arXiv subjects

Benedetta Marmiroli

Publications and source records attributed to Benedetta Marmiroli.

4 recordsLinked to original sources

arXiv2026

Automated Spin-Assisted Layer-by-Layer Epitaxy Produces Highly Oriented Mixed-Linker MOF Thin Films

Control over crystallographic orientation in metal-organic framework (MOF) thin films is crucial for exploiting their anisotropic properties in sensing, catalysis, and separation. Achieving reproducible, highly oriented films remains challenging, especially for mixed-linker, pillared-layered frameworks. Here we present an automated, spin-assisted layer-by-layer liquid-phase epitaxy (LbL-LPE) strategy that enables rapid, ambient-condition fabrication of highly oriented, mixed-linker MOF thin films, demonstrated for Zn2BDC2DABCO (BDC = terephthalate, DABCO = 1,4-diazabicyclo[2.2.2]octane). Correlative process monitoring by grazing-incidence wide-angle X-ray scattering (GIWAXS), grazing-angle infrared (GI-IR) and UV-Vis spectroscopy, contact-angle measurements, scanning electron microscopy (SEM), and time-of-flight secondary ion mass spectrometry (ToF-SIMS) ensure formation of uniform films with exceptional out-of-plane (001) orientation (degree of orientation >85%, Hermans parameter ~0.95) and excellent reproducibility. This strategy enables highly reproducible, high-throughput fabrication of orientation-controlled MOF thin films, providing a generalizable alternative to conventional LbL approaches. By enabling reproducible and entirely automated fabrication of highly anisotropic architectures, this work establishes a platform for integrating oriented MOFs into next-generation optoelectronic, sensing, and membrane devices where directional transport and ordered pore alignment are essential.

cond-mat.mtrl-sci↗

arXiv2025

Multi-wavelength transparent microfluidics for UV-visible spectroscopy and X-ray scattering studies of photoactive systems

Microfluidic devices are increasingly used in synchrotron-based experiments to deliver and probe liquid samples, offering advantages such as minimal sample consumption and reduced radiation damage. Despite their growing use, few devices have been specifically designed for monitoring liquids under photoexcitation, a promising approach for fast structural transitions. Here, a microfluidic device that is transparent to X-rays in one direction, and simulaneously transmits UV and visible light in the perpendicular direction is presented. The device is fabricated using lamination and UV lithography on a dry-film resist, eliminating the need for cleanroom facilities and simplifying production. Its multi-wavelength transparency was validated through UV-visible spectroscopy, where photoexcitation at different wavelengths induced reversible trans-to-cis isomerization of azobenzene and fluoro-azobenzene. X-ray transparency was validated through Small Angle X-ray Scattering (SAXS) measurements on hemoglobin and CO-ligated hemoglobin sensitive to quaternary structural changes. These resusts confirm the suitability of the device for resolving protein structures and photoinduced conformational dynamics. The design further supports, as some proof of concept results show, temperature-jump and time resolved pump-probe experiments, providing a versatile platform for studying structural evolution in liquid samples using synchrotron SAXS.

physics.app-ph↗

arXiv2023

Implication of the double-gating mode in hybrid photon counting detector for measurements of transient heat conduction in GaAs/AlAs superlattice structures

Understanding and control of thermal transport in solids at nanoscale is crucial to engineer and to enhance properties of a new generation of optoelectronic, thermoelectric, and photonic devices. In this regard, semiconductor superlattice structures provide a unique platform to study phenomena associated with phonon propagations in solids such as heat conduction. Transient X-ray diffraction can directly probe atomic motions and therefore is among the rare techniques sensitive to phonon dynamics in a condensed matter. Here, we study optically induced transient heat conduction in GaAs/AlAs superlattice structures using EIGER2 detector. Benchmark experiments have been performed at the Austrian SAXS beamline at Elettra Sincrotrone Trieste that operated in the hybrid filling mode. We demonstrate that drifts of experimental conditions, such as synchrotron beam fluctuations, become less essential when utilizing EIGER2 double gating mode that results in a faster acquisition of high quality data and facilitates data analysis and data interpretation.

physics.app-ph↗

arXiv2018

Laser Ablation and Injection Moulding as Techniques for Producing Micro Channels Compatible with Small Angle X-Ray Scattering

Microfluidic mixing is an important means for in-situ sample preparation and handling while Small Angle X-Ray Scattering (SAXS) is a proven tool for characterising (macro-)molecular structures. In combination those two techniques enable investigations of fast reactions with high time resolution (<1 ms). The goal of combining a micro mixer with SAXS, however, puts constraints on the materials and production methods used in the device fabrication. The measurement channel of the mixer needs good x-ray transparency and a low scattering background. While both depend on the material used, the requirement for low scattering especially limits the techniques suitable for producing the mixer, as the fabrication process can induce molecular orientations and stresses that can adversely influence the scattering signal. Not only is it important to find a production method that results in a device with low background scattering, but it also has to be versatile enough to produce appropriate mixer designs. Here we discuss two methods - laser ablation of polycarbonate and injection moulding of Topas - which were found suitable for our needs, provided care is taken in aligning the mixing/reaction channel, where the actual measurements will be carried out. We find injection moulding to be the better of the two methods.

physics.app-ph↗