arXiv subjects

Bernard Field

Publications and source records attributed to Bernard Field.

8 recordsLinked to original sources

arXiv2026

Colossal Magnetoresistance and Phonon Driven Exchange Dynamics in Eu$_5$Sn$_2$As$_6$

The emergence of colossal magnetoresistance in a new generation of Eu$^{2+}$-based antiferromagnets is intriguing given stark contrasts to the archetypal perovskite manganites and doped Eu-chalcogenides. In this study the thermal conductivity and magnetostriction of Eu$_5$Sn$_2$As$_6$ -- one such representative -- have been measured to better understand the role of the crystal lattice. Both properties are strongly field-dependent and mirror the magnetization, saturating once the Eu$^{2+}$ moments are polarized. The field-enhancement of the phonon-dominated thermal conductivity is interpreted through the lifting of a degeneracy of spin configurations, and the subsequent saturation due to quenched magnetostrain in high field. Comparison with spin-glass insulators suggests that this phenomenon is not a byproduct but rather the driver of electron delocalization due to the suppression of strong phonon scattering arising from exchange frustration.

cond-mat.mes-hall↗

arXiv2025

Atomic-scale control of substrate-spin coupling via vertical manipulation of a 2D metal-organic framework

Two-dimensional (2D) materials with frustrated crystal geometries can host strongly correlated electrons, potentially leading to a range of exotic many-body quantum phases such as Mott insulators, quantum spin-liquids, and Kondo lattices. The ability to control exchange-coupling within these systems is therefore highly desirable. Here, we use an atomically sharp scanning tunneling microscope probe to vertically manipulate a 2D Mott insulating kagome metal-organic framework (MOF) featuring Kondo-screened local magnetic moments on Ag(111). We show that by controlling the adsorption height of the MOF, we can also controllably and reversibly change the strength of Kondo coupling between the MOF's local spins and the substrate's conduction electrons. This mechanical control of Kondo coupling could be extended to other forms of interlayer exchange coupling, potentially allowing for atomic-scale design or control of spintronics technologies.

cond-mat.str-el↗

arXiv2024

Symmetries of all lines in monolayer crystals

As "2D" materials (i.e. materials just a few atoms thick) continue to gain prominence, understanding their symmetries is critical for unlocking their full potential. In this work, we present comprehensive tables that tabulate the rod group symmetries of all crystallographic lines in all 80 layer groups, which describe the symmetries of 2D materials. These tables are analogous to the scanning tables for space groups found in Volume E of the International Tables for Crystallography, but are specifically tailored for layer groups and their applications to 2D materials. This resource will aid in the analysis of line defects, such as domain walls, which play a crucial role in determining the properties and functionality of 2D materials.

cond-mat.mtrl-sci↗

arXiv2023

Local gate control of Mott metal-insulator transition in a 2D metal-organic framework

Electron-electron interactions in materials lead to exotic many-body quantum phenomena including Mott metal-insulator transitions (MITs), magnetism, quantum spin liquids, and superconductivity. These phases depend on electronic band occupation and can be controlled via the chemical potential. Flat bands in two-dimensional (2D) and layered materials with a kagome lattice enhance electronic correlations. Although theoretically predicted, correlated-electron Mott insulating phases in monolayer 2D metal-organic frameworks (MOFs) with a kagome structure have not yet been realised experimentally. Here, we synthesise a 2D kagome MOF on a 2D insulator. Scanning tunnelling microscopy (STM) and spectroscopy reveal a MOF electronic energy gap of ~200 meV, consistent with dynamical mean field theory predictions of a Mott insulator. Combining template-induced (via work function variations of the substrate) and STM probe-induced gating, we locally tune the electron population of the MOF kagome bands and induce Mott MITs. These findings enable technologies based on electrostatic control of many-body quantum phases in 2D MOFs.

cond-mat.str-el↗

arXiv2022

Correlation-induced magnetism in substrate-supported 2D metal-organic frameworks

Two-dimensional (2D) metal-organic frameworks (MOFs) in a kagome lattice can exhibit strong electron-electron interactions, which can lead to tunable quantum phases including many exotic magnetic phases. While technological developments of 2D MOFs typically take advantage of substrates for growth, support, and electrical contacts, investigations often ignore substrates and their dramatic influence on electronic properties of MOFs. Here, we show how substrates alter the correlated magnetic phases in kagome MOFs using systematic density functional theory and mean-field Hubbard calculations. We demonstrate that MOF-substrate coupling, MOF-substrate charge transfer, strain, and external electric fields are key variables, activating and deactivating magnetic phases in these materials. While we consider the example of kagome-arranged 9,10-dicyanoanthracene molecules coordinated with copper atoms, our findings should generalise to any kagome lattice. This work offers useful predictions for tunable interaction-induced magnetism in surface-supported 2D organic materials, opening the door to solid-state electronic and spintronic technologies based on such systems.

cond-mat.str-el↗

arXiv2021

Manifestation of strongly correlated electrons in a 2D kagome metal-organic framework

The kagome lattice, whose electronic valence band (VB) structure includes two Dirac bands and one flat band, offers a rich space to realise tuneable topological and strongly correlated electronic phases in two-dimensional (2D) and layered materials. While strong electron correlations have been observed in inorganic kagome crystals, they remain elusive in organic systems. The latter offer versatile synthesis protocols via molecular self-assembly and metal-ligand coordination. Here, we report the synthesis of a 2D metal-organic framework (MOF) where di-cyano-anthracene (DCA) molecules form a kagome arrangement via coordination with copper (Cu) atoms on a silver surface [Ag(111)]. Low-temperature scanning tunnelling spectroscopy revealed Kondo screening--by the Ag(111) conduction electrons--of magnetic moments localised at Cu and DCA sites of the MOF. Density functional theory and mean-field Hubbard modelling show that these local moments emerge from strong interactions between kagome MOF electrons, enabling organic 2D materials as viable platforms for strongly correlated nanoelectronics and spintronics.

cond-mat.str-el↗

arXiv2019

Fate of the Bose polaron at finite temperature

We consider an impurity immersed in a Bose-Einstein condensate with tunable boson-impurity interactions. Such a Bose polaron has recently been predicted to exhibit an intriguing energy spectrum at finite temperature, where the ground-state quasiparticle evenly splits into two branches as the temperature is increased from zero [Guenther et al., Phys. Rev. Lett. 120, 050405 (2018)]. To investigate this theoretical prediction, we employ a recently developed variational approach that systematically includes multi-body correlations between the impurity and the finite-temperature medium, thus allowing us to go beyond previous finite-temperature methods. Crucially, we find that the number of quasiparticle branches is simply set by the number of hole excitations of the thermal cloud, such that including up to one hole yields one splitting, two holes yields two splittings, and so on. Moreover, this effect is independent of the impurity mass. We thus expect that the exact ground-state quasiparticle will evolve into a single broad peak for temperatures $T>0$, with a broadening that scales as $T^{3/4}$ at low temperatures and sufficiently weak boson-boson interactions. In the zero-temperature limit, we show that our calculated ground-state polaron energy is in excellent agreement with recent quantum Monte Carlo results and with experiments.

cond-mat.quant-gas↗

arXiv2018

Introduction to topological quantum computation with non-Abelian anyons

Topological quantum computers promise a fault tolerant means to perform quantum computation. Topological quantum computers use particles with exotic exchange statistics called non-Abelian anyons, and the simplest anyon model which allows for universal quantum computation by particle exchange or braiding alone is the Fibonacci anyon model. One classically hard problem that can be solved efficiently using quantum computation is finding the value of the Jones polynomial of knots at roots of unity. We aim to provide a pedagogical, self-contained, review of topological quantum computation with Fibonacci anyons, from the braiding statistics and matrices to the layout of such a computer and the compiling of braids to perform specific operations. Then we use a simulation of a topological quantum computer to explicitly demonstrate a quantum computation using Fibonacci anyons, evaluating the Jones polynomial of a selection of simple knots. In addition to simulating a modular circuit-style quantum algorithm, we also show how the magnitude of the Jones polynomial at specific points could be obtained exactly using Fibonacci or Ising anyons. Such an exact algorithm seems ideally suited for a proof of concept demonstration of a topological quantum computer.

quant-ph↗