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Bhaskar Sen Gupta

Publications and source records attributed to Bhaskar Sen Gupta.

At least 19 recordsLinked to original sources

Activity-Driven Dewetting and Rupture in Thin Liquid Films

Thin-film dewetting is classically governed by an adhesion-mediated spinodal instability in which curvature-driven diffusion controls post-rupture coarsening. We show that internal activity fundamentally restructures this instability. Using a minimal microscopic model of an active liquid film on a solid substrate, we identify a competition between active stresses and film-substrate adhesion that produces two independently regulated dynamical length scales: vertical liquid accumulation and lateral rupture propagation. While passive films exhibit universal diffusion-limited growth, $\ell_z(t)\sim t^{1/3}$, activity converts transport from curvature-controlled diffusion to persistence-driven motion, yielding a continuous increase of the coarsening exponent from $\approx 0.33$ to $\approx 0.6$. The growth law analysis shows that persistent self-propulsion introduces an advective flux that competes with curvature-induced chemical potential gradients, enhancing growth when the persistence length becomes comparable to the evolving domain size. Simultaneously, the rupture front transitions from dissipative spreading to strongly accelerated propagation approaching ballistic scaling. This decoupling shows that activity does not simply renormalize effective surface forces but generates a distinct nonequilibrium interfacial instability governed by the balance between persistence length and adhesion. The results provide a minimal physical mechanism linking classical thin-film dewetting to dewetting-like rupture observed in active and biological materials.

cond-mat.soft

Active alignment-driven coarsening in confined near-critical fluids

We investigate vapor-liquid phase separation of an active near critical Lennard-Jones fluid confined within a cylindrical pore using molecular dynamics simulations. Activity is introduced via Vicsek-type alignment interactions, enabling a systematic study of how self-propulsion modifies domain morphology and coarsening kinetics under quasi-one-dimensional confinement. In the passive limit, the system undergoes early-time spinodal decomposition (diffusive growth characterized by the Lifshitz-Slyozov exponent $α= 1/3$), followed by the formation of periodically modulated, plug-like liquid domains along the pore axis. At late times, coarsening becomes kinetically arrested, and the system remains trapped in a metastable striped state. Introducing activity destabilizes this arrested morphology by enhancing collective domain transport, leading to frequent domain mergers and complete phase separation at sufficiently high activity. The late-stage coarsening then exhibits a crossover to faster, ballistic growth with an effective exponent $α= 2/3$, consistent with a cluster-coalescence mechanism. Analysis of two-point correlation functions and structure factors confirms dynamic scaling across all activity regimes. Our results demonstrate that alignment-induced activity can overcome confinement-driven kinetic arrest, providing new insight into phase separation in confined active fluids. The relevant growth laws are analyzed and interpreted using appropriate theoretical frameworks.

cond-mat.soft

Breaking the Logarithmic Barrier: Activity-Induced Recovery of Phase Separation Dynamics in Confined Geometry

Phase separation in confined environments is a fundamental process underlying geological flows, porous filtration, emulsions, and intracellular organization. Yet, how confinement and activity jointly govern coarsening kinetics and interfacial morphology remains poorly understood. Here, we use large-scale molecular dynamics simulations to investigate vapor-liquid phase separation of passive and active fluids embedded in complex porous media. By generating porous host structures via a freeze-quench protocol, we systematically control the average pore size and demonstrate that confinement induces a crossover from the Lifshitz-Slyozov power-law growth to logarithmically slowed coarsening, ultimately arresting domain evolution. Analysis of correlation functions and structure factors reveals that confined passive systems exhibit fractal interfaces, violating Porod's law and indicating rough morphological arrest. In contrast, introducing self-propulsion dramatically changes the coarsening pathway: activity restores smooth interfaces, breaks the confinement-induced scaling laws, and drives a transition from logarithmic to ballistic domain growth at high activity levels. Our findings reveal an activity-controlled mechanism to overcome geometric restrictions and unlock coarsening in structurally heterogeneous environments. These insights establish a unifying framework for nonequilibrium phase transitions in porous settings, with broad relevance to active colloids, catalytic media, and biologically crowded systems, where living matter routinely reorganizes within geometric constraints to sustain function.

cond-mat.soft

Viscous Growth Law in Bubble Coarsening: A Molecular Dynamics Perspective

We investigate the kinetics of bubble coarsening in a single component Lennard-Jones fluid using large-scale molecular dynamics simulations. A homogeneous high-temperature system is quenched below the critical temperature to induce the nucleation and growth of vapor bubbles within a dense liquid matrix. The structural evolution is characterized by two point correlation functions and the static structure factor, both of which exhibit dynamic scaling and sharp interfaces consistent with Porod law. The time-dependent characteristic length scale, extracted from the correlation function, shows a robust power law growth $\ell(t) \sim t^α$. Finite size scaling analysis across different system sizes yields $α\approx 1.0$, establishing that coarsening is dominated by viscous hydrodynamic interactions rather than classical diffusion-limited Ostwald ripening predicted by the Lifshitz-Slyozov-Wagner theory. These results provide atomistic evidence for fluid flow controlled coarsening in vapor-liquid systems and emphasize the need to go beyond diffusion-based theories to describe bubble dynamics in dense fluids.

cond-mat.soft

Crossover in growth law in the vapor-liquid phase separation inside complex porous medium

We employ molecular dynamics simulations to investigate the domain morphology and growth kinetics of a vapor-liquid system embedded within a complex porous medium. By systematically varying the pore structure, we analyze the scaling behavior of correlation functions, structure factors, and domain growth exponents. The structure factor confirms the breakdown of Porod law and the emergence of fractal-like domain boundaries. Our key finding is the clear crossover in the domain growth law, from the classical power-law behavior observed in bulk fluids to a slower, logarithmic regime in highly confined systems. This transition is driven by energy barriers introduced by the porous geometry, which inhibit coarsening dynamics at later time. We provide a scaling analysis which further confirms this crossover and quantitatively connects the growth behavior with the average pore size.

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Phase separation and rheology of segregating binary fluid under shear

We employ molecular dynamics simulation to study the phase separation and rheological properties of a three-dimensional binary liquid mixture with hydrodynamics undergoing simple shear deformation. The impact of shear intensity on domain growth is investigated, with a focus on how shear primarily distorts the domains, leading to the formation of anisotropic structures. The structural anisotropy is quantified by evaluating domain sizes along the flow and shear direction. The rheological properties of the system is studied in terms of shear stress and excess viscosity. At low shear rates, the system behaves like a Newtonian fluid. However, the strong-shear case is marked by a transition characterized by non-Newtonian behavior.

cond-mat.soft

Kinetics of vapor-liquid transition of active matter system under quasi one-dimensional confinement

We study the kinetics of vapor-liquid phase separation in a quasi one-dimensional confined active matter system using molecular dynamics simulations. Activity is invoked via the Vicsek rule, while passive interaction follows the Lennard-Jones potential. With the system density near the vapor branch, the evolution morphology features disconnected liquid clusters. In the passive limit, coarsening begins with nucleation, followed by an evaporation-condensation growth mechanism, leading to a metastable state without complete phase separation. We aim to understand the impact of Vicsek-like self-propulsion on the structure and growth of these clusters. Our key finding is that Vicsek activity results in a distinct growth mechanism, notably rapid cluster growth and the breakdown of the metastable state through ballistic aggregation. Relevant growth laws are analyzed and explained using appropriate theoretical models.

cond-mat.soft

Effect of annealed disorder on the plasticity of amorphous solids

We investigate the effect of annealed disorder on the mechanical properties and plasticity of a modeled amorphous solid by introducing a small fraction of heavy impurities into the material which resembles real experimental systems. The disorder being mobile, the total degrees of freedom and the potential energy landscape of the pure system are preserved in our model. The mechanical failure and the shear band formation in the amorphous solid in the presence of annealed disorder are studied at the microscopic level by employing the finite shear deformation protocol at nonzero temperature. A significant enhancement in the shear modulus and yield stress is observed as a function of the heaviness of the impurity particles. Via the analysis of the non-affine displacement field and the microscopic strain fluctuations and the nature of their spatial correlations we find that the shear band formation in the plastic regime is gradually suppressed with increasing impurity mass. Eventually, a critical mass of the disordered particles is identified above which the plastic events become completely localized. This is marked by a transition from a power law to an exponential decay in the spatial correlations non-affine displacement field. Likewise, a similar change is observed in the strain correlation function, transitioning from a slower $1/r$ decay to a more rapid $1/r^3$ decay. Finally, the effect shear rate on the plastic events in the presence of annealed disorder is explored.

cond-mat.soft

Kinetics Of Vapor-Liquid And Vapor-Solid Phase Separation Under Gravity

We study the kinetics of vapor-liquid and vapor-solid phase separation of a hydrodynamics preserving three-dimensional one component Lennard Jones system in the presence of external gravitational field using extensive molecular dynamic simulation. A bicontinuous domain structure is formed when the homogeneous system near the critical density is quenched inside the coexistence region. In the absence of gravity, the domain morphology is statistically self-similar and the length scale grows as per the existing laws. However, the presence of gravity destroys the isotropy of the system and affects the scaling laws. We observe an accelerated domain growth in the direction of the field at late time which resembles sedimentation process. Consequently, a new length scale emerges which strongly depends on the field strength. Similar behavior is observed in the direction perpendicular to the applied field, with a different growth rate. Finally, the validity of Porod's law and Superuniversality in such anisotropic systems is verified in terms of two-point equal time order parameter correlation function and static structure factor.

cond-mat.soft

Surface directed spinodal decomposition of fluids confined in cylindrical pore

The surface directed spinodal decomposition of a binary liquid confined inside cylindrical pore is investigated using molecular dynamics simulation. One component of the liquid wets the pore surface while the other remains neutral. A variety of wetting conditions are studied. For the partial wetting case, after an initial period of phase separation, the domains organize themselves into plug-like structure and the system enters into a metastable state. Therefore, a complete phase separation is never achieved. Analysis of domain growth and the structure factor suggests an one-dimensional growth dynamics for partial wetting case. As the wetting interaction is increased beyond a critical value, a transition from the plug-like to tube-like domain formation is observed which corresponds to the full wetting morphology. Thus, a complete phase separation is achieved as the wetting species moves towards the pore surface and forms layers enclosing the non wetting species residing around the axis of the cylinder. The coarsening dynamics of both the species are studied separately. The wetting species is found to follow a two-dimensional domain growth dynamics with a growth exponent 1/2 in the viscous hydrodynamic regime. This was substantiated by the Porod tail of the structure factor. On the other hand, the domain grows linearly with time for the non wetting species. This suggests that the non wetting species behaves akin to a three-dimensional bulk system. An appropriate reasoning is presented to justify the given observations.

cond-mat.soft

Phase separation kinetics of segregating fluid mixtures in the presence of quenched disorder

Quenched or frozen-in structural disorder is ubiquitous in real experimental systems. Much of the progress is achieved in understanding the phase separation of such systems using the diffusion-driven coarsening in Ising model with quenched disorder. But there is a paucity of research in the phase separation kinetics in fluids with quenched disorder. In this paper, we present results from a detailed Molecular dynamics simulation, the effects of randomly placed localized impurities on the phase separating kinetics of binary fluid mixture. Two different models are offered for representing the impurities. We observe a dramatic slowing down in the pattern formation with increasing impurity concentration. This sluggish domain growth kinetics follows power-law with a disorder-dependent exponent. The correlation function and structure factor show a non-Porod behavior, indicating the roughening of domain interfaces. We have also studied the effect of quenched disorder on the aging dynamics by calculating the two-time order parameter auto correlation function and find that the Fisher and Huse scaling law holds good in presence of quenched disorder.

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Phase separation and aging dynamics of binary liquid in porous media

We employ the state-of-the-art molecular dynamics simulations to study the kinetics of phase separation and aging phenomena of segregating binary fluid mixtures imbibed in porous materials. Different random porous structures are considered to understand the effect of pore morphology on coarsening dynamics. We find the effect of complex geometrical confinement resulting in the dramatic slowing down in the phase separation dynamics. The domain growth follows the power law with an exponent dependent on the porous host structure. After the transient period, a crossover to a slower domain growth is observed when the domain size becomes comparable to the pore size. Due to the geometric confinement, the correlation function and structure factor modify to a non-Porod behavior and violate the superuniversality hypothesis. The role of porous host structure on the nonequilibrium aging dynamics is studied qualitatively by computing the two-time order-parameter autocorrelation function. This quantity exhibits scaling laws with respect to the ratio of the domain length at the observation time and the age of the system. We find the scaling laws hold good for such confined segregating fluid mixtures.

cond-mat.soft

Characteristics and Correlation of Nonaffine Particle Displacements in the Plastic Deformation of Athermal Amorphous Materials

When an amorphous solid is deformed homogeneously, the response exhibits heterogeneous plastic instabilities with localized cooperative rearrangement of cluster of particles. The heterogeneous behavior plays an important role in deciding the mechanical properties of amorphous solids. In this paper, we employ computer simulation to study the characteristics and the spatial correlations of these clusters characterized by the non-affine displacements in amorphous solids under simple shear deformation in the athermal quasistatic limit. The clusters with large displacements are found to be homogeneously distributed in space in the elastic regime, followed by a localization within a system-spanning shear band after yielding. The distributions of the displacement field exhibit power-law nature with exponents strongly dependent on the deformation. The non-affine displacements show strong spatial correlations which become long-ranged with increasing strain. From our results, it is evident that the decay of the correlation functions is exponential in nature in the elastic regime. The yielding transition is marked by an abrupt change in the decay after which it is well described by power-law. These results demonstrate a scale-free character of non-affine correlations in the stead flow regime. These results are found to be robust and independent of the strain window over which the total non-affine displacement is calculated.

cond-mat.soft

Shear Induced Fluidization Of Thermal Amorphous Solids

We study the shear induced fluidization of amorphous solids subjected to external loading by investigating the relaxation dynamics of the deformed states using computer simulation. A simple shear deformation is employed at constant rate to the thermal glassy materials. The shear localization and the plastic deformation heterogeneity with strain is investigated in terms of the non-affine displacement field. The mean square displacement shows an enhanced mobility of the particles with strain, indicating the fluidization of the material. Using the time correlation function we estimate the relaxation time of the sheared glasses. A significant decrease in the relaxation time is observed up to the yielding point as the material loses its solid nature and eventually becomes liquid-like. Finally, the imprint of memory of the quiescent sample on the rheological properties of the shear melted glass is investigated by computing the relaxation of the shear stress. We find a finite persistent residual stress that outlasts the experimental observation time in our system.

cond-mat.soft

Effect of Annealed Disorder on Phase Separation Kinetics and Aging Phenomena in Fluid Mixtures

We use state-of-the-art molecular dynamics simulations to study the effects of annealed disorder on the phase separating kinetics and aging phenomena of a segregating binary fluid mixture. In the presence of disorder, we observe a dramatic slowing down in the phase separation dynamics. The domain growth follows the power-law with a disorder-dependent exponent. Due to the energetically favorable positions, the domain boundary roughens which modifies the correlation function and structure factor to a non-Porod behavior. The correlation function and structure factor provide clear evidence that the superuniversality does not hold in our system. The role of annealed disorder on the non-equilibrium aging dynamics is studied qualitatively by computing the two-time order parameter autocorrelation function. The decay of the correlation function slows down significantly with the disorder. This quantity exhibits scaling laws with respect to the ratio of the domain length at the observation time and the age of the system. We find the scaling laws hold good for the disordered system and therefore, robust and generic to such segregating fluid mixtures.

cond-mat.soft

Mechanical Properties and Pore Size Distribution in Athermal Shear-Strained Porous Glasses

In this paper we study the mechanical properties and pore structure in a three-dimensional molecular dynamics model of porous glass under athermal quasistatic shear. The vitreous samples are prepared by rapid thermal quench from a high temperature molten state. The pore structures form via solid-gas phase separation. The quiescent samples exhibit a wide range of pore topography, from inter-connected pore network to randomly distributed compact pores depending on the material density. We find the shear modulus strongly depends on the density and porosity. Under mechanical loading, the pore structure rearranges which is reflected in the pore size distribution function. Our results show that with increase in strain the distribution widens as the adjacent pores coalesce and form larger pores. We also propose a universal scaling law for the pore size distribution function which offers excellent data collapse for highly porous materials in the undeformed case. From the data scaling we identify a critical density which can be attributed to the transition point from a porous-type to bulk-type material. The validity of the scaling law under finite deformation is also analyzed.

cond-mat.soft

Modeling Barkhausen Noise in Magnetic Glasses with Dipole-Dipole Interactions

Long-ranged dipole-dipole interactions in magnetic glasses give rise to magnetic domains having labyrinthine patterns. Barkhausen Noise is then expected to result from the movement of domain boundaries which is supposed to be modeled by the motion of elastic membranes with random pinning. We propose an atomistic model of such magnetic glasses in which we measure the Barkhausen Noise which indeed results from the movement of domain boundaries. Nevertheless the statistics of the Barkhausen Noise is found in striking disagreement with the expectations in the literature. In fact we find exponential statistics without any power law, stressing the fact that Barkhausen Noise can belong to very different universality classes. In this glassy system the essence of the phenomenon is the ability of spin-carrying particles to move and minimize the energy without any spin flip. A theory is offered in excellent agreement with the measured data without any free parameter.

cond-mat.soft

The Anatomy of Plastic Events in Magnetic Amorphous Solids

Plastic events in amorphous solids can be much more than just "shear transformation zones" when the positional degrees of freedom are coupled non-trivially to other degrees of freedom. Here we consider magnetic amorphous solids where mechanical and magnetic degrees of freedom interact, leading to rather complex plastic events whose nature must be disentangled. In this paper we uncover the anatomy of the various contributions to some typical plastic events. These plastic events are seen as Barkhausen Noise or other "serrated noises". Using theoretical considerations we explain the observed statistics of the various contributions to the considered plastic events. The richness of contributions and their different characteristics imply that in general the statistics of these "serrated noises" cannot be universal, but rather highly dependent on the state of the system and on its microscopic interactions.

cond-mat.soft