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Boris Naydenov

Publications and source records attributed to Boris Naydenov.

At least 19 recordsLinked to original sources

Quantum Vault: Symmetric No-Cloning Protection for Token Issuer and User (Benchmarked on IBMQ)

Quantum tokens are underlying primitives for quantum money and network proposals, which leverage the no-cloning theorem to realize unforgeable authentication. A relevant but overlooked type of attack to such architectures is one in which a hacker steals the classical side information about the token states from the issuing agent (e.g., a bank), enabling the forgery of fake tokens without violating the no-cloning theorem. Our proposal addresses this threat by removing the classical side information about the token states, where instead a copy of the token is stored at the bank, i.e. a quantum vault. This copy can be accessed by anyone to perform authentication, consuming the token pair in the process. We benchmark the protocol and identify quality parameters within a hardware agnostic framework employing IBMQ processors, such that the protocol is applicable to arbitrary quantum platforms. By comparing the efficiency with which genuine tokens are produced and authenticated against a possible estimate-and-forge attack, we quantify the security of the protocol. We achieve probabilities lower than $10^{-4}$ for false-negative errors (Type 1) and $10^{-10}$ for successful attacks (Type 2) when considering quantum bills composed of 200 tokens, even in the worst performing processor and most conservative uncertainty estimate. The quantum vault not only protects both user and bank symmetrically with the same quantum principles, but provides a step towards public key authentication, since any untrusted party can have access granted by the bank to the tokens' authentication interface without being able to clone them. Besides this bank-mediated form of publicly accessible verifiability, our proposal achieves traceability and revocability, since the bank retains the vault copy of the tokens.

quant-ph↗

Quantum Gates via Dynamical Decoupling of Central Qubit on IBMQ and 15NV Center in Diamond

We demonstrate a hardware-agnostic protocol for realizing fast, high-fidelity gates through dynamical decoupling (DD) pulse sequences applied to a central qubit coupled to target qubits. The target qubits are controlled by leveraging their intrinsic interaction with the central qubit, eliminating the need for slow, error-prone direct control. We develop and implement the DD-gate protocol within two distinct frameworks: a general model with minimal assumptions, benchmarked on a gate-based digital quantum simulator given by the IBMQ; and an experimentally realistic case with a nitrogen-15 vacancy center ($^{15}$NV) in diamond. Using IBMQ, we are able to elucidate the underlying quantum dynamics of the DD-gates and test them, independently of experimental constraints. For $^{15}$NV, we realize the protocol considering system-specific properties, which could represent a significant reduction in gate duration and improved technological scalability compared with current dynamical-decoupling-based control. We also propose a simple application for high-efficiency polarization of the $^{15}$N nuclear spin that could potentially be less technically demanding than current methods. Altogether, this work provides a robust strategy for quantum control that can be implemented in arbitrary systems fitting the central-target qubit architecture. Beyond these results, our open-source simulations and implementations for both platforms provide a practical framework for simulating time-dependent qubit dynamics on NISQ-era gate-based quantum processors.

quant-ph↗

Practical quantum tokens: challenges and perspectives

The concept of quantum tokens dates back alongside quantum cryptography to Stephen Wiesner's seminal work in 1983[1]. Already this initial work proposes society-relevant applications such as secure quantum banknotes, which can be exchanged between a bank and a customer. This quantum currency is based on various physical states that can be easily verified but is protected from being copied by the fundamental quantum laws. Four decades later, these ideas have flourished in the field of quantum information, and the concept of quantum banknotes has not only adopted many varying names, such as quantum money, quantum coins, quantum-digital payments, and quantum tokens, but also reached its first experimental demonstrations. In this perspective article, we discuss the current state-of-the-art of quantum tokens in the field of quantum information, as well as their future perspectives. We present a number of physical realizations of quantum tokens with integrated quantum memories and their applicability scenarios in detail. Finally, we discuss how quantum tokens fit into the information security ecosystem and consider their relationship to post-quantum cryptography.

quant-ph↗

Digital Twin Simulations Toolbox of the Nitrogen-Vacancy Center in Diamond

The nitrogen-vacancy (NV) center in diamond is a crucial platform for quantum technologies, where its precise numerical modeling is indispensable for the continued advancement of the field. We present here a Python library for simulating the NV spin dynamics under general experimental conditions, i.e. a digital twin. Our library accounts for electromagnetic pulses and other environmental inputs, which are used to solve the system's time evolution, resulting in a physical output in the form of a quantum observable given by fluorescence. The simulation framework is based on a non-perturbative time-dependent Hamiltonian model, where the states initialization and readout are postulated from the interaction with optical fields. By eliminating oversimplifications such as the adoption of rotating frames for the microwave and radio frequency fields, our simulations reveal subtle dynamics emerging from realistic pulse constraints. The software is illustrated with three examples and validated by comparing the simulations with experimental reports, relevant to the fields of quantum computing (conditional logic gates), sensing (dynamical decoupling sequences with coupled spins) and networks (state teleportation). Overall, this digital twin delivers a robust numerical modeling of the NV spin dynamics, with simple and accessible usability, which can be used for a wide range of applications.

quant-ph↗

Ensemble-Based Quantum Token Protocol Benchmarked on IBM Quantum Processors

Quantum tokens envision to store unclonable quantum states in a physical device, with the goal of being used for personal authentication protocols, as required by banks. Still, the experimental realization of such devices faces many technical challenges, which can be partially mitigated using ensembles instead of single qubits. In this work, we thus propose an ensemble-based quantum token protocol, describing it through a simple yet general model based on a quantum mechanical observable. The protocol is benchmarked on five IBM quantum processors and a general hacker attack scenario is analyzed, in which the attacker attempts to read the bank token and forge a fake one, based on the information gained from this measurement. We experimentally demonstrate that the probability that the bank erroneously accepts a forged coin composed of multiple tokens can reach values below $10^{-22}$, while the probability that the bank accepts its own coin is above 0.999. The overall security of the protocol is therefore demonstrated within a hardware-agnostic framework, confirming the practical viability of the protocol in arbitrary quantum systems and thus paving the way for future applications with different ensembles of qubits, such as color center defects in solids.

quant-ph↗

Security Analysis of Ensemble-Based Quantum Token Protocol Under Advanced Attacks

We present and characterize advanced attacks on an ensemble-based quantum token protocol that allows for implementing non-clonable quantum coins. Multiple differently initialized tokens of identically prepared qubit ensembles are combined to a quantum coin that can be issued by a bank. A sophisticated attempt to copy tokens can assume that measurements on sub-ensembles can be carried through and that even individual qubits can be measured. Even though such an advanced attack might be perceived as technically unfeasible, we prove the security of the protocol under these conditions. We performed numerical simulations and verified our results by experiments on the IBM Quantum Platforms for different types of advanced attacks. Finally, we demonstrate that the security of the quantum coin can be made high by increasing the number of tokens. This paper in conjunction with provided numerical simulation tools verified against experimental data from the IBM Quantum Platforms allows for securely implementing our ensemble-based quantum token protocol with arbitrary quantum systems.

quant-ph↗

Local nanoscale probing of electron spins using NV centers in diamond

Substitutional nitrogen atoms in a diamond crystal (P1 centers) are, on one hand, a resource for creation of nitrogen-vacancy (NV) centers, that have been widely employed as nanoscale quantum sensors. On the other hand, P1's electron spin is a source of paramagnetic noise that degrades the NV's performance by shortening its coherence time. Accurate quantification of nitrogen concentration is therefore essential for optimizing diamond-based quantum devices. However, bulk characterization methods based on optical absorption or electron paramagnetic resonance often overlook local variations in nitrogen content. In this work, we use a helium ion microscope to fabricate nanoscale NV center ensembles at predefined sites in a diamond crystal containing low concentrations of nitrogen. We then utilize these NV-based probes to measure the local nitrogen concentration on the level of 230 ppb (atomic parts per billion) using the double electron-electron resonance (DEER) technique. Moreover, by comparing the DEER spectra with numerical simulations, we managed to determine the concentration of other unknown paramagnetic defects created during the ion implantation, reaching 15 ppb depending on the implantation dose.

quant-ph↗

Impact of Annealing and Nanostructuring on Properties of NV Centers Created by Different Techniques

Nitrogen-vacancy (NV) centers in diamonds have been an epicenter of research for diverse applications in quantum technologies. It is therefore imperative that their fabrication techniques are well understood and characterized for the technological scalability of these applications. A comparative study of the optical and spin properties of NVs created by ion implantation and chemical vapor deposition delta-doping is thus presented, combined with an investigation on the impact of annealing in vacuum at different temperatures. In addition, nanopillars are fabricated with electron beam lithography and reactive ion etching for enhanced photon collection efficiency. An extensive combination of characterization techniques is employed. Notably, the smallest nanopillars present fluorescence enhancements of factor around 50, compared to the unstructured regions. Annealing is also demonstrated to increase the optical contrast between the NVs' electronic states, the coherence and relaxation times both in bulk as in pillars. Regarding the NV preparation technique, the delta-doping is shown to create NVs with less lattice defects and strain compared to implantation.

physics.app-ph↗

Ambiguous Resonances in Multipulse Quantum Sensing with Nitrogen Vacancy Centers

Dynamical decoupling multipulse sequences can be applied to solid state spins for sensing weak oscillating fields from nearby single nuclear spins. By periodically reversing the probing system's evolution, other noises are counteracted and filtered out over the total evolution. However, the technique is subject to intricate interactions resulting in additional resonant responses, which can be misinterpreted with the actual signal intended to be measured. We experimentally characterized three of these effects present in single nitrogen vacancy centers in diamond, where we also developed a numerical simulations model without rotating wave approximation, showing robust correlation to the experimental data. Regarding centers with the $^{15}$N nitrogen isotope, we observed that a small misalignment in the bias magnetic field causes the precession of the nitrogen nuclear spin to be sensed by the electronic spin of the center. Another studied case of ambiguous resonances comes from the coupling with lattice $^{13}$C nuclei, where we used the echo modulation frequencies to obtain the interaction Hamiltonian and then utilized the latter to simulate multipulse sequences. Finally, we also measured and simulated the effects from the free evolution of the quantum system during finite pulse durations. Due to the large data volume and the strong dependency of these ambiguous resonances with specific experimental parameters, we provide a simulations dataset with a user-friendly graphical interface, where users can compare simulations with their own experimental data for spectral disambiguation. Although focused with nitrogen vacancy centers and dynamical decoupling sequences, these results and the developed model can potentially be applied to other solid state spins and quantum sensing techniques.

quant-ph↗

Characterization of the photon emission statistics in nitrogen-vacancy centers

We model and experimentally demonstrate the full time-dependent counting statistics of photons emitted by a single nitrogen-vacancy (NV) center in diamond under non-resonant laser excitation and resonant microwave control. A generalization of the quantum jump formalism for the seven electronic states involved in the fast intrinsic dynamics of an NV center provides a self-contained model that allows for the characterization of its emission and clarifies the relation between the quantum system internal states and the measurable detected photon counts. The model allows the elaboration of detection protocols to optimize the energy and time resources while maximizing the system sensitivity to magnetic-field measurements.

quant-ph↗

Efficient Conversion of Nitrogen to Nitrogen-Vacancy Centers in Diamond Particles with High-Temperature Electron Irradiation

Fluorescent nanodiamonds containing negatively-charged nitrogen-vacancy (NV$^-$) centers are promising for a wide range of applications, such as for sensing, as fluorescence biomarkers, or to hyperpolarize nuclear spins. NV$^-$ centers are formed from substitutional nitrogen (P1 centers) defects and vacancies in the diamond lattice. Maximizing the concentration of NVs is most beneficial, which justifies the search for methods with a high yield of conversion from P1 to NV$^-$. We report here the characterization of surface cleaned fluorescent micro- and nanodiamonds, obtained by irradiation of commercial diamond powder with high-energy (10 MeV) electrons and simultaneous annealing at 800°C. Using this technique and increasing the irradiation dose, we demonstrate the creation of NV$^-$ with up to 25 % conversion yield. Finally, we monitor the creation of irradiation-induced spin-1 defects in microdiamond particles, which we associate with W16 and W33 centers, and investigate the effects of irradiation dose and particle size on the coherence time of NV$^-$.

cond-mat.mtrl-sci↗

Controllable Non-Markovianity for a Spin Qubit in Diamond

We present a flexible scheme to realize non-artificial non-Markovian dynamics of an electronic spin qubit, using a nitrogen-vacancy center in diamond where the inherent nitrogen spin serves as a regulator of the dynamics. By changing the population of the nitrogen spin, we show that we can smoothly tune the non-Markovianity of the electron spin's dynamic. Furthermore, we examine the decoherence dynamics induced by the spin bath to exclude other sources of non-Markovianity. The amount of collected measurement data is kept at a minimum by employing Bayesian data analysis. This allows for a precise quantification of the parameters involved in the description of the dynamics and a prediction of so far unobserved data points.

quant-ph↗

Pulsed polarisation for robust DNP

Dynamical nuclear polarisation (DNP) is an important technique that uses polarisation transfer from electron to nuclear spins to achieve nuclear hyperpolarisation. As the electron spin of the nitrogen vacancy (NV) centres in diamond can be optically initialised nearly perfectly even at room temperature and ambient conditions, new opportunities become possible by the combination of efficient DNP with optically polarised NV centres. Among such applications are nanoscale nuclear magnetic resonance spectroscopy of liquids, hyperpolarised nanodiamonds as MRI contrast agents as well as the initialisation of nuclear spin based diamond quantum simulators. Current realisations of DNP perform the polarisation transfer by achieving energetic resonance between electrons and nuclei via carefully tuned microwave fields or by using quasi-adiabatic sweep-based schemes across resonance points. The former limits robustness against control errors while the latter limits polarisation rates, making the realisation of the applications extremely challenging. Here we introduce the concept of Hamiltonian engineering by pulse sequences and use it for the systematic design of polarisation sequences that are simultaneously robust and fast. We derive sequences theoretically and demonstrate experimentally that they are capable of efficient polarisation transfer from an optically polarised nitrogen-vacancy centre in diamond to the surrounding $^{13}$C nuclear spin bath even in the presence of control errors, making it an ideal tool for the realisation of the above NV centre based applications.

quant-ph↗

Coherent control of solid state nuclear spin nano-ensembles

Detecting and controlling nuclear spin nano-ensembles is crucial for the further development of nuclear magnetic resonance (NMR) spectroscopy and for the emerging solid state quantum technology. Here we present the fabrication of a $\approx$ 1 nanometre thick diamond layer consisting of $^{13}$C nuclear spins doped with Nitrogen-Vacancy centres (NV) embedded in a spin-free $^{12}$C crystal matrix. A single NV in the vicinity of the layer is used for polarization of the $^{13}$C spins and the readout of their magnetization. We demonstrate a method for coherent control of few tens of nuclear spins by using radio frequency pulses and show the basic coherent control experiments - Rabi oscillations, Ramsey spectroscopy and Hahn echo, though any NMR pulse sequence can be implemented. The results shown present a first steps towards the realization of a nuclear spin based quantum simulator.

quant-ph↗

Robust techniques for polarization and detection of nuclear spin ensembles

Highly sensitive nuclear spin detection is crucial in many scientific areas including nuclear magnetic resonance spectroscopy (NMR), imaging (MRI) and quantum computing. The tiny thermal nuclear spin polarization represents a major obstacle towards this goal which may be overcome by Dynamic Nuclear Spin Polarization (DNP) methods. The latter often rely on the transfer of the thermally polarized electron spins to nearby nuclear spins, which is limited by the Boltzmann distribution of the former. Here we demonstrate the polarization and read out of a nuclear spin bath consisting of $^{13}$C nuclear spins in diamond by using a single nitrogen-vacancy (NV) center. Our method utilizes microwave dressed states to transfer the NV's high ($>$~92~\%) non-equilibrium electron spin polarization induced by short laser pulses to the surrounding carbon nuclear spins, where the NV is repeatedly repolarized optically, thus providing an effectively infinite polarization reservoir. A saturation of the polarization in the nuclear "frozen core" is achieved, which is confirmed by the decay of the polarization transfer signal and shows an excellent agreement with theoretical simulations. Hereby we introduce the Polarization Read Out by Polarization Inversion (PROPI) method as a quantitative magnetization measure of the nuclear spin bath. Moreover, we show that using the integrated solid effect both for single and double quantum transitions a nuclear spin polarization can be achieved even when the static magnetic field is not aligned along the NV's crystal axis. This opens a path for the application of our DNP technique to spins in and outside of nanodiamonds, enabling their application as MRI tracers.

quant-ph↗

Unambiguous nuclear spin detection using engineered quantum sensing sequence

Sensing, localising and identifying individual nuclear spins or frequency components of a signal in the presence of a noisy environments requires the development of robust and selective methods of dynamical decoupling. An important challenge that remains to be addressed in this context are spurious higher order resonances in current dynamical decoupling sequences as they can lead to the misidentification of nuclei or of different frequency components of external signals. Here we overcome this challenge with engineered quantum sensing sequences that achieve both, enhanced robustness and the simultaneous suppression of higher order harmonic resonances. We demonstrate experimentally the principle using a single nitrogen-vacancy center spin sensor which we apply to the unambiguous detection of external protons.

quant-ph↗

Low field nuclear polarization using Nitrogen Vacancy centers in diamonds

It was recently demonstrated that bulk nuclear polarization can be obtained using Nitrogen Vacancy (NV) color centers in diamonds, even at ambient conditions. This is based on the optical polarization of the NV electron spin, and using several polarization transfer methods. One such method is the NOVEL sequence, where a spin-locked sequence is applied on the NV spin, with a microwave power equal to the nuclear precession frequency. This was performed at relatively high fields, to allow for both polarization transfer and noise decoupling. As a result, this scheme requires accurate magnetic field alignment in order preserve the NV properties. Such a requirement may be undesired or impractical in many practical scenareios. Here we present a new sequence, termed the refocused NOVEL, which can be used for polarization transfer (and detection) even at low fields. Numerical simulations are performed, taking into account both the spin Hamiltonian and spin-decoherence, and we show that, under realistic parameters, it can outperform the NOVEL sequence.

quant-ph↗

Sub-millihertz magnetic spectroscopy with a nanoscale quantum sensor

Precise timekeeping is critical to metrology, forming the basis by which standards of time, length and fundamental constants are determined. Stable clocks are particularly valuable in spectroscopy as they define the ultimate frequency precision that can be reached. In quantum metrology, where the phase of a qubit is used to detect external fields, the clock stability is defined by the qubit coherence time, which determines the spectral linewidth and frequency precision. Here we demonstrate a quantum sensing protocol where the spectral precision goes beyond the sensor coherence time and is limited by the stability of a classical clock. Using this technique, we observe a precision in frequency estimation scaling in time $T$, as $T^{-3/2}$ for classical oscillating fields. The narrow linewidth magnetometer based on single spins in diamond is used to sense nanoscale magnetic fields with an intrinsic frequency resolution of 607 $μ$Hz, 8 orders of magnitude narrower than the qubit coherence time.

quant-ph↗