arXiv subjects

Anwesha Kanjilal

Publications and source records attributed to Anwesha Kanjilal.

4 recordsLinked to original sources

arXiv2026

Resolving room temperature microscale fracture and plasticity of iron oxides along the cascade of iron ore reduction via nanoindentation and microcantilever bending

Understanding the fundamental mechanical behaviour of iron oxide phases is essential for controlling attrition and fracture during iron ore reduction process, particularly in hydrogen-based direct reduction systems. This study investigates the room temperature plasticity and fracture behaviour of single-crystal hematite, magnetite, and Wustite using nanoindentation and micro-cantilever fracture testing. Hematite exhibited the highest hardness, H and elastic modulus, E (H=18.5 GPa, E=281 GPa), followed by magnetite (H=8.7 GPa, E=165 GPa) and Wustite (H=7.5 GPa, E=145 GPa), reflecting differences in slip activity along the iron oxide reduction sequence. Furthermore, fracture toughness was measured using notched microcantilevers for all three iron oxide phases, aligned along low index and high index crystallographic planes, respectively. For the low index-oriented case hematite showed increased fracture toughness owing to crack deviation and faceting while magnetite and Wustite exhibited single plane cleavage fracture. Distinct changes in the deformation behavior in terms of plasticity and cracking of the three iron oxides were evident from both methods. Further investigation of a magnetite-gangue interface, particularly relevant to low-concentration ores, revealed significantly reduced fracture toughness compared to the magnetite phase. Overall, these results provide a comprehensive set of mechanical properties of iron oxides with potential application in material models for predicting fracture and attrition during hydrogen-based direct reduction.

cond-mat.mtrl-sci↗

arXiv2024

Microscale deformation of intermetallic-Mg interface under shear loading

While intermetallic (IM)-metal interfaces in metallic alloys are critical for tuning mechanical properties, they can also act as failure sites, underscoring the importance of determining their strength. This study reports on a novel microshear geometry, and demonstrates its applicability for testing the strength and deformation behavior of IM-metal interfaces in Mg-Al-Ca alloys, a key material for light weight automotive applications. The shear tests are applied to a model bi-layered system grown by magnetron sputtering, comprising of a CaMg2 film deposited onto a Mg layer. A parametric study was performed using finite element modeling to optimize the specimen dimensions. Subsequently, in situ microshear tests conducted inside a scanning electron microscope revealed an interface shear strength of ~136 MPa, and provided insights into the stages of deformation progression. Post mortem examination of the sheared interface revealed an irregular surface indicating ductile deformation at room temperature.

cond-mat.mtrl-sci↗

arXiv2024

Nanoscale brittle-to-ductile transition of the C15 CaAl$_2$ Laves phase

The influence of temperature on the deformation behaviour of the C15 CaAl$_2$ Laves phase, a key constituent for enhancing the mechanical properties of Mg alloys up to service temperatures of 200 °C, remains largely unexplored. This study presents, for the first time, the nanoscale brittle-to-ductile transition (BDT) of this intermetallic phase through in situ testing including nanoindentation, scratch testing, and micropillar splitting conducted at elevated temperatures. By correlating observations from these techniques, changes in deformation of CaAl$_2$ were identified in relation to temperature. High-temperature nanoindentation quantitatively determined the temperature range for the BDT, and revealed that CaAl$_2$ undergoes a BDT at ~0.55T$_m$, exhibiting an intermediate region of microplasticity. A noticeable decrease in nanoindentation hardness was observed at ~450-500 °C, accompanied by an increase in residual indent size, while indentation cracking was not observed above 300 °C. Results from high-temperature micropillar splitting revealed cracking and brittle pillar splitting up to 300 °C, with an increase in apparent fracture toughness from 0.9 $\pm$ 0.1 MPa$\cdot\sqrt m$ to 2.8 $\pm$ 0.3 MPa$\cdot\sqrt m$, and subsequent crack-free plastic deformation from 400 °C. Transmission electron microscopy analysis of the deformed material from nanoindentation revealed that the BDT of CaAl$_2$ may be attributed to enhanced dislocation plasticity with increasing temperature.

cond-mat.mtrl-sci↗

arXiv2024

Fracture of the $C$15 CaAl$_2$ Laves phase at small length-scales

The cubic $C$15 CaAl$_2$ Laves phase is a crucial brittle intermetallic precipitate in Mg-Al-Ca alloys. Although knowledge of the mechanical properties of coexisting phases is essential for improved alloy design, the fracture toughness is not yet studied experimentally due to the need for miniaturised testing. Here, micropillar splitting and microcantilever bending are used to experimentally determine the toughness of CaAl$_2$. It is found that the toughness value of ~1 $MPa\cdot\sqrt m$ from pillar splitting is largely insensitive to sample heat treatment, ion beam used for fabrication, micropillar diameter, and surface orientation. From nanoindentation supported by electron channelling contrast imaging and backscatter diffraction, fracture is observed to take place mostly on {011} planes. Atomistic fracture simulations on a model $C$15 Laves phase showed that the preference of {011} cleavage planes over the more energetically favourable {111} is due to lattice trapping and kinetics controlling fracture. Using rectangular microcantilever bending tests where the notch plane was misoriented to the closest possible {112} cleavage plane by ~8°, and the closest {001}, {011} and {111} plane by >20°, a toughness of ca. 2 $MPa\cdot\sqrt m$ was determined along with the electron microscopy observation of significant deviations of the crack path, demonstrating that preferential crystallographic cleavage planes determine the toughness in this material. Further investigation using pentagonal microcantilevers with precise alignment of the notch with the cleavage planes revealed similar fracture toughness values for different low-index planes. The results presented here are the first detailed experimental study of fracture toughness of the $C$15 CaAl$_2$ Laves phase, and can be understood in terms of crack plane and crack front dependent fracture toughness.

cond-mat.mtrl-sci↗