arXiv subjects

Armandas Balcytis

Publications and source records attributed to Armandas Balcytis.

16 recordsLinked to original sources

arXiv2022

Spatio-temporal isolator in lithium niobate on insulator

In this contribution, we simulate, design, and experimentally demonstrate an integrated optical isolator based on spatiotemporal modulation in the thin-film lithium niobate on insulator waveguide platform. We used two cascaded travelling wave phase modulators for spatiotemporal modulation and a ring resonator as a wavelength filter to suppress the sidebands of the reverse propagating light. This enabled us to achieve an isolation of 27 dB. The demonstrated suppression of the reverse propagating light makes such isolators suitable for the integration with III-V laser diodes and Erbium doped gain sections in the thin-film lithium niobate on insulator waveguide platform.

physics.optics↗

arXiv2020

Lithography-free Kirchhoff's Metasurfaces

Lithography-free metasurfaces composed of a nano-layered stack of materials are attractive not only due to their optical properties but also by virtue of fabrication simplicity and cost reduction of devices based on such structures. We demonstrate a multi-layer metasurface with engineered electromagnetic absorption in the mid-infrared (MIR) wavelength range. Characterisation of thin SiO$_2$ and Si films sandwiched between two Au layers by way of experimental absorption and thermal radiation measurements as well as finite difference time domain (FDTD) numerical simulations is presented. Comparison of experimental and simulation data of optical properties of multilayer metasurfaces show guidelines for the absorber/emitter applications.

physics.optics↗

arXiv2019

Nanoscale optical and structural characterisation of silk

Background: Nanoscale composition of silk defining its unique properties via a hierarchical structural anisotropy has to be analysed at the highest spatial resolution of tens-of-nanometers corresponding to the size of fibrils made of b-sheets, which are the crystalline building blocks of silk. Results: Nanoscale optical and structural properties of silk have been measured from 100-nm thick longitudinal slices of silk fibers with ~10 nm resolution, the highest so far. Optical sub-wavelength resolution in hyperspectral mapping of absorbance and molecular orientation were carried out for comparison at IR wavelengths 2-10 micrometers using synchrotron radiation. Conclusion: Reliable distinction of transmission changes by only 1-2% due to anisotropy of amide bands was obtained from nano-thin slices of silk.

physics.app-ph↗

arXiv2018

Paracetamol Micro-Structure Analysis by Optical Mapping

Domain structure of paracetamol -- popular antipyretic analgesic -- was investigated by infrared (IR) spectroscopy using synchrotron radiation. Absorbance and retardance maps reveal molecular orientation inside the micro-domains of the paracetamol form II which has a better water solubility and compressibility compared to the commercially used forms I. The developed method of analysis representing orientation of optical slow(fast)-axis is compared with azimuthal orientation of the absorbance at several specific IR bands using vector maps. High brightness of synchrotron radiation and hyper-spectral mapping of structural domains in paracetamol clearly reveals the domain boundaries and can potentially be used to observe \emph{in situ} intra-phase transformations of paracetamol forms-I, II, III and melting, which are important for making medical tablets and powders by an industrial process.

cond-mat.mtrl-sci↗

arXiv2018

Kirchhoff's metasurfaces

Thermo-optical properties of the nanodisc and metal hole array plasmonic perfect absorber (PPA) metasurfaces were designed and characterised at midinfrared wavelengths. Both, light emitter and detector systems are highly thought after for the future sensor networks in the internet-of-things for various spectral domains. Reciprocity of the absorbance and emittance is shown experimentally, i.e., the PPAs are following Kirchhoff's law where the patterns exhibiting a strong optical absorption were found enhanced thermal radiation. Design principles and scaling for photo-thermal conversion are discussed. The highest efficiency of light-to-heat and heat-to-radiation were obtained for the Au-Si-Au structures.

physics.optics↗

arXiv2018

Micro-thermocouple on nano-membrane: thermometer for nanoscale measurements

A thermocouple of Au-Ni with only 2.5-micrometers-wide electrodes on a 30-nm-thick Si3N4 membrane was fabricated by a simple low-resolution electron beam lithography and lift off procedure. The thermocouple is shown to be sensitive to heat generated by laser as well as an electron beam. Nano-thin membrane was used to reach a high spatial resolution of energy deposition and to realise a heat source of sub-1 micrometer diameter. This was achieved due to a limited generation of secondary electrons, which increase a lateral energy deposition. A low thermal capacitance of the fabricated devices is useful for the real time monitoring of small and fast temperature changes, e.g., due to convection, and can be detected through an optical and mechanical barrier of the nano-thin membrane. Temperature changes up to ~2x10^5 K/s can be measured at 10 kHz rate. A simultaneous down-sizing of both, the heat detector and heat source strongly required for creation of thermal microscopy is demonstrated. Peculiarities of Seebeck constant (thermopower) dependence on electron injection into thermocouple are discussed. Modeling of thermal flows on a nano-membrane with presence of a micro-thermocouple was carried out to compare with experimentally measured temporal response.

cond-mat.mes-hall↗

arXiv2017

Nanoscale chemical mapping of laser-solubilized silk

A water soluble amorphous form of silk was made by ultra-short laser pulse irradiation and detected by nanoscale IR mapping. An optical absorption-induced nanoscale surface expansion was probed to yield the spectral response of silk at IR molecular fingerprinting wavelengths with a high ~20 nm spatial resolution defined by the tip of the probe. Silk microtomed sections of 1-5 micrometers in thickness were prepared for nanoscale spectroscopy and a laser was used to induce amorphisation. Comparison of silk absorbance measurements carried out by table-top and synchrotron Fourier transform IR spectroscopy proved that chemical imaging obtained at high spatial resolution and specificity (able to discriminate between amorphous and crystalline silk) is reliably achieved by nanoscale IR. A nanoscale material characterization using synchrotron IR radiation is discussed.

physics.app-ph↗

arXiv2017

Trapping ultracold atoms at 100 nm from a chip surface in a 0.7-micrometer-period magnetic lattice

We report the trapping of ultracold 87Rb atoms in a 0.7 micron-period 2D triangular magnetic lattice on an atom chip. The magnetic lattice is created by a lithographically patterned magnetic Co/Pd multilayer film plus bias fields. Rubidium atoms in the F=1, mF=-1 low-field seeking state are trapped at estimated distances down to about 100 nm from the chip surface and with calculated mean trapping frequencies as high as 800 kHz. The measured lifetimes of the atoms trapped in the magnetic lattice are in the range 0.4 - 1.7 ms, depending on distance from the chip surface. Model calculations suggest the trap lifetimes are currently limited mainly by losses due to surface-induced thermal evaporation following loading of the atoms from the Z-wire trap into the very tight magnetic lattice traps, rather than by fundamental loss processes such as surface interactions, three-body recombination or spin flips due to Johnson magnetic noise. The trapping of atoms in a 0.7 micrometer-period magnetic lattice represents a significant step towards using magnetic lattices for quantum tunneling experiments and to simulate condensed matter and many-body phenomena in nontrivial lattice geometries.

physics.atom-ph↗

arXiv2017

Photoacoustic signal enhancements from gold nano-colloidal suspensions excited by a pair of time-delayed femtosecond pulses

Photoacoustic signal enhancements were observed with a pair of time-delayed femtosecond pulses upon excitation of gold nanosphere colloidal suspension. A systematic experimental investigation of photoacoustic intensity within the delay time, t = 0 to 15 ns, was carried out. The results revealed a significant enhancement factor of ~2 when the pre-pulse energy is 20-30% of the total energy. Pre-pulse and main pulse energy ratios, E(1)p-pol. :E(2)s-pol. were varied to determine the optimal ratio that yields to maximum photoacoustic signal enhancement. This enhancement was ascribed to the initial stage of thermalization and bubble generation in the nanosecond time scale. Pre-pulse scattering intensity measurements and numerical finite-difference time-domain calculations were performed to reveal dynamics and light field enchancement, respectively.

cond-mat.mes-hall↗

arXiv2017

Polarisation of THz synchrotron radiation: from its measurement to control

Polarisation analysis of synchrotron THz radiation was carried out with a standard stretched polyethylene polariser and revealed that the linearly polarised (horizontal) component contributes up to 22 +/- 5% to the circular polarised synchrotron emission extracted by a gold-coated mirror with a horizontal slit inserted near a bending magnet edge. Comparison with theoretical predictions shows a qualitative match with dominance of the edge radiation. Grid polarisers 3D-printed out of commercial acrilic resin were tested for the polariser function and showed spectral regions where the dichroic ratio DR > 1 and < 1 implying importance of molecular and/or stress induced anisotropy. Metal-coated 3D-printed THz optical elements can find a range of applications in intensity and polarisation control of THz beams.

physics.ins-det↗

arXiv2017

Optical readout of hydrogen storage in films of Au and Pd

For hydrogen sensor and storage applications, films of Au and Pd were (i) co-sputtered at different rates or (ii) deposited in a sequential layer-by-layer fashion on a cover glass. Peculiarities of hydrogen uptake and release were optically monitored using 1.3 micrometers wavelength light. Increase of optical transmission was observed for hydrogenated Pd-rich films of 10-30 nm thickness. Up to a three times slower hydrogen release took place as compared with the hydrogen uptake. Composition ratio of Au:Pd and thermal treatment of films provided control over the optical extinction changes and hydrogen uptake/release time constants. Higher uptake and release rates were observed in the annealed Au:Pd films as compared to those deposited at room temperature and were faster for the Au-richer films. Three main parameters relevant for sensors: sensitivity, selectivity, stability (reproducibility) are discussed together with the hydrogenation mechanism in Au:Pd alloys.

cond-mat.mes-hall↗

arXiv2017

Orientational Mapping Augmented Sub-Wavelength Hyper-Spectral Imaging of Silk

Molecular alignment underpins optical, mechanical, and thermal properties of materials, however, its direct measurement from volumes with micrometer dimensions is not accessible, especially, for structurally complex bio-materials. How the molecular alignment is linked to extraordinary properties of silk and its amorphous-crystalline composition has to be accessed by a direct measurement from a single silk fiber. Here, we show orientation mapping of the internal silk fiber structure via polarisation-dependent IR absorbance at high spatial resolution of 4.2 micrometers and 1.9 micrometers in a hyper-spectral IR imaging by attenuated total reflection using synchrotron radiation in the spectral fingerprint region around 6 micrometers wavelength. Free-standing longitudinal micro-slices of silk fibers, thinner than the fiber cross section, were prepared by microtome for the four polarisation method to directly measure the orientational sensitivity of absorbance in the molecular fingerprint spectral window of the amide bands of b-sheets and amorphous polypeptides of silk. Flat lateral micro-slices of silk eliminates shape related artefact in determination of absorbance anisotropy and order parameters of the amide bands.

physics.bio-ph↗

arXiv2016

Efficient X-ray generation from gold colloidal solutions

Hard X-ray generation for Au nanoparticle dispersion was systematically investigated for different particle diameters ranging from 10 to 100 nm with a narrow size distribution of +/- 2%. Scaling law of X-ray generation is close to a 6-photon process before the onset of saturation for excitation by 45 fs laser pulses with central wavelength of 800 nm. This is consistent with bulk plasmon excitation at wavelength ~ 138 nm. The longitudinal E-field component due to nanoparticle focusing is responsible for the excitation of the longitudinal bulk plasmon. The proposed analysis also explains X-ray emission from water breakdown via an electron solvation mechanism at ~6.2 eV. The most efficient emission of X-rays was observed for 40 +/- 10 nm diameter nanoparticles which also had the strongest UV extinction. X-ray emission was the most efficient when induced by pre-chirped 370 +/- 20 fs laser pulses and exhibited the highest intensity at a negative chirp.

cond-mat.mes-hall↗

arXiv2016

Au-Ag-Cu nano-alloys: tailoring of permittivity

Precious metal alloys enables new possibilities to tailor materials for specific optical functions. Here we present a systematic study of the effects of a nanoscale alloying on the permittivity of Au-Ag-Cu metals at 38 different atomic mixing ratios. The permittivity was measured and analyzed numerically by applying the Drude model. X-ray diffraction (XRD) revealed the face centered cubic lattice of the alloys. Both, optical spectra and XRD results point towards an equivalent composition-dependent electron scattering behavior. Correlation between the fundamental structural parameters of alloys and the resulting optical properties is elucidated. Plasmonic properties of the Au-Ag-Cu alloy nanoparticles were investigated by numerical simulations. Guidelines for designing plasmonic response of nano- structures and their patterns are presented from the material science perspective.

cond-mat.mtrl-sci↗

arXiv2016

UV-photoelectric effect for augmented contrast and resolution in electron microscopy

A new tool providing material contrast control in scanning electron microscopy (SEM) is demonstrated. The approach is based on deep-UV illumination during SEM imaging and delivers a novel material based contrast as well as higher resolution due to the photoelectric effect. Electrons liberated from illuminated sample surface contribute to the imaging which can be carried out at a faster acquisition rate, provide material selective contrast, reduce distortions caused by surface charging, and can substitute metal coating in SEM. These features provide high fidelity SEM imaging and are expected to significantly improve the performance of electron beam instruments as well as to open new opportunities for imaging and characterization of materials at the nanoscale.

physics.ins-det↗

arXiv2016

Percolation threshold gold films on columnar coatings: characterisation for SERS applications

Percolation of gold films of ~15 nm thickness was controlled to achieve the largest openings during Au deposition. Gold was evaporated on 300-nm-thick films of nanostructured porous and columnar SiO2, TiO2 and MgF2 which were deposited by controlling the angle, rotation speed during film formation and ambient pressure. The gold films were tested for SERS performance using thiophenol reporter molecules which form a stable self-assembled monolayer on gold. The phase retardation of these SERS substrates was up to 5% for wavelengths in the visible spectral range, as measured by Stokes polarimetry. The SERS intensity on gold percolation films can reach 10^3 counts/(mW.s) for tight focusing in air, while back-side excitation through the substrate has shown the presence of an additional SERS enhancement via the Fresnel near-field mechanism.

physics.optics↗