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Armel Descamps-Mandine

Publications and source records attributed to Armel Descamps-Mandine.

3 recordsLinked to original sources

Electrically-pumped near-infrared VCSEL epitaxially-grown on Si

The monolithic integration of compact laser sources onto silicon remains a critical bottleneck for the scalable development of silicon photonics. In particular, the direct epitaxial growth of near-infrared vertical-cavity surface-emitting lasers (VCSELs) on silicon has long been hindered by the simultaneous requirements of low crystalline defect density in the active region and smooth interfaces in the distributed Bragg reflector (DBR) mirrors, both essential to achieving high cavity quality factors and low lasing thresholds. Here, we report the direct epitaxial integration of near-infrared VCSELs on silicon substrates using a two-step growth strategy specifically designed to suppress defect propagation while preserving mirror interface abruptness. This approach enables effective confinement of threading dislocations away from the active region and ensures high-reflectivity DBRs with excellent structural uniformity. Structural and optical characterizations reveal an epitaxial stack of high crystalline quality, leading to laser performance comparable to VCSELs commonly grown on GaAs substrates. We demonstrate, for the first time, directly grown VCSELs on silicon wafers exhibiting threshold currents of only a few milliamperes. These results establish a decisive proof of concept for the monolithic integration of good-performance VCSELs onto silicon platforms and open a viable pathway toward fully integrated, low-cost silicon-based photonic systems.

physics.optics↗

One-dimensional self-organization of water molecules in proton conducting Andersson-Wadsley titanates

Layered alkali titanates with M 2 Ti 2 O 5 chemical formula (MTO, M=K,Rb) belonging to the Andersson-Wadsley perovskite family spontaneously incorporate water to form MTO.(H 2 O) x compounds, which exhibit superionic conductivity. At very low hydration x, scanning electron microscopy evidences one-dimensional heterogeneous patterns oriented along ___ b that are arranged in an orderly manner. At higher hydration, the material is observed to spontaneously exfoliate by creating (001) surfaces. Simulations carried out using Density Functional Theory reveal an ordered arrangement of the guest water molecules in Rb 2 Ti 2 O 5 , with strong hydrogen bonds between the water molecules and the apical oxygen of the host crystal. At low hydration x, the water molecules form self-organized one dimensional (1D) double chains along ___ b. Further increase of the water content leads to the creation of hydrated (001)-surfaces that are made of densely packed water chains in agreement with the infrared spectroscopy measurements. Rb 2 Ti 2 O 5 exhibits highly anisotropic proton conductivity, with respect to the crystal orientation, with super-ionic conductivity along ___ b reaching 3 mS/cm at room temperature after hydration. The combined observations and simulations suggest that these water chains are thus at the root of fast proton conduction, which is likely powered by a Grotthuss-like mechanism.

cond-mat.mtrl-sci↗

Rb2Ti2O5 : a layered ionic conductor at the sub-micrometer scale

Over the past few years, ionic conductors have gained a lot of attention given the possibility to implement them in various applications such as supercapacitors, batteries or fuel cells as well as for resistive memories. Especially, layered two-dimensional (2D) crystals such as h-BN, graphene oxide and MoSe2 have shown to provide unique properties originating from the specific 2D confinement of moving ions. Two important parameters are the ion conductivity and the chemical stability over a wide range of operating conditions. In this vein, Rb2Ti2O5 has been recently found displaying remarkable properties such as superionic conduction and colossal equivalent dielectric constant. Here, a first approach to the study of the electrical properties of layered Rb2Ti2O5 at the 100-nanometer scale is presented. Characterizations by means of micro-Raman spectroscopy and atomic force microscope (AFM) measurements of mechanically exfoliated RTO nanocrystals via the so-called adhesive-tape technique are reported. Finally, the results of electrical measurements performed on an exfoliated RTO nanocrystals are presented, and are found to be consistent with the results obtained on macroscopic crystals. 4

cond-mat.mtrl-sci↗