arXiv subjects

B. J. McCall

Publications and source records attributed to B. J. McCall.

13 recordsLinked to original sources

arXiv2012

The Low-Temperature Nuclear Spin Equilibrium of H3+ in Collisions with H2

Recent observations of H2 and H3+ in diffuse interstellar sightlines revealed a difference in the nuclear spin excitation temperatures of the two species. This discrepancy comes as a surprise, as H3+ and H2 should undergo frequent thermalizing collisions in molecular clouds. Non-thermal behavior of the fundamental H3+ / H2 collision system at low temperatures was considered as a possible cause for the observed irregular populations. Here, we present measurements of the steady-state ortho/para ratio of H3+ in collisions with H2 molecules in a temperature-variable radiofrequency ion trap between 45-100 K. The experimental results are close to the expected thermal outcome and they agree very well with a previous micro-canonical model. We briefly discuss the implications of the experimental results for the chemistry of the diffuse interstellar medium.

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arXiv2011

Absorption Line Survey of H3+ toward the Galactic Center Sources III. Extent of the Warm and Diffuse Clouds

We present follow-up observations to those of Geballe & Oka (2010), who found high column densities of H3+ ~100 pc off of the Galactic center (GC) on the lines of sight to 2MASS J17432173-2951430 (J1743) and 2MASS J17470898-2829561 (J1747). The wavelength coverages on these sightlines have been extended in order to observe two key transitions of H3+, R(3,3)l and R(2,2)l, that constrain the temperatures and densities of the environments. The profiles of the H3+ R(3,3)l line, which is due only to gas in the GC, closely matches the differences between the H3+ R(1,1)l and CO line profiles, just as it does for previously studied sightlines in the GC. Absorption in the R(2,2)l line of H3+ is present in J1747 at velocities between -60 and +100 km/s. This is the second clear detection of this line in the interstellar medium after GCIRS 3 in the Central Cluster. The temperature of the absorbing gas in this velocity range is 350 K, significantly warmer than in the diffuse clouds in other parts of the Central Molecular Zone. This indicates that the absorbing gas is local to Sgr B molecular cloud complex. The warm and diffuse gas revealed by Oka et al. (2005) apparently extends to ~100 pc, but there is a hint that its temperature is somewhat lower in the line of sight to J1743 than elsewhere in the GC. The observation of H3+ toward J1747 is compared with the recent Herschel observation of H2O+ toward Sgr B2 and their chemical relationship and remarkably similar velocity profiles are discussed.

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arXiv2009

Studies of the Diffuse Interstellar Bands. III. HD 183143

Echelle spectra of HD 183143 [B7Iae, E(B-V) = 1.27] were obtained on three nights, at a resolving power R = 38,000 and with a signal-to-noise ratio ~1000 at 6400 A in the final, combined spectrum. A catalog is presented of 414 diffuse interstellar bands (DIBs) measured between 3900 and 8100 A in this spectrum. The central wavelengths, the widths (FWHM), and the equivalent widths of nearly all of the bands are tabulated, along with the minimum uncertainties in the latter. Among the 414 bands, 135 (or 33%) were not reported in four previous, modern surveys of the DIBs in the spectra of various stars, including HD 183143. The principal result of this study is that the great majority of the bands in the catalog are very weak and fairly narrow. Typical equivalent widths amount to a few mA, and the bandwidths (FWHM) are most often near 0.7 A. No preferred wavenumber spacings among the 414 bands are identified which could provide clues to the identities of the large molecules thought to cause the DIBs. At generally comparable detection limits in both spectra, the population of DIBs observed toward HD 183143 is systematically redder, broader, and stronger than that seen toward HD 204827 (Paper II). In addition, interstellar lines of C2 molecules have not been detected toward HD 183143, while a very high value of N(C2)/E(B-V) is observed toward HD 204827. Therefore, either the abundances of the large molecules presumed to give rise to the DIBs, or the physical conditions in the absorbing clouds, or both, must differ significantly between the two cases.

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arXiv2008

Absorption Line Survey of H3+ toward the Galactic Center Sources II. Eight Infrared Sources within 30 pc of the Galactic Center

Infrared absorption lines of H3+, including the metastable R(3,3)l line, have been observed toward eight bright infrared sources associated with hot and massive stars located in and between the Galactic Center Cluster and the Quintuplet Cluster 30 pc to the east. The absorption lines with high velocity dispersion arise in the Galaxy's Central Molecular Zone (CMZ) as well as in foreground spiral arms. The temperature and density of the gas in the CMZ, as determined from the relative strengths of the H3+ lines, are T=200-300K and n=50-200cm^-3. The detection of high column densities of H3+ toward all eight stars implies that this warm and diffuse gaseous environment is widespread in the CMZ. The products of the ionization rate and path length for these sight lines are 1000 and 10 times higher than in dense and diffuse clouds in the Galactic disk, respectively, indicating that the ionization rate, zeta, is not less than 10^-15 s^-1 and that L is at least on the order of 50 pc. The warm and diffuse gas is an important component of the CMZ, in addition to the three previously known gaseous environments: (1) cold molecular clouds observed by radio emission of CO and other molecules, (2) hot (T=10^4-10^6K) and highly ionized diffuse gas (n_e=10-100cm^-3) seen in radio recombination lines, far infrared atomic lines, and radio-wave scattering, and (3) ultra-hot (T=10^7-10^8K) X-ray emitting plasma. Its prevalence significantly changes the understanding of the environment of the CMZ. The sight line toward GC IRS 3 is unique in showing an additional H3+ absorption component, which is interpreted as due to either a cloud associated with circumnuclear disk or the "50 km s^-1 cloud" known from radio observations. An infrared pumping scheme is examined as a mechanism to populate the (3,3) metastable level in this cloud.

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arXiv2008

A Catalog of Diffuse Interstellar Bands in the Spectrum of HD 204827

Echelle spectra of the double-lined spectroscopic binary HD 204827 were obtained on five nights, at a resolving power R = 38,000 and with a S/N ratio = 750 near 6000 A in the final, combined spectrum. The stars show E(B-V) = 1.11 and spectral types near O9.5V and B0.5III. A catalog is presented of 380 diffuse interstellar bands (DIBs) measured between 3900 and 8100 A in the stars' spectrum. The central wavelengths, the widths (FWHM), and the equivalent widths of nearly all of the bands are tabulated, along with the minimum uncertainties in the latter. The reliable removal of very weak stellar lines from the catalog, and of some stellar lines from the less severe blends with DIBs, is made generally easy by the highly variable radial velocities of both stars. The principal result of this investigation is that the great majority of the bands in the catalog are very weak and relatively narrow. Typical equivalent widths amount to a few mA, and the band widths (FWHM) are most often near 0.55 A. Therefore, most of these DIBs can be detected only in spectra obtained at a resolving power and a S/N ratio at least comparable to those used here. In addition, the anomalous interstellar reddening and the very high value of the ratio N(C2)/E(B-V) seen toward HD 204827 indicate that the physical conditions in one or more of the several interstellar clouds seen in this direction differ significantly from those found toward the prototypical DIB target HD 183143, for example. Probably primarily for these reasons, 113 of the 380 bands, or 30%, were not detected in four previous, modern surveys of the DIBs seen in the spectra of stars other than HD 204827. Both the tabulated data for the DIBs and a plot of our spectrum of HD 204827 are available online at http://dibdata.org

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arXiv2006

The Interstellar Medium of IRAS 08572+3915 NW: H3+ and Warm High Velocity CO

We confirm the first detection of the molecular ion H3+ in an extragalactic object, the highly obscured ultraluminous galaxy IRAS 08572+3915 NW. We also have detected absorption lines of the fundamental band of CO in this galaxy. The CO absorption consists of a cold component close to the systemic velocity and warm, highly blueshifted and redshifted components. The warm blueshifted component is remarkably strong and broad and extends at least to -350 km/s. Some analogies can be drawn between the H3+ and cold CO in IRAS08572+3915 NW and the same species seen toward the Galactic center. The profiles of the warm CO components are not those expected from a dusty torus of the type thought to obscure active galactic nuclei. They are probably formed close to the dust continuum surface near the buried and active nucleus and are probably associated with an unusual and energetic event there.

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arXiv2005

Hot and Diffuse Clouds near the Galactic Center Probed by Metastable H3+

Using an absorption line from the metastable (J, K) = (3, 3) level of H3+ together with other lines of H3+ and CO observed along several sightlines, we have discovered a vast amount of high temperature (T ~ 250 K) and low density (n ~ 100 cm-3) gas with a large velocity dispersion in the Central Molecular Zone (CMZ) of the Galaxy, i.e., within 200 pc of the center. Approximately three fourths of the H3+ along the line of sight to the brightest source we observed, the Quintuplet object GCS 3-2, is inferred to be in the CMZ, with the remaining H3+ located in intervening spiral arms. About half of H3+ in the CMZ has velocities near ~ - 100 km s-1 indicating that it is associated with the 180 pc radius Expanding Molecular Ring which approximately forms outer boundary of the CMZ. The other half, with velocities of ~ - 50 km s-1 and ~ 0 km s-1, is probably closer to the center. CO is not very abundant in those clouds. Hot and diffuse gas in which the (3, 3) level is populated was not detected toward several dense clouds and diffuse clouds in the Galactic disk where large column densities of colder H3+ have been reported previously. Thus the newly discovered environment appears to be unique to the CMZ. The large observed H3+ column densities in the CMZ suggests an ionization rate much higher than in the diffuse interstellar medium in the Galactic disk. Our finding that the H3+ in the CMZ is almost entirely in diffuse clouds indicates that the reported volume filling factor (f ≥ 0.1) for n ≥ 104 cm-3 clouds in the CMZ is an overestimate by at least an order of magnitude.

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arXiv2005

Search for H3+ in HD141569A

A search for H3+ line emission, reported to have been detected toward the young star HD 141569A and possibly originating in a clump of planet-forming gas orbiting the star, has yielded negative results. Observations made at the United Kingdom Infrared Telescope and at the Subaru Telescope during 2001-2005 covered 11 major transitions of H3+ from 3.42 to 3.99 um. No H3+ emission lines were detected; one marginal detection at 3.9855 um in June 2002 was not confirmed in later spectra. The upper limits to the line strengths are significantly lower than the previously reported detections. Supplemental slit-scanning spectroscopy using adaptive optics was performed within 0.38 of HD 141569A to search for extended emission from H3+, but no emission was detected. We compare our upper limit to the luminosity in H3+ from HD 141569A with that possible from a gas giant protoplanet and also from a jovian mass exoplanet in close orbit about its central star.

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arXiv2003

Enhanced cosmic-ray flux toward zeta Persei inferred from laboratory study of H3+ - e- recombination rate

The H3+ molecular ion plays a fundamental role in interstellar chemistry, as it initiates a network of chemical reactions that produce many interstellar molecules. In dense clouds, the H3+ abundance is understood using a simple chemical model, from which observations of H3+ yield valuable estimates of cloud path length, density, and temperature. On the other hand, observations of diffuse clouds have suggested that H3+ is considerably more abundant than expected from the chemical models. However, diffuse cloud models have been hampered by the uncertain values of three key parameters: the rate of H3+ destruction by electrons, the electron fraction, and the cosmic-ray ionisation rate. Here we report a direct experimental measurement of the H3+ destruction rate under nearly interstellar conditions. We also report the observation of H3+ in a diffuse cloud (towards zeta Persei) where the electron fraction is already known. Taken together, these results allow us to derive the value of the third uncertain model parameter: we find that the cosmic-ray ionisation rate in this sightline is forty times faster than previously assumed. If such a high cosmic-ray flux is indeed ubiquitous in diffuse clouds, the discrepancy between chemical models and the previous observations of H3+ can be resolved.

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arXiv2002

Absorption Line Survey of H3+ toward the Galactic Center Sources I. GCS 3-2 and GC IRS3

We present high-resolution (R = 20000) spectroscopy of H3+ absorption toward the luminous Galactic center sources GCS 3-2 and GC IRS 3. With the efficient wavelength coverage afforded by Subaru IRCS, six absorption lines of H3+ have been detected in each source from 3.5 to 4.0 um, three of which are new. In particular the 3.543 um absorption line of the R(3, 3)^l transition arising from the metastable (J, K) = (3, 3) state has been tentatively detected for the first time in the interstellar medium, where previous observations of H3+ had been limited to absorption lines from the lowest levels: (J, K) = (1, 0) of ortho-H3+ and (1, 1) of para-H3+. The H3+ absorption toward the Galactic center takes place in dense and diffuse clouds along the line of sight as well as the molecular complex close to the Galactic nucleus. At least four kinematic components are found in the H3+ absorption lines. We suggest identifications of the velocity components with those of HI, CO, and H2CO previously reported from radio and infrared observations. H3+ components with velocities that match those of weak and sharp CO and H2CO lines are attributed to diffuse clouds. Our observation has revealed a striking difference between the absorption profiles of H3+ and CO, demonstrating that the spectroscopy of H3+ provides information complementary to that obtained from CO spectroscopy. The tentative detection of the R(3, 3)^l line and the non-detection of spectral lines from other J > 1 levels provide observational evidence for the metastability of the (3, 3) level, which is theoretically expected. This suggests that other metastable J = K levels with higher J may also be populated.

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arXiv2002

Unusually Weak Diffuse Interstellar Bands toward HD 62542

As part of an extensive survey of diffuse interstellar bands (DIBs), we have obtained optical spectra of the moderately reddened B5V star HD 62542, which is known to have an unusual UV extinction curve of the type usually identified with dark clouds. The typically strongest of the commonly catalogued DIBs covered by the spectra -- those at 5780, 5797, 6270, 6284, and 6614 A -- are essentially absent in this line of sight, in marked contrast with other lines of sight of similar reddening. We compare the HD 62542 line of sight with others exhibiting a range of extinction properties and molecular abundances and interpret the weakness of the DIBs as an extreme case of deficient DIB formation in a dense cloud whose more diffuse outer layers have been stripped away. We comment on the challenges these observations pose for identifying the carriers of the diffuse bands.

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arXiv2001

Observations of H3+ in the Diffuse Interstellar Medium

Surprisingly large column densities of H3+ have been detected using infrared absorption spectroscopy in seven diffuse cloud sightlines (Cygnus OB2 12, Cygnus OB2 5, HD 183143, HD 20041, WR 104, WR 118, and WR 121), demonstrating that H3+ is ubiquitous in the diffuse interstellar medium. Using the standard model of diffuse cloud chemistry, our H3+ column densities imply unreasonably long path lengths (~1 kpc) and low densities (~3 cm^-3). Complimentary millimeter-wave, infrared, and visible observations of related species suggest that the chemical model is incorrect and that the number density of H3+ must be increased by one to two orders of magnitude. Possible solutions include a reduced electron fraction, an enhanced rate of H2 ionization, and/or a smaller value of the H3+ dissociative recombination rate constant than implied by laboratory experiments.

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arXiv2001

Rejection of the C7- Diffuse Interstellar Band Hypothesis

Using the new high resolution (~ 8 km/s) echelle spectrograph on the 3.5-m telescope at the Apache Point Observatory, we have begun a high sensitivity survey of the diffuse interstellar bands in a large sample of reddened stars. Now that we are two years into this long-term survey, our sample includes over 20 reddened stars which show at least one of the DIBs that had been suggested to be caused by C7-, based on the gas phase measurement of the C7- spectrum by J. P. Maier's group. The high quality astronomical data from this larger sample of stars, along with the spectroscopic constants from the new laboratory work recently reported by Maier's group, have enabled us to examine more carefully the agreement between C7- and the DIBs. We find that none of the C7- bands matches the DIBs in wavelength or expected profile. One of the DIBs (lambda5748) attributed to C7- is actually a stellar line. The two strongest DIBs attributed to C7- (lambda 6270 and lambda4964) do not vary together in strength, indicating that they do not share the same carrier. On the whole, we find no evidence supporting the hypothesis that C7- is a carrier of the diffuse interstellar bands.

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