arXiv subjects

Bhagyashree Chalke

Publications and source records attributed to Bhagyashree Chalke.

5 recordsLinked to original sources

arXiv2025

A Rapid Thermal Chemical Vapor Deposition System for Fast Synthesis of Epitaxial Graphene Under Ambient Pressure

Graphene has emerged as a promising material for next-generation electronic and thermal devices owing to its exceptional charge transport and thermal conductivity. However, high-quality samples are predominantly obtained via mechanical exfoliation from graphite crystals, a process that inherently lacks scalability. Despite extensive efforts toward large-area synthesis, cost-effective approaches for producing high-quality, large-area, single-crystalline graphene with fast turnaround time remain limited. Here, we report the design, fabrication, and performance benchmarking of a rapid thermal chemical vapor deposition (RTCVD) system capable of synthesizing epitaxial monolayer graphene under atmospheric pressure. The entire growth process, from sample loading to unloading, is achieved within $25$ minutes with a temperature ramp rate exceeding $23^\circ\mathrm{C}/s$. Growth at atmospheric pressure eliminates the need for vacuum components, thereby reducing both system complexity and operational costs. The structural and electronic quality of epitaxial graphene is comprehensively characterized using Raman spectroscopy, selected area electron diffraction (SAED), and magnetotransport measurements, which reveal signatures of quantum Hall effect in synthesized graphene samples. Furthermore, we demonstrate van der Waals epitaxial growth of palladium (Pd) thin films on graphene transferred to Si/SiO$_{2}$ substrates, establishing its single-crystalline nature over a large area and its potential as a versatile platform for subsequent heteroepitaxial growth.

cond-mat.mtrl-sci↗

arXiv2025

Four-fold Anisotropic Magnetoresistance in Antiferromagnetic Epitaxial Thin Films of MnPt$_{x}$Pd$_{1-x}$

Antiferromagnets are emerging as promising alternatives to ferromagnets in spintronics applications. A key feature of antiferromagnets is their anisotropic magnetoresistance (AMR), which has the potential to serve as a sensitive marker for the antiferromagnetic order parameter. However, the underlying origins of this behavior remains poorly understood, particularly, in thin film geometries. In this study, we report the observation of AMR in epitaxial thin films of the collinear L1$_{0}$ antiferromagnet MnPt$_{x}$Pd$_{1-x}$. In the thicker films, AMR is dominated by a non-crystalline two-fold component, which emerges from domain reconfiguration and spin canting under applied magnetic field. As the film thickness is reduced, however, a crystalline four-fold component emerges, accompanied by the appearance of uncompensated magnetic moment, which strongly modifies the magnetotransport properties in the thinner films. We demonstrate that interfacial interactions lead to a large density of states (DOS) at the Fermi level. This enhanced DOS, combined with disorder in the thinner films, stabilizes the uncompensated moment and results in a four-fold modulation of the DOS as the Neel vector rotates, explaining the observed AMR behavior.

cond-mat.mtrl-sci↗

arXiv2023

Origin of superconductivity in tungsten thin films

The most common allotrope of tungsten, α-W, has a superconducting transition at a temperature of ~11 mK. However, two other forms of tungsten have been reported to have superconducting transitions in the temperature range Tc ~ 2-5 K when synthesized as thin films: Crystalline \b{eta}-W and amorphous W (a-W). In this work we carry out a systematic study of W films synthesized using d.c. magnetron sputtering, using transport, low frequency magnetic shielding response, and transmission electron microscopy. Our results show that while a-W is indeed a bulk superconductor, superconductivity in \b{eta}-W probably originates from an amorphous phase that forms along with the \b{eta}-W phase. Our findings reconcile some of the anomalies earlier reported in \b{eta}-W, such the very small superconducting gap and the decrease of Tc with increase in film thickness.

cond-mat.supr-con↗

arXiv2021

Synchrotron x-ray diffraction studies of the $α\rightleftharpoons β$ structural phase transition in Sn and Sn-Cu

The transformation between the metallic ($β$) and semi-conducting ($α$) allotropes of tin is still not well understood. The phase transition temperature stated in the literature, 286.2 K, seems to be inconsistent with recent calorimetric measurements. In this paper, this intriguing aspect has been explored in Sn and Sn-Cu (alloyed 0.5% Cu by weight) using temperature resolved synchrotron x-ray diffraction measurements performed at the Indus-2 facility. Additionally, the $α\rightleftharpoons β$ Sn transition has been recorded using in-situ heating/cooling experiments in a scanning electron microscope. Based on these measurements, a protocol has been suggested to reduce the formation of $α$-Sn in potentially susceptible systems. This will be useful in experiments like TIN.TIN (The INdia-based TIN detector), which proposes to employ ~100 - 1000 kg of superconducting tin-based detectors to search for neutrinoless double beta decay in the isotope $^{124}$Sn.

cond-mat.mtrl-sci↗

arXiv2015

Superconductivity in im-miscible Cu-Nb phase separated nano-composite thin films

Superconductivity in granular films is controlled by the grain size and the inter-grain coupling. In a two-component granular system formed by a random mixture of a normal metal (N) and a superconductor (S), the superconducting nano-grains may become coupled through S-N weak links, thereby affecting the superconducting properties of the network. We report on the study of superconductivity in immiscible Nb-Cu nanocomposite films with varying compositions. The microstructure of the films revealed the presence of phase separated, closely spaced, nano-grains of Nb and Cu whose sizes changed marginally with composition. The superconducting transition temperature (Tc0) of the films decreased with increasing concentration of Cu with a concomitant decrease in the upper critical field (Hc2) and the critical current (Ic). Our results indicate the presence of superconducting phase fluctuations in all films with varying Nb:Cu content which not only affected the temperature for the formation of a true phase coherent superconducting condensate in the films but also other superconducting properties.

cond-mat.mes-hall↗