arXiv subjects

Bibek Tiwari

Publications and source records attributed to Bibek Tiwari.

5 recordsLinked to original sources

arXiv2026

Proton-Transfer Ferroelectrics with Exceptional Switching Endurance

Reliable organic ferroelectrics for memory applications require extreme endurance under repeated electrical switching. Here we demonstrate exceptional fatigue resistance in highly crystalline 2-methylbenzimidazole (MBI) films grown by low-temperature deposition followed by restrained crystallization (LDRC) in a simple Pt/MBI/Pt capacitor geometry. Switching kinetics analyzed using the Kolmogorov-Avrami-Ishibashi (KAI) model reveal characteristic millisecond switching times and quasi-one-dimensional domain growth associated with proton transfer along hydrogen-bond chains. Guided by these kinetics, we implemented a stringent fatigue protocol designed to maximize switching stress, involving bipolar switching at approximately 2Ec with 5 ms pulses, well beyond the characteristic switching time, for continuous operation over approximately 2 weeks. The remanent polarization exhibits only a minor wake-up (+10% within the first 10^4 cycles) and ultimately returns to approximately its initial value after 10^8 cycles, with testing limited by experimental duration rather than device failure. This robust endurance is achieved in an unengineered structure and contrasts with polymer ferroelectrics such as P(VDF-TrFE), where comparable performance typically relies on interfacial engineering. The combination of LDRC-enabled high crystallinity and localized proton-transfer switching, which introduces minimal structural perturbation during polarization reversal, enables this outstanding fatigue tolerance and highlights MBI as a simple, fluorine-free platform for durable organic ferroelectric devices.

cond-mat.mtrl-sci↗

arXiv2025

Spin Dynamics in the van der Waals Ferromagnet CrTe2 Engineered by Niobium Doping

Understanding and controlling spin dynamics in two-dimensional (2D) van der Waals (vdW) ferromagnets is essential for their application in magnonics and hybrid quantum platforms. Here, we investigate the spin dynamics of the vdW ferromagnet 1T-CrTe_{2} and demonstrate their systematic tunability via niobium (Nb) substitution in Cr_{1-x}Nb_{x}Te_{2}(x=0-0.2). Ferromagnetic resonance (FMR) spectroscopy reveals that Nb doping enables wide-band tuning of the resonance frequency from 40 GHz down to the few-GHz regime, accompanied by a moderate increase in the Gilbert damping constant from ~0.066 to ~0.14, while preserving robust room-temperature ferromagnetism. Complementary magnetometry shows a concurrent reduction of the Curie temperature and saturation magnetization with increasing Nb content. Density functional theory calculations attribute the observed spin-dynamic trends to Nb-induced modifications of magnetic anisotropy and magnetic exchange interactions. Furthermore, CrTe_{2} flakes (~80 nm thick) exhibit lower resonance frequencies and damping than bulk crystals, consistent with thickness, surface/interface, and shape-dependent magnetic anisotropy. These results establish Nb-doped CrTe_{2} as a tunable vdW ferromagnet with controllable spin dynamics, extending its functionality from spintronics to broadband magnonics and quantum magnonics.

cond-mat.mtrl-sci↗

arXiv2024

Spherulite-enhanced Macroscopic Polarization in Molecular Ferroelectric Films from Vacuum Deposition

Proton-transfer type molecular ferroelectrics hold great application potential due to their large spontaneous polarizations, high Curie temperatures, and small switching fields. However, it is puzzling that preparation of quasi-2D films with macroscopic ferroelectric behaviors has only been reported in few molecular ferroelectrics. To resolve this puzzle, we studied the effect of microstructures on macroscopic ferroelectric properties of 5,6-Dichloro-2-methylbenzimidazole (DC-MBI) films grown using low-temperature deposition followed by restrained crystallization (LDRC) method. We revealed a competition between dense spherulites and porous microstructures containing randomly oriented nanograins in as-grown films. Post-growth annealing at moderate temperature promotes the formation of spherulites which leads to macroscopic ferroelectric polarization switching. These results highlight microstructure density as a critical factor for macroscopic ferroelectric properties, potentially resolving the puzzle for absence of macroscopic ferroelectric behavior in molecules ferroelectric films. We expect the approach for enhancing microstructure density offered in this work to greatly advance fabrication of quasi-2D molecular ferroelectrics films and to unlock their potential in device applications.

cond-mat.mes-hall↗

arXiv2023

Berry Curvature and Topological Hall Effect in Magnetic Nanoparticles

Analytical calculations and micromagnetic simulations are used to determine the Berry curvature and topological Hall effect (THE) due to conduction electrons in small ferromagnetic particles. Our focus is on small particles of nonellipsoidal shapes, where noncoplanar spin structures yield a nonzero topological Hall signal quantified by the skyrmion number Q. We consider two mechanisms leading to noncoplanarity in aligned nanoparticles, namely flower-state spin configurations due to stray fields near corners and edges, and curling-type magnetostatic selfinteractions. In very small particles, the reverse magnetic fields enhance Q due to the flower state until the reversal occurs, whereas for particles with a radius greater than coherence radius Rcoh the Q jumps to a larger value at the nucleation field representing the transition from the flower state to the curling state. We calculate the Skyrmion density (average Berry curvature) from these spin structures as a function of particle size and applied magnetic field. Our simulation results agree with analytical calculations for both flower state and flux closure states. We showed the presence of Berry curvature in small particles as long as the size of the particle is less than the single domain limit. Using magnetic force microscopy (MFM), we also showed that in a nanodot of Co with a suitable size, a magnetic vortex state with perpendicular (turned-up) magnetization at the core is realized which can be manifested for Berry curvature and emergent magnetic field in confined geometries for single domain state at room temperature.

cond-mat.mtrl-sci↗

arXiv2019

Novel high efficiency quadruple junction solar cell with current matching and quantum efficiency simulations

A high theoretical efficiency of 47.2% was achieved by a novel combination of In0.51Ga0.49P, GaAs, In0.24Ga0.76As and In0.19Ga0.81Sb subcell layers in a simulated quadruple junction solar cell under 1 sun concentration. The electronic bandgap of these materials are 1.9 eV, 1.42 eV, 1.08 eV and 0.55 eV respectively. This unique arrangement enables the cell absorb photons from ultraviolet to deep infrared wavelengths of the sunlight. Emitter and base thicknesses of the subcells and doping levels of the materials were optimized to maintain the same current in all the four junctions and to obtain the highest conversion efficiency. The short-circuit current density, open circuit voltage and fill factor of the solar cell are 14.7 mA/cm2, 3.38 V and 0.96 respectively. In our design, we considered 1 sun, AM 1.5 global solar spectrum.

physics.app-ph↗