arXiv subjects

Bosen Wang

Publications and source records attributed to Bosen Wang.

At least 19 recordsLinked to original sources

arXiv2026

NMR evidence of pressure-induced structural transition and enhanced spin fluctuations up to 14~GPa in SrCu$_2$(BO$_3$)$_2$

The Shastry-Sutherland compound SrCu$_2$(BO$_3$)$_2$ has attracted considerable interest as a platform for exploring quantum phases and quantum phase transitions driven by magnetic frustration. The pressure-induced structural and magnetic phase transitions in SrCu$_2$(BO$_3$)$_2$, however, remain controversial. To address this issue, we performed high-pressure $^{11}$B nuclear magnetic resonance (NMR) measurements on SrCu$_2$(BO$_3$)$_2$ up to 14~GPa. The NMR spectra reveal two pressure-induced monoclinic phases. With pressure above 4~GPa and with temperature below 10~K, the rapid broadening of the NMR spectrum and the power-law behavior in the spin-lattice relaxation rate $1/T_1$ provide clear evidence for a gapless 3D antiferromagnetic (AFM) phase in the monoclinic phase. At an intermediate temperature range around 20~K, the emergence of the field-dependent NMR line splits resolves a two-dimensional, short-range ordered AFM phase; at temperature above 30~K, the sublinear power-law behavior of $1/T_1$ identifies an extended correlated paramagnetic regime.

cond-mat.str-el↗

arXiv2026

Nearly Isotropic Quantum-Critical Transport in Single-Crystal CeNiC2

Pressure-induced superconductivity and $T$-linear resistivity have been reported in polycrystalline CeNiC$_2$, but orientational averaging has left the directional character of the critical scattering unresolved. We report pressure-dependent resistivity of high-quality single crystals for current along each crystallographic axis. These crystals have substantially lower residual resistivity and a slightly higher maximum onset $T_c$ than the polycrystalline sample, placing superconductivity in a cleaner transport regime. Near $P_c \approx 9.5-10$ GPa, the normal-state resistivity becomes nearly $T$-linear along every axis, the fitted residual resistivity is strongly enhanced, and superconductivity forms a narrow dome. For $I \parallel b$, the $T$-linear normal state remains nearly unchanged in magnetic fields up to 9 T applied along $a$ and $c$; the upper critical field is large and only moderately anisotropic. The common evolution along all three axes establishes a nearly isotropic quantum-critical transport regime, inconsistent with a simple low-dimensional spin-fluctuation picture and implicates valence fluctuations as the leading source of critical scattering associated with the superconducting dome.

cond-mat.supr-con↗

arXiv2026

Soft point-contact Andreev reflection spectroscopy in a palm-type cubic anvil-pressure cell

We have implemented soft point-contact Andreev reflection spectroscopy (PCARS) in a palm-type cubic anvil pressure cell by combining a substrate anchoring strategy with an external wire-splitting technique. This design enables the stable formation of multiple point contact junctions under hydrostatic pressures up to 15 GPa. Benchmark measurements on the elemental superconductor Nb demonstrate high reproducibility and yield a zero-temperature superconducting gap with a gap ratio of 3.3. We further apply this technique to the Kagome metal superconductor CsCr3Sb5 and the bilayer nickelate superconductor La2PrNi2O7. Pronounced zero-bias conductance peaks are observed, and their evolution with temperature, magnetic field and applied pressure is investigated, together with the superconducting gap magnitude and possible pairing symmetries. These measurements provide spectroscopic evidence consistent with unconventional superconductivity in these materials. Our work establishes a robust experimental platform that bridges macroscopic electrical transport and microscopic spectroscopic probes, opening a new avenue for investigating pairing symmetry in a wide range of pressure-induced unconventional superconductors.

cond-mat.supr-con↗

arXiv2026

Chiral-Structured Superconductors TrX4 (Tr = Rh, Ir; X = Ge, Si): A Platform for Mixed-Parity Pairing and Topological States

Chiral-structured superconductors, with simultaneous broken mirror and inversion symmetries, promote unconventional superconductivity through parity-mixing mechanisms. Yet a few bulk chiral-structured superconductors are known, partly due to the difficulty in directly determining their atomic-scale chirality. Here we report three chiral-structured superconductors, , RhGe4, IrGe4, and IrSi4, synthesized under high pressure, with Tc values of about 1.6 K, 1.1 K, and 2.5 K, respectively.Using atomic resolution Cs-corrected scanning transmission electron microscopy (STEM) combined with X-ray diffraction characterizations, we directly confirm their chiral structure (space group P3121). This real space imaging approach overcomes ambiguities in traditional diffraction based methods. These materials exhibit type-II superconductivity, and the enhancement of spin-orbit coupling (SOC) leads to the emergence of mixed parity pairing. Calculations also reveal symmetry protected Weyl points near the Fermi level, which is robust against the SOC. Our work not only expands the family of chiral-structured superconductors but also demonstrates the indispensable role of STEM in directly determining chiral crystal structures. These materials thus offer a clean platform to explore the interplay among structural chirality, SOC, mixed parity superconductivity, and topological quantum phenomena.

cond-mat.supr-con↗

arXiv2026

Anomalous Structural Response of Quasi-One-Dimensional Antiferromagnetic Metal KMn6Bi5 under high pressure

We report high-pressure single-crystal X-ray diffraction measurements on the quasi-one-dimensional (Q1D) antiferromagnetic metal KMn6Bi5 up to 12.5 GPa, revealing the detailed pressure evolution of its atomic coordination environment. We find that the lattice exhibits pronounced anisotropic compressibility-the relative changes in the a and b lattice parameters reach a/a0=0.91 and b/b0 = 0.94 at 12.5 GPa-and a distinct structural anomaly emerges near 11 GPa without any symmetry-breaking. Detailed structural analysis further uncovers an anomalous hardening of the Mn nanotubes between 5 and 11 GPa, followed by a configuration optimization of the Mn/Bi nanotubes around 11 GPa. These features correlate closely with the reported pressure-temperature phase diagram of KMn6Bi5 and compare favorably with the chemical pressure effects induced by substituting K with Na, Rb, or Cs. Our findings provide key microscopic insights into how coordination environment modulation governs the stability of electronic orders in low-dimensional systems.

cond-mat.mtrl-sci↗

arXiv2026

Structural responses incipient to pressure-driven antiferromagnetic quantum critical point of van der Waals heavy-fermion metal CeSiI

CeSiI is a van der Waals heavy-fermion metal recently found to exhibit unconventional superconductivity near a pressure-induced antiferromagnetic quantum critical point (QCP) at Pc =6 GPa. Here, we report a comprehensive single-crystal X-ray diffraction study of CeSiI under high pressures up to 8.3 GPa at room temperature, revealing subtle structural responses that precede pressure-driven QCP. We find that the unit-cell volume decreases smoothly upon compression without showing any structural phase transition in the investigated pressure range. Intriguingly, we observe abrupt and concurrent anisotropic responses of the lattice parameters around Pc =6 GPa, i.e., the a-axis contracts while the c-axis enlongated suddenly, with the unit-cell volume smoothily varies with pressure. Structural refinements further show that these lattice anomalies primarily originate from changes of Ce-Ce and Ce-Si bond lengths, as well as a flattening of the inner honeycomb Si layer within the CeSiI monolayer around Pc. Our findings establish an interesting case linking pressure-driven electronic transition of QCP at low temperatures to incipient structural responses at room temperature, thereby providing fresh insight into the pressure-temperature phase diagram of CeSiI.

cond-mat.str-el↗

arXiv2026

Two distinct superconducting regimes in Ti4Co2O under pressures

We report on the pressure dependence of superconducting transition temperature Tc and upper critical field Bc2(0) through electrical transport of the Ti4Co2O superconductor (eg.,the superconducting transition temperature Tc = 2.5 K and the Bc2(0)=7.2T=2.9Tc). We find that the Tc exhibits non-monotonic pressure dependence:it rises monotonically at first with a pressure coefficient of dTc/dP=0.034 K/GPa, but rapidly decreases around 10-20 GPa, and then increases with the dTc/dP = 0.023 K/GPa, up to= 4.31 K at 69.7 GPa. Concurrently, the Bc2(0)exhibits a dome shaped pressure dependence, with its maximum at 5 GPa of almost twice the value at ambient pressure, exceeding the weak-coupling Pauli paramagnetic limit Bp throughout the whole pressure range. By comparing the normal-state and superconducting properties, we identify two distinct superconducting regimes, with a low-pressure superconducting phase characterized by an enhanced Bc2(0)values and Fermi-liquid normal-state electrical transport (the exponent n = 2), and a high-pressure superconducting phase with a monotonically increased Tc and an enhancement in phonon scatterings (the exponent n = 4). Room-temperature synchrotron X-ray diffraction indicates that there is no structural transition up to 55.8 GPa, which gives a relatively large bulk modulus of 192 GPa in comparison with other alloy superconductors. First-principles calculations suggest that the nonmonotonic Tc maybe closely related to the evolution of the density of states of Ti4Co2O upon compression, which is different from those of isostructural superconductors Ti4Ir2O and Nb4Rh2C. Our results show that even in the Ti4Co2O with weak spin-orbit coupling, superconductivity remains highly sensitive to the external stimuli such as pressure.

cond-mat.supr-con↗

arXiv2026

Metallic crossover through the tilt-free transition in La$_3$Ni$_2$O$_7$ at high pressure and temperature

La$_3$Ni$_2$O$_7$, a bilayer nickelate with Ruddlesden-Popper structure, undergoes a pressure-induced structural transition from a tilted Amam phase to an untilted Fmmm (or I4/mmm) phase near 10-15 GPa, concomitant with the emergence of high-T$_c$ superconductivity ($T_c \sim 80$ K). Despite intense interest, the phase boundaries and the impact of structural changes on the electronic properties remain unclear. Here, we combine high-pressure and high-temperature Raman and synchrotron-based infrared spectroscopies to map the structural and electronic evolutions. Raman measurements confirm the pressure-driven structural transition and reveal the emergence of Fano line shapes, indicating enhanced electron-phonon coupling. High-temperature data show analogous spectral signatures above 544 K, suggesting an upper temperature limit of the Amam phase within the T-P phase diagram of this system. Infrared reflectivity measurements evidence a concomitant enhanced metallicity, with a tremendous two-order-of-magnitude increase in carrier density, marking a crossover from a weakly to highly metallic state. These results establish a unified picture of the structural transition and its strong coupling to the electronic properties.

cond-mat.supr-con↗

arXiv2026

Pressure-Induced Metal-Insulator and Paramagnet-Altermagnet Transitions in Rutile OsO2 Single Crystals

Altermagnets with compensated spin structures and nonrelativistic spin splitting have emerged as a new class of magnetic materials. Rutile OsO2 has been theoretically predicted to be altermagnetic, but experimental studies have been limited by synthesis challenges. We have succeeded in synthesizing high-quality single crystals of rutile OsO2. Electrical transport studies reveal that OsO2 is highly conductive and exhibits clear Fermi liquid behavior, indicating strong electron-electron scattering. Magnetic measurements show that the crystals are isotropically paramagnetic. Density-functional theory calculations indicate that bulk OsO2 is semimetallic with coexisting electron and hole pockets, with its magnetic ground state strongly dependent on the on-site Coulomb correlation U. Angle-resolved photoemission spectroscopy studies unveil that the bulk bands do not yet show altermagnetic spin splitting. Interestingly, resistivity is rather pressure sensitive: at 44 GPa, a clear metal-insulator transition occurs. Hybrid functional calculations reveal that applying pressure significantly increases the Hubbard U value, driving a phase transition from a paramagnetic metal to an altermagnetic metal, and eventually to an altermagnetic insulator. These findings suggest that tuning external pressure effectively modulates the magnetic ground state of OsO2, providing a pathway to realize altermagnetism in this material.

cond-mat.mes-hall↗

arXiv2026

Emergent Polar Metal Phase in a Van der Waals Mott Magnet

We report the emergence of a two-dimensional (2D) polar metal phase in van der Waals compound FePSe$_3$ under moderate pressures. This layered material is a Mott insulator with antiferromagnetic order under ambient conditions. We show that FePSe$_3$ uniquely allows tuning a 2D correlated insulator into an exotic metal state where a loss of inversion symmetry leads to periodic polar displacements of ions, within a conducting phase - a polar metal. Our combined synchrotron and neutron diffraction data allow us to present a long-sought, unambiguous high-pressure structural model and show the polar displacements of this new phase. We also observe the suppression of magnetic ordering at the insulator-to-metal transition correspondent with this structural change. Our work outlines a comprehensive temperature-pressure phase diagram of FePSe$_3$, combining detailed structural, magnetic and transport data. The high-pressure phase exhibits activated semiconductor behavior at high temperatures, a $T^2$-dependence in its resistivity at lower temperatures - despite the conditions required for a `good metal' Fermi-Liquid description not being met in this case - and a low-temperature resistivity upturn which is suppressed as the system is tuned away from the concomitant transitions. The realisation of a tunable 2D polar metal state in FePSe$_3$ due to the loss of its inversion symmetry combined with pressure-induced metallicity offers a promising new platform to investigate this exotic phase at accessible pressures.

cond-mat.str-el↗

arXiv2026

Superconductivity under pressure in the two-dimensional van der Waals heavy-fermion metal CeSiI

CeSiI is a newly discovered exfoliable van der Waals (vdW) heavy-fermion metal featured by a long-range antiferromagnetic (AF) order (TN =7.5 K) inside the Kondo coherent state below T* = 50 K. To gain a more profound understanding of the intriguing physics of this material and to uncover novel phenomena driven by quantum criticality, it is imperative to construct the phase diagram of CeSiI detailing the evolutions of T* and TN as a function of external tuning parameters such as pressure (P).In this study, we employ high pressure as an effective tuning knob to investigate this system, thereby generating a comprehensive T-P phase diagram of CeSiI. This diagram is characterized by an unusual V-shaped nonmonotonic evolution of T*(P) and the emergence of a superconducting dome with Tcmax = 240 mK upon suppression of AF order at Pc = 6 GPa, coinciding with the minimum of T*(P).The close proximity of the superconductivity (SC) to the AF instability and an unusually large upper critical field Bc2(0) exceeding 4-7 times the Pauli paramagnetic limit, suggests an unconventional pairing mechanism in CeSiI. Further analyses of normal-state transport properties provide evidence of quantum criticality, i.e., non-Fermi-liquid behavior and divergence of quasiparticle effective mass near Pc = 7 GPa. Our findings not only establish CeSiI as the first vdW heavy-fermion superconductor but also highlight an unconventional nature for the Kondo coherent state at T* at ambient pressure, hence opening a new avenue to study the interplay of strong electron correlation, Kondo hybridization, magnetism, and unconventional SC in the vdW heavy-fermion systems.

cond-mat.supr-con↗

arXiv2025

High Pressure Superconducting transition in Dihydride BiH$_2$ with Bismuth Open-Channel Framework

Metal hydrides MHx with low hydrogen content are not expected to show high-Tc superconductivity owing to the low hydrogen-derived electronic density of states at Fermi level and the limited hydrogen contribution to electron-phonon coupling strength. In this work, we report on the successful synthesis of a novel bismuth dihydride superconductor, Cmcm-BiH$_2$, at approximately 150 GPa, and the discovery of superconductivity with Tc about 62 K at 163 GPa, marking the first instance of superconductor among the MH$_2$-type metal dihydrides. Cmcm-BiH$_2$ adopts a unique host-guest type structure, in which the Bi atoms via weak Bi-Bi covalent bonds form a three-dimensional open-channel framework that encapsulates H$_2$-like molecules as guests, thereby broadening the structural diversity of hydrides under high pressures. The occurrence of superconductivity is evidenced by a sharp drop of resistivity to zero and the characteristic downward shift of Tc under applied magnetic fields. Notably, Cmcm-BiH$_2$ remains stable down to at least 97 GPa during decompression, with the calculated lowest pressure for dynamic stability of 10 GPa. In-depth analysis reveals that the covalent bismuth open-channel structure forms metallic conduction channels, dominates the electronic states near the Fermi level, and contributes approximately 51% of the total $lambda$ in Cmcm-BiH$_2$, distinguishing it from known high-pressure hydride superconductors. These findings highlight the critical role of non-hydrogen elements in producing superconductivity and open new avenues for the design and optimization of high-Tc hydride superconductors.

cond-mat.supr-con↗

arXiv2025

Strongly Entangled Kondo and Kagome Lattices and the Emergent Magnetic Ground State in Heavy-Fermion Kagome Metal YbV$_6$Sn$_6$

Applying angle-resolved photoemission spectroscopy and density functional theory calculations, we present compelling spectroscopic evidence demonstrating the intertwining and mutual interaction between the Kondo and kagome sublattices in heavy-fermion intermetallic compound YbV$_6$Sn$_6$. We reveal the Yb 4$f$-derived states near the Fermi level, along with the presence of bulk kagome bands and topological surface states. We unveil strong interactions between the 4$f$ and itinerant electrons, where the kagome bands hosting the Dirac fermions and van Hove singularities predominate. Such findings are well described using a $c$-$f$ hybridization model. On the other hand, our systematic characterization of magnetic properties demonstrates an unusually enhanced antiferromagnetic ordering, where the kagome-derived van Hove singularities near $E_F$ play a vital role in determining the unconventional nature of the Ruderman-Kittel-Kasuya-Yosida interaction and Kondo coupling. These unique kagome-state-mediated exchange interactions have never been reported before and could lead to a novel phase diagram and various quantum critical behaviors in YbV$_6$Sn$_6$ and its siblings. Our results not only expand the family of exotic quantum phases entangled with kagome structure to the strongly correlated regime, but also establish YbV$_6$Sn$_6$ as an unprecedented platform to explore unconventional many-body physics beyond the standard Kondo picture.

cond-mat.str-el↗

arXiv2025

Enhanced superconductivity in the compressively strained bilayer nickelate thin films by pressure

The discovery of high temperature superconductivity in the nickelate system has stimulated enormous interest in the community of condensed matter physics. Recently, superconductivity with an onset transition temperature (Tc^onset) over 40 K was achieved in La3Ni2O7 and (La,Pr)3Ni2O7 thin films at ambient pressure due to in-plane compressive strain. This observation has sparked enormous attention because measurements on superconducting properties can be accessible with many commonly used experimental tools. On the other hand, the Tc in these thin films is much lower than that of the bulk bilayer nickelates under pressure. Here we report the enhancement of Tc^onset to over 60 K by applying hydrostatic pressure on the compressively strained superconducting bilayer nickelate thin films. The Tc^onset firstly ramps up with pressure, then it slightly drops down after reaching the maximum Tc^onset at about 61.5 K under a pressure of 9 GPa, showing a dome-like phase diagram. Hall effect measurements reveal that the dominant charge carriers are hole-like with a slight enhancement of charge carrier density with pressure in accompanying with the increase of Tc. Our theoretical results demonstrate that the enhancement of Tc arises from a cooperative amplification of magnetic fluctuations within and between the layers and increased metallicity under pressure. However, this enhancement exhibits saturation at higher pressures. These findings highlight the critical role of the interplay between interlayer and intralayer electronic correlations in bilayer nickelate superconductors and point to the potential of tuning Tc through controlled manipulation of the electronic structure and interactions.

cond-mat.supr-con↗

arXiv2025

Two Plaquette-Singlet Phases and Emergent SO(5) Deconfined Quantum Criticality in SrCu2(BO3)2

The deconfined quantum critical point (DQCP) has become a central open concept in the physics of quantum matter, and its proposed presence in the Shastry-Sutherland model was followed by the experimental observation of at least a minimal DQC scenario induced by an applied magnetic field in SrCu$_2$(BO$_3$)$_2$. However, the nature of the plaquette-singlet phase in SrCu$_2$(BO$_3$)$_2$ remains unresolved, and with it the identification of the DQCP symmetry from among several theoretical scenarios. Here we perform detailed high-pressure $^{11}$B NMR studies to reveal the presence of both the full-plaquette (FP) and empty-plaquette (EP) phases in SrCu$_2$(BO$_3$)$_2$, phase-separated at a first-order, pressure-driven transition with a volume-fraction effect. The field-driven transition from the EP to the antiferromagnetic (AFM) phase complements our previous observations of the FP--AFM transition, with both showing deconfined quantum criticality, while the scaling of the spin-lattice relaxation rate near the EP--AFM transition, $1/T_1 \propto T^{0.6}$, suggests a DQCP governed by a different universality class. We discuss possible extensions to the Shastry-Sutherland model that account for these pressure and field effects. The expanded phase space we discover mandates an SO(5) DQCP symmetry, and hence our results take an important step towards a complete understanding of deconfined quantum criticality in SrCu$_2$(BO$_3$)$_2$.

cond-mat.str-el↗

arXiv2025

New phase space of hardness materials and synergic enhancement of hardness and toughness in superconducting Ti2Co and Ti4Co2X (X = B, C, N, O)

Compared to traditional superhard materials with high electron density and strong covalent bonds, alloy materials mainly composed of metallic bonding structures typically have great toughness and lower hardness. Breaking through the limits of alloy materials is a preface and long term topic, which is of great significance and value for improving the comprehensive mechanical properties of alloy materials. Here, we report on the discovery of a cubic alloy semiconducting material Ti2Co with large Vickers of hardness Hvexp = 6.7 GPa and low fracture toughness of KICexp =1.51 MPa m0.5. Unexpectedly, the former value is nearly triple of the Hvcal = 2.66 GPa predicted by density functional theory (DFT) calculations and the latter value is about one or two orders of magnitude smaller than that of ordinary titanium alloy materials (KICexp = 30-120 MPa m0.5).These specifications place Ti2Co far from the phase space of the known alloy materials, but close to medium hardness materials such as MgO or TiO2. Upon incorporation of oxygen into structural void positions, both values were simultaneously improved for Ti4Co2O to = 9.7 GPa and 2.19 MPa m0.5, respectively. Further DFT calculations on the electron localization function of Ti4Co2X (X = B, C, N, O) vs. the interstitial elements indicate that these simultaneous improvements originate from the coexistence of Ti-Co metallic bonds, the emergence of newly oriented Ti-X covalent bonds, and the increase of electron concentration. Moreover, the large difference between Hvexp and Hvcal of Ti2Co suggests underlying mechanism concerning the absence of the O(16d) or Ti2-O bonds in the O-(Ti2)6 octahedron.Our discovery expands the phase space of alloy materials and illuminates the path of exploring superconducting materials with excellent mechanical performances.

cond-mat.mtrl-sci↗

arXiv2025

Strong superconducting pairing strength and pseudogap features in a putative multiphase heavy-fermion superconductor CeRh2As2 by soft point-contact spectroscopy

CeRh2As2 is a newly discovered candidate of multiphase heavy-fermion superconductor (Tc=0.3 K) with intriguing physical properties. Here, we employ soft point-contact spectroscopy to investigate its energy gap behaviors in both the normal and superconducting states. The differential conductance below Tc reveals an estimated superconducting energy gap of 2ΔSC=0.24 meV and thus an extremely strong superconducting pairing strength 2ΔSC/kBTc=8.8, which is comparable to those of cuprates and iron-based high-Tc superconductors as well as infinite-layer nickelates. Above Tc, a well-defined pseudogap feature is manifested as a V-shaped dip in the differential conductance spanning an energy scale of 2Δg=0.95-3.0 meV. The pseudogap feature persists to the highest characteristic temperature of Tg=8-9 K and is gradually suppressed by magnetic field of Bg=9.0T regardless of its direction relative to the crystallographic axes. The observation of pseudogap features prior to the superconducting phase transition enriches the phase diagram of CeRh2As2 and provides a novel platform to study the interplay of unconventional superconductivity and pseudogap phenomena.

cond-mat.supr-con↗

arXiv2024

Simultaneous achievement of record-breaking colossal magnetoresistance and angular magnetoresistance in an antiferromagnetic semiconductor EuSe2

Magnetoresistance effect lays the foundation for spintronics, magnetic sensors and hard drives. The pursuit of magnetic materials with colossal magnetoresistance (CMR) and/or angular magnetoresistance (AMR) has attracted enduring research interest and extensive investigations over past decades. Here we report on the discovery of field-induced record-breaking CMR of ~ -10^14 % and AMR ~ 10^14% achieved simultaneously in an antiferromagnetic rare-earth dichalcogenide EuSe2. Such intriguing observations are attributed to strong magnetic anisotropy and magnetic-field induced antiferromagnetic to ferromagnetic transition of the localized Eu2+ spins, which in turn closes the bandgap by lifting the degeneracy of Se-5p bands near Fermi level. Our DFT calculations perfectly replicate the experimental findings based on the Brillouin function and carries transport model. The present work provides a potential simple antiferromagnetic material for achieving angle-sensitive spintronic devices.

cond-mat.str-el↗