arXiv subjects

Atsushi Ikeda

Publications and source records attributed to Atsushi Ikeda.

At least 37 records · Page 2Linked to original sources

arXiv2022

Collective dynamics in a glass-former with Mari-Kurchan interactions

We numerically study the equilibrium relaxation dynamics of a two-dimensional Mari-Kurchan glass model. The tree-like structure of particle interactions forbids both non-trivial structural motifs and the emergence of a complex free-energy landscape leading to a thermodynamic glass transition, while the finite-dimensional nature of the model prevents the existence of a mode-coupling singularity. Nevertheless, the equilibrium relaxation dynamics is shown to be in excellent agreement with simulations performed in conventional glass-formers. Averaged time-correlation functions display a phenomenology typical of supercooled liquids, including the emergence of an excess signal in relaxation spectra at intermediate frequencies. We show that this evolution is accompanied by strong signatures of collective and heterogeneous dynamics which cannot be interpreted in terms of single particle hopping and emerge from dynamic facilitation. Our study demonstrates that an off-lattice interacting particle model with extremely simple structural correlations displays quantitatively realistic glassy dynamics.

cond-mat.dis-nn↗

arXiv2022

Relaxation dynamics in the energy landscape of glass-forming liquids

We numerically study the zero-temperature relaxation dynamics of several glass-forming models to their inherent structures, following quenches from equilibrium configurations sampled across a wide range of initial temperatures. In a mean-field Mari-Kurchan model, we find that relaxation changes from a power-law to an exponential decay below a well-defined temperature, consistent with recent findings in mean-field $p$-spin models. By contrast, for finite-dimensional systems, the relaxation is always algebraic, with a non-trivial universal exponent at high temperatures crossing over to a harmonic value at low temperatures. We demonstrate that this apparent evolution is controlled by a temperature-dependent population of localised glassy excitations. Our work unifies several recent lines of studies aiming at a detailed characterisation of the complex potential energy landscape of glass-formers, and challenges both mean-field and real space descriptions of glasses.

cond-mat.stat-mech↗

arXiv2022

Phonon transport properties of particulate physical gels

Particulate physical gels are sparse, low-density amorphous materials in which clusters of glasses are connected to form a heterogeneous network structure. This structure is characterized by two length scales, $ξ_s$ and $ξ_G$: $ξ_s$ measures the length of heterogeneities in the network structure, and $ξ_G$ is the size of glassy clusters. Accordingly, the vibrational states of such a material also exhibit a multiscale nature with two characteristic frequencies, $ω_\ast$ and $ω_G$, which are associated with $ξ_s$ and $ξ_G$, respectively: (i) phonon-like vibrations in the homogeneous medium at $ω< ω_\ast$, (ii) phonon-like vibrations in the heterogeneous medium at $ω_\ast < ω< ω_G$, and (iii) disordered vibrations in the glassy clusters at $ω> ω_G$. Here, we demonstrate that the multiscale characteristics seen in the static structures and vibrational states also extend to the phonon transport properties. Phonon transport exhibits two distinct crossovers at the frequencies $ω_\ast$ and $ω_G$~(or at wavenumbers of $\sim ξ_s^{-1}$ and $\sim ξ_G^{-1}$). In particular, both transverse and longitudinal phonons cross over between Rayleigh scattering at $ω< ω_\ast$ and diffusive damping at $ω>ω_\ast$. Remarkably, the Ioffe--Regel limit is located at the very low frequency of $ω_\ast$. Thus, phonon transport is localized above $ω_\ast$, even where phonon-like vibrational states persist. This markedly strong scattering behavior is caused by the sparse, porous structure of the gel.

cond-mat.soft↗

arXiv2022

Revisiting the single-saddle model for the $β$-relaxation of supercooled liquids

The dynamics of glass-forming liquids display several outstanding features, such as two-step relaxation and dynamic heterogeneities, which are difficult to predict quantitatively from first principles. In this work, we revisit a simple theoretical model of the $β$-relaxation, i.e., the first step of the relaxation dynamics. The model, first introduced by Cavagna et al., describes the dynamics of the system in the neighborhood of a saddle point of the potential energy surface. We extend the model to account for density-density correlation functions and for the 4-point dynamic susceptibility. We obtain analytical results for a simple schematic model, making contact with related results for p-spin models and with the predictions of inhomogeneous mode-coupling theory. Building on recent computational advances, we also explicitly compare the model predictions against overdamped Langevin dynamics simulations of a glass-forming liquid close to the mode-coupling crossover. The agreement is quantitative at the level of single-particle dynamic properties only up to the early $β$-regime. Due to its inherent harmonic approximation, however, the model is unable to predict the dynamics on the time scale relevant for structural relaxation. Nonetheless, our analysis suggests that the agreement with the simulations may be largely improved if the modes' spatial localization is properly taken into account.

cond-mat.stat-mech↗

arXiv2021

Geometrical properties of mechanically annealed systems near the jamming transition

Geometrical properties of two-dimensional mixtures near the jamming transition point are numerically investigated using harmonic particles under mechanical training. The configurations generated by the quasi-static compression and oscillatory shear deformations exhibit anomalous suppression of the density fluctuations, known as hyperuniformity, below and above the jamming transition. For the jammed system trained by compression above the transition point, the hyperuniformity exponent increases. For the system below the transition point under oscillatory shear, the hyperuniformity exponent also increases until the shear amplitude reaches the threshold value. The threshold value matches with the transition point from the point-reversible phase where the particles experience no collision to the loop-reversible phase where the particles' displacements are non-affine during a shear-cycle before coming back to an original position. The results demonstrated in this paper are explained in terms of neither of universal criticality of the jamming transition nor the nonequilibrium phase transitions.

cond-mat.soft↗

arXiv2021

Structural, mechanical, and vibrational properties of particulate physical gels

Our lives are surrounded by a rich assortment of disordered materials. In particular, glasses are well known as dense, amorphous materials, whereas gels exist in low-density, disordered states. Recent progress has provided a significant step forward in understanding the material properties of glasses, such as mechanical, vibrational, and transport properties. In contrast, our understanding of particulate physical gels is still highly limited. Here, using molecular dynamics simulations, we study a simple model of particulate physical gels, the Lennard-Jones (LJ) gels, and provide a comprehensive understanding of their structural, mechanical, and vibrational properties, all of which are markedly different from those of glasses. First, the LJ gels show sparse, heterogeneous structures, and the length scale $ξ_s$ of the structures grows as the density is lowered. Second, the gels are extremely soft, with both shear $G$ and bulk $K$ moduli being orders of magnitude smaller than those of glasses. Third, many low-frequency vibrational modes are excited, which form a characteristic plateau with the onset frequency $ω_\ast$ in the vibrational density of states. Structural, mechanical, and vibrational properties, characterized by $ξ_s$, $G$, $K$, and $ω_\ast$, respectively, show power-law scaling behaviors with the density, which establishes a close relationship between them. Throughout the present work, we reveal that gels are multiscale, solid-state materials: (i) homogeneous elastic bodies at long lengths, (ii) heterogeneous elastic bodies with fractal structures at intermediate lengths, and (iii) amorphous structural bodies at short lengths.

cond-mat.soft↗

arXiv2021

Shear-induced Criticality in Glasses Shares Qualitative Similarities with the Gardner Phase

Although glass phases are found in various soft matter systems ubiquitously, we are still far from a complete understanding of them. The concept of marginal stability predicted by infinite-dimensional mean-field theories is drawing attention as a candidate for universal and distinguishing unique features of glasses. While among theoretical predictions, the non-Debye scaling has indeed been observed universally over various classes of glasses, and the Gardner phase is found only in hard sphere systems if we restrict ourselves to the physical dimensions. In this work, we numerically demonstrate that plastic events observed in two-dimensional Lennard-Jones glasses under quasistatic shear exhibit statistical properties that are qualitatively very similar to the Gardner phase.

cond-mat.dis-nn↗

arXiv2021

Multiple glass transitions and higher order replica symmetry breaking of binary mixtures

We extend the replica liquid theory in order to describe the multiple glass transitions of binary mixtures with large size disparities, by taking into account the two-step replica symmetry breaking (2RSB). We determine the glass phase diagram of the mixture of large and small particles in the large-dimension limit where the mean-field theory becomes exact. When the size ratio of particles is beyond a critical value, the theory predicts three distinct glass phases; (i) the 1RSB double glass where both components vitrify simultaneously, (ii) the 1RSB single glass where only large particles are frozen while small particles remain mobile, and (iii) a new glass phase called the 2RSB double glass where both components vitrify simultaneously but with an energy landscape topography distinct from the 1RSB double glass.

cond-mat.soft↗

arXiv2021

Relaxation dynamics of non-Brownian spheres below jamming

We numerically study the relaxation dynamics and associated criticality of non-Brownian frictionless spheres below jamming in spatial dimensions $d=2$, $3$, $4$, and $8$, and in the mean-field Mari-Kurchan model. We discover non-trivial finite-size and volume fraction dependences of the relaxation time associated to the relaxation of unjammed packings. In particular, the relaxation time is shown to diverge logarithmically with system size at any density below jamming, and no critical exponent can characterise its behaviour approaching jamming. In mean-field, the relaxation time is instead well-defined: it diverges at jamming with a critical exponent that we determine numerically and differs from an earlier mean-field prediction. We rationalise the finite $d$ logarithmic divergence using an extreme-value statistics argument in which the relaxation time is dominated by the most connected region of the system. The same argument shows that the earlier proposition that relaxation dynamics and shear viscosity are directly related breaks down in large systems. The shear viscosity of non-Brownian packings is well-defined in all $d$ in the thermodynamic limit, but large finite-size effects plague its measurement close to jamming.

cond-mat.soft↗

arXiv2021

Computational simulations of the vibrational properties of glasses

Glasses show vibrational properties that are markedly different to those of crystals which are known as phonons. For example, excess low-frequency modes (the so-called boson peak), vibrational localization, and strong scattering of phonons have been the most discussed topics, and a theoretical understanding of these phenomena is challenging. To address this problem, computational simulations are a powerful tool, which have been employed by many previous works. In this chapter, we describe simulation methods for studying the vibrational properties of glasses (and any solid-state materials). We first present a method for studying vibrational eigenmodes. Since vibrational motions of particles are excited along eigenmodes, the eigenmodes are fundamental to descriptions of vibrational properties. The eigenmodes in glasses are non-phonon modes in general, and some of them are even localized in space. We next present a method of analysing phonon transport, which is also crucial for understanding vibrational properties. Since phonons are not eigenmodes in glasses, they are decomposed into several different, non-phonon eigenmodes. As a result, phonons in glasses are strongly scattered. In addition, we describe how to analyse the elastic response. The elastic response of glasses is also anomalous with respect to that of crystals. Finally, we briefly introduce recent advances that have been achieved by means of large-scale computational simulations.

cond-mat.soft↗

arXiv2020

Instantaneous Normal Modes Reveal Structural Signatures for the Herschel-Bulkley Rheology in Sheared Glasses

The Herschel-Bulkley law, a universal constitutive relation, has been empirically known to be applicable to a vast range of soft materials, including sheared glasses. Although the Herschel- Bulkley law has attracted public attention, its structural origin has remained an open question. In this letter, by means of atomistic simulation of binary Lennard-Jones glasses, we report that the instantaneous normal modes with negative eigenvalues, or so-called imaginary modes, serve as the structural signatures for the Herschel-Bulkley rheology in sheared glasses.

cond-mat.soft↗

arXiv2020

Spatial structure of unstable normal modes in a glass-forming liquid

The phenomenology of glass-forming liquids is often described in terms of their underlying, high-dimensional potential energy surface. In particular, the statistics of stationary points sampled as a function of temperature provides useful insight into the thermodynamics and dynamics of the system. To make contact with the real space physics, however, analysis of the spatial structure of the normal modes is required. In this work, we numerically study the potential energy surface of a glass-forming ternary mixture. Starting from liquid configurations equilibrated over a broad range of temperatures using a swap Monte Carlo method, we locate the nearby stationary points and investigate the spatial architecture and the energetics of the associated unstable modes. Through this spatially-resolved analysis, originally developed to study local minima, we corroborate recent evidence that the nature of the unstable modes changes from delocalized to localized around the mode-coupling temperature. We find that the displacement amplitudes of the delocalized modes have a slowly decaying far field, whereas the localized modes consist of a core with large displacements and a rapidly decaying far field. The fractal dimension of unstable modes around the mobility edge is equal to 1, consistent with the scaling of the participation ratio. Finally, we find that around and below the mode-coupling temperature the unstable modes are localized around structural defects, characterized by a disordered local structure markedly different from the liquid's locally favored structure. These defects are similar to those associated to quasi-localized vibrations in local minima and are good candidates to predict the emergence of localized excitations at low temperature.

cond-mat.stat-mech↗

arXiv2020

Novel elastic instability of amorphous solids in finite spatial dimensions

Recently, progress has been made in the understanding of anomalous vibrational excitations in amorphous solids. In the lowest-frequency region, the vibrational spectrum follows a non-Debye quartic law, which persists up to zero frequency without any frequency gap. This gapless vibrational density of states (vDOS) suggests that glasses are on the verge of instability. This feature of marginal stability is now highlighted as a key concept in the theories of glasses. In particular, the elasticity theory based on marginal stability predicts the gapless vDOS. However, this theory yields a quadratic law and \textit{not} the quartic law. To address this inconsistency, we presented a new type of instability, which is different from the conventional one, and proposed that amorphous solids are marginally stable considering the new instability in the preceding study~[M. Shimada, H. Mizuno, and A. Ikeda, Soft Matter, {\bf 16}, 7279, 2020]. In this study, we further extend and detail the results for these instabilities. By analyzing various examples of disorder, we demonstrate that real glasses in finite spatial dimensions can be marginally stable by the proposed novel instability.

cond-mat.dis-nn↗

arXiv2020

Phase transition in the binary mixture of jammed particles with large size dispersity

It has been well established that particulate systems show the jamming transition and critical scaling behaviors associated with it. However, our knowledge is limited to (nearly) monodisperse systems. Recently, a binary mixture of jammed particles with large size dispersity was studied, and it was suggested that two distinct jammed phases appeared. Here, we conduct a thorough numerical study on this system with a special focus on the statistics of and finite-size effects on the fraction of small particles that participate in the rigid network. We present strong evidence that two distinct jammed phases appear depending on the pressure and composition of two species, which are separated by the first-order phase transition. In one of two phases, only large particles are jammed, whereas both small and large particles are jammed in the other phase. We also describe the phase diagram in the pressure-composition plane, where the first-order phase transition line terminates at a critical point. In addition, we investigate the mechanical properties in terms of the elastic moduli over the phase diagram and find that discontinuous changes in elastic moduli emerge across the phase transition. Remarkably, despite the discontinuities, the elastic moduli in each jammed phase exhibit identical scaling laws to those in the monodisperse systems.

cond-mat.soft↗

arXiv2020

Unified View of Avalanche Criticality in Sheared Glasses

Plastic events in sheared glasses are considered an example of so-called avalanches, whose sizes obey a power-law probability distribution with the avalanche critical exponent $τ$. Although mean-field theory predicts a universal value of this exponent, $τ_{\rm MF}=1.5$, numerical simulations have reported different values depending on the literature. Moreover, in the elastic regime, it has been noted that the critical exponent can be different from that in the steady state, and even criticality itself is a matter of debate. Because these confusingly varying results were reported under different setups, our knowledge of avalanche criticality in sheared glasses is greatly limited. To gain a unified understanding, in this work, we conduct a comprehensive numerical investigation of avalanches in Lennard-Jones glasses under athermal quasistatic shear. In particular, by excluding the ambiguity and arbitrariness that has crept into the conventional measurement schemes, we achieve high-precision measurement and demonstrate that the exponent $τ$ in the steady state follows the mean-field prediction of $τ_{\rm MF}=1.5$. Our results also suggest that there are two qualitatively different avalanche events. This binariness leads to the non-universal behavior of the avalanche size distribution and is likely to be the cause of the varying values of $τ$ reported thus far. To investigate the dependence of criticality and universality on applied shear, we further study the statistics of avalanches in the elastic regime and the ensemble of the first avalanche event in different samples, which provide information about the unperturbed system. We show that while the unperturbed system is indeed off-critical, criticality gradually develops as shear is applied. Moreover, the critical exponent obeys the mean-field prediction $τ_{\rm MF}$ universally, once the system becomes critical.

cond-mat.soft↗

arXiv2020

Intermittent rearrangements accompanying thermal fluctuations distinguish glasses from crystals

It is a persistent problem in condensed matter physics that glasses exhibit vibrational and thermal properties that are markedly different from those of crystals. While recent works have advanced our understanding of vibrational excitations in glasses at the harmonic approximation limit, efforts in understanding finite-temperature anharmonic processes have been limited. It is well known that phonons in crystals couple through phonon-phonon interactions, an extremely efficient mechanism for anharmonic decay that is also important in glasses. Here, however, we show that an additional anharmonic channel of different origin emerges in the case of glasses, which induces intermittent rearrangements of particles. We have found that thermal vibrations in glasses trigger transitions among numerous different local minima of the energy landscape, which, however, are located within the same wide (meta)basin. These processes generate motions that are different from both diffusive and out-of-equilibrium aging dynamics. We suggest that the intermittent rearrangements accompanying thermal fluctuations are crucial features distinguishing glasses from crystals.

cond-mat.soft↗

arXiv2020

Mechanical and Vibrational Properties of Three-Dimensional Dimer Packings Near the Jamming Transition

We comprehensively study mechanical and vibrational properties of dimer packings in three-dimensional space with particular attention on critical scaling behaviors near the jamming transition. First, we confirm the dependence of the packing fraction at the transition on the aspect ratio, the isostatic contact number at the transition, and the scaling dependence of the excess contact number on the excess density. Second, we study the elastic moduli, bulk and shear moduli, and establish power-law scaling of them. Finally, we study the vibrational density of states and its characteristic frequency. The vibrational density of states shows two plateaus in the lower- and higher-frequency regions, which are characterized by rotational and translational vibrational modes, respectively. The onset frequency of the lower-frequency plateau scales linearly to the square root of excess density. The scaling laws in the mechanical and vibrational properties are consistent between two- and three-dimensional dimers, and they are identical to those in spheres.

cond-mat.soft↗

arXiv2020

Phase separation kinetics of a symmetric binary mixture of glass-forming liquids

Mixtures of glass-forming fluids sometimes exhibit glass-glass phase separation at low temperatures. Here, we use a molecular dynamics simulation to study one of the simplest examples of the glass-glass phase separation. We consider a mixture composed of type A and B particles, in which the A-A and B-B interactions are the identical Lennard-Jones interactions and the A-B interaction is repulsive only. To avoid crystallization, we also introduce the polydispersity in the particle sizes for each component. We study the phase separation kinetics of this model at a 50:50 concentration at various temperatures. We find that hydrodynamic coarsening takes place when the temperature is higher than the onset temperature of the glassy dynamics. At lower temperatures, diffusive coarsening is observed over a long duration, and a further slower coarsening appears within a shorter time. Below the glass transition temperature, the domain growth does not stop but becomes logarithmically slow or even slower than logarithmic. By analyzing two-time correlation functions, we show that these slow coarsening processes are accompanied by a slowing down of the microscopic dynamics, which has qualitative similarities with the aging dynamics without phase separation. Based on the results, we discuss a possible link between the slow coarsening and the aging-like microscopic slowing down in the glass-glass phase separation.

cond-mat.stat-mech↗