arXiv subjects

Antonio Coniglio

Publications and source records attributed to Antonio Coniglio.

At least 37 records · Page 2Linked to original sources

arXiv2014

Dynamical arrest: interplay of the glass and of the gel transitions

The structural arrest of a polymeric suspension might be driven by an increase of the cross--linker concentration, that drives the gel transition, as well as by an increase of the polymer density, that induces a glass transition. These dynamical continuous (gel) and discontinuous (glass) transitions might interfere, since the glass transition might occur within the gel phase, and the gel transition might be induced in a polymer suspension with glassy features. Here we study the interplay of these transitions by investigating via event--driven molecular dynamics simulation the relaxation dynamics of a polymeric suspension as a function of the cross--linker concentration and the monomer volume fraction. We show that the slow dynamics within the gel phase is characterized by a long sub-diffusive regime, which is due both to the crowding as well as to the presence of a percolating cluster. In this regime, the transition of structural arrest is found to occur either along the gel or along the glass line, depending on the length scale at which the dynamics is probed. Where the two line meet there is no apparent sign of higher order dynamical singularity. Logarithmic behavior typical of $A_{3}$ singularity appear inside the gel phase along the glass transition line. These findings seem to be related to the results of the mode coupling theory for the $F_{13}$ schematic model.

cond-mat.stat-mech↗

arXiv2012

'Flow & Jam' of frictional athermal systems under shear stress

We report recent results of molecular dynamics simulations of frictional athermal particles at constant volume fraction and constant applied shear stress, focusing on a range of control parameters where the system first flows, but then jams after a time tjam. On decreasing the volume fraction, the mean jamming time diverges, while its sample fluctuations become so large that the jamming time probability distribution P(tjam) becomes a power-law. We obtain an insight on the origin of this phenomenology focusing on the flowing regime, which is characterized by the presence of a clear correlation between the shear velocity and the mean number of contacts per particles Z, whereby small velocities occur when Z acquires higher values.

cond-mat.soft↗

arXiv2012

Absence of `fragility' and mechanical response of jammed granular materials

We perform molecular dynamic (MD) simulations of frictional non-thermal particles driven by an externally applied shear stress. After the system jams following a transient flow, we probe its mechanical response in order to clarify whether the resulting solid is 'fragile'. We find the system to respond elastically and isotropically to small perturbations of the shear stress, suggesting absence of fragility. These results are interpreted in terms of the energy landscape of dissipative systems. For the same values of the control parameters, we check the behaviour of the system during a stress cycle. Increasing the maximum stress value, a crossover from a visco-elastic to a plastic regime is observed.

cond-mat.soft↗

arXiv2011

Dynamical Correlation Length and Relaxation Processes in a Glass Former

We investigate the relaxation process and the dynamical heterogeneities of the kinetically constrained Kob--Anderson lattice glass model, and show that these are characterized by different timescales. The dynamics is well described within the diffusing defect paradigm, which suggest to relate the relaxation process to a reverse--percolation transition. This allows for a geometrical interpretation of the relaxation process, and of the different timescales.

cond-mat.soft↗

arXiv2010

Disordered jammed packings of frictionless spheres

At low volume fraction, disordered arrangements of frictionless spheres are found in un--jammed states unable to support applied stresses, while at high volume fraction they are found in jammed states with mechanical strength. Here we show, focusing on the hard sphere zero pressure limit, that the transition between un-jammed and jammed states does not occur at a single value of the volume fraction, but in a whole volume fraction range. This result is obtained via the direct numerical construction of disordered jammed states with a volume fraction varying between two limits, $0.636$ and $0.646$. We identify these limits with the random loose packing volume fraction $\rl$ and the random close packing volume fraction $\rc$ of frictionless spheres, respectively.

cond-mat.soft↗

arXiv2009

Jamming at zero temperature, zero friction, and finite applied shear stress

Via molecular dynamics simulations, we unveil the hysteretic nature of the jamming transition of soft repulsive frictionless spheres, as it occurs varying the volume fraction or the shear stress. In a given range of control parameters the system may be found both in a flowing and in an jammed state, depending on the preparation protocol. The hysteresis is due to an underlying energy landscape with many minima, as explained by a simple model, and disappears in the presence of strong viscous forces and in the small $σ$ limit. In this limit, structural quantities are continuous at the transition, while the asymptotic values of two time quantities such as the self-intermediate scattering function are discontinuous, giving to the jamming transition a mixed first-order second-order character close to that found at the glass transition of thermal systems.

cond-mat.soft↗

arXiv2008

Random very loose packs

We measure the number Omega(phi) of mechanically stable states of volume fraction phi of a granular assembly under gravity. The granular entropy S(phi) = log Omega(phi) vanishes both at high density, at phi = phi_rcp, and a low density, at phi = phi_rvlp, where phi_rvlp is a new lower bound we call random very loose pack. phi_rlp is the volume fraction where the entropy is maximal. These findings allow for a clear explanation of compaction experiments, and provide the first first-principle definition of the random loose volume fraction. In the context of the statistical mechanics approach to static granular materials, states with phi < phi_rlp are characterized by a negative temperature.

cond-mat.soft↗

arXiv2008

Correlations and Omori law in Spamming

The most costly and annoying characteristic of the e-mail communication system is the large number of unsolicited commercial e-mails, known as spams, that are continuously received. Via the investigation of the statistical properties of the spam delivering intertimes, we show that spams delivered to a given recipient are time correlated: if the intertime between two consecutive spams is small (large), then the next spam will most probably arrive after a small (large) intertime. Spam temporal correlations are reproduced by a numerical model based on the random superposition of spam sequences, each one described by the Omori law. This and other experimental findings suggest that statistical approaches may be used to infer how spammers operate.

physics.soc-ph↗

arXiv2008

Flow, Ordering and Jamming of Sheared Granular Suspensions

We study the rheological properties of a granular suspension subject to constant shear stress by constant volume molecular dynamics simulations. We derive the system `flow diagram' in the volume fraction/stress plane $(ϕ,F)$: at low $ϕ$ the flow is disordered, with the viscosity obeying a Bagnold-like scaling only at small $F$ and diverging as the jamming point is approached; if the shear stress is strong enough, at higher $ϕ$ an ordered flow regime is found, the order/disorder transition being marked by a sharp drop of the viscosity. A broad jamming region is also observed where, in analogy with the glassy region of thermal systems, slow dynamics followed by kinetic arrest occurs when the ordering transition is prevented.

cond-mat.soft↗

arXiv2007

Spatial signal amplification in cell biology: a lattice-gas model for self-tuned phase ordering

Experiments show that the movement of eukaryotic cells is regulated by a process of phase separation of two competing enzymes on the cell membrane, that effectively amplifies shallow external gradients of chemical attractant. Notably, the cell is able to self-tune the final enzyme concentrations to an equilibrium state of phase coexistence, for a wide range of the average attractant concentration. We propose a simple lattice model in which, together with a short-range attraction between enzymes, a long-range repulsion naturally arises from physical considerations, that easily explains such observed behavior.

cond-mat.stat-mech↗

arXiv2007

Granular packs under vertical tapping: structure evolution, grain motion, and dynamical heterogeneities

The compaction dynamics of a granular media subject to a sequence of vertical taps made of fluid pulses is investigated via Molecular Dynamics simulations. Our study focuses on three different levels: macroscopic (volume fraction), mesoscopic (Vorono\"ı volumes, force distributions) and microscopic (grain displacements). We show that the compaction process has many characteristics which are reminiscent of the slow dynamics of glass forming systems, as previously suggested. For instance the mean volume fraction slowly increases in time and approaches a stationary value following a stretched exponential law, and the associated compaction time diverges as the tapping intensity decreases. The study of microscopic quantities also put in evidence the existence of analogies with the dynamics of glass formers, as the existence of dynamical heterogeneities and spatially correlated motion of grains; however it also shows that there are important qualitative differences, as for instance in the role of the cage effect. Correlations between geometry and dynamics of the system at the grain level are put in evidence by comparing a particle Vorono\"ı volume and its displacement in a single tap.

cond-mat.soft↗

arXiv2007

Lamellar order, microphase structures and glassy phase in a field theoretic model for charged colloids

In this paper we present a detailed analytical study of the phase diagram and of the structural properties of a field theoretic model with a short-range attraction and a competing long-range screened repulsion. We provide a full derivation and expanded discussion and digression on results previously reported briefly in M. Tarzia and A. Coniglio, Phys. Rev. Lett. 96, 075702 (2006). The model contains the essential features of the effective interaction potential among charged colloids in polymeric solutions. We employ the self-consistent Hartree approximation and a replica approach, and we show that varying the parameters of the repulsive potential and the temperature yields a phase coexistence, a lamellar and a glassy phase. Our results suggest that the cluster phase observed in charged colloids might be the signature of an underlying equilibrium lamellar phase, hidden on experimental time scales, and emphasize that the formation of microphase structures may play a prominent role in the process of colloidal gelation.

cond-mat.soft↗

arXiv2006

Thermodynamics and Statistical Mechanics of dense granular media

By detailed Molecular Dynamics and Monte Carlo simulations %of a realistic model we show that granular materials at rest can be described as thermodynamics systems. First we show that granular packs can be characterized by few parameters, as much as fluids or solids. Then, in a second independent step, we demonstrate that these states can be described in terms of equilibrium distributions which coincide with the Statistical Mechanics of powders first proposed by Edwards. We also derive the system equation of state as a function of the ``configurational temperature'', its new intensive thermodynamic parameter.

cond-mat.stat-mech↗

arXiv2006

Dynamically induced effective interaction in periodically driven granular mixtures

We discuss the microscopic origin of dynamical instabilities and segregation patterns discovered in granular mixtures under oscillating horizontal shear, by investigating, via molecular dynamics simulations, the effective interaction between like-particles. This turns out to be attractive at short distances and strongly anisotropic, with a longer range repulsive shoulder along the direction of oscillation. This features explain the system rich phenomenology, including segregation and stripe pattern formation. Finally, we show that a modified Cahn-Hilliard equation, taking into account the characteristics of the effective interaction, is capable of describing the dynamics of the mixture.

cond-mat.soft↗

arXiv2005

Shear instabilities in granular mixtures

Dynamical instabilities in fluid mechanics are responsible of a variety of important common phenomena, such as waves on the sea surface or Taylor vorteces in Couette flow. In granular media dynamical instabilities has just begun to be discovered. Here we show by means of molecular dynamics simulation the existence of a new dynamical instability of a granular mixture under oscillating horizontal shear, which leads to the formation of a striped pattern where the components are segregated. We investigate the properties of such a Kelvin-Helmholtz like instability and show how it is connected to pattern formation in granular flow and segregation.

cond-mat.soft↗

arXiv2004

Glass glass transition and new dynamical singularity points in an analytically solvable p-spin glass like model

We introduce and analytically study a generalized p-spin glass like model that captures some of the main features of attractive glasses, recently found by Mode Coupling investigations, such as a glass/glass transition line and dynamical singularity points characterized by a logarithmic time dependence of the relaxation. The model also displays features not predicted by the Mode Coupling scenario that could further describe the attractive glasses behavior, such as aging effects with new dynamical singularity points ruled by logarithmic laws or the presence of a glass spinodal line.

cond-mat.stat-mech↗

arXiv2004

Number of spanning clusters at the high-dimensional percolation thresholds

A scaling theory is used to derive the dependence of the average number of spanning clusters at threshold on the lattice size L. This number should become independent of L for dimensions d<6, and vary as log L at d=6. The predictions for d>6 depend on the boundary conditions, and the results there may vary between L^{d-6} and L^0. While simulations in six dimensions are consistent with this prediction (after including corrections of order loglog L), in five dimensions the average number of spanning clusters still increases as log L even up to L = 201. However, the histogram P(k) of the spanning cluster multiplicity does scale as a function of kX(L), with X(L)=1+const/L, indicating that for sufficiently large L the average will approach a finite value: a fit of the 5D multiplicity data with a constant plus a simple linear correction to scaling reproduces the data very well. Numerical simulations for d>6 and for d=4 are also presented.

cond-mat.stat-mech↗

arXiv2004

Segregation in fluidized versus tapped packs

We compare the predictions of two different statistical mechanics approaches, corresponding to different physical measurements, proposed to describe binary granular mixtures subjected to some external driving (continuous shaking or tap dynamics). In particular we analytically solve at a mean field level the partition function of a simple hard sphere lattice model under gravity and we focus on the phenomenon of size segregation. We find that the two approaches lead to similar results and seem to coincide in the limit of very low shaking amplitude. However they give different predictions of the crossovers from Brazil nut effect to reverse Brazil nut effect with respect to the shaking amplitude, which could be detected experimentally.

cond-mat.stat-mech↗