se,Te) thin films grown on CaF$_2$. Here we present the results of current-voltage characterizations at different temperatures and applied magnetic fields on Fe(Se,Te) microbridges grown on CaF$_2$. These results will be analyzed from the point of view of the most validated models with the aim to identify the nature of the flux flow instabilities features (i.e., thermal or electronic), in order to give a further advance to the high current carrying capability of iron-chalcogenide superconductors.

cond-mat.supr-con↗