Basile Husquinet | Searcharxiv

arXiv2026

Using astrochemical models to simulate reactivity experiments on cold surfaces

The development of molecular complexity during stellar and planetary formation owes much to the interaction of gas and dust. When the first astrochemical models including solid-state chemistry were developed more than forty years ago, data from dedicated laboratory experiments were limited. Since then, many groups have developed specific experimental setups to address this issue, but astrochemical models have rarely been directly confronted with these new results. We want to demonstrate whether it is possible to use rate-equation-type astrochemical models developed in the context of the Interstellar Medium to compare them with laboratory astrophysics experiments. In this work, we use the case of low-temperature hydrogenation of CO, which is known to lead to methanol, among other molecules. We carried out 9 experiments, varying the experimental parameters such as temperature and dose. We give quantitative results and take care of detailing the vocabulary used in the experiments. We use astrochemical codes, NAUTILUS, pyRate and MONACO, to reproduce our experimental conditions, which requires good control of the change of vocabulary and scales, especially for fluxes and time scales. This work demonstrates that it is possible to use different astrochemical codes to compare modelling results directly with the output of experiments. There are discrepancies between models and experiments, as well as between models, but a fair agreement is achieved. We discuss the possible origin of the differences, which could originate from the chemical network or the difference in the description of physical processes.

astro-ph.GA↗

arXiv2025

Neon is an inhibitor of CO hydrogenation in pre-stellar core conditions

Neon (Ne) is the fifth most abundant element in the Universe. Because it is chemically inert, it has never been considered in astrochemical models that studied molecular evolution. In the cold dark environments of pre-stellar cores, where the temperatures are below 10 K, Ne can condense onto the surface of interstellar grains. We investigated the effect of Ne on the production of formaldehyde (H$_2$CO) and methanol (CH$_3$OH) through carbon monoxide (CO) hydrogenation on different cold surfaces. We highlight its role in conditions corresponding to pre-stellar cores. In an ultra-high vacuum system, we conducted two types of experiments. The first experiment involved the co-deposition of CO and H atoms with or without Ne. The second experiment involved depositing a monolayer of CO and separately a monolayer of Ne (or vice versa), followed by bombarding the layers with hydrogen atoms. Additionally, we used a gas-grain chemical code to simulate a pre-stellar core and determine where Ne can affect the chemistry. The presence of Ne on the surface significantly inhibits CO hydrogenation at temperatures below 12 K. In the co-deposition experiments, we observed a 38% decrease in the H$_2$CO production at 11 K when the quantity of Ne in the mixture was lower than a monolayer. At 10 K and with one monolayer in the mixture, the production decreased to 77%, and it reached 91% for a few monolayers of Ne in the mixture at 9 K. While the decrease in CH$_3$OH formation is still notable, it is less pronounced: 43% at 11 K, 61% at 10 K, and 77% at 9 K. Experiments with stacked layers revealed that the CO layer decay varies slightly when the Ne layer is positioned above or below it. This observation indicates that Ne and CO create a mixture in which Ne can diffuse and stabilize at the surface, which isolates CO molecules from the accreting H atoms.

astro-ph.GA↗