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Ayako Yamamoto

Publications and source records attributed to Ayako Yamamoto.

12 recordsLinked to original sources
arXiv2026

Charge-Transfer Electronic Structure of NiX$_2$ (X = S, Se)

We investigate the electronic structures of NiS$_2$ and NiSe$_2$ using density functional theory combined with dynamical mean-field theory (DFT+DMFT). A realistic electronic structure within DFT+DMFT was determined by optimizing the double-counting correction to reproduce experimental valence-band photoemission spectra. The validity of the present model is further confirmed by its successful description of the Ni 2$p$ core-level photoemission and Ni $L$-edge x-ray absorption spectra of NiS$_2$. Our results reveal a smaller charge-transfer energy than previously assumed, resulting in substantial ligand-to-Ni charge transfer and a reduced Ni local moment. We clarify how the relative position and interaction between the Ni upper Hubbard band and the antibonding chalcogen-dimer states shape the evolution of the low-energy electronic structure across the NiS$_{2-x}$Se$_x$ series.

cond-mat.mtrl-sci↗
arXiv2026

Disentangling peripheral hearing loss from central and cognitive effects on speech intelligibility in older adults

Age-related hearing loss (HL) reduces speech intelligibility (SI) in older adults (OAs). However, deficits in central and cognitive processing also substantially impact SI. Understanding these contributions is essential for explaining individual differences and developing effective assistive hearing strategies. This study presents a framework that distinguishes peripheral HL from central and cognitive influences on SI. This framework uses the Wakayama University Hearing Impairment Simulator (WHIS), and the Gammachirp Envelope Similarity Index (GESI), an objective measure of intelligibility. First, speech-in-noise tests were conducted with young, normal-hearing listeners (YNHs) using WHIS to simulate the audiogram of a target OA. The target OA achieved SI scores comparable to or higher than those of YNHs with simulated HL, suggesting contributions beyond peripheral hearing function. Then, GESI was used to predict SI scores for YNHs and OAs across different hearing levels. The prediction accuracy was comparable for both groups. Interestingly, many OAs' subjective SI scores were higher than those predicted using parameters derived from YNHs' experiments. This finding is inconsistent with previous research indicating that speech perception ability declines with age. This issue will be discussed. There was no significant correlation between the average hearing levels and the residual differences between the subjective and predicted SI scores. This suggests that GESI effectively absorbed the effects of peripheral HL. Thus, the proposed framework may facilitate systematic examination and comparison of central and cognitive factors beyond peripheral HL among individual YNHs and OAs with and without HL.

eess.AS↗
arXiv2025

Predicting speech intelligibility in older adults for speech enhancement using the Gammachirp Envelope Similarity Index, GESI

We propose an objective intelligibility measure (OIM), called the Gammachirp Envelope Similarity Index (GESI), that can predict speech intelligibility (SI) in older adults. GESI is a bottom-up model based on psychoacoustic knowledge from the peripheral to the central auditory system. It computes the single SI metric using the gammachirp filterbank (GCFB), the modulation filterbank, and the extended cosine similarity measure. It takes into account not only the hearing level represented in the audiogram, but also the temporal processing characteristics captured by the temporal modulation transfer function (TMTF). To evaluate performance, SI experiments were conducted with older adults of various hearing levels using speech-in-noise with ideal speech enhancement on familiarity-controlled Japanese words. The prediction performance was compared with HASPIw2, which was developed for keyword SI prediction. The results showed that GESI predicted the subjective SI scores more accurately than HASPIw2. GESI was also found to be at least as effective as, if not more effective than, HASPIv2 in predicting English sentence-level SI. The effect of introducing TMTF into the GESI algorithm was insignificant, suggesting that TMTF measurements and models are not yet mature. Therefore, it may be necessary to perform TMTF measurements with bandpass noise and to improve the incorporation of temporal characteristics into the model.

eess.AS↗
arXiv2024

GESI: Gammachirp Envelope Similarity Index for Predicting Intelligibility of Simulated Hearing Loss Sounds

We propose an objective intelligibility measure (OIM), called the Gammachirp Envelope Similarity Index (GESI), which can predict the speech intelligibility (SI) of simulated hearing loss (HL) sounds for normal hearing (NH) listeners. GESI is an intrusive method that computes the SI metric using the gammachirp filterbank (GCFB), the modulation filterbank, and the extended cosine similarity measure. The unique features of GESI are that i) it reflects the hearing impaired (HI) listener's HL that appears in the audiogram and is caused by active and passive cochlear dysfunction, ii) it provides a single goodness metric, as in the widely used STOI and ESTOI, that can be used immediately to evaluate SE algorithms, and iii) it provides a simple control parameter to accept the level asymmetry of the reference and test sounds and to deal with individual listening conditions and environments. We evaluated GESI and the conventional OIMs, STOI, ESTOI, MBSTOI, and HASPI versions 1 and 2 by using four SI experiments on words of male and female speech sounds in both laboratory and remote environments. GESI was shown to outperform the other OIMs in the evaluations. GESI could be used to improve SE algorithms in assistive listening devices for individual HI listeners.

eess.AS↗
arXiv2023

Speech intelligibility of simulated hearing loss sounds and its prediction using the Gammachirp Envelope Similarity Index (GESI)

In the present study, speech intelligibility (SI) experiments were performed using simulated hearing loss (HL) sounds in laboratory and remote environments to clarify the effects of peripheral dysfunction. Noisy speech sounds were processed to simulate the average HL of 70- and 80-year-olds using Wadai Hearing Impairment Simulator (WHIS). These sounds were presented to normal hearing (NH) listeners whose cognitive function could be assumed to be normal. The results showed that the divergence was larger in the remote experiments than in the laboratory ones. However, the remote results could be equalized to the laboratory ones, mostly through data screening using the results of tone pip tests prepared on the experimental web page. In addition, a newly proposed objective intelligibility measure (OIM) called the Gammachirp Envelope Similarity Index (GESI) explained the psychometric functions in the laboratory and remote experiments fairly well. GESI has the potential to explain the SI of HI listeners by properly setting HL parameters.

cs.SD↗
arXiv2022

What is in a Name: Defining -High Entropy- Oxides

High entropy oxides are emerging as an exciting new avenue to design highly tailored functional behaviors that have no traditional counterparts. Study and application of these materials are bringing together scientists and engineers from physics, chemistry, and materials science. The diversity of each of these disciplines comes with perspectives and jargon that may be confusing to those outside of the individual fields, which can result in miscommunication of important aspects of research. In this perspective, we provide examples of research and characterization taken from these different fields to provide a framework for classifying the differences between compositionally complex oxides, high entropy oxides, and entropy stabilized oxides, which is intended to bring a common language to this emerging area. We highlight the critical importance of understanding a materials crystallinity, composition, and mixing length scales in determining its true definition.

cond-mat.mtrl-sci↗
arXiv2022

Effective data screening technique for crowdsourced speech intelligibility experiments: Evaluation with IRM-based speech enhancement

It is essential to perform speech intelligibility (SI) experiments with human listeners in order to evaluate objective intelligibility measures for developing effective speech enhancement and noise reduction algorithms. Recently, crowdsourced remote testing has become a popular means for collecting a massive amount and variety of data at a relatively small cost and in a short time. However, careful data screening is essential for attaining reliable SI data. We performed SI experiments on speech enhanced by an "oracle" ideal ratio mask (IRM) in a well-controlled laboratory and in crowdsourced remote environments that could not be controlled directly. We introduced simple tone pip tests, in which participants were asked to report the number of audible tone pips, to estimate their listening levels above audible thresholds. The tone pip tests were very effective for data screening to reduce the variability of crowdsourced remote results so that the laboratory results would become similar. The results also demonstrated the SI of an oracle IRM, giving us the upper limit of the mask-based single-channel speech enhancement.

cs.SD↗
arXiv2021

Comparison of remote experiments using crowdsourcing and laboratory experiments on speech intelligibility

Many subjective experiments have been performed to develop objective speech intelligibility measures, but the novel coronavirus outbreak has made it very difficult to conduct experiments in a laboratory. One solution is to perform remote testing using crowdsourcing; however, because we cannot control the listening conditions, it is unclear whether the results are entirely reliable. In this study, we compared speech intelligibility scores obtained in remote and laboratory experiments. The results showed that the mean and standard deviation (SD) of the remote experiments' speech reception threshold (SRT) were higher than those of the laboratory experiments. However, the variance in the SRTs across the speech-enhancement conditions revealed similarities, implying that remote testing results may be as useful as laboratory experiments to develop an objective measure. We also show that the practice session scores correlate with the SRT values. This is a priori information before performing the main tests and would be useful for data screening to reduce the variability of the SRT distribution.

eess.AS↗
arXiv2011

Metal-Insulator Transition and Magnetic Order in the Pyrochlore Oxide Hg2Ru2O7

We report results of NMR experiments on the ruthenium oxide Hg2Ru2O7 with the pyrochlore structure, which exhibits a metal-insulator transition at TMI = 107 K. In the metallic phase above TMI, the nuclear spin-lattice relaxation rate 1/T1 and the Knight shift at the Hg sites follow the Korringa relation, indicating the absence of substantial spatial spin correlation. At low temperatures in the insulating phase, 99,101Ru-NMR signals are observed at zero magnetic field, providing evidence for a commensurate antiferromagnetic order. The estimated ordered moment is about 1 muB per Ru, much smaller than 3 muB expected for the ionic (4d)3plus configuration of Ru5plus. Thus the localized spin models are not appropriate for the insulating phase of Hg2Ru2O7. We also discuss possible antiferromagnetic spin structures.

cond-mat.str-el↗
arXiv2007

Metal-insulator Transition in a Pyrochlore-type Ruthenium oxide, Hg2Ru2O7

A new pyrochlore ruthenium oxide, Hg2Ru2O7 was synthesized under a high pressure of 6 GPa. In contrast to the extensively studied Ru4+ oxides, this compound possesses a novel Ru5+ valence state, corresponding to a half-filled t_2g_3 electron configuration. Hg2Ru2O7 exhibits a first order metal-insulator transition at 107 K, accompanied by a structural transition from cubic to lower symmetry. The behavior of the magnetic susceptibility suggests the possible formation of a spin singlet in the insulating low temperature state.

cond-mat.str-el↗
arXiv2003

Carbon-substituted MgB2 single crystals

Carbon-substituted MgB2 single crystals, Mg(B_1-xC_x)_2 of 0.3-1.0 mm size were grown for x=0.02-0.15 by a high-pressure technique. The doping dependence of lattice constants studied in a range of x=0.0-0.2 shows a monotonic decrease in a, while the c parameter remains almost invariant. Using X-ray diffraction and Auger electron spectroscopy, the solubility limit of C in MgB2 was estimated to be about 15(+/-)1%,which is substantially larger than that reported for the polycrystalline samples synthesized by encapsulation techniques. Measurements of temperature dependence of magnetization and resistivity showed a dramatic decrease in Tc with C-substitution, followed by complete suppression of superconductivity for x>0.125. Resistivity measurements in magnetic fields parallel and perpendicular to the basal plane of the crystals showed a nearly isotropic state in the heavily-doped crystals (x>0.1).

cond-mat.supr-con↗