arXiv subjects

Brant M. Jones

Publications and source records attributed to Brant M. Jones.

2 recordsLinked to original sources

arXiv2026

Electron-Stimulated Desorption of D Atoms from Gibbsite (Al(OD)3) and D2O Ice: Energy and Temperature Dependence of Translational Energy Distributions

The electron-stimulated desorption (ESD) of neutral D atoms from gibbsite (\ce{Al(OD)3}) nanoplatelets and amorphous \ce{D2O} ice has been investigated using $2+1$ resonance-enhanced multiphoton ionization (REMPI) time-of-flight mass spectroscopy in a high vacuum chamber at temperatures 15 and 300\,K. Electron irradiation at 540, 250, and 150\,eV produces similar translational energy distributions at $\sim$300\,K, with a dominant intermediate-temperature component ($T \sim 1500$--$2100$\,K). Cooling to 15\,K suppresses the D atom yield by approximately 50\% and removes the lowest-temperature (slowest) component. This decrease in yield is consistent with diminished hole mobility and restricted diffusion at cryogenic temperatures. Under identical conditions, \ce{D2O} amorphous solid water ice films produce approximately 20 times greater D atom signal than bare gibbsite, with significantly hotter translational distributions, reflecting the higher deuterium surface density and distinct bonding environments of bulk ice relative to the terminal hydroxyl groups on gibbsite. These results identify hole transport to terminal hydroxyl sites as the rate-limiting step for nonthermal D atom production and provide a mechanistic framework for understanding atomic hydrogen release from aluminum hydroxide phases relevant to radioactive waste storage at the Hanford Site.

physics.chem-ph↗

arXiv2025

Creation of Lunar-Like Rims in Ilmenite using Synthetic Solar Wind

Space weathering of lunar minerals, due to bombardment from solar wind (SW) particles and micrometeoroid impacts, modifies the mineralogy within tens of nanometers of the surface, i.e., the rim. Spectroscopic signatures of these modifications, observed via remote sensing, have long been used to gauge surface exposure times on the Moon. However, the relative contributions of SW and micrometeoroids in the creation of rim features are still debated, particularly for the nanometer-scale clusters known as nanophase iron (npFe0), which commonly form in ferrous minerals. We address this issue in the laboratory, using deuterium ions and low-energy electrons as a synthetic solar wind plasma to irradiate ilmenite (FeTiO3), a common lunar mineral. Characterization by high-resolution scanning transmission electron microscopy and electron energy-loss spectroscopy shows that the SW alone creates rims with all the main characteristics of lunar samples. We conclusively identify npFe0 and quantify its distribution as a function of depth and fluence, allowing us to estimate the SW exposure of Apollo soil 71501. Our results confirm that small npFe0 particles (<10 nm in diameter) form from SW irradiation. Such experiments provide microscopic details of space weathering, improving the link between surface modification processes and macroscopic remote-sensing data.

astro-ph.EP↗