arXiv subjects

Antonio Suma

Publications and source records attributed to Antonio Suma.

30 records · Page 2Linked to original sources

arXiv2021

Work Fluctuations in the Active Ornstein- Uhlenbeck Particle model

We study the large deviations of the power injected by the active force for an Active Ornstein-Uhlenbeck Particle (AOUP), free or in a confining potential. For the free-particle case, we compute the rate function analytically in d-dimensions from a saddle-point expansion, and numerically in two dimensions by it a) direct sampling of the active work in numerical solutions of the AOUP equations and b) Legendre-Fenchel transform of the scaled cumulant generating function obtained via a cloning algorithm. The rate function presents asymptotically linear branches on both sides and it is independent of the system's dimensionality, apart from a multiplicative factor. For the confining potential case, we focus on two-dimensional systems and obtain the rate function numerically using both methods a) and b). We find a different scenario for harmonic and anharmonic potentials: in the former case, the phenomenology of fluctuations is analogous to that of a free particle, but the rate function might be non-analytic; in the latter case the rate functions are analytic, but fluctuations are realised by entirely different means, which rely strongly on the particle-potential interaction. Finally, we check the validity of a fluctuation relation for the active work distribution. In the free-particle case, the relation is satisfied with a slope proportional to the bath temperature. The same slope is found for the harmonic potential, regardless of activity, and for an anharmonic potential with low activity. In the anharmonic case with high activity, instead, we find a different slope which is equal to an effective temperature obtained from the fluctuation-dissipation theorem.

cond-mat.stat-mech↗

arXiv2020

A particle-based Ising model

We characterize equilibrium properties and relaxation dynamics of a two-dimensional lattice containing, at each site, two particles connected by a double-well potential (dumbbell). Dumbbells are oriented in the orthogonal direction with respect to the lattice plane and interact with each other through a Lennard-Jones potential truncated at the nearest neighbor distance. We show that the system's equilibrium properties are accurately described by a two-dimensional Ising model with an appropriate coupling constant. Moreover, we characterize the coarsening kinetics by calculating the cluster size as a function of time and compare the results with Monte Carlo simulations based on Glauber or reactive dynamics rate constants.

cond-mat.stat-mech↗

arXiv2020

Effective temperatures in inhomogeneous passive and active bidimensional Brownian particle systems

We study the stationary dynamics of an active interacting Brownian particle system. We measure the violations of the fluctuation dissipation theorem, and the corresponding effective temperature, in a locally resolved way. Quite naturally, in the homogeneous phases the diffusive properties and effective temperature are also homogeneous. Instead, in the inhomogeneous phases (close to equilibrium and within the MIPS sector) the particles can be separated in two groups with different diffusion properties and effective temperatures. Notably, at fixed activity strength the effective temperatures in the two phases remain distinct and approximately constant within the MIPS region, with values corresponding to the ones of the whole system at the boundaries of this sector of the phase diagram. We complement the study of the globally averaged properties with the theoretical and numerical characterization of the fluctuation distributions of the single particle diffusion, linear response, and effective temperature in the homogeneous and inhomogeneous phases. We also distinguish the behavior of the (time-delayed) effective temperature from the (instantaneous) kinetic temperature, showing that the former is independent on the friction coefficient.

cond-mat.stat-mech↗

arXiv2018

Active dumbbells: dynamics and morphology in the coexisting region

With the help of molecular dynamics simulations we study an ensemble of active dumbbells in purely repulsive interaction. We derive the phase diagram in the density-activity plane and we characterise the various phases with liquid, hexatic and solid character. The analysis of the structural and dynamical properties, such as enstrophy, mean square displacement, polarisation, and correlation functions, shows the continuous character of liquid and hexatic phases in the coexisting region when the activity is increased starting from the passive limit.

cond-mat.stat-mech↗

arXiv2018

Full phase diagram of active Brownian disks: from melting to motility-induced phase separation

We establish the complete phase diagram of self-propelled hard disks in two spatial dimensions from the analysis of the equation of state and the statistics of local order parameters. The equilibrium melting scenario is maintained at small activities, with coexistence between active liquid and hexatic order, followed by a proper hexatic phase and a further transition to an active solid. As activity increases, the emergence of hexatic and solid order is shifted towards higher densities. Above a critical activity and for a certain range of packing fractions, the system undergoes MIPS and demixes into low and high density phases; the latter can be either disordered (liquid) or ordered (hexatic or solid) depending on activity.

cond-mat.stat-mech↗

arXiv2017

Phase co-existence in bidimensional passive and active dumbbell systems

We demonstrate that there is macroscopic co-existence between regions with hexatic order and regions in the liquid/gas phase over a finite interval of packing fractions in active dumbbell systems with repulsive power-law interactions in two dimensions. In the passive limit this interval remains finite, similarly to what has been found in bidimensional systems of hard and soft disks. We did not find discontinuous behaviour upon increasing activity from the passive limit.

cond-mat.stat-mech↗

arXiv2017

Large fluctuations and dynamic phase transition in a system of self-propelled particles

We study the statistics, in stationary conditions, of the work $W_τ$ done by the active force in different systems of self-propelled particles in a time $τ$. We show the existence of a critical value $W_τ^†$ such that fluctuations with $W_τ>W_τ^†$ correspond to configurations where interaction between particles plays a minor role whereas those with $W_τ< W_τ^†$ represent states with single particles dragged by clusters. This two-fold behavior is fully mirrored by the probability distribution $P(W_τ)$ of the work, which does not obey the large-deviation principle for $W_τ<W_τ^†$. This pattern of behavior can be interpreted as due to a phase transition occurring at the level of fluctuating quantities and an order parameter is correspondingly identified.

cond-mat.stat-mech↗

arXiv2016

How to fold intricately: using theory and experiments to unravel the properties of knotted proteins

Over the years, advances in experimental and computational methods have helped us to understand the role of thermodynamic, kinetic and active (chaperone-aided) effects in coordinating the folding steps required to achieving a knotted native state. Here, we review such developments by paying particular attention to the complementarity of experimental and computational studies. Key open issues that could be tackled with either or both approaches are finally pointed out.

q-bio.BM↗

arXiv2015

Rotational and translational diffusion in an interacting active dumbbell system

We study the dynamical properties of a two-dimensional ensemble of self-propelled dumbbells with only repulsive interactions. This model undergoes a phase transition between a homogeneous and a segregated phase and we focus on the former. We analyse the translational and rotational mean square displacements in terms of the Péclet number, describing the relative role of active forces and thermal fluctuations, and of particle density. We find that the four distinct regimes of the translational mean square displacement of the single active dumbbell survive at finite density for parameters that lead to a separation of time-scales. We establish the Péclet number and density dependence of the diffusion constant in the last diffusive regime. We prove that the ratio between the diffusion constant and its value for the single dumbbell depends on temperature and active force only through the Péclet number at all densities explored. We also study the rotational mean square displacement proving the existence of a rich behavior with intermediate regimes only appearing at finite density. The ratio of the rotational late-time diffusion constant and its vanishing density limit depends on the Péclet number and density only. At low Péclet number it is a monotonically decreasing function of density. At high Péclet number it first increases to reach a maximum and next decreases as a function of density. We interpret the latter result advocating the presence of large-scale fluctuations close to the transition, at large enough density, that favour coherent rotation inhibiting, however, rotational motion for even larger packing fractions.

cond-mat.stat-mech↗

arXiv2015

Motility-induced phase separation and coarsening in active matter

Active systems, or active matter, are self-driven systems which live, or function, far from equilibrium - a paradigmatic example which we focus on here is provided by a suspension of self-motile particles. Active systems are far from equilibrium because their microscopic constituents constantly consume energy from the environment in order to do work, for instance to propel themselves. The nonequilibrium nature of active matter leads to a variety of non-trivial intriguing phenomena. An important one which has recently been the subject of intense interest among biological and soft matter physicists is that of the so-called "motility-induced phase separation", whereby self-propelled particles accumulate into clusters in the absence of any explicit attractive interactions between them. Here we review the physics of motility-induced phase separation, and discuss this phenomenon within the framework of the classic physics of phase separation and coarsening. We also discuss theories for bacterial colonies where coarsening may be arrested. Most of this work will focus on the case of run-and-tumble and active Brownian particles in the absence of solvent-mediated hydrodynamic interactions - we will briefly discuss at the end their role, which is not currently fully understood in this context.

cond-mat.soft↗

arXiv2015

Fluctuations of rotational and translational degrees of freedom in an interacting active dumbbell system

We study the dynamical properties of a two-dimensional ensemble of self-propelled dumbbells with only repulsive interactions. After summarizing the behavior of the translational and rotational mean-square displacements in the homogeneous phase that we established in a previous study, we analyze their fluctuations. We study the dependence of the probability distribution functions in terms of the Péclet number, describing the relative role of active forces and thermal fluctuations, and of particle density.

cond-mat.stat-mech↗

arXiv2014

Dynamics of a homogeneous active dumbbell system

We analyse the dynamics of a two dimensional system of interacting active dumbbells. We characterise the mean-square displacement, linear response function and deviation from the equilibrium fluctuation-dissipation theorem as a function of activity strength, packing fraction and temperature for parameters such that the system is in its homogeneous phase. While the diffusion constant in the last diffusive regime naturally increases with activity and decreases with packing fraction, we exhibit an intriguing non-monotonic dependence on the activity of the ratio between the finite density and the single particle diffusion constants. At fixed packing fraction, the time-integrated linear response function depends non-monotonically on activity strength. The effective temperature extracted from the ratio between the integrated linear response and the mean-square displacement in the last diffusive regime is always higher than the ambient temperature, increases with increasing activity and, for small active force it monotonically increases with density while for sufficiently high activity it first increases to next decrease with the packing fraction. We ascribe this peculiar effect to the existence of finite-size clusters for sufficiently high activity and density at the fixed (low) temperatures at which we worked. The crossover occurs at lower activity or density the lower the external temperature. The finite density effective temperature is higher (lower) than the single dumbbell one below (above) a cross-over value of the Peclet number.

cond-mat.stat-mech↗