arXiv subjects

Ashok Ajoy

Publications and source records attributed to Ashok Ajoy.

At least 55 records · Page 3Linked to original sources

arXiv2021

Magnetic-field-induced delocalization in hybrid electron-nuclear spin ensembles

We use field-cycling-assisted dynamic nuclear polarization and continuous radio-frequency (RF) driving over a broad spectral range to demonstrate magnetic-field-dependent activation of nuclear spin transport from strongly-hyperfine-coupled 13C sites in diamond. We interpret our observations with the help of a theoretical framework where nuclear spin interactions are mediated by electron spins. In particular, we build on the results from a 4-spin toy model to show how otherwise localized nuclear spins must thermalize as they are brought in contact with a larger ancilla spin network. Further, by probing the system response to a variable driving field amplitude, we witness stark changes in the RF-absorption spectrum, which we interpret as partly due to contributions from heterogeneous multi-spin sets, whose 'zero-quantum' transitions become RF active thanks to the hybrid electron-nuclear nature of the system. These findings could prove relevant in applications to dynamic nuclear polarization, spin-based quantum information processing, and nanoscale sensing.

cond-mat.mes-hall↗

arXiv2021

Nuclear spin temperature reversal via continuous radio-frequency driving

Optical spin pumping of color centers in diamond is presently attracting broad interest as a platform for dynamic nuclear polarization at room temperature, but the mechanisms involved in the generation and transport of polarization within the host crystal are still partly understood. Here we investigate the impact of continuous radio-frequency (RF) excitation on the generation of nuclear magnetization produced by optical illumination. In the presence of RF excitation far removed from the nuclear Larmor frequency, we witness a magnetic-field-dependent sign reversal of the measured nuclear spin signal when the drive is sufficiently strong, a counter-intuitive finding that immediately points to non-trivial spin dynamics. With the help of analytical and numerical modeling, we show our observations indicate a modified form of 'solid effect', down-converted from the microwave to the radio-frequency range through the driving of hybrid transitions involving one (or more) nuclei and two (or more) electron spins. Our results open intriguing opportunities for the manipulation of many-electron spin systems by exploiting hyperfine couplings as a means to access otherwise forbidden intra-band transitions.

physics.app-ph↗

arXiv2020

Optically pumped spin polarization as a probe of many-body thermalization

The interplay between disorder and transport is a problem central to the understanding of a broad range of physical processes, most notably the ability of a system to reach thermal equilibrium. Disorder and many body interactions are known to compete, with the dominance of one or the other giving rise to fundamentally different dynamical phases. Here we investigate the spin diffusion dynamics of 13C in diamond, which we dynamically polarize at room temperature via optical spin pumping of engineered color centers. We focus on low-abundance, strongly hyperfine-coupled nuclei, whose role in the polarization transport we expose through the integrated impact of variable radio-frequency excitation on the observable bulk 13C magnetic resonance signal. Unexpectedly, we find good thermal contact throughout the nuclear spin bath, virtually independent of the hyperfine coupling strength, which we attribute to effective carbon-carbon interactions mediated by the electronic spin ensemble. In particular, observations across the full range of hyperfine couplings indicate the nuclear spin diffusion constant takes values up to two orders of magnitude greater than that expected from homo-nuclear spin couplings. Our results open intriguing opportunities to study the onset of thermalization in a system by controlling the internal interactions within the bath.

quant-ph↗

arXiv2019

Novel Trotter formulas for digital quantum simulation

Quantum simulation promises to address many challenges in fields ranging from quantum chemistry to material science, and high-energy physics, and could be implemented in noisy intermediate-scale quantum devices. A challenge in building good digital quantum simulators is the fidelity of the engineered dynamics given a finite set of elementary operations. Here we present a framework for optimizing the order of operations based on a geometric picture, thus abstracting from the operation details and achieving computational efficiency. Based on this geometric framework, we provide two alternative second-order Trotter expansions, one with optimal fidelity at a short time scale, and the second robust at a long time scale. Thanks to the improved fidelity at different time scale, the two expansions we introduce can form the basis for experimental-constrained digital quantum simulation.

quant-ph↗

arXiv2019

Cross-sensor feedback stabilization of an emulated quantum spin gyroscope

Quantum sensors, such as the Nitrogen Vacancy (NV) color center in diamond, are known for their exquisite sensitivity, but their performance over time are subject to degradation by environmental noise. To improve the long-term robustness of a quantum sensor, here we realize an integrated combinatorial spin sensor in the same micrometer-scale footprint, which exploits two different spin sensitivities to distinct physical quantities to stabilize one spin sensor with local information collected in realtime via the second sensor. We show that we can use the electronic spins of a large ensemble of NV centers as sensors of the local magnetic field fluctuations, affecting both spin sensors, in order to stabilize the output signal of interleaved Ramsey sequences performed on the 14N nuclear spin. An envisioned application of such a device is to sense rotation rates with a stability of several days, allowing navigation with limited or no requirement of geo-localization. Our results would enable stable rotation sensing for over several hours, which already reflects better performance than MEMS gyroscopes of comparable sensitivity and size.

quant-ph↗

arXiv2019

Two-electron-spin ratchets as a platform for microwave-free dynamic nuclear polarization of arbitrary material targets

Optically-pumped color centers in semiconductor powders can potentially induce high levels of nuclear spin polarization in surrounding solids or fluids at or near ambient conditions, but complications stemming from the random orientation of the particles and the presence of unpolarized paramagnetic defects hinder the flow of polarization beyond the defect's host material. Here, we theoretically study the spin dynamics of interacting nitrogen-vacancy (NV) and substitutional nitrogen (P1) centers in diamond to show that outside protons spin-polarize efficiently upon a magnetic field sweep across the NV-P1 level anti-crossing. The process can be interpreted in terms of an NV-P1 spin ratchet, whose handedness - and hence the sign of the resulting nuclear polarization - depends on the relative timing of the optical excitation pulse. Further, we find that the polarization transfer mechanism is robust to NV misalignment relative to the external magnetic field, and efficient over a broad range of electron-electron and electron-nuclear spin couplings, even if proxy spins feature short coherence or spin-lattice relaxation times. Therefore, these results pave the route towards the dynamic nuclear polarization of arbitrary spin targets brought in proximity with a diamond powder under ambient conditions.

quant-ph↗

arXiv2019

Dynamics of frequency-swept nuclear spin optical pumping in powdered diamond at low magnetic fields

A broad effort is underway to improve the sensitivity of nuclear magnetic resonance through the use of dynamic nuclear polarization. Nitrogen-vacancy (NV) centers in diamond offer an appealing platform because these paramagnetic defects can be optically polarized efficiently at room temperature. However, work thus far has been mainly limited to single crystals because most polarization transfer protocols are sensitive to misalignment between the NV and magnetic field axes. Here we study the spin dynamics of NV-13C pairs in the simultaneous presence of optical excitation and microwave frequency sweeps at low magnetic fields. We show that a subtle interplay between illumination intensity, frequency sweep rate, and hyperfine coupling strength leads to efficient, sweep-direction-dependent 13C spin polarization over a broad range of orientations of the magnetic field. In particular, our results strongly suggest that finely-tuned, moderately coupled nuclear spins are key to the hyperpolarization process, which makes this mechanism distinct from other known dynamic polarization channels. These findings pave the route to applications where powders are intrinsically advantageous, including the hyper-polarization of target fluids in contact with the diamond surface or the use of hyperpolarized particles as contrast agents for in-vivo imaging.

cond-mat.mes-hall↗

arXiv2019

Hyperpolarized relaxometry based nuclear T1 noise spectroscopy in hybrid diamond quantum registers

Understanding the origins of spin lifetimes in hybrid quantum systems is a matter of current importance in several areas of quantum information and sensing. Methods that spectrally map spin relaxation processes provide insight into their origin and can motivate methods to mitigate them. In this paper, using a combination of hyperpolarization and precision field cycling over a wide range (1mT-7T), we map frequency dependent relaxation in a prototypical hybrid system of 13C nuclear spins in diamond coupled to Nitrogen Vacancy centers. Nuclear hyperpolarization through the optically pumped NV electrons allows signal time savings for the measurements exceeding million-fold over conventional methods. We observe that 13C lifetimes show a dramatic field dependence, growing rapidly with field up to 100mT and saturating thereafter. Through a systematic study with increasing substitutional electron (P1 center) concentration as well as 13C enrichment levels, we identify the operational relaxation channels for the nuclei in different field regimes. In particular, we demonstrate the dominant role played by the 13C nuclei coupling to the interacting P1 electronic spin bath. These results pave the way for quantum control techniques for dissipation engineering to boost spin lifetimes in diamond, with applications ranging from engineered quantum memories to hyperpolarized 13C imaging.

quant-ph↗

arXiv2018

Room temperature "Optical Nanodiamond Hyperpolarizer": physics, design and operation

Dynamic Nuclear Polarization (DNP) is a powerful suite of techniques that deliver multifold signal enhancements in NMR and MRI. The generated athermal spin states can also be exploited for quantum sensing and as probes for many-body physics. Typical DNP methods require use of cryogens, large magnetic fields, and high power microwaves, which are expensive and unwieldy. Nanodiamond particles, rich in Nitrogen-Vacancy (NV) centers, have attracted attention as alternative DNP agents because they can potentially be optically hyperpolarized at room temperature. Indeed the realization of a miniature "optical nanodiamond hyperpolarizer", where 13C nuclei are optically hyperpolarized has been a longstanding goal but has been technically challenging to achieve. Here, unravelling new physics underlying an optical DNP mechanism first introduced in [Ajoy et al., Sci. Adv. 4, eaar5492 (2018)], we report the realization of such a device in an ultracompact footprint and working fully at room temperature. Instrumental requirements are very modest: low polarizing fields, extremely low optical and microwave irradiation powers, and convenient frequency ranges that enable device miniaturization. We obtain best reported optical 13C hyperpolarization in diamond particles exceeding 720 times of the thermal 7T value (0.86% bulk polarization), corresponding to a ten-million-fold gain in NMR averaging time. In addition the hyperpolarization signal can be background-suppressed by over two-orders of magnitude and retained for multiple-minute long periods. Besides compelling applications in quantum sensing, and bright-contrast MRI imaging, this work paves the way for low-cost DNP platforms that relay the 13C polarization to liquids in contact with the high surface-area particles. This will ultimately allow development of miniature "quantum-assisted" NMR spectrometers for chemical analysis.

quant-ph↗

arXiv2018

Dynamic Hamiltonian engineering of 2D rectangular lattices in a one-dimensional ion chain

Controlling the interaction graph between spins or qubits in a quantum simulator allows user-controlled tailoring of native interactions to achieve a target Hamiltonian. The flexibility of engineering long-ranged phonon-mediated spin-spin interactions in a trapped ion quantum simulator offers such a possibility. Trapped ions, a leading candidate for simulating computationally hard quantum many-body dynamics, are most readily trapped in a linear 1D chain, limiting their utility for readily simulating higher dimensional spin models. In this work, we introduce a hybrid method of analog-digital simulation for simulating 2D spin models and dynamically changing interactions to achieve a new graph using a linear 1D chain. The method relies on time domain Hamiltonian engineering through a successive application of Stark shift gradient pulses, and wherein the pulse sequence can simply be obtained from a Fourier series decomposition of the target Hamiltonian over the space of lattice couplings. We focus on engineering 2D rectangular nearest-neighbor spin lattices, demonstrating that the required control parameters scale linearly with ion number. This hybrid approach offers compelling possibilities for the use of 1D chains in the study of Hamiltonian quenches, dynamical phase transitions, and quantum transport in 2D and 3D. We discuss a possible experimental implementation of this approach using real experimental parameters.

quant-ph↗

arXiv2017

Multi-spin-assisted optical pumping of bulk 13C nuclear spin polarization in diamond

One of the most remarkable properties of the nitrogen-vacancy (NV) center in diamond is that optical illumination initializes its electronic spin almost completely, a feature that can be exploited to polarize other spin species in their proximity. Here we use field-cycled nuclear magnetic resonance (NMR) to investigate the mechanisms of spin polarization transfer from NVs to 13C spins in diamond at room temperature. We focus on the dynamics near 51 mT, where a fortuitous combination of energy matching conditions between electron and nuclear spin levels gives rise to alternative polarization transfer channels. By monitoring the 13C spin polarization as a function of the applied magnetic field, we show 13C spin pumping takes place via a multi-spin cross relaxation process involving the NV- spin and the electronic and nuclear spins of neighboring P1 centers. Further, we find that this mechanism is insensitive to the crystal orientation relative to the magnetic field, although the absolute level of 13C polarization - reaching up to ~3% under optimal conditions - can vary substantially depending on the interplay between optical pumping efficiency, photo-generated carriers, and laser-induced heating.

quant-ph↗

arXiv2017

Selective decoupling and Hamiltonian engineering in dipolar spin networks

We present a protocol to selectively decouple, recouple, and engineer effective couplings in mesoscopic dipolar spin networks. In particular, we develop a versatile protocol that relies upon magic angle spinning to perform Hamiltonian engineering. By using global control fields in conjunction with a local actuator, such as a diamond Nitrogen Vacancy center located in the vicinity of a nuclear spin network, both global and local control over the effective couplings can be achieved. We show that the resulting effective Hamiltonian can be well understood within a simple, intuitive geometric picture, and corroborate its validity by performing exact numerical simulations in few-body systems. Applications of our method are in the emerging fields of two-dimensional room temperature quantum simulators in diamond platforms, as well as in dipolar coupled polar molecule networks.

quant-ph↗

arXiv2017

Evolution-free Hamiltonian parameter estimation through Zeeman markers

We provide a protocol for Hamiltonian parameter estimation which relies only on the Zeeman effect. No time-dependent quantities need to be measured, it fully suffices to observe spectral shifts induced by fields applied to local `markers'. We demonstrate the idea with a simple tight-binding Hamiltonian and numerically show stability with respect to Gaussian noise on the spectral measurements. Then we generalize the result to show applicability to a wide range of systems, including quantum spin chains, networks of qubits, and coupled harmonic oscillators, and suggest potential experimental implementations.

quant-ph↗

arXiv2014

Atomic-scale nuclear spin imaging using quantum-assisted sensors in diamond

Nuclear spin imaging at the atomic level is essential for the understanding of fundamental biological phenomena and for applications such as drug discovery. The advent of novel nano-scale sensors has given hope of achieving the long-standing goal of single-protein, high spatial-resolution structure determination in their natural environment and ambient conditions. In particular, quantum sensors based on the spin-dependent photoluminescence of Nitrogen Vacancy (NV) centers in diamond have recently been used to detect nanoscale ensembles of external nuclear spins. While NV sensitivity is approaching single-spin levels, extracting relevant information from a very complex structure is a further challenge, since it requires not only the ability to sense the magnetic field of an isolated nuclear spin, but also to achieve atomic-scale spatial resolution. Here we propose a method that, by exploiting the coupling of the NV center to an intrinsic quantum memory associated with the Nitrogen nuclear spin, can reach a tenfold improvement in spatial resolution, down to atomic scales. The spatial resolution enhancement is achieved through coherent control of the sensor spin, which creates a dynamic frequency filter selecting only a few nuclear spins at a time. We propose and analyze a protocol that would allow not only sensing individual spins in a complex biomolecule, but also unraveling couplings among them, thus elucidating local characteristics of the molecule structure.

quant-ph↗

arXiv2013

Decay of spin coherences in one-dimensional spin systems

Strategies to protect multi-qubit states against decoherence are difficult to formulate because of their complex many-body dynamics. A better knowledge of the decay dynamics would help in the construction of decoupling control schemes. Here we use solid-state nuclear magnetic resonance techniques to experimentally investigate the decay of coherent multi-spin states in linear spin chains. Leveraging on the quasi-one-dimensional geometry of Fluorapatite crystal spin systems, we can gain a deeper insight on the multi-spin states created by the coherent evolution, and their subsequent decay, than it is possible in 3D systems. We are then able to formulate an analytical model that captures the key features of the decay. We can thus compare the decoherence behavior for different initial states of the spin chain and link their decay rate to the state characteristics, in particular their coherence and long-range correlation among spins. Our experimental and theoretical study shows that the spin chains undergo a rich dynamics, with a slower decay rate than for the 3D case, and thus might be more amenable to decoupling techniques.

quant-ph↗

arXiv2013

Quantum simulation via filtered Hamiltonian engineering: application to perfect quantum transport in spin networks

We propose a method for Hamiltonian engineering in quantum information processing architectures that requires no local control, but only relies on collective qubit rotations and field gradients. The technique achieves a spatial modulation of the coupling strengths via a dynamical construction of a weighting function combined with a Bragg grating. As an example, we demonstrate how to generate the ideal Hamiltonian for perfect quantum information transport between two separated nodes of a large spin network. We engineer a spin chain with optimal couplings from a large spin network, such as naturally occurring in crystals, while decoupling all unwanted interactions. For realistic experimental parameters, our method can be used to drive perfect quantum information transport at room-temperature. The Hamiltonian engineering method can be made more robust under coherence and coupling disorder by a novel apodization scheme. Thus the method is quite general and can be used engineer the Hamiltonian of many complex spin lattices with different topologies and interactions.

quant-ph↗

arXiv2012

Perfect quantum transport in arbitrary spin networks

Spin chains have been proposed as wires to transport information between distributed registers in a quantum information processor. Unfortunately, the challenges in manufacturing linear chains with engineered couplings has hindered experimental implementations. Here we present strategies to achieve perfect quantum information transport in arbitrary spin networks. Our proposal is based on the weak coupling limit for pure state transport, where information is transferred between two end-spins that are only weakly coupled to the rest of the network. This regime allows disregarding the complex, internal dynamics of the bulk network and relying on virtual transitions or on the coupling to a single bulk eigenmode. We further introduce control methods capable of tuning the transport process and achieve perfect fidelity with limited resources, involving only manipulation of the end-qubits. These strategies could be thus applied not only to engineered systems with relaxed fabrication precision, but also to naturally occurring networks; specifically, we discuss the practical implementation of quantum state transfer between two separated nitrogen vacancy (NV) centers through a network of nitrogen substitutional impurities.

quant-ph↗

arXiv2012

Stable Three-Axis Nuclear Spin Gyroscope in Diamond

We propose a sensitive and stable three-axis gyroscope in diamond. We achieve high sensitivity by exploiting the long coherence time of the N14 nuclear spin associated with the Nitrogen-Vacancy center in diamond, and the efficient polarization and measurement of its electronic spin. While the gyroscope is based on a simple Ramsey interferometry scheme, we use coherent control of the quantum sensor to improve its coherence time as well as its robustness against long-time drifts, thus achieving a very robust device with a resolution of 0.5mdeg/s/(Hz mm^3)^(1/2). In addition, we exploit the four axes of delocalization of the Nitrogen-Vacancy center to measure not only the rate of rotation, but also its direction, thus obtaining a compact three-axis gyroscope.

quant-ph↗