arXiv subjects

Anna Grassellino

Publications and source records attributed to Anna Grassellino.

At least 55 records · Page 3Linked to original sources

arXiv2023

Quasiparticle spectroscopy in technologically-relevant niobium using London penetration depth measurements

London penetration depth was measured in niobium foils, thin films, single crystals, and superconducting radio-frequency (SRF) cavity pieces cut out from different places. The low-temperature (T<Tc/3) variation, sensitive to the low-energy quasiparticles with states inside the superconducting gap, differs dramatically between different types of samples. With the help of phenomenological modeling, we correlate these different behaviors with known pair-breaking mechanisms and show that such measurements may help distinguish between different pair-breaking mechanisms, such as niobium hydrides and two-level systems (TLS). The conclusions also apply to SRF cavities when tracking the temperature-dependent quality factor and the resonant frequency.

cond-mat.supr-con↗

arXiv2023

Millikelvin measurements of permittivity and loss tangent of lithium niobate

Lithium Niobate is an electro-optic material with many applications in microwave signal processing, communication, quantum sensing, and quantum computing. In this letter, we present findings on evaluating the complex electromagnetic permittivity of lithium niobate at millikelvin temperatures. Measurements are carried out using a resonant-type method with a superconducting radio-frequency (SRF) cavity operating at 7 GHz and designed to characterize anisotropic dielectrics. The relative permittivity tensor and loss tangent are measured at 50 mK with unprecedented accuracy.

quant-ph↗

arXiv2023

First Direct Observation of Nanometer size Hydride Precipitations on Superconducting Niobium

Superconducting niobium serves as a key enabling material for superconducting radio frequency (SRF) technology as well as quantum computing devices. At room temperature, hydrogen commonly occupies tetragonal sites in the Nb lattice as metal (M)-gas (H) phase. When the temperature is decreased, however, solid solution of Nb-H starts to be precipitated. In this study, we show the first identified topographical features associated with nanometer-size hydride phase (Nb1-xHx) precipitates on metallic superconducting niobium using cryogenic-atomic force microscopy (AFM). Further, high energy grazing incidence X-ray diffraction reveals information regarding the structure and stoichiometry that these precipitates exhibit. Finally, through time-of-flight secondary ion mass spectroscopy (ToF-SIMS), we are able to locate atomic hydrogen sources near the top surface. This systematic study further explains localized degradation of RF superconductivity by the proximity effect due to hydrogen clusters.

cond-mat.mtrl-sci↗

arXiv2022

SRF cavities and Superconducting qubits for Gravitational Waves and Dark Photons detection

A short review which focuses on the employment of a Superconducting Radio Frequency cavity for detection of Gravitational Waves. This first part is inspired by the works of Berlin et al.. In the second part, we analyze also the idea to use a cavity-qubit system for the GWs detection and the Dark Photons detection. In this case, the starting point is the work of Dixit et al. which will be extended for SQMS cavities.

hep-ph↗

arXiv2022

Stabilizing and improving qubit coherence by engineering noise spectrum of two-level systems

Superconducting circuits are a leading platform for quantum computing. However, their coherence times are still limited and exhibit temporal fluctuations. Those phenomena are often attributed to the coupling between qubits and material defects that can be well described as an ensemble of two-level systems (TLSs). Among them, charge fluctuators inside amorphous oxide layers contribute to both low-frequency $1/f$ charge noise and high-frequency dielectric loss, causing fast qubit dephasing and relaxation. Moreover, spectral diffusion from mutual TLS interactions varies the noise amplitude over time, fluctuating the qubit lifetime. Here, we propose to mitigate those harmful effects by engineering the relevant TLS noise spectral densities. Specifically, our protocols smooth the high-frequency noise spectrum and suppress the low-frequency noise amplitude via depolarizing and dephasing the TLSs, respectively. As a result, we predict a drastic stabilization in qubit lifetime and an increase in qubit pure dephasing time. Our detailed analysis of feasible experimental implementations shows that the improvement is not compromised by spurious coupling from the applied noise to the qubit.

quant-ph↗

arXiv2022

Developing a Chemical and Structural Understanding of the Surface Oxide in a Niobium Superconducting Qubit

Superconducting thin films of niobium have been extensively employed in transmon qubit architectures. Although these architectures have demonstrated remarkable improvements in recent years, further improvements in performance through materials engineering will aid in large-scale deployment. Here, we use information retrieved from secondary ion mass spectrometry and electron microscopy to conduct a detailed assessment of the surface oxide that forms in ambient conditions for transmon test qubit devices patterned from a niobium film. We observe that this oxide exhibits a varying stoichiometry with NbO and NbO$_2$ found closer to the niobium film and Nb$_2$O$_5$ found closer to the surface. In terms of structural analysis, we find that the Nb$_2$O$_5$ region is semicrystalline in nature and exhibits randomly oriented grains on the order of 1-2 nm corresponding to monoclinic N-Nb$_2$O$_5$ that are dispersed throughout an amorphous matrix. Using fluctuation electron microscopy, we are able to map the relative crystallinity in the Nb$_2$O$_5$ region with nanometer spatial resolution. Through this correlative method, we observe that amorphous regions are more likely to contain oxygen vacancies and exhibit weaker bonds between the niobium and oxygen atoms. Based on these findings, we expect that oxygen vacancies likely serve as a decoherence mechanism in quantum systems.

cond-mat.mes-hall↗

arXiv2022

Stress-induced omega phase transition in Nb thin films for superconducting qubits

We report the observation of omega phase formation in Nb thin films deposited by high-power impulse magnetron sputtering (HiPIMS) for superconducting qubits using transmission electron microscopy (TEM). We hypothesize that this phase transformation to the omega phase with hexagonal structure from bcc phase as well as the formation of {111}<112> mechanical twins is induced by internal stress in the Nb thin films. In terms of lateral dimensions, the size of the omega phase of Nb range from 10 to 100 nm, which is comparable to the coherence length of Nb (~40 nm). In terms of overall volume fraction, ~1 vol.% of the Nb grains exhibit this omega phase. We also find that the omega phase in Nb is not observed in large grain Nb samples, suggesting that the phase transition can be suppressed through reducing the grain boundary density, which may serve as a source of strain and dislocations in this system. The current finding may indicate that the Nb thin film is prone to the omega phase transition due to the internal stress in the Nb thin film. We conclude by discussing effects of the omega phase on the superconducting properties of Nb thin films and discussing pathways to mitigate their formation.

cond-mat.supr-con↗

arXiv2022

Design of axion and axion dark matter searches based on ultra high Q SRF cavities

The Superconducting Quantum Materials and Systems center is developing searches for dark photons, axions and ALPs with the goal of improving upon the current state-of-the-art sensitivity. These efforts leverage on Fermi National Accelerator expertise on ultra-high quality factor superconducting radio frequency cavities combined with the center research on quantum technology. Here we focus on multiple axion searches that utilize ~1E10 quality factor superconducting radio frequency cavities and their resonant modes to enhance the production and/or detection of axions in the cavity volume. In addition, we present preliminary results of single-mode and multi-mode nonlinearity measurements that were carried out as part of an experimental feasibility study to gain insight on the behavior of the ultra-high quality factor resonators and the experimental RF system in the regime relevant for axion searches.

hep-ex↗

arXiv2022

High-efficiency microwave-optical quantum transduction based on a cavity electro-optic superconducting system with long coherence time

Frequency conversion between microwave and optical photons is a key enabling technology to create links between superconducting quantum processors and to realize distributed quantum networks. We propose a microwave-optical transduction platform based on long-coherence-time superconducting radio-frequency (SRF) cavities coupled to electro-optic optical cavities to mitigate the loss mechanisms that limit the attainment of high conversion efficiency. In the design, we optimize the microwave-optical field overlap and optical coupling losses, while achieving long microwave and optical photon lifetime at milli-Kelvin temperatures. This represents a significant enhancement of the transduction efficiency up to 50% under pump power of 140$μ$W, corresponding to few-photon quantum regime. Furthermore, this scheme exhibits high resolution for optically reading out the dispersive shift induced by a superconducting transmon qubit coupled to the SRF cavity. We also show that the fidelity of heralded entanglement generation between two remote quantum systems is enhanced by the low microwave losses. Finally, high-precision in quantum sensing can be reached below the standard quantum limit.

quant-ph↗

arXiv2022

Measurement of the Low-temperature Loss Tangent of High-resistivity Silicon with a High Q-factor Superconducting Resonator

In this letter, we present the direct loss tangent measurement of a high-resistivity intrinsic (100) silicon wafer in the temperature range from ~ 70 mK to 1 K, approaching the quantum regime. The measurement was performed using a technique that takes advantage of a high quality factor superconducting niobium resonator and allows to directly measure the loss tangent of insulating materials with high level of accuracy and precision. We report silicon loss tangent values at the lowest temperature and for electric field amplitudes comparable to those found in planar transmon devices one order of magnitude larger than what was previously estimated. In addition, we discover a non-monotonic trend of the loss tangent as a function of temperature that we describe by means of a phenomenological model based on variable range hopping conduction between localized states around the Fermi energy. We also observe that the dissipation increases as a function of the electric field and that this behavior can be qualitatively described by the variable range hopping conduction mechanism as well. This study lays the foundations for a novel approach to investigate the loss mechanisms and accurately estimate the loss tangent in insulating materials in the quantum regime, leading to a better understanding of coherence in quantum devices.

quant-ph↗

arXiv2022

High-Order Qubit Dephasing at Sweet Spots by Non-Gaussian Fluctuators: Symmetry Breaking and Floquet Protection

Although the Gaussian-noise assumption is widely adopted in the study of qubit decoherence, non-Gaussian noise sources, especially the strong discrete fluctuators, have been detected in many qubits. It remains an important task to further understand and mitigate the distinctive decoherence effect of the non-Gaussian noise. Here, we study the qubit dephasing caused by the non-Gaussian fluctuators, and predict a symmetry-breaking effect that is unique to the non-Gaussian noise. This broken symmetry results in an experimentally measurable mismatch between the extremum points of the dephasing rate and qubit frequency, which demands extra carefulness in characterizing the noise and locating the optimal working point. To further enhance the coherence time at the sweet spot, we propose to suppress the second-order derivative of the qubit frequency by the Floquet engineering. Our simulation with a heavy fluxonium shows an order of magnitude improvement of the dephasing time, even after including the noise introduced by the drive.

quant-ph↗

arXiv2022

Plasma Cleaning of LCLS-II-HE verification cryomodule cavities

Plasma cleaning is a technique that can be applied in superconducting radio-frequency (SRF) cavities in situ in cryomodules in order to decrease their level of field emission. We developed the technique for the Linac Coherent Light Source II (LCLS-II) cavities and we present in this paper the full development and application of plasma processing to the LCLS-II High Energy (HE) verification cryomodule (vCM). We validated our plasma processing procedure on the vCM, fully processing four out of eight cavities of this CM, demonstrating that cavities performance were preserved in terms of both accelerating field and quality factor. Applying plasma processing to this clean, record breaking cryomodule also showed that no contaminants were introduced in the string, maintaining the vCM field emission-free up to the maximum field reached by each cavity. We also found that plasma processing eliminates multipacting (MP) induced quenches that are typically observed frequently within the MP band field range. This suggests that plasma processing could be employed in situ in CMs to mitigate both field emission and multipacting, significantly decreasing the testing time of cryomodules, the linac commissioning time and cost and increasing the accelerator reliability.

physics.acc-ph↗

arXiv2022

Quantum computing hardware for HEP algorithms and sensing

Quantum information science harnesses the principles of quantum mechanics to realize computational algorithms with complexities vastly intractable by current computer platforms. Typical applications range from quantum chemistry to optimization problems and also include simulations for high energy physics. The recent maturing of quantum hardware has triggered preliminary explorations by several institutions (including Fermilab) of quantum hardware capable of demonstrating quantum advantage in multiple domains, from quantum computing to communications, to sensing. The Superconducting Quantum Materials and Systems (SQMS) Center, led by Fermilab, is dedicated to providing breakthroughs in quantum computing and sensing, mediating quantum engineering and HEP based material science. The main goal of the Center is to deploy quantum systems with superior performance tailored to the algorithms used in high energy physics. In this Snowmass paper, we discuss the two most promising superconducting quantum architectures for HEP algorithms, i.e. three-level systems (qutrits) supported by transmon devices coupled to planar devices and multi-level systems (qudits with arbitrary N energy levels) supported by superconducting 3D cavities. For each architecture, we demonstrate exemplary HEP algorithms and identify the current challenges, ongoing work and future opportunities. Furthermore, we discuss the prospects and complexities of interconnecting the different architectures and individual computational nodes. Finally, we review several different strategies of error protection and correction and discuss their potential to improve the performance of the two architectures. This whitepaper seeks to reach out to the HEP community and drive progress in both HEP research and QIS hardware.

quant-ph↗

arXiv2022

Searches for New Particles, Dark Matter, and Gravitational Waves with SRF Cavities

This is a Snowmass white paper on the utility of existing and future superconducting cavities to probe fundamental physics. Superconducting radio frequency (SRF) cavity technology has seen tremendous progress in the past decades, as a tool for accelerator science. With advances spear-headed by the SQMS center at Fermilab, they are now being brought to the quantum regime becoming a tool in quantum science thanks to the high degree of coherence. The same high quality factor can be leveraged in the search for new physics, including searches for new particles, dark matter, including the QCD axion, and gravitational waves. We survey some of the physics opportunities and the required directions of R&D. Given the already demonstrated integration of SRF cavities in large accelerator systems, this R&D may enable larger scale searches by dedicated experiments.

hep-ph↗

arXiv2022

Materials and devices for fundamental quantum science and quantum technologies

Technologies operating on the basis of quantum mechanical laws and resources such as phase coherence and entanglement are expected to revolutionize our future. Quantum technologies are often divided into four main pillars: computing, simulation, communication, and sensing & metrology. Moreover, a great deal of interest is currently also nucleating around energy-related quantum technologies. In this Perspective, we focus on advanced superconducting materials, van der Waals materials, and moiré quantum matter, summarizing recent exciting developments and highlighting a wealth of potential applications, ranging from high-energy experimental and theoretical physics to quantum materials science and energy storage.

quant-ph↗

arXiv2021

Internal Friction Measures to Study Precipitates Formation in EP and N-Doped Bulk Nb for SRF Applications

Main focus of this study is the investigation of thermodynamics phenomena responsible for the High Field Q Slope (HFQS) in SRF cavities by Internal Friction (IF) measurement. Mechanical spectroscopy is, indeed, a well-established technique to study precipitate formations in BCC materials and several works on the effects of impurities as N and O on the Snoek peak have been published so far and will be taken as reference to explain the mechanisms behind the observed dissipation effects. Internal Friction measurements were performed in Belgium at IMCE on Nb rectangular shape samples with different RRR values prepared at Fermilab by using Electro Polishing (EP), N-doping and heat treatments in order to reproduce the same conditions during the standard treatments applied on bulk Nb SRF cavities. From IF spectra, the H trapping mechanism by interstitial atoms (N and O and/or vacancies, depending on the purity level, RRR) can be easily recognized leading to results that perfectly corroborate previous findings on Q-disease, HFQS and RRR phenomena.

physics.app-ph↗

arXiv2021

TOF-SIMS Analysis of Decoherence Sources in Nb Superconducting Resonators

Superconducting qubits have emerged as a potentially foundational platform technology for addressing complex computational problems deemed intractable with classical computing. Despite recent advances enabling multiqubit designs that exhibit coherence lifetimes on the order of hundreds of $μ$s, material quality and interfacial structures continue to curb device performance. When niobium is deployed as the superconducting material, two-level system defects in the thin film and adjacent dielectric regions introduce stochastic noise and dissipate electromagnetic energy at the cryogenic operating temperatures. In this study, we utilize time-of-flight secondary ion mass spectrometry (TOF-SIMS) to understand the role specific fabrication procedures play in introducing such dissipation mechanisms in these complex systems. We interrogated Nb thin films and transmon qubit structures fabricated by Rigetti Computing and at the National Institute of Standards and Technology through slight variations in the processing and vacuum conditions. We find that when Nb film is sputtered onto the Si substrate, oxide and silicide regions are generated at various interfaces. We also observe that impurity species such as niobium hydrides and carbides are incorporated within the niobium layer during the subsequent lithographic patterning steps. The formation of these resistive compounds likely impact the superconducting properties of the Nb thin film. Additionally, we observe the presence of halogen species distributed throughout the patterned thin films. We conclude by hypothesizing the source of such impurities in these structures in an effort to intelligently fabricate superconducting qubits and extend coherence times moving forward.

physics.app-ph↗

arXiv2020

Field emission mitigation studies in LCLS-II cavities via in situ plasma processing

Field emission is one of the factors that can limit the performance of superconducting radio frequency cavities. In order to reduce possible field emission in LCLS-II (Linac Coherent Light Source II), we are developing plasma processing for 1.3 GHz 9-cell cavities. Plasma processing can be applied in situ in the cryomodule to mitigate field emission related to hydrocarbon contamination present on the cavity surface. In this paper, plasma cleaning was applied to single cell and 9-cell cavities, both clean and contaminated; the cavities were cold tested before and after plasma processing in order to compare their performance. It was proved that plasma cleaning does not negatively affect the nitrogen doping surface treatment; on the contrary, it preserves the high quality factor and quench field. Plasma processing was also applied to cavities with natural field emission or artificially contaminated. It was found that this technique successfully removes carbon-based contamination from the cavity iris and that it is able to remove field emission in a naturally field emitting cavity. Vacuum failure experiments were simulated on four cavities, and in some cases plasma processing was able to achieve an increase in performance.

physics.acc-ph↗