arXiv subjects

Anton Zubayer

Publications and source records attributed to Anton Zubayer.

10 recordsLinked to original sources

arXiv2026

Persistent Uncorrelated Magnetic Domains in Fe/Si Multilayers and their suppression by incorporating 11B4C

This study investigates magnetic domains in Fe/Si and Fe/Si + B4C multilayers using spin flip off-specular polarized neutron reflectometry. The results show that Fe/Si multilayers exhibit pronounced spin flip off-specular scattering originating from magnetic domains that are uncorrelated out of plane. With increasing external magnetic field the domains progressively coalesce and their magnetization rotates toward alignment with the applied field, approaching a homogeneous magnetic state at higher fields. In contrast, Fe/Si + B4C multilayers exhibit no detectable spin flip off-specular scattering already at low fields, indicating that the multilayer reaches magnetic saturation at significantly lower applied fields. The scattering patterns are interpreted using distorted wave Born approximation simulations in BornAgain, enabled by our added code for simulating magnetic domains and magnetic ordering. To further probe the magnetic behavior, low-energy mu+SR measurements were performed, representing the first mu+SR investigation of polarizing neutron optics multilayers. Together with comparison to previously reported VSM data, these measurements provide insight into the magnetic behavior across short range, medium range, and long range length scales. The results show that incorporating approximately 15 vol.% B4C makes the magnetic configuration highly responsive to external magnetic fields, with clear sensitivity to both in-plane and out-of-plane field geometries. These results show that B4C suppresses magnetic domains and spin flip off-specular scattering, improving Fe/Si coatings for neutron polarization optics in regards to off-specular scattering, and other applications requiring easy magnetic manipulation.

cond-mat.mtrl-sci↗

arXiv2025

Optimization of magnetic contrast layer for neutron reflectometry

Neutron reflectivity is a powerful technique for probing density profiles in films, with applications across Physics, Chemistry, and Biology. However, challenges arise when dealing with samples characterized by high roughness, unknown scattering length density (SLD) with low contrast, very thin layers, or complex multi-layered structures, that cannot be uniquely resolved due to the phase problem. Incorporating a magnetic reference layer (MRL) and using polarized neutron reflectivity improves sensitivity and modeling accuracy by providing complementary information. In this study, we introduce a quantitative way to compare MRL systems in a model-free way. We apply this approach to demonstrate that CoTi alloys offer a superior solution as an MRL compared to the commonly used Fe or Ni-based MRLs. The low nuclear and magnetic scattering length densities of CoTi significantly enhance sensitivity, making it particularly advantageous for soft matter research. Furthermore, the tunable Co vs Ti ratio allows for optimization of the SLDs to achieve maximum sensitivity, establishing CoTi as a highly effective choice for MRL applications. The applied simulation framework for optimizing MRL sensitivity to a specific materials system and research question is a generic approach that can be used prior to growing the MRL for a given experiment.

cond-mat.mtrl-sci↗

arXiv2025

Magnetic hysteresis control in thin film Fe/Si multilayers by incorporation of B4C

Magnetic hysteresis properties in Fe/Si multilayers have been studied as a function of the B4C content to control magnetization amplitude, coercivity, and hysteresis tilt, properties that are beneficial to tune for advancing applications in e.g. data storage, spintronics, and sensors. With an ion-assisted magnetron sputtering technique, 35 distinct thin film multilayer samples were prepared and their magnetic and structural properties were characterized by vibrating sample magnetometry, X-ray photoelectron spectroscopy, near edge X-ray absorption fine structure spectroscopy, and X-ray and neutron scattering methods. Key findings indicate that adding B4C lowers the coercivity and can decrease the saturation magnetization, demonstrating the tunability of magnetic responses based on composition. For samples with =30Å periodicity, 10-15% of B4C addition produces antiferromagnetically (AF) coupled multilayers, and such AF coupling strength increases with the B4C content. Our findings reveal that B atoms do not chemically bind within the Fe atoms but instead occupy interstitial positions, disrupting medium- to long-range crystallinity thereby inducing the amorphization. Thereon, the observed effects on magnetic properties are directly attributed to this amorphization process caused by the presence of B4C. The demonstrated ability to finely adjust magnetic properties by varying the B4C content offers a promising approach to overcome challenges in magnetic device performance and efficiency.

cond-mat.mtrl-sci↗

arXiv2025

The Role of 11B4C Interlayers in Enhancing Fe/Si Multilayer Performance for Polarized Neutron Mirrors

This study investigates the effects of incorporating 11B4C interlayers into Fe/Si multilayers, with a focus on interface quality, reflectivity, polarization, and magnetic properties for polarized neutron optics. It is found that the introduction of 1 Å and 2 Å 11B4C interlayers significantly improves the interface sharpness, reducing interface width and preventing excessive Si diffusion into the Fe layers. X-ray reflectivity and polarized neutron reflectivity measurements show enhanced reflectivity and polarization, with a notable increase in polarization for 30 Å period multilayers. The inclusion of interlayers also helps prevent the formation of iron-silicides, improving both the magnetic properties and neutron optical performance. However, the impact of interlayers is less pronounced in thicker-period multilayers (100 Å), primarily due to the ratio between layer and interface widths. These results suggest that 11B4C interlayers offer a promising route for optimizing Fe/Si multilayer performance in polarized neutron mirrors.

cond-mat.mtrl-sci↗

arXiv2025

Diminished spin-flip reflectivity in stacked multilayers with varying period thicknesses of Fe/Si by incorporating 11B4C

This study investigates the effects of 11B4C co-sputtering on the structural and optical properties of Fe/Si stacked multilayers, with a focus on neutron supermirror applications. X-ray and neutron reflectivity techniques reveal that 11B4C incorporation improves interface sharpness, reduces roughness, and enhances reflectivity for all multilayer periods. Neutron reflectivity measurements show reduced spin-flip intensities, while wafer-curvature measurements indicate a 50% reduction in internal stress, allowing for higher mechanical stability of the multilayers. These improvements are attributed to the amorphization of Fe layers, which also suppress the formation of structural and magnetic domains responsible for stress and spin-flip scattering. In contrast, the pure Fe/Si sample exhibits a persistent half-order Bragg peak, indicating residual antiferromagnetic coupling. The results demonstrate that 11B4C enhances neutron optics by reducing spin-flip effects, increasing reflectivity and polarization, and alleviating stress, enabling the use of polarizers at reduced external fields compared to pure Fe/Si multilayers. These findings establish 11B4C as a transformative material for advancing neutron supermirror technology, paving the way for more efficient, stable, and high-performance polarizers in next-generation neutron optics.

cond-mat.mtrl-sci↗

arXiv2024

Morphology of buried interfaces in ion-assisted magnetron sputter deposited 11B4C-containing Ni/Ti multilayer neutron optics investigated by grazing incidence small angle scattering

Multilayer neutron optics require precise control of interface morphology for optimal performance. In this work, we investigate the effects of different growth conditions on the interface morphology of Ni/Ti based multilayers, with a focus on incorporating low-neutron-absorbing 11B4C and using different ion assistance schemes. Grazing incidence small angle X-ray scattering was used to probe the structural and morphological details of buried interfaces, revealing that the layers become more strongly correlated and the interfaces form mounds with increasing amounts of 11B4C. Applying high flux ion assistance during growth can reduce mound formation but lead to interface mixing, while a high flux modulated ion assistance scheme with an initial buffer layer grown at low ion energy and the top layer at higher ion energy prevents intermixing. The optimal condition was found to be adding 26.0 at.% 11B4C combined with high flux modulated ion assistance. A multilayer with a period of 48.2 Å and 100 periods was grown under these conditions, and coupled fitting to neutron and X-ray reflectivity data revealed an average interface width of only 2.7 Å, a significant improvement over the current state-of-the-art commercial Ni/Ti multilayers. Overall, our study demonstrates that the addition of 11B4C and the use of high flux modulated ion assistance during growth can significantly improve the interface morphology of Ni/Ti multilayers, leading to improved neutron optics performance.

cond-mat.mtrl-sci↗

arXiv2024

Material design optimization for large-m 11B4C-based Ni/Ti supermirror neutron optics

State-of-the-art Ni/Ti supermirror neutron optics have limited reflected intensity and a restricted neutron energy range due to the interface width. Incorporating low-neutron-absorbing 11B4C enhances reflectivity and allows for thinner layers to be deposited, with which more efficient supermirrors with higher m-values can be realized. However, incorporating 11B4C reduces the optical contrast, limiting the attainable reflectivity at low scattering vectors, making this approach infeasible. This study explores various approaches to optimize the material design of 11B4C-containing Ni/Ti supermirrors to maintain high reflectivity at low scattering vectors and achieve low interface widths at large scattering vectors. The scattering length density contrast versus interface width is investigated for multilayer periods of 30 Å, 48 Å, and 84 Å, for designs involving pure Ni/Ti multilayers, multilayers with 11B4C co-deposited in Ni and Ti layers, multilayers with 11B4C co-deposited only in Ni layers, and multilayers with 11B4C as thin interlayers between Ni and Ti layers. Our results suggest that a depth-graded hybrid material design by incorporating 11B4C inside the Ni and Ti layers, below approximately 26 Å, and introducing 1.5 Å 11B4C interlayers between the thicker Ni and Ti layers can achieve a higher reflectivity than state-of-the-art Ni/Ti multilayers over the entire scattering vector range.

cond-mat.mtrl-sci↗

arXiv2022

Revised Magnetic Structure and Tricritical Behavior of the CMR Compound NaCr$_2$O$_4$ Investigated with High Resolution Neutron Diffraction and $μ^+$SR

The mixed valence Cr compound NaCr$_2$O$_4$, synthesized using a high-pressure technique, offers a unique playground for investigating unconventional physical properties in condensed matter. In the present study, muon spin rotation/relaxation ($μ^+$SR) and high-resolution neutron powder diffraction (NPD) measurements were carried out to clarify the true magnetic ground state of this interesting compound. Our detailed study brings new insight, allowing us to confirm the existence of a commensurate antiferromagnetic order (C-AFM) and to extract its ordered Cr moment $μ^{\rm C}_{\rm Cr}=(4.30\pm0.01)μ_B$. Such a value of the ordered moment is in fact compatible with the existence of high-spin Cr sites. Further, the value of the canting angle of the Cr spin axial vector is refined as $θ_{\rm c}=(8.8\pm0.5)^{\circ}$. Employing high-quality samples in combination with time-of-flight NPD, a novel magnetic supercell was also revealed. Such supercell display an incommensurate (IC)-AFM propagation vector (0~0~${\textstyle \frac{1}{2}-}δ$), having an ordered moment $μ^{\rm IC}_{\rm Cr}=(2.20\pm0.03)μ_B$. It is suggested that the C-AFM and IC-AFM modulations are due to itinerant and localized contributions to the magnetic moment, respectively. Finally, the direct measurement of the magnetic order parameter provided a value of the critical exponent $β= 0.245 \approx \frac{1}{4}$, suggesting a non conventional critical behavior for the magnetic phase transition in NaCr$_2$O$_4$.

cond-mat.str-el↗

arXiv2022

Na-ion Dynamics in the Solid Solution Na$_{\rm x}$Ca$_{1- \rm x}$Cr$_2$O$_4$ Studied by Muon Spin Rotation and Neutron Diffraction

In this work we present systematic set of measurements carried out by muon spin rotation/relaxation ($μ^+$SR) and neutron powder diffraction (NPD) on the solid solution Na$_{\rm x}$Ca$_{1- \rm x}$Cr$_2$O$_4$. This study investigates Na-ion dynamics in the quasi-1D (Q1D) diffusion channels created by the honeycomb-like arrangement of CrO$_6$ octahedra, in the presence of defects introduced by Ca doping. With increasing Ca content, the size of the diffusion channels is enlarged, however, this effect does not enhance the Na ion mobility. Instead the overall diffusivity is hampered by the local defects and the Na hopping probability is lowered. The diffusion mechanism in Na$_{\rm x}$Ca$_{1- \rm x}$Cr$_2$O$_4$ was found to be interstitial and the activation energy as well as diffusion coefficient were determined for all the members of the solid solution.

cond-mat.mtrl-sci↗

arXiv2020

Honeycomb Layered Oxides: Structure, Energy Storage, Transport, Topology and Relevant Insights

The advent of nanotechnology has hurtled the discovery and development of nanostructured materials with stellar chemical and physical functionalities in a bid to address issues in energy, environment, telecommunications and healthcare. In this quest, a class of two-dimensional layered materials consisting of alkali or coinage metal atoms sandwiched between slabs exclusively made of transition metal and chalcogen (or pnictogen) atoms arranged in a honeycomb fashion have emerged as materials exhibiting fascinatingly rich crystal chemistry, high-voltage electrochemistry, fast cation diffusion besides playing host to varied exotic electromagnetic and topological phenomena. Currently, with a niche application in energy storage as high-voltage materials, this class of honeycomb layered oxides serves as ideal pedagogical exemplars of the innumerable capabilities of nanomaterials drawing immense interest in multiple fields ranging from materials science, solid-state chemistry, electrochemistry and condensed matter physics. In this review, we delineate the relevant chemistry and physics of honeycomb layered oxides, and discuss their functionalities for tunable electrochemistry, superfast ionic conduction, electromagnetism and topology. Moreover, we elucidate the unexplored albeit vastly promising crystal chemistry space whilst outlining effective ways to identify regions within this compositional space, particularly where interesting electromagnetic and topological properties could be lurking within the aforementioned alkali and coinage-metal honeycomb layered oxide structures. We conclude by pointing towards possible future research directions, particularly the prospective realisation of Kitaev-Heisenberg-Dzyaloshinskii-Moriya interactions with single crystals and Floquet theory in closely-related honeycomb layered oxide materials.

cond-mat.mtrl-sci↗