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Artyom Aguichine

Publications and source records attributed to Artyom Aguichine.

At least 19 recordsLinked to original sources

JWST COMPASS Program: The 3--5$μ$m transmission spectrum of LTT 1445 A b

The search for an atmosphere on the closest rocky M dwarf planet, LTT 1445 A b, has been the subject of intense investigation from both the ground and space. Here, we present the first JWST transmission spectrum of LTT 1445 A b using a single visit spanning 3-5~$μ$m using NIRSpec/G395H. We conduct two independent reductions of the data using both the Eureka! and ExoTiC-JEDI pipelines. Overall, we measure the NRS1 transit depths to a median precision of $\sim23$~ppm in 41 spectroscopic channels with uniform widths of 30 pixels ($\sim$ 0.02 $μ$m), and the NRS2 transit depths to $\sim36$~ppm precision in 65 spectroscopic channels, also with uniform widths of 30 pixels. We rule out any statistically significant spectral features at this precision and place limits on atmospheric metallicity using a grid of chemical equilibrium models with grey opaque clouds. Using NIRSpec/G395H alone, we can place limits on the atmospheric metallicity of $\gtrsim350~\times$ Solar when the opaque pressure level is greater than 0.01~bars. We also conduct a combined analysis of JWST/NIRSpec and HST/WFC3 transmission data and find our atmospheric limits can be extended $\gtrsim500~\times$ Solar when considering both datasets. Future analyses both in transit and emission will uncover whether there are detectable atmospheric features.

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JWST COMPASS: NIRSpec/G395H Transmission Observations of the Sub-Neptune HD 15337 c

We present the 3-5 $μ$m transmission spectrum of HD 15337 c (TOI-402.02), a sub-Neptune (2.526 R$_{\oplus}$, 6.792 M$_{\oplus}$, T$_{\rm eq}$$\sim$656 K) around a K1V star observed as part of the JWST COMPASS program. We reduce these observations with two pipelines and find consistent transmission spectra. The resulting median precisions in 30 pixel spectroscopic bins for visit 1 are $\sim$40 ppm and $\sim$70 ppm and for visit 2 are $\sim$30 ppm and $\sim$54 ppm for NRS1 and NRS2, respectively. We attribute the differing precisions to the lack of adequate pre-transit baseline in visit 1 from an early transit arrival caused by previously undetected transit timing variations (TTVs), hinting at a potential exterior companion. Our median JWST timing precision is 10 seconds, revealing TTVs $>$20 minutes when combined with previous TESS and CHEOPS data, highlighting JWST's TTV measurement capabilities. The transmission spectrum of HD 15337 c is featureless and can best be described by a step function with an offset between the NRS1 and NRS2 detectors, likely caused by instrumental systematics. From thermochemical equilibrium retrievals we find that, to $>$3$σ$, the data can rule out atmospheres with metallicities $<$600 or $<$310 $\times$ solar, depending on the reduction, for opaque pressures greater than a few millibars. HD 15337 c joins other sub-Neptunes with similar masses, radii, and temperatures in possessing a featureless transmission spectrum indicative of high metallicity and/or high-altitude aerosols and adds support to recent studies showing that aerosol opacity reaches a maximum for planets with equilibrium temperatures of 500-700 K.

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JWST COMPASS: A NIRSpec G395H Transmission Spectrum of Radius Valley-Dweller TOI-260 b

We present a JWST/NIRSpec G395H transmission spectrum of TOI-260 b, a $T_\mathrm{eq}\sim 490$ K, $R_\mathrm{p} = 1.76\,R_\oplus$ planet. The transmission spectrum is derived by combining two transit observations, collected as part of the JWST COMPASS program. We achieved the same median transit depth precision of 37 ppm in both visits, and a median precision of 26 ppm when combining the spectroscopic light curves from the two visits. Implementing a 30-pixel-wide ($R\sim 200$) spectroscopic binning scheme, we find that the transmission spectrum is mostly featureless, with a possible feature around 3.17 $μ$m. We assess the significance of any features in the transmission spectrum with a suite of non-parametric models, which confirm the presence of a potential feature in the NRS1 bandpass and an offset between the NRS1 and NRS2 detectors. To investigate the atmospheric composition of TOI-260 b, we run a series of PLATON retrievals. We do not detect any clear molecular signatures, but the combined data from the two visits are sufficient to constrain the atmospheric metallicity to greater than $200\times$ solar, assuming no opaque deck $\lesssim2.5$ mbar. We also investigate causes of the potential feature near 3.17 $μ$m; while we find some compatible gaseous species and cannot fully discard an astrophysical origin, we suspect a systematics origin due to the variance in strength and position of the feature. Overall, this look at TOI-260 b adds to the small sample of radius-valley planets, which already seem to show a diversity in their atmospheric compositions. Determining the true nature of these enigmatic planets will require a larger telescope time investment.

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The Radius Cliff is a Waterfall: Explaining Sub-Neptune Exoplanets with Steam Worlds

The demographics of Kepler planets provide a key testbed for models of planet formation and evolution, particularly for explaining the radius valley separating super-Earths and sub-Neptunes. A primordial interpretation based on differences in bulk densities -- where rocky and water-rich planets form via migration pathways -- offers an alternative to atmospheric loss scenarios. Updated interior structure models of water worlds with adiabatic steam atmospheres reproduce the observed valley near $\sim2~R_\oplus$ more accurately. Furthermore, migration models from our Genesis library suggest that these formation pathways can also account for the distinct period distributions of super-Earths and sub-Neptunes, as well as the emergence of the hot Neptune desert. Motivated by this, we develop a Bayesian hierarchical mixture model for close-in Kepler planets ($P<100$ days), combining rocky planets and water worlds without H/He envelopes. The inferred mass distributions of rocky and water-rich planets peak at $\sim2.6~M_\oplus$ and $\sim7~M_\oplus$, respectively, with the water mass fraction of water worlds peaking at $\sim41\%$. Water worlds provide a good representation of the Kepler sub-Neptune population, with the radius cliff emerging as a ``waterfall" -- a sharp decline in their occurrence. However, our mass-radius analysis shows that water worlds alone cannot explain planets with $R \gtrsim 3~R_\oplus$, implying that at least $\sim20\%$ of sub-Neptunes in the sample are enriched in H/He gas.

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JWST COMPASS: Insights into the Systematic Noise Properties of NIRSpec/G395H From a Uniform Reanalysis of Seven Transmission Spectra

JWST has already observed near-infrared transmission spectra of over a dozen super-Earths and sub-Neptunes. While some observations have allowed astronomers to characterize sub-Neptunes in unprecedented detail, small feature amplitudes and poorly-understood systematics have led to ambiguous results for others. Using the first seven targets from the COMPASS program, which is currently surveying 12 small planet atmospheres using NIRSpec/G395H, we investigate these timeseries systematics. We implement a model that uses the principle components of the normalized pixel fluxes to account for variations in the shape and position of the spectral trace. We find that observations with a smaller number of groups-per-integration benefit most profoundly from the use of this model, and that systematics are particularly strong between 2.8 and 3.5 $μ$m. Despite these systematics, \texttt{pandexo} is a relatively accurate predictor of the precision of the spectra, with real error bars on average 5\% larger in NRS1 and 12\% larger in NRS2 than predicted. We compute new limits on metallicity and opaque pressure level for each target and compare these to previous results from the COMPASS program. Next, we co-add spectra from multiple targets to reduce the effective noise in the combined spectra in hopes of detecting transmission features in common between the targets, but this exercise does not yield compelling evidence any signals. We find that a handful of additional transits are sufficient to break the degeneracy between metallicity and aerosols for the majority of our targets, pointing towards the possibility of unraveling the mysteries of these worlds with future allocations of JWST time.

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JWST COMPASS: A NIRSpec G395H Transmission Spectrum of the Super-Earth GJ 357 b

We present JWST NIRSpec/G395H transmission spectroscopy observations of GJ 357 b, a warm ($T_{\mathrm{eq}} \approx 525$ K) super-Earth ($1.2\ \mathrm{R_{\oplus}} $, $1.84\ \mathrm{M_{\oplus}} $) orbiting a nearby M3-type star, with a median precision of 18 ppm and 27 ppm in NRS1 and NRS2, respectively. These precisions are obtained by binning the spectrum into 53 spectroscopic channels with a resolution of 60 pixels (around 0.02 $μ$m) each. Our analysis of the transmission spectrum reveals no detectable atmospheric spectral features. By comparing the observed spectrum with 1D forward models, we rule out atmospheres with mean molecular weights (MMW) lower than 8 g/mol to $3 σ$, as well as atmospheres with metallicities less than 300x solar. The lack of a low MMW primary atmosphere is consistent with a primordial H$_2$ rich atmosphere having escaped, given the planet's $\gtrsim5$ Gyr age, relatively low surface gravity (log g = 3.09), and its likely history of substantial incident extreme ultraviolet radiation. We conclude that GJ 357 b most likely possesses either a high-MMW secondary atmosphere, perhaps rich in oxidized gases like CO$_2$, or is a bare rock with no atmosphere. Upcoming scheduled JWST thermal emission observations could help distinguish between these scenarios by detecting signatures indicative of atmospheric heat redistribution or molecular absorption.

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Evolution of steam worlds: energetic aspects

Sub-Neptunes occupy an intriguing region of planetary mass-radius space, where theoretical models of interior structure predict that they could be water-rich, where water is in steam and supercritical state. Such planets are expected to evolve according to the same principles as canonical H$_2$-He rich planets, but models that assume a water-dominated atmosphere consistent with the interior have not been developed yet. Here, we present a state of the art structure and evolution model for water-rich sub-Neptunes. Our set-up combines an existing atmosphere model that controls the heat loss from the planet, and an interior model that acts as the reservoir of energy. We compute evolutionary tracks of planetary radius over time. We find that planets with pure water envelopes have smaller radii than predicted by previous models, and the change in radius is much slower (within $\sim$10\%). We also find that water in the deep interior is colder than previously suggested, and can transition from plasma state to superionic ice, which can have additional implications for their evolution. We provide a grid of evolutionary tracks that can be used to infer the bulk water content of sub-Neptunes. We compare the bulk water content inferred by this model and other models available in the literature, and find statistically significant differences between models when the uncertainty on measured mass and radius are both smaller than 10\%. This study shows the importance of pursuing efforts in the modeling of volatile-rich planets, and how to connect them to observations.

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JWST COMPASS: NIRSpec/G395H Transmission Observations of TOI-776 c, a 2 Rearth M Dwarf Planet

The atmospheres of planets between the size of Earth and Neptune at short orbital periods have been under intense scrutiny. Of the ~dozen planets in this regime with atmospheres studied so far, a few appear to have prominent molecular features while others appear relatively void of detectable atmospheres. Further work is therefore needed to understand the atmospheres of these planets, starting with observing a larger sample. To this end, we present the 3-5 micron transmission spectrum of TOI-776 c, a warm (Teq ~420 K), ~2 Rearth, ~7 Mearth planet orbiting an M1V star, measured with JWST NIRSpec/G395H. By combining two visits, we measure a median transit precision of ~18 ppm and ~32 ppm in the NRS1 and NRS2 detectors, respectively. We compare the transmission spectrum to both non-physical and physical models, and find no strong evidence for molecular features. For cloud-top pressures larger than 10^-3 bar, we rule out atmospheric metallicities less than 180-240x solar (depending on the reduction and modeling technique), which corresponds to a mean molecular weight of ~6-8 g/mol. However, we find simple atmosphere mixture models (H2O+H2/He or CO2+H2/He) give more pessimistic constraints, and caution that mean molecular weight inferences are model dependent. We compare TOI-776 c to the similar planet TOI-270 d, and discuss possible options for further constraining TOI-776 c's atmospheric composition. Overall, we suggest these TOI-776 c observations may represent a combination of planetary and stellar parameters that fall just below the threshold of detectable features in small planet spectra; finding this boundary is one of the main goals of the COMPASS program.

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JWST COMPASS: NIRSpec/G395H Transmission Observations of the Super-Earth TOI-776b

We present two transit observations of the $\sim$520K, 1.85R$_\oplus$, 4.0M$_\oplus$ super-Earth TOI-776b with JWST NIRSpec/G395H, resulting in a 2.8-5.2$μ$m transmission spectrum. Producing reductions using the ExoTiC-JEDI and Eureka! pipelines, we obtain a median transit depth precision of 34ppm for both visits and both reductions in spectroscopic channels 30 pixels wide ($\sim$0.02$μ$m). We find that our independent reductions produce consistent transmission spectra, however, each visit shows differing overall structure. For both reductions, a flat line is preferred for Visit 1 while a flat line with an offset between the NRS1 and NRS2 detectors is preferred for Visit 2; however, we are able to correct for this offset during our modeling analysis following methods outlined in previous literature. Using picaso forward models, we can rule out metallicities up to at least 100$\times$ solar with an opaque pressure of 10$^{-3}$ bar to $\geq$3$σ$ in all cases, however, the exact lower limit varies between the visits, with Visit 1 ruling out $\lesssim$100$\times$ solar while the lower limits for Visit 2 extend beyond $\sim$350$\times$ solar. Our results add to the growing list of super-Earth atmospheric constraints by JWST, which provide critical insight into the diversity and challenges of characterizing terrestrial planets.

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Volatile-rich Sub-Neptunes as Hydrothermal Worlds: The Case of K2-18 b

Temperate exoplanets between the sizes of Earth and Neptune, known as "sub-Neptunes", have emerged as intriguing targets for astrobiology. It is unknown whether these planets resemble Earth-like terrestrial worlds with a habitable surface, Neptune-like giant planets with deep atmospheres and no habitable surface, or something exotic in between. Recent JWST transmission spectroscopy observations of the canonical sub-Neptune, K2-18 b, revealed ~1% CH4, ~1% CO2, and a non-detection of CO in the atmosphere. While previous studies proposed that the observed atmospheric composition could help constrain the lower atmosphere's conditions and determine the interior structure of sub-Neptunes like K2-18 b, the possible interactions between the atmosphere and a hot, supercritical water ocean at its base remain unexplored. In this work, we investigate whether a global supercritical water ocean, resembling a planetary-scale hydrothermal system, can explain these observations on K2-18 b-like sub-Neptunes through equilibrium aqueous geochemical calculations. We find that the observed atmospheric CH4/CO2 ratio implies a minimum ocean temperature of ~710 K, whereas the corresponding CO/CO2 ratio allows ocean temperatures up to ~1070 K. These results indicate that a global supercritical water ocean on K2-18 b is plausible. While life cannot survive in such an ocean, this work represents the first step towards understanding how a global supercritical water ocean may influence observable atmospheric characteristics on volatile-rich sub-Neptunes. Future observations with better constrained CO and NH$_3$ mixing ratios could further help distinguish between possible interior compositions of K2-18 b.

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JWST COMPASS: The first near- to mid-infrared transmission spectrum of the hot super-Earth L 168-9 b

We present the first broadband near- to mid-infrared (3-12 microns) transmission spectrum of the highly-irradiated (T_eq = 981 K) M dwarf rocky planet L 168-9 b (TOI-134 b) observed with the NIRSpec and MIRI instruments aboard JWST. We measure the near-infrared transit depths to a combined median precision of 20 ppm across the three visits in 54 spectroscopic channels with uniform widths of 60 pixels (~0.2 microns wide; R~100), and the mid-infrared transit depths to 61 ppm median precision in 48 wavelength bins (~0.15 microns wide; R~50). We compare the transmission spectrum of L 168-9 b to a grid of 1D thermochemical equilibrium forward models, and rule out atmospheric metallicities of less than 100x solar (mean molecular weights <4 g mol$^{-1}$) to 3-sigma confidence assuming high surface pressure (>1 bar), cloudless atmospheres. Based on photoevaporation models for L 168-9 b with initial atmospheric mass fractions ranging from 2-100%, we find that this planet could not have retained a primordial H/He atmosphere beyond the first 200 Myr of its lifetime. Follow-up MIRI eclipse observations at 15 microns could make it possible to confidently identify a CO2-dominated atmosphere on this planet if one exists.

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JWST COMPASS: The 3-5 Micron Transmission Spectrum of the Super-Earth L 98-59 c

We present a JWST NIRSpec transmission spectrum of the super-Earth exoplanet L 98-59 c. This small (R$_p=1.385\pm0.085$R$_\oplus$, M$_p=2.22\pm0.26$R$_\oplus$), warm (T$_\textrm{eq}=553$K) planet resides in a multi-planet system around a nearby, bright (J = 7.933) M3V star. We find that the transmission spectrum of L 98-59 c is featureless at the precision of our data. We achieve precisions of 22ppm in NIRSpec G395H's NRS1 detector and 36ppm in the NRS2 detector at a resolution R$\sim$200 (30 pixel wide bins). At this level of precision, we are able rule out primordial H$_2$-He atmospheres across a range of cloud pressure levels up to at least $\sim$0.1mbar. By comparison to atmospheric forward models, we also rule out atmospheric metallicities below $\sim$300$\times$ solar at 3$σ$ (or equivalently, atmospheric mean molecular weights below $\sim$10~g/mol). We also rule out pure methane atmospheres. The remaining scenarios that are compatible with our data include a planet with no atmosphere at all, or higher mean-molecular weight atmospheres, such as CO$_2$- or H$_2$O-rich atmospheres. This study adds to a growing body of evidence suggesting that planets $\lesssim1.5$R$_\oplus$ lack extended atmospheres.

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Insights on the Formation Conditions of Uranus and Neptune from their Deep Elemental Compositions

This study, placed in the context of the preparation for the Uranus Orbiter Probe mission, aims to predict the bulk volatile compositions of Uranus and Neptune. Using a protoplanetary disk model, it examines the evolution of trace species through vapor and solid transport as dust and pebbles. Due to the high carbon abundance found in their envelopes, the two planets are postulated to have formed at the carbon monoxide iceline within the protosolar nebula. The time evolution of the abundances of the major volatile species at the location of the CO iceline is then calculated to derive the abundance ratios of the corresponding key elements, including the heavy noble gases, in the feeding zones of Uranus and Neptune. Supersolar metallicity in their envelopes likely results from accreting solids in these zones. Two types of solids are considered: pure condensates (Case 1) and a mixture of pure condensates and clathrates (Case 2). The model, calibrated to observed carbon enrichments, predicts deep compositions. In Case 1, argon is deeply depleted, while nitrogen, oxygen, krypton, phosphorus, sulfur, and xenon are significantly enriched relative to their protosolar abundances in the two planets. Case 2 predicts significant enrichments for all species, including argon, relative to their protosolar abundances. Consequently, Case 1 predicts near-zero Ar/Kr or Ar/Xe ratios, while Case 2 suggests these ratios are 0.1 and 0.5-1 times their protosolar ratios. Both cases predict a bulk sulfur-to-nitrogen ratio consistent with atmospheric measurements.

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Recipes for forming a carbon-rich giant planet

The exploration of carbon-to-oxygen ratios has yielded intriguing insights into the composition of close-in giant exoplanets, giving rise to a distinct classification: carbon-rich planets, characterized by a carbon-to-oxygen ratio $\ge$ 1 in their atmospheres, as opposed to giant planets exhibiting carbon-to-oxygen ratios close to the protosolar value. In contrast, despite numerous space missions dispatched to the outer solar system and the proximity of Jupiter, Saturn, Uranus, and Neptune, our understanding of the carbon-to-oxygen ratio in these giants remains notably deficient. Determining this ratio is crucial as it serves as a marker linking a planet's volatile composition directly to its formation region within the disk. This article provides an overview of the current understanding of the carbon-to-oxygen ratio in the four gas giants of our solar system and explores why there is yet no definitive dismissal of the possibility that Jupiter, Saturn, Uranus, or Neptune could be considered carbon-rich planets. Additionally, we delve into the three primary formation scenarios proposed in existing literature to account for a bulk carbon-to-oxygen ratio $\ge$ 1 in a giant planet. A significant challenge lies in accurately inferring the bulk carbon-to-oxygen ratio of our solar system's gas giants. Retrieval methods involve integrating in situ measurements from entry probes equipped with mass spectrometers and remote sensing observations conducted at microwave wavelengths by orbiters. However, these methods fall short of fully discerning the deep carbon-to-oxygen abundance in the gas giants due to their limited probing depth, typically within the 10-100 bar range.

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JWST COMPASS: A NIRSpec/G395H Transmission Spectrum of the Sub-Neptune TOI-836c

Planets between the sizes of Earth and Neptune are the most common in the Galaxy, bridging the gap between the terrestrial and giant planets in our Solar System. Now that we are firmly in the era of JWST, we can begin to measure, in more detail, the atmospheres of these ubiquitous planets to better understand their evolutionary trajectories. The two planets in the TOI-836 system are ideal candidates for such a study, as they fall on either side of the radius valley, allowing for direct comparisons of the present-day atmospheres of planets that formed in the same environment but had different ultimate end states. We present results from the JWST NIRSpec G395H transit observation of the larger and outer of the planets in this system, TOI-836c (2.587 R$_{\oplus}$, 9.6 M$_{\oplus}$, T$_{\rm eq}$$\sim$665 K). While we measure average 30-pixel binned precisions of $\sim$24ppm for NRS1 and $\sim$43ppm for NRS2 per spectral bin, we do find residual correlated noise in the data, which we attempt to correct using the JWST Engineering Database. We find a featureless transmission spectrum for this sub-Neptune planet, and are able to rule out atmospheric metallicities $<$175$\times$ Solar in the absence of aerosols at $\lesssim$1 millibar. We leverage microphysical models to determine that aerosols at such low pressures are physically plausible. The results presented herein represent the first observation from the COMPASS (Compositions of Mini-Planet Atmospheres for Statistical Study) JWST program, which also includes TOI-836b and will ultimately compare the presence and compositions of atmospheres for 12 super-Earths/sub-Neptunes.

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JWST COMPASS: NIRSpec/G395H Transmission Observations of the Super-Earth TOI-836b

We present two transit observations of the ~870K, 1.7R$_E$ super-Earth TOI-836b with JWST NIRSpec/G395H, resulting in a 2.8-5.2$μ$m transmission spectrum. Using two different reduction pipelines, we obtain a median transit depth precision of 34ppm for Visit 1 and 36ppm for Visit 2, leading to a combined precision of 25ppm in spectroscopic channels 30 pixels wide (~0.02$μ$m). We find that the transmission spectrum from both visits is well fit by a zero-sloped line by fitting zero-sloped and sloped lines, as well as step functions to our data. Combining both visits, we are able to rule out atmospheres with metallicities <250xSolar for an opaque pressure level of 0.1 bar, corresponding to mean molecular weights to <6gmol$^{-1}$. We therefore conclude that TOI-836b does not have an H$_2$-dominated atmosphere, in possible contrast with its larger, exterior sibling planet, TOI-836c. We recommend that future proposals to observe small planets exercise caution when requiring specific numbers of transits to rule out physical scenarios, particularly for high metallicities and planets around bright host stars, as PandExo predictions appear to be more optimistic than that suggested by the gains from additional transits implied by our data.

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TOI-733 b: a planet in the small-planet radius valley orbiting a Sun-like star

We report the discovery of a hot ($T_{\rm eq}$ $\approx$ 1055 K) planet in the small planet radius valley transiting the Sun-like star TOI-733, as part of the KESPRINT follow-up program of TESS planets carried out with the HARPS spectrograph. TESS photometry from sectors 9 and 36 yields an orbital period of $P_{\rm orb}$ = $4.884765 _{ - 2.4e-5 } ^ { + 1.9e-5 }$ days and a radius of $R_{\mathrm{p}}$ = $1.992 _{ - 0.090 } ^ { + 0.085 }$ $R_{\oplus}$. Multi-dimensional Gaussian process modelling of the radial velocity measurements from HARPS and activity indicators, gives a semi-amplitude of $K$ = $2.23 \pm 0.26 $ m s$^{-1}$, translating into a planet mass of $M_{\mathrm{p}}$ = $5.72 _{ - 0.68 } ^ { + 0.70 }$ $M_{\oplus}$. These parameters imply that the planet is of moderate density ($ρ_\mathrm{p}$ = $3.98 _{ - 0.66 } ^ { + 0.77 }$ g cm$^{-3}$) and place it in the transition region between rocky and volatile-rich planets with H/He-dominated envelopes on the mass-radius diagram. Combining these with stellar parameters and abundances, we calculate planet interior and atmosphere models, which in turn suggest that TOI-733 b has a volatile-enriched, most likely secondary outer envelope, and may represent a highly irradiated ocean world - one of only a few such planets around G-type stars that are well-characterised.

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Evolution of the reservoirs of volatiles in the protosolar nebula

The supersolar abundances of volatiles observed in giant planets suggest that a compositional gradient was present at the time of their formation in the protosolar nebula. To explain this gradient, several studies have investigated the radial transport of trace species and the effect of icelines on the abundance profiles of solids and vapors formed in the disk. However, these models only consider the presence of solids in the forms of pure condensates or amorphous ice during the evolution of the protosolar nebula. They usually neglect the possible crystallization and destabilization of clathrates, along with the resulting interplay between the abundance of water and those of these crystalline forms. This study is aimed at pushing this kind of investigation further by considering all possible solid phases together in the protosolar nebula: pure condensates, amorphous ice, and clathrates. To this end, we used a one-dimensional (1D) protoplanetary disk model coupled with modules describing the evolution of trace species in the vapor phase, as well as the dynamics of dust and pebbles. Eleven key species are considered here, including H$_2$O, CO, CO$_2$, CH$_4$, H$_2$S, N$_2$, NH$_3$, Ar, Kr, Xe, and PH$_3$. Two sets of initial conditions are explored for the protosolar nebula. In a first scenario, the disk is initially filled with icy grains in the forms of pure condensates. In this case, we show that clathrates can crystallize and form enrichment peaks up to about ten times the initial abundances at their crystallization lines. In a second scenario, the volatiles were delivered to the protosolar nebula in the forms of amorphous grains. In this case, the presence of clathrates is not possible because there is no available crystalline water ice in their formation region. Enrichment peaks of pure condensates also form beyond the snowline up to about seven times the initial abundances.

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