arXiv subjects

Brian C. Odom

Publications and source records attributed to Brian C. Odom.

16 recordsLinked to original sources

arXiv2026

The Quantum Many-Worlds Interpretation, Simply Told

The many-worlds interpretation (MWI) of quantum mechanics poses a simple question. What would reality look like if everything evolved in time according to the same quantum equations? There is an attractive consistency to treating microscopic objects, measuring devices, and observers all on the same footing, but do the predictions match our observations? Here, we build a model for a bolometer detector making a which-path measurement in an atom interferometer. We discuss the MWI claim that, while both measurement outcomes occur in each experimental iteration, an observer will experience only one outcome or the other, with a probability consistent with experiment. Finally, we discuss how MWI does not have action at a distance. This article is written to be accessible to anyone with an undergraduate course in quantum mechanics.

quant-ph↗

arXiv2025

Beyond Copenhagen: Following the Trail of Decoherence in Feynman's Light Microscope

Feynman's light microscope invites us to reconsider what we thought we knew about quantum reality. Rather than invoking wavefunction collapse to predict the loss of fringes in a monitored interferometer, Feynman analyzes the problem in terms of a disturbance. This approach raises the question of whether the classical world, including its localized particles and definite measurement outcomes, might emerge as the universe evolves smoothly according to Schrödinger's equation. Treating the particle and its environment as an entangled system, unmodified quantum mechanics shows remarkable success toward this end. This is the purview of decoherence theory. How we then think about macroscopic reality becomes dependent on how we think about microscopic reality. Is quantum mechanics successful because it describes what microscopic particles are really doing, such as traveling both interferometer paths at the same time? Or is the wavefunction only a mathematical tool which predicts measurement outcomes but does not describe microscopic reality? Both options are uncomfortable. The first implies that each moment in time branches into a vast number of divergent macroscopic realities. The second represents, for many practitioners, a weakened view of science. This article is written to be accessible to anyone with an undergraduate course in quantum mechanics.

quant-ph↗

arXiv2025

Enhancing reactivity of SiO$^+$ ions by controlled excitation to extreme rotational states

Optical pumping of molecules provides unique opportunities for control of chemical reactions at a wide range of rotational energies. This work reports a chemical reaction with extreme rotational excitation of a reactant and its kinetic characterization. We investigate the chemical reactivity for the hydrogen abstraction reaction SiO$^+$ + H$_2$ $\rightarrow$ SiOH$^+$ + H in an ion trap. The SiO$^+$ cations are prepared in a narrow rotational state distribution, including super-rotor states with rotational quantum number $\it{(j)}$ as high as 170, using a broad-band optical pumping method. We show that the super-rotor states of SiO$^+$ substantially enhance the reaction rate, a trend reproduced by complementary theoretical studies. We reveal the mechanism for the rotational enhancement of the reactivity to be a strong coupling of the SiO$^+$ rotational mode with the reaction coordinate at the transition state on the dominant dynamical pathway.

physics.atom-ph↗

arXiv2022

Features of Molecular Structure Beneficial for Optical Pumping

Fast and efficient state preparation of molecules can be accomplished by optical pumping. Molecular structure that most obviously facilitates cycling involves a strong electronic transition, with favorable vibrational branching (diagonal Franck-Condon factors, aka FCFs) and without any intervening electronic states. Here, we propose important adjustments to those criteria, based on our experience optically pumping SiO$^+$. Specifically, the preference for no intervening electronic states should be revised, and over-reliance on FCFs can miss important features. The intervening electronic state in SiO$^+$is actually found to be beneficial in ground rotational state preparation, by providing a pathway for population to undergo a parity flip. This contribution demonstrates the possibility that decay through intervening states may help state preparation of non-diagonal or polyatomic molecules. We also expand upon the definition of favorable branching. In SiO$^+$, we find that the off-diagonal FCFs fail to reflect the vibrational heating versus cooling rates. Since the branching rates are determined by transition dipole moments (TDMs) we introduce a simple model to approximate the TDMs for off-diagonal decays. We find that two terms, set primarily by the slope of the dipole moment function ($dμ/dx$) and offset in equilibrium bond lengths ($Δx = r_e^g-r_e^e$), can add (subtract) to increase (decrease) the magnitude of a given TDM. Applying the model to SiO$^+$, we find there is a fortuitous cancellation, where decay leading to vibrational excitation is reduced, causing optical cycling to lead naturally to vibrational cooling.

physics.atom-ph↗

arXiv2021

Precisely Spun Super Rotors

Improved optical control of molecular quantum states promises new applications including chemistry in the quantum regime, precision tests of fundamental physics, and quantum information processing. While much work has sought to prepare ground state molecules, excited states are also of interest. We demonstrate a broadband optical approach to pump trapped SiO$^+$ molecules into pure super rotor ensembles maintained for many minutes. Super rotor ensembles pumped up to rotational state $N=67$, corresponding to the peak of a 9400 K distribution, had a narrow $N$ spread comparable to that of a few-kelvin sample, and were used for spectroscopy of the previously unobserved C$^2Π$ state. Significant centrifugal distortion of super rotors pumped up to $N=230$ allowed probing electronic structure of SiO$^+$ stretched far from its equilibrium bond length.

physics.atom-ph↗

arXiv2020

Protocol for Optically Pumping AlH$^+$ to a Pure Quantum State

We propose an optical pumping scheme to prepare trapped $\mathrm{AlH}^+$ molecules in a pure state, the stretched hyperfine state $\lvert F=\frac{7}{2},\, m_F=\frac{7}{2}\rangle$ of the rovibronic ground manifold $\lvert \mathrm{X}^2Σ^+,\, v=0,\, N=0\rangle$. Our scheme utilizes linearly-polarized and circularly-polarized fields of a broadband pulsed laser to cool the rotational degree of freedom and drive the population to the hyperfine state, respectively. We simulate the population dynamics by solving a representative system of rate equations that accounts for the laser fields, blackbody radiation, and spontaneous emission. In order to model the hyperfine structure, new hyperfine constants of the $\mathrm{A}^2Π$ excited state were computed using a RASSCF wavefunction. We find that adding an infrared laser to drive the $1 \,-\; 0$ vibrational transition within the $ \mathrm{X}^2Σ^+$ manifold accelerates the cooling process. The results show that under optimum conditions, the population in the target state of the rovibronic ground manifold can reach 63 $\%$ after 68 $\mathrmμ$s (330 ms) and 95 $\%$ after 25 ms (1.2 s) with (without) the infrared laser.

physics.atm-clus↗

arXiv2020

Cooling of a Zero-Nuclear-Spin Molecular Ion to a Selected Rotational State

We demonstrate rotational cooling of the silicon monoxide cation via optical pumping by a spectrally filtered broadband laser. Compared with diatomic hydrides, SiO\+ is more challenging to cool because of its smaller rotational interval. However, the rotational level spacing and large dipole moment of SiO\+ allows direct manipulation by microwaves, and the absence of hyperfine structure in its dominant isotopologue greatly reduces demands for pure quantum state preparation. These features make $^{28}$Si$^{16}$O\+ a good candidate for future applications such as quantum information processing. Cooling to the ground rotational state is achieved on a 100 ms time scale and attains a population of 94(3)\%, with an equivalent temperature $T=0.53(6)$ K. We also describe a novel spectral-filtering approach to cool into arbitrary rotational states and use it to demonstrate a narrow rotational population distribution ($N\pm1$) around a selected state.

physics.atom-ph↗

arXiv2018

Optical Pumping of TeH+: Implications for the Search for Varying mp/me

Molecular overtone transitions provide optical frequency transitions sensitive to variation in the proton-to-electron mass ratio ($μ\equiv m_p/m_e$). However, robust molecular state preparation presents a challenge critical for achieving high precision. Here, we characterize infrared and optical-frequency broadband laser cooling schemes for TeH$^+$, a species with multiple electronic transitions amenable to sustained laser control. Using rate equations to simulate laser cooling population dynamics, we estimate the fractional sensitivity to $μ$ attainable using TeH$^+$. We find that laser cooling of TeH$^+$ can lead to significant improvements on current $μ$ variation limits.

physics.atom-ph↗

arXiv2018

Prospects for Polar Molecular Ion Optical Probe of Varying Proton-Electron Mass Ratio

Molecules with deep vibrational potential wells provide optical intervals sensitive to variation in the proton-electron mass ratio ($μ$). On one hand, polar molecules are of interest since optical state preparation techniques have been demonstrated for such species. On the other hand, it might be assumed that polar species are unfavorable candidates, because typical molecule-frame dipole moments reduce vibrational state lifetimes and cause large polarizabilities and associated Stark shifts. Here, we consider single-photon spectroscopy on a vibrational overtone transition of the polar species TeH$^+$, which is of practical interest because its diagonal Franck-Condon factors should allow rapid state preparation by optical pumping. We point out that all but the ground rotational state obtains a vanishing low-frequency scalar polarizability from coupling with adjacent rotational states, because of a fortuitous relationship between rigid rotor spacings and dipole matrix elements. We project that for good choices of spectroscopy states, demonstrated levels of field control should make possible uncertainties of order $1 \times 10^{-18}$, similar to those of leading atomic ion clocks. The moderately long lived vibrational states of TeH$^+$ make possible a frequency uncertainty approaching $1 \times 10^{-17}$ with one day of averaging for a single trapped ion. Observation over one year could probe for variation of $μ$ with a sensitivity approaching the $1 \times 10^{-18}/\textrm{yr}$ level.

physics.atom-ph↗

arXiv2017

IP determination and 1+1 REMPI spectrum of SiO at 210-220 nm with implications for SiO$^{+}$ ion trap loading

The 1+1 REMPI spectrum of SiO in the 210-220 nm range is recorded. Observed bands are assigned to the $A-X$ vibrational bands $(v``=0-3, v`=5-10)$ and a tentative assignment is given to the 2-photon transition from $X$ to the n=12-13 $[X^{2}Σ^{+},v^{+}=1]$ Rydberg states at 216-217 nm. We estimate the IP of SiO to be 11.59(1) eV. The SiO$^{+}$ cation has previously been identified as a molecular candidate amenable to laser control. Our work allows us to identify an efficient method for loading cold SiO$^{+}$ from an ablated sample of SiO into an ion trap via the $(5,0)$ $A-X$ band at 213.977 nm.

physics.atom-ph↗

arXiv2017

Coherent light generation in hybrid atomic-nanophotonic integrated structures

The integration of neutral atoms with nanophotonic structures offer significant potential as a versatile platform to explore fundamental light-matter interactions as well as realizing novel quantum-optical devices. Here, we investigate the possibility of creating low-threshold micro-scale lasers in hybrid systems based on integrating room-temperature atomic gases with both dielectric and metallic nanophotonic systems. We particularly focus on studying two different devices resulting from incorporating an optically-pumped Rb-ethane mixture in a dielectric ring resonator and a plasmonic lattice. We show in both cases the combination of the optical gain provided by the atomic vapor, along with the unique field-confinement properties of nanophotonic structures, enables generating of coherent radiation, i.e. laser light, at low power levels. In addition, we provide general design guidelines for these hybrid nano-lasers and an efficient density matrix-based formalism for studying these systems. Our results demonstrate a unique route towards small foot-print, highly efficient, and fast lasers, which paves the way towards the development of a whole new class of active nanophotonic and metamaterial systems.

physics.optics↗

arXiv2016

High extinction amplitude modulation in ultrashort pulse shaping

We explored the issues related to the resolution and the modulation extinction when filtering the spectrum of a UV femtosecond laser with a standard ultrashort pulse shaper. We have learned that a higher pulse shaping resolution often requires a larger working beam size or a higher density grating for greater dispersion. However, these approaches also introduce more optical errors and degrade the extinction. In this work, we examined specifics of each component to determine the best configuration of our spectral filtering setup. As a proof-of-concept demonstration, we utilized elements available as standard products and achieved 100 GHz filtering resolution with high extinction at the UV-A wavelength, which is superb in this wavelength range. The high extinction spectral filtering is especially important while modifying a broadband laser for the optical control of molecule's internal state.

physics.optics↗

arXiv2016

Noise reduction of a Libbrecht--Hall style current driver

The Libbrecht--Hall circuit is a well-known, low-noise current driver for narrow-linewidth diode lasers. An important feature of the circuit is a current limit to protect the laser diode. As the current approaches the maximum limit, however, the noise in the laser current increases dramatically. This paper documents this behavior and explores simple circuit modifications to alleviate this issue.

physics.ins-det↗

arXiv2016

Raman sideband cooling of a 138Ba+ ion using a Zeeman interval

Motional ground state cooling and internal state preparation are important elements for quantum logic spectroscopy (QLS), a class of quantum information processing. Since QLS does not require the high gate fidelities usually associated with quantum computation and quantum simulation, it is possible to make simplifying choices in ion species and quantum protocols at the expense of some fidelity. Here, we report sideband cooling and motional state detection protocols for $^{138}$Ba$^+$ of sufficient fidelity for QLS without an extremely narrowband laser or the use of a species with hyperfine structure. We use the two S$_{1/2}$ Zeeman sublevels of $^{138}$Ba$^+$ to Raman sideband cool a single ion to the motional ground state. Because of the small Zeeman splitting, near-resonant Raman sideband cooling of $^{138}$Ba$^+$ requires only the Doppler cooling lasers and two additional AOMs. Observing the near-resonant Raman optical pumping fluorescence, we estimate a final average motional quantum number $\bar{n}\approx0.17$. We additionally employ a second, far-off-resonant laser driving Raman $π$-pulses between the two Zeeman sublevels to provide motional state detection for QLS and to confirm the sideband cooling efficiency, measuring a final $\bar{n} = 0.15(6)$.

physics.atom-ph↗

arXiv2016

Rotational State Analysis of AlH+ by Two-Photon Dissociation

We perform ab-initio calculations needed to predict the cross-section of an experimentally accessible (1+1') resonance-enhanced multiphoton dissociation (REMPD) pathway in AlH+. Experimenting on AlH+ ions held in a radiofrequency Paul trap, we confirm dissociation via this channel with analysis performed using time-of-flight mass spectrometry. We demonstrate the use of REMPD for rotational state analysis, and we measure the rotational distribution of trapped AlH+ to be consistent with the expected thermal distribution. AlH+ is a particularly interesting species for ion trap work because of its electronic level structure, which makes it amenable to proposals for rotational optical pumping, direct Doppler cooling, and single-molecule fluorescence detection. Potential applications of trapped AlH+ include searches for time-varying constants, quantum information processing, and ultracold chemistry studies.

physics.atom-ph↗

arXiv2015

Broadband optical cooling of molecular rotors from room temperature to the ground state

Laser cycling of resonances can remove entropy from a system via spontaneously emitted photons, with electronic resonances providing the fastest cooling timescales because of their rapid relaxation rates. Although atoms are routinely laser cooled, even simple molecules pose two interrelated challenges for cooling: every populated rotational-vibrational state requires a different laser frequency, and electronic relaxation generally excites vibrations. Here, we cool trapped AlH+ molecules to their ground rotational-vibrational quantum state using an electronically-exciting broadband laser to simultaneously drive cooling resonances from many different rotational levels. Undesired vibrational excitation is avoided because of vibrational-electronic decoupling in AlH+. We demonstrate rotational cooling on the 140(20) ms timescale from room temperature to 3.8(+0.9/-0.3) K, with the ground state population increasing from ~3% to 95.4(+1.3/-2.0) %. This cooling technique could be applied to several other neutral and charged molecular species useful for quantum information processing, ultracold chemistry applications, and precision tests of fundamental symmetries.

physics.atom-ph↗