arXiv subjects

Bingying Pan

Publications and source records attributed to Bingying Pan.

14 recordsLinked to original sources

arXiv2026

On estimating superconducting shielding volume fraction from susceptibility in pressurized Ruddlesden-Popper nickelates: Response to arXiv:2602.19282

In a recent preprint (arXiv:2602.19282) [1], the authors questioned the procedure we used to evaluate the demagnetization-corrected superconducting shielding volume fraction in pressurized Ruddlesden-Popper nickelates [2-5]. They further claimed that this methodology has neither been derived nor used previously, and they proposed an alternative normalization scheme. Here we clarify that our evaluation follows directly from the standard magnetostatic self-consistency relation for finite samples and has been widely adopted in the superconductivity literature for decades. We also demonstrate that the discrepancies claimed in Ref. [1] stem from a fundamental flaw in their approach, namely, the assumption that the measured diamagnetic moment is linearly proportional to the superconducting shielding volume fraction in the presence of a finite demagnetization factor N. This assumption is not valid for strongly demagnetized, thin disk-like specimens, where the internal field and the measured moment are coupled self-consistently through the demagnetizing field.

cond-mat.supr-con↗

arXiv2025

Spinons, solitons and random singlets in the spin-chain compound copper benzoate

The $S=1/2$ antiferromagnetic Heisenberg chain is a paradigmatic quantum system hosting exotic excitations such as spinons and solitons, and forming random singlet state in the presence of quenched disorder. Realizing and distinguishing these excitations in a single material remains a significant challenge. Using nuclear magnetic resonance (NMR) on a high-quality single crystal of copper benzoate, we identify and characterize all three excitation types by tuning the magnetic field at ultra-low temperatures. At a low field of 0.2 T, a temperature-independent spin-lattice relaxation rate ($1/T_1$) over more than a decade confirms the presence of spinons. Below 0.4 K, an additional relaxation channel emerges, characterized by $1/T_1 \propto T$ and a spectral weight growing as $-\ln(T/T_0)$, signaling a random-singlet ground state induced by weak quenched disorder. At fields above 0.5 T, a field-induced spin gap $\Delta \propto H^{2/3}$ observed in both $1/T_1$ and the Knight shift signifies soliton excitations. Our results establish copper benzoate as a unique experimental platform for studying one-dimensional quantum integrability and the interplay of disorder and correlations.

cond-mat.str-el↗

arXiv2024

Spin correlations in the parent phase of Li$_{1-x}$Fe$_x$ODFeSe

Elucidating spin correlations in the parent compounds of high-temperature superconductors is crucial for understanding superconductivity. We used neutron scattering to study spin correlations in Li$_{1-x}$Fe$_x$ODFeSe, an insulating material with reduced electron carriers compared to its superconducting counterpart ($T_c$ = 41 K), serving as the undoped parent compound. Our findings show a reduced total fluctuating moment in this insulator relative to FeSe and 122 iron pnictides, likely due to increased interlayer distances from intercalation, which enhance fluctuations and reduce the intensity of spin excitations. Moreover, we observed a V-shaped spin wave-like excitation dispersion, contrasting with the twisted hourglass pattern in the superconducting counterpart. Electron doping shifts spin excitation from ($\pi$, 0) point to an incommensurate position towards ($\pi$, $\pi$) direction below 65 meV. This transition from V-shaped to hourglass-like dispersion, akin to behaviors in hole-doped cuprates, suggests a potential shared mechanism in magnetism and superconductivity across these diverse systems.

cond-mat.supr-con↗

arXiv2023

Superconductivity in pressurized trilayer La$_4$Ni$_3$O$_{10-{\delta}}$ single crystals

The pursuit of discovering new high-temperature superconductors that diverge from the copper-based paradigm1-3 carries profound implications for elucidating mechanisms behind superconductivity and may also enable new applications4-8. Here, our investigation reveals that application of pressure effectively suppresses the spin and charge order in trilayer nickelate La4Ni3O10-{\delta} single crystals, leading to the emergence of superconductivity with a maximum critical temperature (Tc) of around 30 K at 69.0 GPa. The DC susceptibility measurements confirm a substantial diamagnetic response below Tc, indicating the presence of bulk superconductivity with a volume fraction exceeding 80%. In the normal state, we observe a "strange metal" behavior, characterized by a linear temperature-dependent resistance extending up to 300 K. Furthermore, the layer-dependent superconductivity observed hints at a unique interlayer coupling mechanism specific to nickelates, setting them apart from cuprates in this regard. Our findings provide crucial insights into the fundamental mechanisms underpinning superconductivity, while also introducing a new material platform to explore the intricate interplay between the spin/charge order, flat band structures, interlayer coupling, strange metal behavior and high-temperature superconductivity.

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arXiv2022

Evolution of Superatomic-Charge-density-wave and Superconductivity under Pressure in AuTe$_2$Se$_{4/3}$

Superatomic crystal is a class of hierarchical materials composed of atomically precise clusters assembled via van der Waals or covalent-like interactions. AuTe$_2$Se$_{4/3}$, an all-inorganic superatomic superconductor exhibiting superatomic-charge-density-wave (S-CDW), provides a first platform to study the response of their collectively quantum phenomenon to the external pressure in superatomic crystals. We reveal a competition between S-CDW and superconductivity using cutting-edge measurements on thin flakes at low pressures. Prominently, the pressure modulation of S-CDW ordering is 1$\sim$2 order of magnitudes (0.1 GPa) lower than that of conventional atomic superconductors. As pressure increases to 2.5 GPa, the $T_{\mathrm{CDW}}$ is suppressed and the superconducting transition temperature ($T_{\mathrm{c}}$) is firstly enhanced, and reaches the maximum then quenches with increasing pressure. Above 7.3 GPa, a second superconducting phase emerges, and then a three-fold enhancement in the transition temperature ($T_{\mathrm{c}}$) happens. Analyses of the crystal structure and theoretical calculations suggest a pressure-mediated switch of the conduction channel from the $a$- to the $b$-axis occur, followed by a dimensional crossover of conductivity and the Fermi surface from 2D to 3D.

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arXiv2018

Intertwined Spin and Orbital Density Waves in MnP Uncovered by Resonant Soft X-ray Scattering

Unconventional superconductors are often characterized by numerous competing and even intertwined orders in their phase diagrams. In particular, the electronic nematic phases, which spontaneously break rotational symmetry and often simultaneously involve spin, charge and/or orbital orders, appear conspicuously in both the cuprate and iron-based superconductors. The fluctuations associated with these phases may provide the exotic pairing glue that underlies their high-temperature superconductivity. Helimagnet MnP, the first Mn-based superconductor under pressure, lacks high rotational symmetry. However our resonant soft X-ray scattering (RSXS) experiment discovers novel helical orbital density wave (ODW) orders in this three-dimensional, low-symmetry system, and reveals intertwined ordering phenomena in unprecedented detail. In particular, a ODW forms with half the period of the spin order and fully develops slightly above the spin ordering temperature, their domains develop simultaneously, yet the spin order domains are larger than those of the ODW, and they cooperatively produce another ODW with 1/3 the period of the spin order. These observations provide a comprehensive picture of the intricate interplay between spin and orbital orders in correlated materials, and they suggest that nematic-like physics ubiquitously exists beyond two-dimensional and high-symmetry systems, and the superconducting mechanism of MnP is likely analogous to those of cuprate and iron-based superconductors.

cond-mat.supr-con↗

arXiv2018

Coexistence of ferromagnetic and stripe-type antiferromagnetic spin fluctuations in YFe$_2$Ge$_2$

We report neutron scattering measurements of single-crystalline YFe$_2$Ge$_2$ in the normal state, which has the same crystal structure to the 122 family of iron pnictide superconductors. YFe$_2$Ge$_2$ does not exhibit long range magnetic order, but exhibits strong spin fluctuations. Like the iron pnictides, YFe$_2$Ge$_2$ displays anisotropic stripe-type antiferromagnetic spin fluctuations at ($π$, $0$, $π$). More interesting, however, is the observation of strong spin fluctuations at the in-plane ferromagnetic wavevector ($0$, $0$, $π$). These ferromagnetic spin fluctuations are isotropic in the ($H$, $K$) plane, whose intensity exceeds that of stripe spin fluctuations. Both the ferromagnetic and stripe spin fluctuations remain gapless down to the lowest measured energies. Our results naturally explain the absence of magnetic order in YFe$_2$Ge$_2$ and also imply that the ferromagnetic correlations may be a key ingredient for iron-based materials.

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arXiv2017

Evidence for a spinon Fermi surface in a triangular lattice quantum spin liquid candidate

A quantum spin liquid is an exotic quantum state of matter in which spins are highly entangled and remain disordered down to zero temperature. Such a state of matter is potentially relevant to high-temperature superconductivity and quantum-information applications, and experimental identification of a quantum spin liquid state is of fundamental importance for our understanding of quantum matter. Theoretical studies have proposed various quantum-spin-liquid ground states, most of which are characterized by exotic spin excitations with fractional quantum numbers (termed `spinon'). Here, we report neutron scattering measurements that reveal broad spin excitations covering a wide region of the Brillouin zone in a triangular antiferromagnet YbMgGaO4. The observed diffusive spin excitation persists at the lowest measured energy and shows a clear upper excitation edge, which is consistent with the particle-hole excitation of a spinon Fermi surface. Our results therefore point to a QSL state with a spinon Fermi surface in YbMgGaO4 that has a perfect spin-1/2 triangular lattice as in the original proposal of quantum spin liquids.

cond-mat.str-el↗

arXiv2017

Structure of spin excitations in heavily electron-doped Li0.8Fe0.2ODFeSe superconductors

Heavily electron-doped iron-selenide (HEDIS) high-transition-temperature (high-$T_{\rm{c}}$) superconductors, which have no hole Fermi pockets, but have a notably high $T_{\rm{c}}$, have challenged the prevailing $s$$_\pm$ pairing scenario originally proposed for iron pnictides containing both electron and hole pockets. The microscopic mechanism underlying the enhanced superconductivity in HEDIS remains unclear. Here, we used neutron scattering to study the spin excitations of the HEDIS material Li$_{0.8}$Fe$_{0.2}$ODFeSe ($T_{\rm{c}}$ = 41 K). Our data revealed nearly ring-shaped magnetic resonant excitations surrounding ($π$, $π$) at $\sim$ 21 meV. As the energy increased, the spin excitations assumed a diamond shape, and they dispersed outward until the energy reached $\sim$ 60 meV and then inward at higher energies. The observed energy-dependent momentum structure and twisted dispersion of spin excitations near ($π$, $π$) are analogous to those of hole-doped cuprates in several aspects, thus implying that such spin excitations are essential for the remarkably high $T_{\rm{c}}$ in these materials.

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arXiv2016

Magnetic ground state of FeSe

Elucidating the nature of the magnetism of a high-temperature superconductor is crucial for establishing its pairing mechanism. The parent compounds of the cuprate and iron-pnictide superconductors exhibit Néel and stripe magnetic order, respectively. However, FeSe, the structurally simplest iron-based superconductor, shows nematic order (Ts = 90 K), but not magnetic order in the parent phase, and its magnetic ground state is intensely debated. Here, we report inelastic neutron-scattering experiments that reveal both stripe and Néel spin fluctuations over a wide energy range at 110 K. On entering the nematic phase, a substantial amount of spectral weight is transferred from the Néel to the stripe spin fluctuations. Moreover, the total fluctuating magnetic moment of FeSe is ~ 60% larger than that in the iron pnictide BaFe2As2. Our results suggest that FeSe is a novel S = 1 nematic quantum-disordered paramagnet interpolating between the Néel and stripe magnetic instabilities.

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arXiv2016

Transition from sign-reversed to sign-preserved Cooper-pairing symmetry in sulfur-doped iron selenide superconductors

An essential step toward elucidating the mechanism of superconductivity is to determine the sign/phase of superconducting order parameter, as it is closely related to the pairing interaction. In conventional superconductors, the electron-phonon interaction induces attraction between electrons near the Fermi energy and results in a sign-preserved s-wave pairing. For high-temperature superconductors, including cuprates and iron-based superconductors, prevalent weak coupling theories suggest that the electron pairing is mediated by spin fluctuations which lead to repulsive interactions, and therefore that a sign-reversed pairing with an s+-or d-wave symmetry is favored. Here, by using magnetic neutron scattering, a phase sensitive probe of superconducting gap, we report the observation of a transition from the sign-reversed to sign-preserved Cooper-pairing symmetry with insignificant changes in Tc in the S-doped iron selenide superconductors KxFe2-y(Se1-zSz)2. We show that a rather sharp magnetic resonant mode well below the superconducting gap (2delta) in the undoped sample (z = 0) is replaced by a broad hump structure above 2delta under 50% S doping. These results cannot be readily explained by simple spin fluctuation-exchange pairing theories and, therefore, multiple pairing channels are required to describe superconductivity in this system. Our findings may also yield a simple explanation for the sometimes contradictory data on the sign of the superconducting order parameter in iron-based materials.

cond-mat.supr-con↗

arXiv2015

Structural and Magnetic Phase Diagram of CrAs and its Relationship with Pressure-induced Superconductivity

Most unconventional superconductors, including cuprates and iron-based superconductors, are derived from chemical doping or application of pressure on their collinearly magnetic-ordered parent compounds[1-5]. The recently discovered pressure-induced superconductor CrAs, as a rare example of a non-collinear helimagnetic superconductor, has therefore generated great interest in understanding microscopic magnetic properties and their interplay with superconductivity [6-8]. Unlike cuprates and iron based superconductors where the magnetic moment direction barely changes upon doping, here we show that CrAs exhibits a spin reorientation from the ab plane to the ac plane, along with an abrupt drop of the magnetic propagation vector at a critical pressure (Pc~0.6 GPa). This magnetic phase transition coincides with the emergence of bulk superconductivity, indicating a direct connection between magnetism and superconductivity. With further increasing pressure, the magnetic order completely disappears near the optimal Tc regime (P~0.94 GPa). Moreover, the Cr magnetic moments between nearest neighbors tend to be aligned antiparallel with increasing pressure toward the optimal superconductivity regime. Our findings suggest that the non-collinear helimagnetic order is strongly coupled to structural and electronic degrees of freedom, and that antiferromagnetic correlations associated with the low magnetic vector phase are crucial for superconductivity.

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arXiv2015

Strong Interplay between Stripe Spin Fluctuations, Nematicity and Superconductivity in FeSe

Elucidating the microscopic origin of nematic order in iron-based superconducting materials is important because the interactions that drive nematic order may also mediate the Cooper pairing. Nematic order breaks fourfold rotational symmetry in the iron plane, which is believed to be driven by either orbital or spin degrees of freedom. However, as the nematic phase often develops at a temperature just above or coincides with a stripe magnetic phase transition, experimentally determining the dominant driving force of nematic order is difficult. Here, we use neutron scattering to study structurally the simplest iron-based superconductor FeSe, which displays a nematic (orthorhombic) phase transition at $T_s=90$ K, but does not order antiferromagnetically. Our data reveal substantial stripe spin fluctuations, which are coupled with orthorhombicity and are enhanced abruptly on cooling to below $T_s$. Moreover, a sharp spin resonance develops in the superconducting state, whose energy (~4 meV) is consistent with an electron boson coupling mode revealed by scanning tunneling spectroscopy, thereby suggesting a spin fluctuation-mediated sign-changing pairing symmetry. By normalizing the dynamic susceptibility into absolute units, we show that the magnetic spectral weight in FeSe is comparable to that of the iron arsenides. Our findings support recent theoretical proposals that both nematicity and superconductivity are driven by spin fluctuations.

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arXiv2013

Re-entrance of Gapless Quantum Spin Liquids Observed in a Newly Synthesized Spin-1/2 Kagome Antiferromagnet $ZnCu_{3}(OH)_{6}SO_{4}$

Quantum spin liquid (QSL) is a novel state of matter with exotic excitations and was theoretically predicted to be realized most possibly in an S=1/2 kagome antiferromagnet. Experimentally searching for the candidate materials is a big challenge in condensed matter physics and only two such candidates were reported so far. Here we report the successful synthesis of a new spin-1/2 kagome antiferromagnet ZnCu3(OH)6SO4. No magnetic ordering is observed down to 50 mK, despite a moderately high Weiss temperature of θW ~ -79 K. It strongly suggests that the material is a new QSL candidate. Most interestingly, the magnetic specific heat clearly exhibits linear behaviors in two low-temperature regions. Both behaviors exactly correspond to two temperature-independent susceptibilities. These consistently reveal a novel re-entrance phenomenon of gapless QSL state at the lowest temperatures. The findings provide new insights into QSL ground and excited states and will inspire new theoretical and experimental studies.

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