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Bin Cui

Publications and source records attributed to Bin Cui.

214 records · Page 12Linked to original sources

DeGNN: Characterizing and Improving Graph Neural Networks with Graph Decomposition

Despite the wide application of Graph Convolutional Network (GCN), one major limitation is that it does not benefit from the increasing depth and suffers from the oversmoothing problem. In this work, we first characterize this phenomenon from the information-theoretic perspective and show that under certain conditions, the mutual information between the output after $l$ layers and the input of GCN converges to 0 exponentially with respect to $l$. We also show that, on the other hand, graph decomposition can potentially weaken the condition of such convergence rate, which enabled our analysis for GraphCNN. While different graph structures can only benefit from the corresponding decomposition, in practice, we propose an automatic connectivity-aware graph decomposition algorithm, DeGNN, to improve the performance of general graph neural networks. Extensive experiments on widely adopted benchmark datasets demonstrate that DeGNN can not only significantly boost the performance of corresponding GNNs, but also achieves the state-of-the-art performances.

cs.LG↗

Realization of Lieb Lattice in Covalent-organic Frameworks with Tunable Topology and Magnetism

Lieb lattice, a two-dimensional edge-depleted square lattice, has been predicted to host various exotic electronic properties due to its unusual band structure, i.e., Dirac cone intersected by a flat band (Dirac-flat bands). Until now, although a few artificial Lieb lattices have been discovered in experiments, the realization of a Lieb lattice in a real material is still unachievable. In this article, based on tight-binding modeling and first-principles calculations, we predict that the two covalent organic frameworks (COFs), i.e., sp2C-COF and sp2N-COF, which have been synthesized in the recent experiments, are actually the first two material realizations of organic-ligand-based Lieb lattice. It is found that the lattice distortion can govern the bandwidth of the Dirac-flat bands and in turn determine its electronic instability against spontaneous spin-polarization during carrier doping. The spin-orbit coupling effects could drive these Dirac-flat bands in a distorted Lieb lattice presenting nontrivial topological properties, which depend on the position of Fermi level. Interestingly, as the hole doping concentration increases, the sp2C-COF can experience the phase transitions from a paramagnetic state to a ferromagnetic one and then to a Néel antiferromagnetic one. Our findings not only confirm the first material realization of Lieb lattice in COFs, but also offer a possible way to achieve tunable topology and magnetism in d- (f-) orbital-free organic lattices.

cond-mat.mtrl-sci↗

An Experimental Evaluation of Large Scale GBDT Systems

Gradient boosting decision tree (GBDT) is a widely-used machine learning algorithm in both data analytic competitions and real-world industrial applications. Further, driven by the rapid increase in data volume, efforts have been made to train GBDT in a distributed setting to support large-scale workloads. However, we find it surprising that the existing systems manage the training dataset in different ways, but none of them have studied the impact of data management. To that end, this paper aims to study the pros and cons of different data management methods regarding the performance of distributed GBDT. We first introduce a quadrant categorization of data management policies based on data partitioning and data storage. Then we conduct an in-depth systematic analysis and summarize the advantageous scenarios of the quadrants. Based on the analysis, we further propose a novel distributed GBDT system named Vero, which adopts the unexplored composition of vertical partitioning and row-store and suits for many large-scale cases. To validate our analysis empirically, we implement different quadrants in the same code base and compare them under extensive workloads, and finally compare Vero with other state-of-the-art systems over a wide range of datasets. Our theoretical and experimental results provide a guideline on choosing a proper data management policy for a given workload.

cs.LG↗

The role of ionic liquid breakdown in the electrochemical metallization of VO2: An NMR study of gating mechanisms and VO2 reduction

Metallization of initially insulating VO2 via ionic liquid electrolytes (electrolyte gating) has recently been a topic of much interest. It is clear that the metallization takes place electrochemically and there has previously been extensive evidence for the removal of small amounts of oxygen during ionic liquid gating. Hydrogen intercalation has also been proposed, but the source of the hydrogen has remained unclear. In this work, solid-state magic angle spinning NMR spectroscopy is used to investigate the thermal metal-insulator transition in VO2, before progressing to catalytically hydrogenated and electrochemically metallized VO2. Electrochemical metallization of bulk VO2 particles is shown to be associated with intercalation of hydrogen, the degree of which can be measured with quantitative 1H NMR spectroscopy. Possible sources of the hydrogen are explored, and by using a selectively deuterated ionic liquid, it is revealed that the hydrogenation is due to deprotonation of the ionic liquid; specifically, for the commonly used dialkylimidazolium based ionic liquids, it is the "carbene" proton that is responsible. Increasing the temperature of the electrochemistry is shown to increase the degree of hydrogenation, forming first a less hydrogenated metallic phase then a more hydrogenated insulating Curie-Weiss paramagnetic phase, both of which were also observed for catalytically hydrogenated VO2. The NMR results are supported by magnetic susceptibility measurements, which corroborate the degree of Pauli and Curie-Weiss paramagnetism. NMR spectroscopy is used to identify the presence of hydrogen in an electrolyte gated thin film of VO2, suggesting that electrolyte breakdown, proton intercalation and reactions with decomposition products within the electrolyte should not be ignored when interpreting the electronic and structural changes observed in electrochemical gating experiments.

cond-mat.str-el↗

Tunable Bi-frustrated Electron Spin and Charge States in a Cu-Hexaaminobenzene Framework

A geometrically frustrated lattice may host frustrated electron spin or charge states that spawn exotic quantum phases. We show that a newly synthesized metal-organic framework of Cu-Hexaaminobenzene [Cu$_3$(HAB)$_2$] exhibits a multi spectra of unusual quantum phases long sought after in condensed matter physics. On one hand, the Cu$^{2+}$ ions form an ideal $S$-1/2 antiferromagnetic kagome lattice. On the other hand, the conjugated-electrons from the organic ligands give rise to completely dispersionless energy bands around the Fermi level, reproducing a frustrated $π_x$-$π_y$ hopping model on a honeycomb lattice. We propose to characterize the coexistence of frustrated local spins and conjugated electrons through scanning tunneling microscopy simulations. Most remarkably, their close energy proximity enables one to tune the system between the two frustrated states by doping up to one hole per HAB unit. Thus, Cu$_3$(HAB)$_2$ provides a unique exciting platform to investigate the interplay of frustrated spins and electrons in one single lattice, e.g. by gating experiments, which will undoubtedly raise interesting theoretical questions leading to possible new condensed-matter phases.

cond-mat.str-el↗

Superconducting Two-Dimensional Metal-Organic Framework

Superconductivity is a fascinating quantum phenomenon characterized by zero electrical resistance and the Meissner effect. To date, several distinct families of superconductors (SCs) have been discovered. These include three-dimensional (3D) bulk SCs in both inorganic and organic materials as well as two-dimensional (2D) thin film SCs but only in $inorganic$ materials. Here we predict superconductivity in 2D and 3D $organic$ metal-organic frameworks by using first-principles calculations. We show that the highly conductive and recently synthesized Cu-benzenehexathial (BHT) is a Bardeen-Cooper-Schrieffer SC. Remarkably, the monolayer Cu-BHT has a critical temperature ($T_{c}$) of 4.43 K while $T_{c}$ of bulk Cu-BHT is 1.58 K. Different from the enhanced $T_{c}$ in 2D inorganic SCs which is induced by interfacial effects, the $T_{c}$ enhancement in this 2D organic SC is revealed to be the out-of-plane soft-mode vibrations, analogous to surface mode enhancement originally proposed by $Ginzburg$. Our findings not only shed new light on better understanding 2D superconductivity, but also open a new direction to search for SCs by interface engineering with organic materials.

cond-mat.mtrl-sci↗

Creation of Half-metallic f -orbital Dirac Fermion with Superlight Elements in Orbital-Designed Molecular Lattice

Magnetism in solids generally originates from the localized $d$- or $f$-orbitals that are hosted by heavy transition-metal elements. Here, we demonstrate a novel mechanism for designing half-metallic $f$-orbital Dirac fermion from superlight $sp$-elements. Combining first-principles and model calculations, we show that bare and flat-band-sandwiched (FBS) Dirac bands can be created when C$_{20}$ molecules are deposited into a 2D hexagonal lattice, which are composed of $f$-molecular orbitals (MOs) derived from $sp$-atomic orbitals (AOs). Furthermore, charge doping of the FBS Dirac bands induces spontaneous spin-polarization, converting the system into a half-metallic Dirac state. Based on this discovery, a model of spin field effect transistor is proposed to generate and transport 100\% spin-polarized carriers. Our finding illustrates a novel concept to realize exotic quantum states by manipulating MOs, instead of AOs, in orbital-designed molecular crystal lattices.

cond-mat.mes-hall↗

Photon-gated spin transistor

Spin-polarized field-effect transistor (spin-FET), where a dielectric layer is generally employed for the electrical gating as the traditional FET, stands out as a seminal spintronic device under the miniaturization trend of electronics. It would be fundamentally transformative if optical gating was used for spin-FET. We report a new type of spin-polarized field-effect transistor (spin-FET) with optical gating, which is fabricated by partial exposure of the (La,Sr)MnO3 channel to light-emitting diode (LED) light. The manipulation of the channel conductivity is ascribed to the enhanced scattering of the spin-polarized current by photon-excited antiparallel aligned spins. And the photon-gated spin-FET shows strong light power dependence and reproducible enhancement of resistance under light illumination, indicting well-defined conductivity cycling features. Our finding would enrich the concept of spin-FET and promote the use of optical means in spintronics for low power consumption and ultrafast data processing.

cond-mat.mtrl-sci↗

Recent progress in voltage control of magnetism: Materials, mechanisms, and performance

Voltage control of magnetism (VCM) is attracting increasing interest and exciting significant research activity driven by its profound physics and enormous potential for application. This review article aims to provide a comprehensive review of recent progress in VCM in different thin films. We first present a brief summary of the modulation of magnetism by electric fields and describe its discovery, development, classification, mechanism, and potential applications. In the second part, we focus on the classification of VCM from the viewpoint of materials, where both the magnetic medium and dielectric gating materials, and their influences on magnetic modulation efficiency are systematically described. In the third part, the nature of VCM is discussed in detail, including the conventional mechanisms of charge, strain, and exchange coupling at the interfaces of heterostructures, as well as the emergent models of orbital reconstruction and electrochemical effect. The fourth part mainly illustrates the typical performance characteristics of VCM, and discusses, in particular, its promising application for reducing power consumption and realizing high-density memory in several device configurations. The present review concludes with a discussion of the challenges and future prospects of VCM, which will inspire more in-depth research and advance the practical applications of this field.

cond-mat.mtrl-sci↗

SF-sketch: A Two-stage Sketch for Data Streams

A sketch is a probabilistic data structure used to record frequencies of items in a multi-set. Sketches are widely used in various fields, especially those that involve processing and storing data streams. In streaming applications with high data rates, a sketch "fills up" very quickly. Thus, its contents are periodically transferred to the remote collector, which is responsible for answering queries. In this paper, we propose a new sketch, called Slim-Fat (SF) sketch, which has a significantly higher accuracy compared to prior art, a much smaller memory footprint, and at the same time achieves the same speed as the best prior sketch. The key idea behind our proposed SF-sketch is to maintain two separate sketches: a small sketch called Slim-subsketch and a large sketch called Fat-subsketch. The Slim-subsketch is periodically transferred to the remote collector for answering queries quickly and accurately. The Fat-subsketch, however, is not transferred to the remote collector because it is used only to assist the Slim-subsketch during the insertions and deletions and is not used to answer queries. We implemented and extensively evaluated SF-sketch along with several prior sketches and compared them side by side. Our experimental results show that SF-sketch outperforms the most widely used CM-sketch by up to 33.1 times in terms of accuracy. We have released the source codes of our proposed sketch as well as existing sketches at Github. The short version of this paper will appear in ICDE 2017.

cs.DS↗

Bending Strain Engineering of Spin Transport in Quantum Spin Hall Systems: Topological Nano-mechanospintronics

Quantum spin Hall (QSH) system can exhibit exotic spin transport phenomena, mediated by its topological edge states. Here a novel concept of bending strain engineering to tune the spin transport properties of a QSH system is demonstrated by both model and first-principles calculations. Interestingly, we discover that bending strain can be used to mitigate the spin conservation of a QSH system to generate a non-zero spin current (SC), meanwhile the preservation of time reversal symmetry renders its edge states topologically protected to transport robust SC without back scattering. This novel physics mechanism can be applied to effectively tune the SC and spin Hall current in a QSH system by control of its bending curvature. Furthermore, the realization of QSH systems with controllable curvature can be achieved by the concept of "topological nanomechnical architecture". Taking Bi/Cl/Si(111) as a material example, we demonstrate that the relative spin orientations between two edge states of a Bi/Cl/Si(111) film can indeed be tuned dramatically by its self-bending behaviors induced by the pre-designed inherent strain. Therefore, this concept of "bending strain engineering of spins" via topological nanomechanical architecture affords a promising route towards the realization of topological nano-mechanospintronics.

cond-mat.mes-hall↗

Electrical control of magnetism in oxides

This review article aims at illustrating the recent progresses in the electrical control of magnetism in oxides with profound physics and enormous potential applications. In the first part, we provide a comprehensive summary of the electrical control of magnetism in the classic multiferroic heterostructures and clarify their various mechanisms lying behind. The second part focuses on the novel route of electric double layer gating for driving a significantly electronic phase transition in magnetic oxides by a small voltage. The electric field applied on the ordinary dielectric oxide in the third part is used to control the magnetic phenomenon originated from the charge transfer and orbital reconstruction at the interface between dissimilar correlated oxides. At last, we analyze the challenges in electrical control of magnetism in oxides, both on mechanism and practical application, which would inspire more in-depth researches and advance the development in this field.

cond-mat.mtrl-sci↗

Magnetoelectric coupling induced by interfacial orbital reconstruction

The magnetoelectric coupling effect with profound physics and enormous potential applications has provoked a great number of research activities in materials science. Here, we report that the reversible orbital reconstruction driven by ferroelectric polarization modulates the magnetic performance of ferroelectric ferromagnetic heterostructure. Mn in plane orbital occupancy and related interfacial exotic magnetic state are enhanced and weakened by the negative and positive electric field, respectively. Our findings thus not only present a broad opportunity to fill the missing member, orbital in the mechanism of magnetoelectric coupling, but also make the orbital degree of freedom straight forward to the application in microelectronic device.

cond-mat.str-el↗

Electrical manipulation of orbital occupancy and magnetic anisotropy in manganites

Electrical manipulation of lattice, charge, and spin has been realized respectively by the piezoelectric effect, field-effect transistor, and electric field control of ferromagnetism, bringing about dramatic promotions both in fundamental research and industrial production. However, it is generally accepted that the orbital of materials are impossible to be altered once they have been made. Here we use electric-field to dynamically tune the electronic phase transition in (La,Sr)MnO3 films with different Mn^4+/(Mn^3+ + Mn^4+) ratios. The orbital occupancy and corresponding magnetic anisotropy of these thin films are manipulated by gate voltage in a reversible and quantitative manner. Positive gate voltage increases the proportion of occupancy of the orbital and magnetic anisotropy that were initially favored by strain (irrespective of tensile and compressive), while negative gate voltage reduces the concomitant preferential orbital occupancy and magnetic anisotropy. Besides its fundamental significance in orbital physics, our findings might advance the process towards practical oxide-electronics based on orbital.

cond-mat.mtrl-sci↗

Community Specific Temporal Topic Discovery from Social Media

Studying temporal dynamics of topics in social media is very useful to understand online user behaviors. Most of the existing work on this subject usually monitors the global trends, ignoring variation among communities. Since users from different communities tend to have varying tastes and interests, capturing community-level temporal change can improve the understanding and management of social content. Additionally, it can further facilitate the applications such as community discovery, temporal prediction and online marketing. However, this kind of extraction becomes challenging due to the intricate interactions between community and topic, and intractable computational complexity. In this paper, we take a unified solution towards the community-level topic dynamic extraction. A probabilistic model, CosTot (Community Specific Topics-over-Time) is proposed to uncover the hidden topics and communities, as well as capture community-specific temporal dynamics. Specifically, CosTot considers text, time, and network information simultaneously, and well discovers the interactions between community and topic over time. We then discuss the approximate inference implementation to enable scalable computation of model parameters, especially for large social data. Based on this, the application layer support for multi-scale temporal analysis and community exploration is also investigated. We conduct extensive experimental studies on a large real microblog dataset, and demonstrate the superiority of proposed model on tasks of time stamp prediction, link prediction and topic perplexity.

cs.SI↗

Challenging the Long Tail Recommendation

The success of "infinite-inventory" retailers such as Amazon.com and Netflix has been largely attributed to a "long tail" phenomenon. Although the majority of their inventory is not in high demand, these niche products, unavailable at limited-inventory competitors, generate a significant fraction of total revenue in aggregate. In addition, tail product availability can boost head sales by offering consumers the convenience of "one-stop shopping" for both their mainstream and niche tastes. However, most of existing recommender systems, especially collaborative filter based methods, can not recommend tail products due to the data sparsity issue. It has been widely acknowledged that to recommend popular products is easier yet more trivial while to recommend long tail products adds more novelty yet it is also a more challenging task. In this paper, we propose a novel suite of graph-based algorithms for the long tail recommendation. We first represent user-item information with undirected edge-weighted graph and investigate the theoretical foundation of applying Hitting Time algorithm for long tail item recommendation. To improve recommendation diversity and accuracy, we extend Hitting Time and propose efficient Absorbing Time algorithm to help users find their favorite long tail items. Finally, we refine the Absorbing Time algorithm and propose two entropy-biased Absorbing Cost algorithms to distinguish the variation on different user-item rating pairs, which further enhances the effectiveness of long tail recommendation. Empirical experiments on two real life datasets show that our proposed algorithms are effective to recommend long tail items and outperform state-of-the-art recommendation techniques.

cs.DB↗