arXiv subjects

Audrey Chatain

Publications and source records attributed to Audrey Chatain.

11 recordsLinked to original sources

arXiv2026

Terrestrial Analogs to Titan for Geophysical Research

Saturn's moon Titan exhibits remarkable parallels to the Earth in many geophysical and geological processes not found elsewhere in the solar system at the present day. These include a nitrogen atmosphere with a condensible gas - methane - replacing the Earth's water, leading to an active meteorology with rainfall and surface manifestations including rivers, lakes and seas, and the dissolution of karstic terrain. Other phenomena such as craters, dunes, and tectonic features are found elsewhere - e.g. on Mars and Venus - but their continuing alteration by pluvial, fluvial and lacustrine processes can be studied only on Earth and Titan. Meanwhile Titan also hosts an interior liquid water ocean with similarities to the Earth as well as to ocean worlds such as Europa and Enceladus. Our focus in this review paper is twofold: to describe the geophysical and geological parallels between Earth and Titan, and to evaluate the yet-underexploited possibilities for field analog research to gain new knowledge about these processes. To date, Titan's much colder temperature and different atmospheric and crustal materials have led to a skepticism that useful analogs can be found on Earth. Our conclusion, however, is that a much larger range of useful analog field work is possible and this work will substantially enhance our knowledge of both worlds. Such investigation will supplement the existing sparse data for Titan returned by space missions, will greatly enhance our understanding of such datasets, and will help to provide science impetus and goals for future missions.

astro-ph.EP↗

arXiv2023

The impact of lake shape and size on lake breezes and air-lake exchanges on Titan

Titan, the largest moon of Saturn, has many lakes on its surface, formed mainly of liquid methane. Like water lakes on Earth, these methane lakes on Titan likely profoundly affect the local climate. Previous studies (Rafkin and Soto 2020, Chatain et al 2022) showed that Titan's lakes create lake breeze circulations with characteristic dimensions similar to the ones observed on Earth. However, such studies used a model in two dimensions; this work investigates the consequences of the addition of a third dimension to the model. Our results show that 2D simulations tend to overestimate the extension of the lake breeze over the land, and underestimate the strength of the subsidence over the lake, due to divergence/convergence geometrical effects in the mass conservation equations. In addition, 3D simulations including a large scale background wind show the formation of a pocket of accelerated wind behind the lake, which did not form in 2D simulations. An investigation of the effect of shoreline concavity on the resulting air circulation shows the formation of wind currents over peninsulas. Simulations with several lakes can either result in the formation of several individual lake breeze cells (during the day), or the emergence of a large merged cell with internal wind currents between lakes (during the night). Simulations of several real-shaped lakes located at a latitude of 74{\deg}N on Titan at the autumn equinox show that larger lakes trigger stronger winds, and that some sections of lakes might accumulate enough methane vapor to form a thin fog. The addition of a third dimension, along with adjustments in the parametrizations of turbulence and subsurface land temperature, results in a reduction in the magnitude of the average lake evaporate rate, namely to ~6 cm/Earth year.

astro-ph.EP↗

arXiv2023

Humid Evolution of Haze in the Atmosphere of Super-Earths in the Habitable Zone

Photochemical hazes are expected to form and significantly contribute to the chemical and radiative balance of exoplanets with relatively moderate temperatures, possibly in the habitable zone of their host star. In the presence of humidity, haze particles might thus serve as cloud condensation nuclei and trigger the formation of water droplets. In the present work, we are interested in the chemical impact of such a close interaction between photochemical hazes and humidity on the organic content composing the hazes and on the capacity to generate organic molecules with high prebiotic potential. For this purpose, we explore experimentally the sweet spot by combining N-dominated super-Earth exoplanets in agreement with Titan's rich organic photochemistry and humid conditions expected for exoplanets in habitable zones. A logarithmic increase with time is observed for the relative abundance of oxygenated species, with O-containing molecules dominating after 1 month only. The rapidity of the process suggests that the humid evolution of N-rich organic haze provides an efficient source of molecules with high prebiotic potential.

astro-ph.EP↗

arXiv2023

Characterization of a DC glow discharge in $N_2-H_2$ with electrical measurements and neutral and ion mass spectrometry

The addition of small amounts of $H_2$ were investigated in a DC glow discharge in $N_2$, at low pressure (~1 mbar) and low power (0.05 to 0.2 $W.cm^{-3}$). We quantified the electric field, the electron density, the ammonia production and the formation of positive ions for amounts of $H_2$ varying between 0 and 5%, pressure values between 0.5 and 4 mbar, and currents between 10 and 40 mA. The addition of less than 1% $H_2$ has a strong effect on the $N_2$ plasma discharges. Hydrogen quenches the (higher) vibrational levels of $N_2$ and some of its highly energetic metastable states. This leads to the increase of the discharge electric field and consequently of the average electron energy. As a result, higher quantities of radical and excited species are suspected to be produced. The addition of hydrogen also leads to the formation of new species. In particular, ammonia and hydrogen-bearing ions have been observed: $N_2H^+$ and $NH_4^+$ being the major ones, and also $H_3^+$, $NH^+$, $NH_2^+$, $NH_3^+$, $N_3H^+$ and $N_3H_3^+$. The comparison to a radiofrequency capacitively coupled plasma (RF CCP) discharge in similar experimental conditions shows that both discharges led to similar observations. The study of $N_2-H_2$ discharges in the laboratory in the adequate ionization conditions then gives some insights on which plasma species made of nitrogen and hydrogen could be present in the ionosphere of Titan. Here, we identified some protonated ions, which are reactive species that could participate to the erosion of organic aerosols on Titan.

physics.plasm-ph↗

arXiv2023

Interaction dust-plasma in Titan's ionosphere: feedbacks on the gas phase composition

Titan's organic aerosols are formed in the ionosphere, a layer ionized by solar VUV photons and energetic particles from the magnetosphere of Saturn, forming a natural N2-CH4-H2 plasma. Previous works showed some chemical evolution processes: VUV photons slightly alter the aerosols nitrile bands, hydrogen atoms tend to hydrogenate their surface and carbon-containing species participate to the growth of the aerosols. This work investigates the effect of the other plasma species, namely the N2-H2 derived ions, radicals and excited states. Industrial plasmas often use N2-H2 discharges to form ammonia-based fertilizers, for metal nitriding, and to erode organic surfaces. Consequently, these are likely to affect Titan's organic aerosols. We therefore developed the THETIS experiment to study the interactions between analogues of Titan's aerosols (tholins) and the erosive N2-H2 plasma species found in Titan's ionosphere. Following a first paper on the evolution of the solid phase by Scanning Electron Microscopy and IR transmission spectroscopy (Chatain et al., Icarus, 2020), this paper focuses on evolution of the gas phase composition, by neutral and ion mass spectrometry. Newly formed HCN, NH3-CN and C2N2 are extracted from the tholins as well as some other carbon-containing species and their derived ions. On the other hand, the production of ammonia strongly decreases, probably because the H, NH and N radicals are rather used for the production of HCN at the surface of tholins. Heterogeneous processes are suggested: chemical processes induced by radicals at the surface would modify and weaken the tholin structure, while ion sputtering would desorb small molecules and highly unsaturated ions. The effect of plasma erosion on aerosols in Titan's ionosphere could therefore lead to the formation of CN bonds in the aerosol structure and the production of HCN or R-CN species in the gas phase.

astro-ph.EP↗

arXiv2022

Detection and characterization of wind-blown charged sand grains on Titan with the DraGMet/EFIELD experiment on Dragonfly

The EFIELD instrument is part of the geophysics and meteorology sensor package DraGMet on the Dragonfly mission, which will explore the surface of Titan in the mid-2030s. EFIELD consists of two electrodes designed to passively record the AC electric field at each landing site. The exploration zone of Dragonfly will mostly consist of dune fields, covered with sand grains. Little is known on the properties of these grains, although Cassini-Huygens observations suggest they are mostly made of organic material produced by Titan's atmospheric photochemistry and evolved at the surface. Little is known also about dune formation and in general about the transport of sediments by winds. The latter much depends on inter-particle forces and therefore on how grains are charged by friction. We demonstrate here that the EFIELD experiment can bring new insights on these questions. We have developed a hydrodynamic-electrostatic model to simulate the trajectory of a wind-blown charged sand grain in the vicinity of an idealized EFIELD probe and to predict how such a grain flying close to the probe would affect its potential. We show that, in some conditions, the resulting perturbation will be strong enough to be detected by the EFIELD probe. More specifically, we find that the detection of typical charged wind-blown grains (200 microns) on Titan requires an instrument standard deviation noise inferior to 1mV, though occasional larger grains flying close to one electrode could be detected with a higher noise level. Furthermore, we propose a method to retrieve information on the charge and velocity of wind-blown charged grains detected by the EFIELD experiment. This method well applies for cases where the particle trajectory can be regarded as quasi-linear. We validate our inversion approach on both synthetic and experimental data obtained with a laboratory prototype of the EFIELD experiment.

astro-ph.EP↗

arXiv2022

Air-sea interactions on Titan: effect of radiative transfer on the lake evaporation and atmospheric circulation

Titan's northern high latitudes host many large hydrocarbon lakes. Like water lakes on Earth, Titan's lakes are constantly subject to evaporation. This process strongly affects the atmospheric methane abundance, the atmospheric temperature, the lake mixed layer temperature, and the local wind circulation. In this work we use a 2D atmospheric mesoscale model coupled to a slab lake model to investigate the effect of solar and infrared radiation on the exchange of energy and methane between Titan's lakes and atmosphere. The magnitude of solar radiation reaching the surface of Titan through its thick atmosphere is only a few $Wm^{-2}$. However, we find that this small energy input is important and is comparable in absolute magnitude to the latent and sensible heat fluxes, as suggested in the prior study by Rafkin and Soto (2020). The implementation of a gray radiative scheme in the model confirms the importance of radiation when studying lakes at the surface of Titan. Solar and infrared radiation change the energy balance of the system leading to an enhancement of the methane evaporation rate, an increase of the equilibrium lake temperature almost completely determined by its environment (humidity, insolation, and background wind), and a strengthening of the local sea breeze, which undergoes diurnal variations. The sea breeze efficiently transports methane vapor horizontally, from the lake to the land, and vertically due to rising motion along the sea breeze front and due to radiation-induced turbulence over the land.

astro-ph.EP↗

arXiv2021

Seasonal Variability of the Daytime and Nighttime Atmospheric Turbulence Experienced by InSight on Mars

The InSight mission, featuring continuous high-frequency high-sensitivity pressure measurements, is in ideal position to study the active atmospheric turbulence of Mars. Data acquired during 1.25 Martian year allows us to study the seasonal evolution of turbulence and its diurnal cycle. We investigate vortices (abrupt pressure drops), local turbulence (frequency range 0.01-2 Hz) and non-local turbulence often caused by convection cells and plumes (frequency range 0.002-0.01 Hz). Contrary to non-local turbulence, local turbulence is strongly sensitive at all local times and seasons to the ambient wind. We report many remarkable events with the arrival of northern autumn at the InSight landing site: a spectacular burst of daytime vortices, the appearance of nighttime vortices, and the development of nighttime local turbulence as intense as its daytime counterpart. Nighttime turbulence at this dusty season appears as a result of the combination of a stronger low-level jet, producing shear-driven turbulence, and a weaker stability.

astro-ph.EP↗

arXiv2021

N2-H2 capacitively coupled radio-frequency discharges at low pressure. Part I. Experimental results: effect of the H2 amount on electrons, positive ions and ammonia formation

The mixing of N2 with H2 leads to very different plasmas from pure N2 and H2 plasma discharges. Numerous issues are therefore raised involving the processes leading to ammonia (NH3) formation. The aim of this work is to better characterize capacitively-coupled radiofrequency plasma discharges in N2 with few percents of H2 (up to 5 pct), at low pressure (0.3 to 1 mbar) and low coupled power (3 to 13 W). Both experimental measurements and numerical simulations are performed. For clarity, we separated the results in two complementary parts. The actual one (first part), presents the details on the experimental measurements, while the second focuses on the simulation, a hybrid model combining a 2D fluid module and a 0D kinetic module. Electron density is measured by a resonant cavity method. It varies from 0.4 to 5e9 cm-3, corresponding to ionization degrees from 2e-8 to 4e-7. Ammonia density is quantified by combining IR absorption and mass spectrometry. It increases linearly with the amount of H2 (up to 3e13 cm-3 at 5 pct H2). On the contrary, it is constant with pressure, which suggests the dominance of surface processes on the formation of ammonia. Positive ions are measured by mass spectrometry. Nitrogen-bearing ions are hydrogenated by the injection of H2, N2H+ being the major ion as soon as the amount of H2 is larger than 1 pct. The increase of pressure leads to an increase of secondary ions formed by ion (or radical) - neutral collisions (ex: N2H+, NH4+, H3+), while an increase of the coupled power favours ions formed by direct ionization (ex: N2+, NH3+, H2+).

physics.plasm-ph↗

arXiv2021

N2-H2 capacitively coupled radio-frequency discharges at low pressure. Part II. Modelling results: the relevance of plasma-surface interaction

In this work, we present the results of simulations carried out for N2-H2 capacitively coupled radio-frequency discharges, running at low pressure (0.3-0.9 mbar), low power (5-20 W), and for amounts of H2 up to 5 pct. Simulations are performed using a hybrid code that couples a two-dimensional time-dependent fluid module, describing the dynamics of the charged particles in the discharge, to a zero-dimensional kinetic module, that solves the Boltzmann equation and describes the production and destruction of neutral species. The model accounts for the production of several vibrationally and electronic excited states, and contains a detailed surface chemistry that includes recombination processes and the production of NHx molecules. The results obtained highlight the relevance of the interactions between plasma and surface, given the role of the secondary electron emission in the electrical parameters of the discharge and the critical importance of the surface production of ammonia to the neutral and ionic chemistry of the discharge.

physics.plasm-ph↗

arXiv2020

Interaction dust-plasma in Titan's ionosphere: an experimental simulation of aerosols erosion

Organic aerosols accumulated in Titan's orange haze start forming in its ionosphere. This upper part of the atmosphere is highly reactive and complex ion chemistry takes place at altitudes from 1200 to 900 km. The ionosphere is a nitrogen plasma with a few percent of methane and hydrogen. Carbon from methane enables the formation of macromolecules with long organic chains, finally leading to the organic aerosols. On the other hand, we suspect that hydrogen and the protonated ions have a different erosive effect on the aerosols. Here we experimentally studied the effect of hydrogen and protonated species on organic aerosols. Analogues of Titan's aerosols were formed in a CCP RF plasma discharge in 95% N2 and 5% CH4. Thereafter, the aerosols were exposed to a DC plasma in 99% N2 and 1% H2. Samples were analysed by scanning electron microscopy and in situ infrared transmission spectroscopy. Two pellet techniques - KBr pressed pellets and thin metallic grids - were compared to confirm that modifications seen are not due to the material used to make the pellet. We observed that the spherical aerosols of ~500 nm in diameter were eroded under N2-H2 plasma exposure, with the formation of holes of ~10 nm at their surface. Aerosols were globally removed from the pellet by the plasma. IR spectra showed a faster disappearance of isonitriles and/or carbo-diimides compared to the global band of nitriles. The opposite effect was seen with beta-unsaturated nitriles and/or cyanamides. Double bonds as C=C and C=N were more affected than amines and C-H bonds. N-H and C-H absorption bands kept a similar ratio in intensity and their shape did not vary. Therefore, it seems that carbon and hydrogen play opposite roles in Titan's ionosphere: the carbon from methane lead to organic growth while hydrogen and protonated species erode the aerosols and react preferentially with unsaturated chemical functions.

astro-ph.EP↗