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Ben J. Powell

Publications and source records attributed to Ben J. Powell.

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Higgs gap modes in superconducting circuit quantisation

We extend a recently developed projective circuit quantisation approach to incorporate superconducting Higgs modes associated to gap dynamics. This approach starts from a microscopic fermionic Hamiltonian for mesoscopic superconductors, and projects the system onto its low-energy "BCS" Hilbert space. We derive analytical results for the superconducting Higgs mass, "spring" constant, and oscillation frequency of the gap dynamics, which we validate numerically. We compute anharmonic corrections to the Higgs frequency for higher excitations of small superconducting islands, and compare our results to previous long-wavelength calculations.

cond-mat.supr-con

Fingerprints of collective magnetic excitations in inelastic electron tunneling spectroscopy

Spin-flip inelastic electron tunneling spectroscopy allows magnetic materials to be probed at the single-atom level via scanning tunneling microscopy. Previously, the local spectral weight of spin excitations of small systems has been deduced from discrete steps in the differential conductance. However, this is not viable for large systems. We show that the local spin density of states can be measured via the double differential conductance. This contrasts with elastic measurements where the local density of electronic states is deduced from the differential conductance. We study the tunneling currents of the spin-1/2 and -1 Heisenberg chains and propose a method to probe zero-frequency modes.

cond-mat.str-el

Circuit Quantisation from First Principles

Superconducting circuit quantisation conventionally starts from classical Euler-Lagrange circuit equations-of-motion. Invoking the correspondence principle yields a canonically quantised circuit description of circuit dynamics over a bosonic Hilbert space. This process has been very successful for describing experiments, but implicitly starts from the classical Ginsberg-Landau (GL) mean field theory for the circuit. Here we employ a different approach which starts from a microscopic fermionic Hamiltonian for interacting electrons, whose ground space is described by the Bardeen-Cooper-Schrieffer (BCS) many-body wavefuction that underpins conventional superconductivity. We introduce the BCS ground-space as a subspace of the full fermionic Hilbert space, and show that projecting the electronic Hamiltonian onto this subspace yields the standard Hamiltonian terms for Josephson junctions, capacitors and inductors, from which standard quantised circuit models follow. Importantly, this approach does not assume a spontaneously broken symmetry, which is important for quantised circuits that support superpositions of phases, and the phase-charge canonical commutation relations are derived from the underlying fermionic commutation properties, rather than imposed. By expanding the projective subspace, this approach can be extended to describe phenomena outside the BCS ground space, including quasiparticle excitations.

quant-ph

Competing quantum effects in spin crossover chains: spin-orbit coupling, magnetic exchange, and elastic interactions

We derive and study a model of square planar, d8 spin crossover materials that treats elastic, magnetic and spin-orbit interactions on an equal footing. For 1D chains density matrix renormalization group calculations show that the competition between these interactions leads to six different phases. For weak spin-orbit coupling (SOC) and large antiferromagnetic interactions we find a symmetry protected topological (SPT) Haldane phase. This is equivalent to the Haldane-large-D phase transition driven by single ion anisotropy(D) in the spin-one Heisenberg model. For strong SOC the Sz=+-1 HS states are high-energy excitations. Thus, the system can be understood as a transverse field Ising model with the SOC playing the role of the transverse field. Consistent with this, we find a quantum phase transition between the THS phase and a quantum disordered (QD) phase. However, if the magnetic coupling is non-zero or the HS and LS states of a single molecule are non-degenerate the Z2 (Ising) symmetry is broken and the phase transition becomes a crossover. Thus, the QD phase and the THS phases are adiabatically connected, as, equivalently, are the large-D phase of the spin-one Heisenberg model and the quantum disordered phase of the transverse field Ising model. We also find a ferroelastic LS phase, and antierroelastic phase, with alternating HS and LS complexes, and a dimer phase, which results from the competition between antiferromagnetic and antiferroelastic interactions.

cond-mat.str-el

Local gate control of Mott metal-insulator transition in a 2D metal-organic framework

Electron-electron interactions in materials lead to exotic many-body quantum phenomena including Mott metal-insulator transitions (MITs), magnetism, quantum spin liquids, and superconductivity. These phases depend on electronic band occupation and can be controlled via the chemical potential. Flat bands in two-dimensional (2D) and layered materials with a kagome lattice enhance electronic correlations. Although theoretically predicted, correlated-electron Mott insulating phases in monolayer 2D metal-organic frameworks (MOFs) with a kagome structure have not yet been realised experimentally. Here, we synthesise a 2D kagome MOF on a 2D insulator. Scanning tunnelling microscopy (STM) and spectroscopy reveal a MOF electronic energy gap of ~200 meV, consistent with dynamical mean field theory predictions of a Mott insulator. Combining template-induced (via work function variations of the substrate) and STM probe-induced gating, we locally tune the electron population of the MOF kagome bands and induce Mott MITs. These findings enable technologies based on electrostatic control of many-body quantum phases in 2D MOFs.

cond-mat.str-el

Topological superconductivity from doping a triplet quantum spin liquid in a flat band system

We explore superconductivity in strongly interacting electrons on a decorated honeycomb lattice (DHL). An easy-plane ferromagnetic interaction arises from spin-orbit coupling in the Mott insulating phase, which favors a triplet resonance valence bond spin liquid state. Hole doping leads to partial occupation of a flat band and to triplet superconductivity. The order parameter is highly sensitive to the doping level and the interaction parameters, with $p+ip$, $f$ and $p+f$ superconductivity found, as the flat band leads to instabilities in multiple channels. Typically, first order transitions separate different superconducting phases, but a second order transition separates two time reversal symmetry breaking $p+ip$ phases with different Chern numbers ($ν=0$ and 1). The Majorana edge modes in the topological ($ν=1$) superconductor are almost localized due to the strong electronic correlations in a system with a flat band at the Fermi level. This suggests that these modes could be useful for topological quantum computing. The `hybrid' $p+f$ state does not require two phase transitions as temperature is lowered. This is because the symmetry of the model is lowered in the $p$-wave phase, allowing arbitrary admixtures of $f$-wave basis functions as overtones. We show that the multiple sites per unit cell of the DHL, and hence multiple bands near the Fermi energy, lead to very different nodal structures in real and reciprocal space. We emphasize that this should be a generic feature of multi-site/multi-band superconductors.

cond-mat.supr-con

Unconventional superconductivity near a flat band in organic and organometallic materials

We study electron correlation driven superconductivity on a decorated honeycomb lattice (DHL), which has a low-energy flat band. On doping, we find singlet superconductivity with extended-s, extended-d and f-wave symmetry mediated by magnetic exchange. f-wave singlet pairing is enabled by the lattice decoration. The critical temperature is predicted to be significantly higher than on similar lattices lacking flat bands. We discuss how high-temperature superconductivity could be realized in the DHL materials such as Rb3TT. 2 H2O and Mo3S7(dmit)3.

cond-mat.supr-con

Emergent particles and gauge fields in quantum matter

I give a pedagogical introduction to some of the many particles and gauge fields that can emerge in correlated matter. The standard model of materials is built on Landau's foundational principles: adiabatic continuity and spontaneous symmetry breaking. These ideas lead to quasiparticles that inherit their quantum numbers from fundamental particles, Nambu-Goldstone bosons, the Anderson-Higgs mechanism, and topological defects in order parameters. I then describe the modern discovery of physics beyond the standard model. Here, quantum correlations (entanglement) and topology play key roles in defining the properties of matter. This can lead to fractionalised quasiparticles that carry only a fraction of the quantum numbers that define fundamental particles. These particles can have exotic properties: for example Majorana fermions are their own antiparticles, anyons have exchange statistics that are neither bosonic nor fermionic, and magnetic monopoles do not occur in the vacuum. Gauge fields emerge naturally in the description of highly correlated matter and can lead to gauge bosons. Relationships to the standard model of particle physics are discussed.

cond-mat.str-el

Exact mapping from short-ranged harmonic elastic models of spin crossover materials to Ising models with interactions at all length scales

Spin crossover (SCO) materials are reversible molecular switches found in a wide range of transition metal complexes and metal organic frameworks (MOFs). They exhibit diverse spin state orderings and transitions between them. Here we present an exact mapping from harmonic elastic models to Ising-like models with both a short-range Ising interaction that decays with a power law at large distances and a long-range (infinite-range) Husimi-Temperley interaction that is independent of distance. We apply this mapping to a simple model of SCO frameworks. This provides a microscopic justification for an Ising-Husimi-Temperley model description, which has previously only been justified on phenomenological grounds. Elastic frustration is required for non-zero Ising interactions, but whether or not the short-range interactions in the Ising model are geometrically frustrated depends on the ratio of the bulk and shear moduli, or equivalently Poisson's ratio. The long-range interaction has two origins: (i) a self-interaction on the average spin state, mediated through the coupling between the average spin state and the unit cell parameters; and (ii) an infrared divergence in the spin state-spin state coupling mediated by displacements of metals and ligands within the unit cell. %In the absence of elastic frustration these terms are equal and opposite so there is no long-range interaction. However, in general they do not cancel and there is a long-range Ising interaction. The long-range interaction is independent of the distance between metal centers, nevertheless it leads to an extensive contribution to the (free) energy. In this model the Husimi-Temperley interaction dominates transitions of spin states, whereas multistep transitions and intermediate order are observed if only the pure (power-law) Ising interaction are retained, only single-step transitions are found in the full model.

cond-mat.str-el

Spin liquid phase in a spatially anisotropic frustrated antiferromagnet

We explore the effect of the third nearest-neighbors on the magnetic properties of the Heisenberg model on an anisotropic triangular lattice. We obtain the phase diagram of the model using Schwinger-boson mean-field theory. Competition between Néel, spiral and collinear magnetically ordered phases is found as we vary the on the ratios of the nearest, J1, next-nearest, J2, and third-nearest, J_3, neighbor exchange couplings. A spin liquid phase is stabilized between the spiral and collinear ordered states when J2/J1 < 1.8 for rather small J3/J1 < 0.1. The lowest energy two-spinon dispersions relevant to neutron scattering experiments are analyzed and compared to semiclassical magnon dispersions finding significant differences in the spiral and collinear phases between the two approaches. The results are discussed in the context of the anisotropic triangular materials: Cs2CuCl4 and Cs2CuBr4 and layered organic materials, kappa-(BEDT-TTF)2X and Y[Pd(dmit)2]2.

cond-mat.str-el

Spin liquid phase due to competing classical orders in the semiclassical theory of the Heisenberg model with ring exchange on an anisotropic triangular lattice

Linear spin wave theory shows that ring exchange induces a quantum disordered region in the phase diagram of the title model. Spin wave spectra show that this is a direct manifestation of competing classical orders. A spin liquid is found in the `Goldilocks zone' of frustration, where the quantum fluctuations are large enough to cause strong competition between different classical orderings but not strong enough to stabilize spiral order. We note that the spin liquid phases of $κ$-(BEDT-TTF)${_2}X$ and $Y$[Pd(dmit)$_2$]$_2$ are found in this Goldilocks zone.

cond-mat.str-el

Towards Quantum Chemistry on a Quantum Computer

The fundamental problem faced in quantum chemistry is the calculation of molecular properties, which are of practical importance in fields ranging from materials science to biochemistry. Within chemical precision, the total energy of a molecule as well as most other properties, can be calculated by solving the Schrodinger equation. However, the computational resources required to obtain exact solutions on a conventional computer generally increase exponentially with the number of atoms involved. This renders such calculations intractable for all but the smallest of systems. Recently, an efficient algorithm has been proposed enabling a quantum computer to overcome this problem by achieving only a polynomial resource scaling with system size. Such a tool would therefore provide an extremely powerful tool for new science and technology. Here we present a photonic implementation for the smallest problem: obtaining the energies of H2, the hydrogen molecule in a minimal basis. We perform a key algorithmic step - the iterative phase estimation algorithm - in full, achieving a high level of precision and robustness to error. We implement other algorithmic steps with assistance from a classical computer and explain how this non-scalable approach could be avoided. Finally, we provide new theoretical results which lay the foundations for the next generation of simulation experiments using quantum computers. We have made early experimental progress towards the long-term goal of exploiting quantum information to speed up quantum chemistry calculations.

quant-ph

Preparation of Metal Mixed Plastic Superconductors: Electrical Properties of Tin-Antimony Thin Films on Plastic Substrates

Metal mixed polymers are a cheap and effective way to produce flexible metals and superconductors. As part of an on-going effort to learn how to tune the properties of these systems with ion implantation, we present a study of the electrical properties of these systems prior to metal-mixing. We show that the electrical properties of tin-antimony thin films are remarkably robust to variations in the substrate morphology. We demonstrate that the optical absorbance of the films at a fixed wavelength provides a reliable and reproducible characterization of the relative film thickness. We find that as the film thickness is reduced, the superconducting transition in the unimplanted thin films is broadened, but the onset of the transition remains at ~3.7 K, the transition temperature of bulk Sn. This is in marked contrast to the behavior of metal mixed films, which suggests that the metal mixing process has a significant effect of the physics of the superconducting state beyond that achieved by reducing the film thickness alone.

cond-mat.mtrl-sci

The effect of irradiation-induced disorder on the conductivity and critical temperature of the organic superconductor $κ$-(BEDT-TTF)$_2$Cu(SCN)$_2$

We have introduced defects into clean samples of the organic superconductor $κ$-(BEDT-TTF)$_2$Cu(SCN)$_2$ in order to determine their effect on the temperature dependence of the conductivity and the critical temperature $T_{\rm c}$. We find a violation of Matthiessen's rule that can be explained by a model of the conductivity involving a defect-assisted interlayer channel which acts in parallel with the band-like conductivity. We observe an unusual dependence of $T_{\rm c}$ on residual resistivity which is not consistent with the generalised Abrikosov-Gor'kov theory for an order parameter with a single component, providing an important constraint on models of the superconductivity in this material.

cond-mat.supr-con