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Ashley T. Barnes

Publications and source records attributed to Ashley T. Barnes.

At least 19 recordsLinked to original sources

ACES VIII: A Survey of Compact, High-Velocity Features Observed in CS(2-1)

The extreme kinematics of the Milky Way's Central Molecular Zone (CMZ) are influenced by processes such as dynamical shearing, cloud collisions, and stellar feedback. These events are visible in molecular data as vertically spiked features in position-velocity (PV) diagrams referred to as high velocity dispersion compact clouds (HVCCs). Using ALMA CMZ Exploration Survey (ACES) CS (2-1) molecular data, we identify a total of 235 HVCC candidates, 163 of which are visually identified, and an additional 72 identified via automated dendrogram methods. For each HVCC we catalog and report the physical and kinematic properties, explore line ratios of the cold dense gas tracer \HNCO with C-shock tracers, classify the morphology of their PV diagrams, and view their position-position-velocity distribution. The sample includes structures which are compact (d<5 pc) and have large velocity extents (20 km/s $<Δ\mathrm{V} <$ 140 km/s), with most structures showing thin, `spiked' PV morphologies. We highlight areas of high ratios between HNCO and C-shock tracers along the edge of known orbital streams, implying a buildup of bar lane gas accreting onto the CMZ. We also find a collection of HVCCs overlapping with the 50 km/s cloud and known circumnuclear disk features. This catalog will be used for future investigation of nuclear inflow and determining dominant mechanisms disrupting average CMZ gas flows.

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ACES VII. Compact Continuum Source Catalog of the Central Molecular Zone

The Central Molecular Zone (CMZ) resides in the inner few hundred parsecs of our Galaxy, and despite being the largest reservoir of dense molecular gas in the Milky Way, it has a relatively low present-day star formation rate (SFR) of $\sim0.08~M_{\odot}~\text{yr}^{-1}$. Continuum and spectral line observations from the Atacama Large Millimeter/submillimeter Array (ALMA) CMZ Exploration Survey (ACES) provide the first full-coverage, high-resolution map of the inner 200 parsecs of the CMZ at 3 mm. In this paper we present the ACES catalog of compact continuum sources, the most complete catalog of potential sites of star formation in the CMZ to date. Using an automated dendrogram-based source extraction procedure in combination with a by-eye morphological classification scheme, we produce a `full' catalog of 1735 detections in total. Additionally, we use spectral index measurements to generate a `filtered' catalog of 567 sources with minimal contamination from non-thermal filaments and extended free-free emission. We find that 359 ($\sim63\%$) of the filtered catalog sources are located at column densities $< 10^{23}$ cm$^{-2}$, outside of the densest molecular cloud regions, 195 of which have not been identified in previous surveys. After cross-referencing with various catalogs generated from data at different wavelengths, we consider it likely that many of these newly discovered detections are produced by pre/protostellar sources or compact HII regions.

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Electron temperature and emission measure of HII regions in the central molecular zone (CMZ) from H40 αrecombination line and continuum emissions by ALMA CMZ Exploration Survey - ACES -

Star formation activity in the Central Molecular Zone (CMZ) directly manifests itself as radio continuum free-free emission (Bremsstrahlung) and radio recombination line emission from HII regions surrounding newly formed massive stars. We derive the overall distribution of the HII regions and their fundamental properties: electron temperature ($\Te$) and emission measure ($EM$), and hence electron density in the form of two dimensional distribution maps over the CMZ by analyzing the ACES (ALMA CMZ Exploration Survey) \h40 (99.02 GHz) recombination line and 99.6 GHz continuum emission data with synthesized beam widths of $2''.45$ (0.097 pc at 8.2 kpc) and $2''.14$, respectively. We apply the 'TeEM' method ($\Te$--$EM$ mapping), which creates $\Te$ and $EM$ maps from input 2D maps of the continuum and integrated line intensity. The analysis covers the entire ACES field from $l\sim -0^\circ.6$ to $+0^\circ.8$ and from $b\sim -0^\circ.2$ to $+0^\circ.1$. The area analyzed is complete and includes previously known HII regions such as Sgr B2, Sgr B1, the Sickle, the Pistol, thermal filaments (Bridges), Sgr A HII regions, the Minispiral, and many other known HII regions. Sgr C is not included in the analysis due to the insufficient signal-to-noise ratio in the recombination line map. The mean electron temperature over the CMZ is determined to be $\Tcmz= 5872 \pm 78 ~{\rm (SE)} ~\pm 3682~{\rm (SD)}$ K (SE:standard error of the mean, SD: pixel-to-pixel standard deviation). Some HII regions, such as Sgr B2 Main and the Minispiral, exhibit large scatter and an internal $\Te$ gradient of several thousand K per parsec. The $EM$ distribution is more diverse, varying by orders of magnitude from $\sim 10^5$ to $\sim 3\times 10^8$ \emunit within the CMZ, as well as within individual HII regions.

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ALMA Central molecular zone Exploration Survey (ACES) VI: ALMA Large Program Reveals a Highly Filamentary Central Molecular Zone

The Central Molecular Zone (CMZ) of the Milky Way is the way station that primarily controls how much gas flows from the disk of the Galaxy towards the central nucleus. While this region is well documented to have extreme gas properties that clearly distinguish it from the rest of the Galaxy, the properties of the bulk molecular gas at high angular resolution are relatively unexplored. Band 3 data from the ALMA (Atacama Large Millimeter/Submillimeter Array) large program ACES (ALMA CMZ Exploration Survey) reveal the highly filamentary nature of CMZ molecular gas at high resolution (3" or 0.1pc) across the entire CMZ. Visual inspection of these data suggests that there are at least two general classes of elongated structures, which we identify as: i) large-scale (10 pc) filamentary structures (LFs) and ii) a ubiquitous population of small-scale (about 1 pc) filamentary structures (SFs). We present detailed morphological and kinematic properties towards three structures in each category, as well as their association with magnetic fields and the correlation of HNCO 4(0,4)-3(0,3) with other molecular species. Our investigation reveals that these structures are largely coherent in position-position-velocity space. The alignment with the magnetic field structure is mixed, with some parallel, some perpendicular, and some intermediate alignments. We find that LFs likely trace pieces of contiguous CMZ orbital structures and are a manifestation of global CMZ dynamics. The second class, SFs, are pervasive and may be the result of complicated turbulence and shearing dynamics in the CMZ gas flows, as seen in numerical simulations.

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Simulations of gas inflow in the Milky Way I. Stellar-Feedback-Regulated Transport from the Central Molecular Zone to the Circumnuclear disk

We perform hydrodynamical simulations with radially varying resolution to study the effects of stellar feedback on the radial inflow of gas from the Central Molecular Zone (CMZ, $R\sim200$ pc) to the Circumnuclear Disk (CND, $R\sim5$ pc) of the Milky Way. The simulations include a realistic Milky Way barred gravitational potential, a cooling function coupled to a non-equilibrium chemical network, gas self-gravity, star formation, supernova feedback, and radiation feedback from massive stars computed via on-the-fly radiative transfer. Our main findings are as follows: 1) Stellar feedback drives a radial inflow that decreases monotonically with decreasing Galactocentric radius. The time-averaged inflow rate in our fiducial SNRad simulation, which includes both supernova and radiation feedback, declines from $\langle \dot{M} \rangle\sim5\times10^{-3}$ Msun/yr at $R\sim100$ pc, to $\langle\dot{M}\rangle\sim10^{-4}$ Msun/yr at $R\sim10$ pc, to $\langle\dot{M}\rangle\sim10^{-6}$ Msun/yr at $R\sim1$ pc. 2) The total inflow rate can be broken down into two components driven by two distinct mechanisms. First, feedback-driven turbulence redistributes the angular momentum of gas clouds, producing a smooth (secular) transport of mass inward, similar to a Shakura-Sunyaev viscous accretion disk. This component contributes inflow rates that vary from $\dot{M}\sim5\times10^{-4}$ Msun/yr at $R\sim100$ pc to $\dot{M}\sim10^{-7}$ Msun/yr at $R\sim1$ pc. Second, episodic inflow events can transiently increase the inflow rate by several orders of magnitude, reaching $\dot{M}\sim10^{-3}$ Msun/yr over timescales of $Δt\sim3$-$5$ Myr at $R=10$ pc. 3) The stellar feedback model significantly affects the episodic inflow but has little impact on the smooth component. Simulations including radiation feedback produce substantially more episodic events than those with supernova feedback alone.

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From gas to stars along the spiral wave: CO, HCN, and star formation variations across the spiral arms in NGC 4321 and M51

Molecular clouds form stars from the interstellar medium via gravitational collapse, following a sequence from low-density gas to high-density cores and eventually the formation of stars. In classical density wave theory, gas clouds orbiting the galaxy experience gas compression and triggered star formation, while encountering the gravitational well of spiral arms. We aim to trace these different phases of the molecular cloud life cycle via tracers of molecular gas (CO), dense molecular gas (HCN), and star formation (H$α$, 24 $μ$m) within the spiral arms of two grand-design spiral galaxies: NGC 4321 and M51 (NGC 5194). In the spiral arms of these galaxies, we investigate the relation between molecular gas, dense gas, and star formation (CO-HCN-SFR) at matched physical resolutions of 270 pc and 125 pc in NGC 4321 and M51, respectively. We employed spiral arm masks for these galaxies and investigate trends of HCN/CO and SFR/HCN (SFR/CO), which serve as proxies for the dense gas fraction and dense (molecular) gas star formation efficiency, perpendicular to the spiral arm spines. We find that HCN/CO, SFR/CO, and SFR/HCN increase from the upstream towards the downstream side of both spiral arms of NGC 4321, while their trends are less prominent in M51. Our results indicate that large-scale galactic dynamics (e.g. density waves) can induce a sequence of gas density and star formation-to-gas density variations perpendicular to the spiral arms. This sequence contributes to the increased scatter seen among spectroscopic ratios such as HCN/CO and SFR/HCN at sub-kiloparsec scales.

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JWST's first view of the most vigorously star-forming cloud in the Galactic center -- Sagittarius B2

We report JWST NIRCAM and MIRI observations of Sgr B2, one of the most active sites of star formation in the Galaxy. These observations, using 14 filters spanning 1.5 to 25 microns, have revealed a multilayered and highly structured cloud that contains both a revealed, low-extinction and hidden, high-extinction population of massive stars. JWST has detected new candidate HII regions around massive stars previously missed by radio telescopes. MIRI has detected radiation escaping from the forming massive cluster Sgr B2 N along its outflow cavities, demonstrating that infrared radiation finds geometric escape routes even in the densest, most heavily embedded regions in the universe. JWST further highlights the gas asymmetry in the cloud, showing a sharp, straight cutoff along the eastern cloud edge. Despite the great sensitivity of these observations, no extended population of YSOs has been detected, placing a limit on their minimum extinction; this result hints that star formation has only just begun in the cloud. Together, these results suggest that, despite already holding the crown for one of the most actively star-forming clouds, we have underestimated the total star formation in Sgr B2. JWST unveils previously hidden massive stars and ionized structures, offering a clearest-yet view of how stars form under some of the most extreme Galactic conditions.

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The PHANGS-Hα survey. Ground-based narrow-band imaging of nearby star-forming galaxies

We present PHANGS-Hα, a narrow-band imaging survey that maps Hα emission over a sample of 65 nearby massive star-forming galaxies. The data were obtained using the MPG-ESO 2.2-meter telescope at La Silla and the du Pont 2.5-meter telescope at Las Campanas Observatory, in the framework of the multi-wavelength cloud-scale (50-100 pc) resolution mapping of molecular gas and star formation conducted by the Physics at High Angular resolution in Nearby GalaxieS (PHANGS) collaboration. PHANGS-Hα complements the already published PHANGS-ALMA, PHANGS-MUSE, PHANGS-HST, and PHANGS-JWST surveys, providing an anchor point for the photometric and astrometric calibration of these datasets, as well as samples of H ii regions, and star formation rate maps for the bulk of the PHANGS sample. We present observations, data processing, and calibration of the PHANGS-Hα dataset, as well as the procedures used to derive emission-line fluxes from narrow-band imaging. A subset of galaxies with available spectroscopic Ha mapping from the PHANGS-MUSE survey allows for a detailed comparison with the narrow-band photometry presented here. This informs a series of best practices for the processing of narrow-band Hα imaging that we apply to the full dataset.

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The Hidden Life of Stars: Embedded Beginnings to AGB Endings in the PHANGS-JWST Sample. I. Catalog of Mid-IR Sources

We present a multiwavelength catalog of mid-infrared-selected compact sources in 19 nearby galaxies, combining JWST NIRCam/MIRI, HST UV-optical broadband, H$α$ narrow-band, and ALMA CO observations. We detect 24,945 compact sources at 21 $μ$m and 55,581 at 10 $μ$m. Artificial star tests show 50% completeness limits of $\sim$5 $μ$Jy for the 10 $μ$m catalog, and $\sim$24 $μ$Jy for the 21 $μ$m catalog. We find that 21 $μ$m compact sources contribute $\sim$20% of the total galaxy emission in that band, but only contribute $5%$ at 10 $μ$m. We classify sources using stellar evolution and population synthesis models combined with empirical classifications derived from the literature. Our classifications include H$α$-bright and dust-embedded optically faint clusters, red supergiants (RSGs), oxygen-rich and carbon-rich AGB stars, and a range of rarer stellar types. In sampling a broad range of star forming environments with a uniform, well-characterized selection, this catalog enables enables analyses of infrared-bright stellar populations. We find that H$α$-faint sources account for only 10% of dusty (likely young) clusters, implying that the infrared-bright, optically-faint phase of cluster evolution is short compared to the H$α$-bright stage. The luminosity functions of 10 and 21 $μ$m sources follow power-law distributions, with the 21 $μ$m slope ($-1.7 \pm 0.1$) similar to that of giant molecular cloud mass functions and ultraviolet bright star-forming complexes, while the 10 $μ$m slope ($-2.0 \pm 0.1$) is closer to that of young stellar clusters.

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ALMA Central molecular zone Exploration Survey (ACES) V: CS(2-1), SO(2_3-1_2), CH3CHO(5_1,4-4_1,3), HC3N(11-10), and H40a lines data

We present data from the ALMA Central Molecular Zone Exploration Survey (ACES) Large Program, which provides broad spectral-line and 3 mm continuum coverage of the Central Molecular Zone (CMZ) at a spatial resolution of 0.1 pc. The survey delivers homogeneous, wide-field mosaics that enable direct comparisons of the physical and chemical conditions across diverse environments in the Galactic center. In this data release paper, we present the CS(2-1), SO(2_3-1_2), CH3CHO(5_1,4-4_1,3), HC3N(11-10), and H40a lines observed simultaneously within two broad spectral windows. These lines reveal pronounced spatial and chemical variations across the CMZ, tracing distinct components of molecular gas, shock-affected regions, and ionized structures. The high angular resolution and multi-line capability of the ACES dataset make it a powerful resource for future studies of gas dynamics, star formation activity, and the physical connection between the CMZ and Sgr A*.

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Cloud-scale gas properties, depletion times, and star formation efficiency per free-fall time in PHANGS--ALMA

We compare measurements of star formation efficiency to cloud-scale gas properties across PHANGS-ALMA. Dividing 67 galaxies into 1.5 kpc scale regions, we calculate the molecular gas depletion time, tau_dep= Sigma_mol/Sigma_SFR, and the star formation efficiency per free-fall time, eff=tau_ff/tau_dep, for each region. Then we test how tau_dep and eff vary as functions of the regional mass-weighted mean molecular gas properties on cloud scales (60-150pc): gas surface density, , velocity dispersion, , virial parameter, , and gravitational free-fall time, . and tau_dep correlate positively, consistent with the expectation that gas density plays a key role in setting the rate of star formation. Our fiducial measurements suggest tau_dep \propto ^0.5 and eff \approx 0.39%, though the exact numbers depend on the adopted fitting methods. We also observe anti-correlations between tau_dep and and between tau_dep^mol and . All three correlations may reflect the same underlying link between density and star formation efficiency combined with systematic variations in the degree to which self-gravity binds molecular gas in galaxies. We highlight the tau_dep- relation because of the lower degree of correlation between the axes. Contrary to theoretical expectations, we observe an anti-correlation between tau_dep^mol and and no significant correlation between eff and . Our results depend sensitively on the adopted CO-to-H2 conversion factor, with corrections for excitation and emissivity effects in inner galaxies playing an important role. We emphasize that our simple methodology and clean selection allow easy comparison to numerical simulations and highlight this as a logical next direction.

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Reconciling 3D Models for the Central 10 parsecs of the Milky Way

The construction of an accurate 3D model of the Milky Way center is necessary to understand inflow processes that drive its overall evolution, and to compare our Galactic nucleus to other galaxies' nuclei. A main point of contention is the line-of-sight location of sources observed toward the central 10 pc of the Galaxy, including recent star formation (the Sgr A East supernova remnant and Sgr A HII regions) and copious gas (the 50 and 20 km/s molecular clouds, the Circumnuclear Disk, and the Sgr A West ionized "minispiral" that encircles the central supermassive black hole, Sgr A*). Some models place all of these structures within a radius of 5 pc from Sgr A*, while others place the 20 and 50 km/s clouds at a distance of at least 30 - 50 pc away from Sgr A* along the line of sight. We present new radio and millimeter observations of the molecular gas toward the central ~10 pc, from which we have constructed an alternative 3D model that is consistent with both prior radio observations and orbital gas kinematics. Our model places the 20 km/s cloud, 50 km/s cloud, and Sgr A East more than 10 pc in front of Sgr A*. While this model does not conclusively rule out a connection between the 50 and 20 km/s clouds and the circumnuclear disk, we argue that prior evidence for these connections is tenuous, especially given the complex spatial and kinematic overlap of structures along the line of sight.

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Stellar associations powering HII regions $\unicode{x2013}$ II. Escape fraction of ionizing photons

Newly formed stars have a profound impact on their environment by depositing energy and momentum into the surrounding gas. However, only a fraction of the stellar feedback is retained in the cloud and observational constraints are needed to further our understanding of this process. In a sample of 19 nearby galaxies, we match HII regions from PHANGS$\unicode{x2013}$MUSE to their ionizing stellar source from PHANGS$\unicode{x2013}$HST and measure the percentage of ionizing radiation that is leaking into the surrounding diffuse ionized gas (DIG). Based on a catalogue, where each HII region is powered by a single young and massive stellar association, we measure a photon escape fraction of $f_\mathrm{esc}=82^{+12}_{-24}$ per cent. Comparable results are obtained when different procedures are used to match the ionized gas to its source. All samples we study contain a substantial fraction of objects (up to 20 per cent), where the stellar source is not sufficient to produce the H$α$ flux observed from the nebula. Many of them are probably related to uncertain age estimates, but we also find numerous regions, where a significant fraction of the ionizing photon budget is contributed by stars that reside outside the boundaries of the HII region. This motivates the use of an alternative galaxy-wide approach, in which we include all HII regions and stellar sources, not just the ones that show a clear overlap. When summing up the ionization budget over entire galaxies, we measure slightly lower, but consistent values.

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ALMA Central Molecular Zone Exploration Survey (ACES)-IV. Data of the two intermediate-width spectral windows

We release the intermediate-width spectral window data from the ALMA Central Molecular Zone Exploration Survey (ACES) Large Program, which covers SiO(2-1), SO(2_2-1_1), H13CO+(1-0), H13CN(1-0), HN13C(1-0), and HC15N (1-0), among other molecular line transitions, with an angular resolution of ~2 arcsec and a velocity resolution of 1.7 km s-1 . The full cubes of the two spectral windows as well as the key data products will be available to the community. We also present the integrated brightness, peak brightness, centroid velocity, and Galactic longitude-velocity maps of the six lines. We briefly discuss morphological correlations between the continuum and the molecular line emission, and brightness ratios between pairs of isotopologue or isotopomer lines. We highlight features and trends in the data that will be followed up in upcoming ACES science papers.

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ALMA Central Molecular Zone Exploration Survey (ACES) II: 3mm continuum images

The ALMA Central Molecular Zone Exploration Survey, ACES, has mapped $\gtrsim1000$ square arcminutes at 3 mm toward the center of our Galaxy. ACES provides the first large-scale, high-resolution ($\sim2.5$") view of the central $\sim200$ parsecs of the Milky Way. In this work, we describe the continuum data processing and present the continuum data products. In the combined mosaic of 45 individual ALMA mosaics, the typical RMS noise achieved is $\sim0.1$ mJy per $\sim2.5$" beam, though there is a tail of substantially higher noise toward regions with bright continuum structure, especially around Sgr A* and Sgr B2. In-band spectral indices are measurable for a small fraction of the brightest and most compact sources, enabling distinction between dust-dominated and free-free- or synchrotron-dominated sources. To recover emission on large angular scales, we present the GBT MUSTANG-2 Three millimeter Extended Nucleus Survey (TENS), a new 10"resolution survey of the CMZ, which we combine with the ACES image by feathering. To demonstrate the quality and reliability of the ACES data, we compare to previously-published ALMA data obtained with higher resolution and sensitivity, finding overall good agreement with past results, but some disagreement toward the brightest sources.

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ALMA Central molecular zone Exploration Survey (ACES) III: Molecular line data reduction and HNCO and HCO$^{+}$ data

The ALMA Central molecular zone Exploration Survey (ACES) large program has observed the inner ~ 200 pc of the Milky Way at 3 mm (Band 3) using ALMA's 12m, 7m, and Total Power arrays. With an angular resolution of ~ 2", ACES provides a contiguous, multi-scale view of the Central Molecular Zone (CMZ) via the dust continuum and a suite of molecular lines. We present an overview of the molecular line data processing for ACES and describe the first data release. We showcase the HNCO (4-3) and HCO$^{+}$ (1-0) data, which were targeted at high spectral resolution (0.2 km s$^{-1}$) to trace the kinematics of the molecular gas in the CMZ. The HNCO and HCO$^{+}$ maps are compared with previous single-dish CMZ surveys and discrete ALMA observations of CMZ clouds to demonstrate the quality of the data. We highlight the ubiquity of parsec-scale, linear absorption features traced by HCO$^{+}$. Their origin is unknown, and ACES provides the first opportunity to study these enigmatic features throughout the CMZ. We release the HNCO and HCO$^{+}$ cubes for all 45 ACES fields, along with the full cube mosaics which combine all fields into a contiguous mosaic of the CMZ. We additionally provide advanced products of these full mosaics, including integrated and peak intensity, noise, and position-velocity maps. These products provide substantial legacy value for the community, offering an unparalleled view of the physical and kinematic structure of the dense gas in the CMZ.

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ALMA Central Molecular Zone Exploration Survey (ACES) I: Overview

The mass flows and energy cycles within the inner regions of galaxies exert a powerful influence on the evolution of the galaxy population. The centre of the Milky Way is the only galactic nucleus for which it is possible to resolve the physical mechanisms that drive these cycles, namely star formation and feedback, while also tracing global (>100 pc) processes which determine where and when star formation and feedback occur. We present an overview of ACES, the 'Atacama Large Millimeter/submillimeter Array (ALMA) CMZ Exploration Survey', a ~1.5" angular resolution, 0.2-3 km/s spectral resolution ALMA Band 3 (85-102 GHz), survey of the 'Central Molecular Zone' (CMZ) -- the inner-100 pc of the Galaxy (l = 359.4 deg to 0.8 deg). ACES spectral setup is tuned to observe optimal tracers of the physical, chemical, and kinematic conditions in over 70 spectral features (e.g. HCO+, HNCO, SiO, H40alpha, complex molecules) of the gas in the CMZ, to derive the properties of all potentially star-forming Galactic Centre gas, from global scales (100 pc) to dense ~0.05 pc structures that are expected to host individual star-forming cores, down to sub-sonic (<0.4 km/s) velocity resolution. In this overview paper, we provide the scientific justification for the ACES survey, explain the choice of observational setup, and describe the data legacy products. Finally, we show some of the initial ACES data which highlight the power of ACES' combination of high angular resolution, unprecedented spatial dynamic range, sensitivity, spectral resolution and spectral bandwidth as an illustration of how ACES aims to understand how global processes set the location, intensity, and timescales for star formation and feedback in the CMZ.

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Localized Deviations from the CO-PAH Relation in PHANGS-JWST Galaxies: Faint PAH Emission or Elevated CO Emissivity?

Polycyclic aromatic hydrocarbon (PAH) emission is widely used to trace the distribution of molecular gas in the interstellar medium, exhibiting a tight correlation with CO(2-1) emission across nearby galaxies. Using PHANGS-JWST and PHANGS-ALMA data, we identify localized regions where this correlation fails, with CO flux exceeding that predicted from 7.7$μ$m PAH emission by more than an order of magnitude. These outlier regions are found in 20 out of 70 galaxies and are located in galaxy centers and bars, without signs of massive star formation. We explore two scenarios to explain the elevated CO-to-PAH ratios, which can either be due to suppressed PAH emission or enhanced CO emissivity. We examine PAH emission in other bands (3.3$μ$m and 11.3$μ$m) and the dust continuum dominated bands (10$μ$m and 21$μ$m), finding consistently high CO-to-PAH (or CO-to-dust continuum) emission ratios, suggesting that 7.7$μ$m PAH emission is not particularly suppressed. In some outlier regions, PAH sizes and spectral energy distribution of the radiation differ slightly from nearby control regions with normal CO-to-PAH ratios, though without a consistent trend. We find that the outlier regions show higher CO velocity dispersions ($Δv_{\mathrm{CO}}$). This increase in $Δv_{\mathrm{CO}}$ lowers CO optical depth and raises its emissivity for a given gas mass. Our results favor a scenario where shear along the bar lanes and shocks at the bar ends elevate CO emissivity, leading to the breakdown of the CO-PAH correlation. Future JWST spectroscopy and deep ALMA observations of CO isotopologues will provide critical tests of this scenario.

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