arXiv subjects

Brett McGuire

Publications and source records attributed to Brett McGuire.

9 recordsLinked to original sources

arXiv2026

Dust Seeding Molecules in a Massive Protostar -- Detection of TiO in Orion Source I

We report the first detection of TiO in star-forming regions based on Atacama Large Millimeter/submillimeter Array observations of Orion Source I, a well-characterized massive protostar. Multiple rotational transitions are identified, with emission spatially resolved within $\sim 50$ au, showing a compact distribution with a velocity structure consistent with the base of a rotating outflow. The spatial and velocity distributions of TiO are consistent with those of AlO, with both species being key dust seeding refractory molecules. \textbf{The column density of TiO is derived to be $(3.0 \pm 0.4)\times10^{15}\ {\rm cm^{-2}}$, corresponding to $X_{\rm TiO/SiO} \sim 12.8 \pm 1.7 \times10^{-3}$, higher than CI chondrites and indicative of efficient dust-to-gas conversion near the protostar.} We also identify a tentative detection of AlOH, which exhibits a more extended distribution along the disk surface, possibly indicating different conditions from those traced by TiO and AlO. The detection of TiO, a key dust seeding species, offers important constraints on refractory chemistry and the formation environments of primitive minerals, linking astrochemical processes in protostellar systems to the earliest stages of Solar System material formation.

astro-ph.GA↗

arXiv2026

Carbon chain diversity in L1544 and IRAS 16293-2422: an astrochemical pathfinder study for the SKAO

Astrochemical observations have revealed a surprisingly high level of chemical complexity, including long carbon chains, in the earliest stages of Sun-like star formation. The origin of these species and whether they undergo further growth, possibly contributing to the molecular complexity of planetary systems, remain open questions. We present recent observations performed using the 100-m Green Bank Telescope of the prestellar core L1544 and the protostellar system IRAS 16293-2422. In L1544, we detected several complex carbon-bearing species, including $\mathrm{C_2S}$, $\mathrm{C_3S}$, $\mathrm{C_3N}$, $\mathrm{c\text{-}C_3H}$, $\mathrm{C_4H}$, and $\mathrm{C_6H}$, complementing previously reported emission of cyanopolyynes. In IRAS 16293-2422, we detected $\mathrm{c\text{-}C_3H}$ and, for the first time, $\mathrm{HC_7N}$. Thanks to the high spectral resolution, we refine the rest frequencies of several $\mathrm{c\text{-}C_3H}$ and $\mathrm{C_6H}$ transitions. We perform radiative transfer analysis, highlighting a chemical difference between the two sources: IRAS 16293-2422 shows column densities 10-100 times lower than L1544. We perform astrochemical modeling, employing an up-to-date chemical network with revised reaction rates. The models reproduce the general trends, with cyanopolyyne and polyynyl radical abundances decreasing as molecular size increases, but they underestimate the abundances of cyanopolyynes longer than $\mathrm{HC_5N}$ by up to two orders of magnitude. Current models, which include the dominant neutral-neutral formation routes, cannot account for this discrepancy, suggesting that the chemical network is incomplete. We propose that additional ion-molecule reactions are crucial for the formation of these species. Developing a more comprehensive chemical network for long carbon chains is essential for accurately interpreting present and future observations.

astro-ph.GA↗

arXiv2024

Key Science Goals for the Next Generation Very Large Array (ngVLA): Update from the ngVLA Science Advisory Council (2024)

In 2017, the next generation Very Large Array (ngVLA) Science Advisory Council, together with the international astronomy community, developed a set of five Key Science Goals (KSGs) to inform, prioritize and refine the technical capabilities of a future radio telescope array for high angular resolution operation from 1.2 - 116 GHz with 10 times the sensitivity of the Jansky VLA and ALMA. The resulting KSGs, which require observations at centimeter and millimeter wavelengths that cannot be achieved by any other facility, represent a small subset of the broad range of astrophysical problems that the ngVLA will be able address. This document presents an update to the original ngVLA KSGs, taking account of new results and progress in the 7+ years since their initial presentation, again drawing on the expertise of the ngVLA Science Advisory Council and the broader community in the ngVLA Science Working Groups. As the design of the ngVLA has also matured substantially in this period, this document also briefly addresses initial expectations for ngVLA data products and processing that will be needed to achieve the KSGs. The original ngVLA KSGs endure as outstanding problems of high priority. In brief, they are: (1) Unveiling the Formation of Solar System Analogues; (2) Probing the Initial Conditions for Planetary Systems and Life with Astrochemistry; (3) Charting the Assembly, Structure, and Evolution of Galaxies from the First Billion Years to the Present; (4) Science at the Extremes: Pulsars as Laboratories for Fundamental Physics; (5) Understanding the Formation and Evolution of Stellar and Supermassive Black Holes in the Era of Multi-Messenger Astronomy.

astro-ph.IM↗

arXiv2024

Maser Activity of Organic Molecules toward Sgr B2(N)

At centimeter wavelengths, single-dish observations have suggested that the Sagittarius (Sgr) B2 molecular cloud at the Galactic Center hosts weak maser emission from several organic molecules, including CH$_2$NH, HNCNH, and HCOOCH$_3$. However, the lack of spatial distribution information of these new maser species has prevented us from assessing the excitation conditions of the maser emission as well as their pumping mechanisms. Here, we present a mapping study toward Sgr B2 North (N) to locate the region where the complex maser emission originates. We report the first detection of the Class I methanol (CH$_3$OH) maser at 84 GHz and the first interferometric map of the methanimine (CH$_2$NH) maser at 5.29 GHz toward this region. In addition, we present a tool for modeling and fitting the unsaturated molecular maser signals with non-LTE radiative transfer models and Bayesian analysis using the Markov-Chain Monte Carlo approach. These enable us to quantitatively assess the observed spectral profiles. The results suggest a two-chain-clump model for explaining the intense CH$_3$OH Class I maser emission toward a region with low continuum background radiation. By comparing the spatial origin and extent of maser emission from several molecular species, we find that the 5.29 GHz CH$_2$NH maser has a close spatial relationship with the 84 GHz CH$_3$OH Class I masers. This relationship serves as observational evidence to suggest a similar collisional pumping mechanism for these maser transitions.

astro-ph.GA↗

arXiv2023

Cyanopolyyne chemistry in the L1544 prestellar core: new insights from GBT observations

We report a comprehensive study of the cyanopolyyne chemistry in the prototypical prestellar core L1544. Using the 100m Robert C. Byrd Green Bank Telescope (GBT) we observe 3 emission lines of HC$_3$N, 9 lines of HC$_5$N, 5 lines of HC$_7$N, and 9 lines of HC$_9$N. HC$_9$N is detected for the first time towards the source. The high spectral resolution ($\sim$ 0.05 km s$^{-1}$) reveals double-peak spectral line profiles with the redshifted peak a factor 3-5 brighter. Resolved maps of the core in other molecular tracers indicates that the southern region is redshifted. Therefore, the bulk of the cyanopolyyne emission is likely associated with the southern region of the core, where free carbon atoms are available to form long chains, thanks to the more efficient illumination of the interstellar field radiation. We perform a simultaneous modelling of the HC$_5$N, HC$_7$N, and HC$_9$N lines, to investigate the origin of the emission. To enable this analysis, we performed new calculation of the collisional coefficients. The simultaneous fitting indicates a gas kinetic temperature of 5--12 K, a source size of 80$\arcsec$, and a gas density larger than 100 cm$^{-3}$. The HC$_5$N:HC$_7$N:HC$_9$N abundance ratios measured in L1544 are about 1:6:4. We compare our observations with those towards the the well-studied starless core TMC-1 and with the available measurements in different star-forming regions. The comparison suggests that a complex carbon chain chemistry is active in other sources and it is related to the presence of free gaseous carbon. Finally, we discuss the possible formation and destruction routes in the light of the new observations.

astro-ph.GA↗

arXiv2022

Searching for Propionamide (C2H5CONH2) Toward Sagittarius B2 at Centimeter Wavelengths

The formation of molecules in the interstellar medium (ISM) remains a complex and unresolved question in astrochemistry. A group of molecules of particular interest involves the linkage between a -carboxyl and -amine group, similar to that of a peptide bond. The detection of molecules containing these peptide-like bonds in the ISM can help elucidate possible formation mechanisms, as well as indicate the level of molecular complexity available within certain regions of the ISM. Two of the simplest molecules containing a peptide-like bond, formamide (NH2CHO) and acetamide (CH3CONH2), have previously been detected toward the star forming region Sagittarius B2 (Sgr B2). Recently, the interstellar detection of propionamide (C2H5CONH2) was reported toward Sgr B2(N) with ALMA observations at millimeter wavelengths. Yet, this detection has been questioned by others from the same set of ALMA observations as no statistically significant line emission was identified from any uncontaminated transitions. Using the PRrbiotic Interstellar MOlecule Survey (PRIMOS) observations, we report an additional search for C2H5CONH2 at centimeter wavelengths conducted with the Green Bank Telescope. No spectral signatures of C2H5CONH2 were detected. An upper limit for C2H5CONH2 at centimeter wavelengths was determined to be less than 1.8e14 cm-2 and an upper limit to the C2H5CONH2/CH3CONH2 ratio is found to be less than 2.34. This work again questions the initial detection of C2H5CONH2 and indicates that more complex peptide-like structures may have difficulty forming in the ISM or are below the detection limits of current astronomical facilities. Additional structurally related species are provided to aid in future laboratory and astronomical searches.

astro-ph.GA↗

arXiv2021

Astrochemistry with the Orbiting Astronomical Satellite for Investigating Stellar Systems (OASIS)

Chemistry along the star- and planet-formation sequence regulates how prebiotic building blocks -- carriers of the elements CHNOPS -- are incorporated into nascent planetesimals and planets. Spectral line observations across the electromagnetic spectrum are needed to fully characterize interstellar CHNOPS chemistry, yet to date there are only limited astrochemical constraints at THz frequencies. Here, we highlight advances to the study of CHNOPS astrochemistry that will be possible with the Orbiting Astronomical Satellite for Investigating Stellar Systems (OASIS). OASIS is a NASA mission concept for a space-based observatory that will utilize an inflatable 14-m reflector along with a heterodyne receiver system to observe at THz frequencies with unprecedented sensitivity and angular resolution. As part of a survey of H2O and HD towards ~100 protostellar and protoplanetary disk systems, OASIS will also obtain statistical constraints on the inventories of light hydrides including NH3 and H2S towards protoplanetary disks, as well as complex organics in protostellar hot corinos and envelopes. Line surveys of additional star-forming regions, including high-mass hot cores, protostellar outflow shocks, and prestellar cores, will also leverage the unique capabilities of OASIS to probe high-excitation organics and small hydrides, as is needed to fully understand the chemistry of these objects.

astro-ph.GA↗

arXiv2019

Orion Source I's disk is salty

We report the detection of NaCl, KCl, and their $^{37}$Cl and $^{41}$K isotopologues toward the disk around Orion SrcI. About 60 transitions of these molecules were identified. This is the first detection of these molecules in the interstellar medium not associated with the ejecta of evolved stars. It is also the first ever detection of the vibrationally excited states of these lines in the ISM above v = 1, with firm detections up to v = 6. The salt emission traces the region just above the continuum disk, possibly forming the base of the outflow. The emission from the vibrationally excited transitions is inconsistent with a single temperature, implying the lines are not in LTE. We examine several possible explanations of the observed high excitation lines, concluding that the vibrational states are most likely to be radiatively excited via rovibrational transitions in the 25-35 μm (NaCl) and 35-45 μm (KCl) range. We suggest that the molecules are produced by destruction of dust particles. Because these molecules are so rare, they are potentially unique tools for identifying high-mass protostellar disks and measuring the radiation environment around accreting young stars.

astro-ph.GA↗

arXiv2017

The Molecular Chemistry of Diffuse and Translucent Clouds in the Line-of-Sight to Sgr B2

The 1-50 GHz GBT PRIMOS data contains ~50 molecular absorption lines observed in diffuse and translucent clouds located in the Galactic Center, Bar, and spiral arms in the line-of-sight to Sgr B2(N). We measure the column densities and estimate abundances, relative to H2, of 11 molecules and additional isotopologues. We use absorption by optically thin transitions of c-C3H2 to estimate the N(H2), and argue that this method is preferable to more commonly used methods. We discuss the kinematic structure and abundance patterns of small molecules including the sulfur-bearing species CS, SO, CCS, H2CS, and HCS+; oxygen-bearing molecules OH, SiO, and H2CO; and simple hydrocarbon molecules c-C3H2, l-C3H, and l-C3H+. We discuss the implications of the observed chemistry for the structure of the gas and dust in the ISM. Highlighted results include the following. First, whereas gas in the disk has a molecular hydrogen fraction of 0.65, clouds on the outer edge of the Galactic Bar and in or near the Galactic Center have molecular fractions of 0.85 and >0.9, respectively. Second, we observe trends in isotope ratios with Galactocentric distance; while carbon and silicon show enhancement of the rare isotopes at low Galactocentric distances, sulfur exhibits no trend with Galactocentric distance; the ratio of c-C3H2/c-H13CCCH provides a good estimate of the 12C:13C ratio, whereas H2CO/H2^13CO exhibits fractionation. Third, we report the presence of l-C3H+ in diffuse clouds for the first time. Finally, we suggest that CS has an enhanced abundance within higher density clumps of material in the disk, and therefore may be diagnostic of cloud conditions. If this holds, the diffuse clouds in the Galactic disk contain multiple embedded hyperdensities in a clumpy structure, and the density profile is not a simple function of A_V.

astro-ph.GA↗