arXiv2026
We present high-resolution UVES+VLT observations of neutral nickel and iron atoms in the coma of the interstellar comet 3I/ATLAS taken after perihelion. Metal emission was strong shortly after perihelion and persisted at large heliocentric distances. At $r_h \sim 2$ au the total metal production rate was found to be at least an order of magnitude larger than that of typical solar-system comets. Post-perihelion production rates exhibit pronounced asymmetry compared to the pre-perihelion behavior: production rates are higher after perihelion and decline more gradually with $r_h$, the difference being stronger for FeI. The NiI/FeI abundance ratio, initially anomalously large before perihelion, evolved toward values comparable to solar-system comets near 2 au, and shows a weaker $r_h$ dependence after perihelion. To interpret these results, we revisited and extended the carbonyl hypothesis in which FeI and NiI are produced by the rapid photodissociation of Fe(CO)$_5$ and Ni(CO)$_4$ vaporized from the nucleus. Fits that include direct sublimation of carbonyls reproduce the observed rates and the high NiI/FeI line ratio, which is determined by the higher volatility of Ni(CO)$_4$. Desorption of carbonyls from sublimating CO$_2$ and H$_2$O ices is found to be negligible. The temperature profiles needed to reproduce the observations were found to be shallower than the equilibrium $T \propto r_h^{-1/2}$ relation, suggesting that the sublimation could occur below the surface of the nucleus. Fits using temperature profiles from thermal models require sublimation from depths of several cm, especially post-perihelion. An additional transient heat source ($T \simeq$ 100-140~K), possibly linked to the amorphous-crystalline ice transition, is proposed to explain the early NiI excess before perihelion.