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Benjamin Goddard

Publications and source records attributed to Benjamin Goddard.

2 recordsLinked to original sources

Pseudospectral Methods and Critical Phenomena

We employ pseudospectral methods to solve the homogeneous Ornstein-Zernike (OZ) equation for a model fluid in the vicinity of the critical point. Focusing on the Mean-Spherical Approximation (MSA) as a closure to the OZ equation, we obtain numerical estimates for the critical exponents $\eta$, $\delta$ and $\gamma$ for a system of hard-core Yukawa particles both in two and three dimensions. The three-dimensional MSA exponents are already well-known from an analytic solution and are recovered by our numerical methods. The two-dimensional exponents are a new output of this work. The pseudospectral method allows for rapid and highly accurate solution of liquid-state integral equation theories, and enables calculations on truely infinite domains, as needed for highly correlated states. In addition, we analyse the standard Picard iteration scheme and propose a variation of it which provides increased stability and speed of convergence.

cond-mat.soft

Singularities in phase separation models: a spectral element approach for the nonlocal Cahn-Hilliard equation

The nonlocal Cahn-Hilliard equation provides a natural extension of the classical model for phase separation by incorporating long-range interactions through a singular convolution kernel. While this formulation admits a rich existence and regularity theory, its numerical approximation remains challenging: discretisation of the nonlocal term leads to dense operators, and the singularity of the kernel requires special treatment in collocation-based schemes. In this work, we develop an efficient and error-controlled numerical framework for the nonlocal Cahn-Hilliard system with constant mobility, logarithmic potential, Newtonian interaction kernel, and no-flux boundary conditions. Our approach is based on a pseudospectral multishape method that accurately approximates the action of singular convolution operators. We present high-resolution numerical solutions for this nonlocal system of equations that can be achieved with limited computational resources.

math.NA