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Brittany E. Miles

Publications and source records attributed to Brittany E. Miles.

At least 19 recordsLinked to original sources

Time-resolved JWST Retrieval Analysis of the Coldest Brown Dwarf: Temperature and Chemical Variations in WISE 0855-07

WISE J0855-07 is the coldest known brown dwarf (estimated Teff~250 K), offering a rare opportunity to probe atmospheric physics in the temperature and mass regime that overlaps directly with exoplanets. At these temperatures, modest perturbations to the thermal structure and chemical abundances can produce measurable changes in the emergent mid-infrared spectrum, making time-resolved spectroscopy a powerful way to test whether the atmosphere is longitudinally and temporally homogeneous. Using James Webb Space Telescope NIRSpec/G395M time-series spectra spanning ~3 to 5.2 μm over 11 hr, we analyze every third spectrum from the dataset with a series of time-resolved atmospheric retrievals using the Brewster retrieval framework. Using this approach, we model epoch-to-epoch changes in the atmospheric state that drive the observed variability, including the thermal structure and key molecular abundances. From the time-series retrievals, we find that the primary source of the observed spectral variability is driven by the variations in the thermal structure, which range from ~1 to <100 K from epoch to epoch, particularly between the pressures of ~0.4 and 10 bar. In addition, changes in the abundances of CO, and possibly PH3 and CO2, further modulate the spectrum within specific molecular features. These measurements provide a retrieval-based view of atmospheric variability in an ultracold, planet-like object, directly constraining how thermal and chemical structure evolve on observable timescales.

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Water Cloud and Chemical Modulations in the Coldest Brown Dwarf

We present high signal-to-noise, medium resolution (R ~ 1000), time-series JWST/NIRSpec spectra of WISE 0855 (265K), the coldest known brown dwarf. Medium resolution, time-series spectroscopy gives us the power to disentangle the effects of chemistry, temperature, and condensates on this cool world. Our observations span 11 hours with a 15 minute cadence covering 2.87 - 5.27 $μ$m. The strongest time variable spectroscopic feature is carbon monoxide gas absorption producing modulations with a peak-to-peak amplitude up to 10\% at some wavelengths. Using principal component analysis, we show that the variations in carbon monoxide and phosphine correlate with one another. By comparing our data to atmospheric and structure models we present evidence of patchy water clouds within the atmosphere of WISE 0855. We find that variations in CO and PH$_{3}$ abundances must originate from quenched atmospheric pressures while variations in water cloud thickness occurs at lower pressures.

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JWST/NIRSpec Spectra for Three Ultracool Brown Dwarfs Detected in Extragalactic Surveys: Further Evidence for Phosphine Absorption

We present JWST NIRSpec prism spectra for three ultracool brown dwarfs discovered in extragalactic survey data, two from the JWST Advanced Deep Extragalactic Survey (JADES), and one from Public Release IMaging for Extragalactic Research (PRIMER) survey observed as part of the Mirage or Miracle (MoM) program. The spectra for these sources indicate that one is a T6 dwarf (JADES-GS-BD-11, T$_{\mathrm{eff}} = \sim 700$ K) and two are Y0-Y1 dwarfs (JADES-GS-BD-5, T$_{\mathrm{eff}} = \sim 400$ K, and MoM-239450, T$_{\mathrm{eff}} = \sim 500$ K). Model atmospheric fits with $\texttt{NIFTY}$ to the spectra are consistent with this classification, and indicate that JADES-GS-BD-5 is only $\sim 150$ pc from the Sun, MoM-239450 is $\sim 700 - 800$ pc from the Sun, and JADES-GS-BD-11 is $\sim 1$ kpc from the Sun, with these latter two more distant sources being best fit at sub-solar metallicities. JADES-GS-BD-5 has an observed spectrum with significantly weaker J and H band emission than Y dwarf atmospheric models, potentially indicating the presence of water ice clouds in the brown dwarf. The spectrum for JADES-GS-BD-11 has a feature at 4.3$μ$m consistent with absorption from the rarely seen phosphine molecule at $2.6σ$ confidence. Given the low metallicity for this source ([M/H] $ = -0.7$), our finding supports the theory that detecting phosphine in brown dwarf atmospheres is tied to atmospheric metallicity. JWST/NIRSpec spectroscopy continues to be a powerful tool for understanding the properties of these distant, and very cold brown dwarfs.

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The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems VIII: patchy forsterite and enstatite clouds in the atmosphere of VHS 1256 b, retrieval lessons learned and outlook to the future

JWST defines a new era for the data-driven approach of retrieval modelling, which has become a cornerstone tool for the statistical inference of exoplanetary and brown dwarf properties. The Early Release Science program #1386 observations of VHS 1256 b represent a huge jump in data quality, data quantity and spectral coverage for such objects. VHS 1256 b is a young, planetary mass and extremely variable companion that populates the enigmatic L/T cohort of substellar atmospheres. In this first retrieval analysis of the full 1 - 18 micron dataset, we apply the Brewster retrieval framework to the NIRSpec and MIRI spectroscopic observations of VHS 1256 b, exploring a variety of cloud species and structures. Using Delta(BIC) we find that the data is best described by a forsterite (Mg$_{2}$SiO$_{4}$) and enstatite (MgSiO$_{3}$) cloud combination. Our analysis shows a strong preference for patchy silicate cloud coverage, which aligns with VHS 1256 b's extensive and well documented spectral variability. Our retrieval is able to place constraints on the abundances of H$_{2}$O, CO, CO$_{2}$, CH$_{4}$ as well as NH$_{3}$. We also show that the retrieved parameters are sensitive to the data used and the relative signal-to-noise ratios between data from different instruments. We conclude with the next steps for the wider retrieval community to better understand young and cloudy exoplanetary atmospheres.

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JADES: An Abundance of Ultra-Distant T- and Y-Dwarfs in Deep Extragalactic Data

Ultra-cool T- (T$_{\mathrm{eff}} \approx$ 500 - 1200 K) and Y-dwarfs (T$_{\mathrm{eff}}$ $\lessapprox 500$ K) have historically been found only a few hundred parsecs from the Sun. The sensitivity and wavelength coverage of the NIRCam instrument on board the James Webb Space Telescope offer a unique method for finding low-temperature brown dwarfs in deep extragalactic datasets out to multiple kiloparsecs. Here we report on the selection of a sample of 41 brown dwarf and brown dwarf candidates across the JWST Advanced Deep Extragalactic Survey (JADES) in the GOODS-S and GOODS-N regions. We introduce a new open-source Bayesian tool, the Near-Infrared Fitting for T and Y-dwarfs (\texttt{NIFTY}), to derive effective temperatures, metallicities, and distances from JWST photometry. We find that 31 candidates have fits consistent with T-dwarf temperatures out to 5 - 6 kpc, and 10 candidates have fits consistent with Y-dwarf temperatures out to 1 - 2 kpc. The majority of the sources are best fit with sub-solar metallicity models, consistent with them being subdwarfs in the Milky Way thick disk and halo. We report proper motions for nine brown dwarf candidates (three are newly presented), and calculate the number density of T- and Y-dwarfs as a function of temperature and distance above the Milky Way midplane. We further discuss how Y-dwarfs can serve as contaminants in the search for ultra-high-redshift galaxies. Together, these results demonstrate the power of deep JWST extragalactic imaging to probe the coldest substellar populations far beyond the solar neighborhood, providing new constraints on the Milky Way's structure and brown dwarf demographics.

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Large-amplitude Variability Driven by Giant Dust Storms on a Planetary-mass Companion

Large-amplitude variations are commonly observed in the atmospheres of directly imaged exoplanets and brown dwarfs. VHS 1256B, the most variable known planet-mass object, exhibits a near-infrared flux change of nearly 40%, with red color and silicate features revealed in recent JWST spectra, challenging current theories. Using a general circulation model, we demonstrate that VHS 1256B's atmosphere is dominated by planetary-scale dust storms persisting for tens of days, with large patchy clouds propagating with equatorial waves. This weather pattern, distinct from the banded structures seen on solar system giants, simultaneously explains the observed spectra and critical features in the rotational light curves, including the large amplitude, irregular evolution, and wavelength dependence, as well as the variability trends observed in near-infrared color-magnitude diagrams of dusty substellar atmospheres.

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A Deep Search for Exomoons Around WISE 0855 With JWST

JWST is collecting time-series observations of many free-floating planets (FFPs) to study their weather, but these light curves are the ideal datasets to search for exomoons that transit the FFP during observations. In this paper, we present observations of the planetary-mass Y dwarf ($T=250-285K$, $M = 6.5\pm3.5 M_{Jup}$, d = 2.3$\,$pc) WISE J085510.83-071442.5 (WISE 0855), whose proximity and brightness make it ideal for a transiting exomoon search. We examine 11 hours of time-series spectra from the JWST Near-Infrared Spectrograph (NIRSpec) whose sensitivity, in combination with Gaussian process (GP) modeling, allows for the disentanglement of exomoon transits from WISE 0855's variability. We do not find statistically significant evidence of an exomoon transit in this dataset. Using injection and recovery tests of artificial transits for depths ranging between 0.1-1% (0.35-1.12 $R_{\oplus}$) we explore the exomoon parameter space where we could successfully detect transits. For transit depths $\geq 0.5\%$ (1.96$\,R_{\text{Titan}}$), our detection rate is 96%, which, for WISE 0855, corresponds to a moon with a companion-to-host mass ratio similar to that of Titan and Saturn. Given our sensitivity, transit probabilities, and our observational duration, we determine a $\sim$91% probability of detecting a Titan mass analog exomoon after 18 such observations if every observed system hosts a Titan mass analog exomoon in a Galilean-like system. This suggests that JWST observations of dozens of FFPs could yield meaningful constraints on the occurrence rate of exomoons. This paper is the first demonstration that JWST is sensitive to Galilean moon mass analogs around FFPs.

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Laboratory testing and characterization of a hybrid fast/slow readout mode for the H2RG detectors in SCALES

The upcoming SCALES (Slicer Combined with Array of Lenslets for Exoplanet Spectroscopy) instrument for W.M. Keck Observatory will enable new imaging and low-/mid-resolution coronagraphic integral field spectroscopic observations over the wavelength range from 2-5 microns. At the heart of the instrument are two HgCdTe Teledyne Imaging H2RG detectors, designed for a 100kHz pixel clock rate (slow mode) with a fixed 4-channel readout. However, in ground-based operation at these wavelengths, the resulting minimum frame readout time will result in the infrared background saturating the detector. To enable high quality observations without saturation from the bright infrared sky background, we operate the detectors using a custom cable for buffered readout via the Teledyne Imaging SIDECAR ASIC followed by an AstroBlank/Markury Scientific MACIE controller card controlled by custom firmware. This combination allows the detector to be read out at faster pixel clock rates. This, in combination with the slow-mode H2RG, is what we characterize as hybrid fast-slow readout, enabling readout up to 18 times faster than would be possible in slow mode alone. In the UCLA Infrared Lab, we have performed room-temperature and cold tests with the H2RG detectors. We test and optimize full-frame data acquisition with pixel clock rates from 0.2-1.8 MHz. In these proceedings, we present a summary of the controller software used to operate the H2RG-ASIC-MACIE system. We present the methodology of, and preliminary results from, the UCLA tests of cryogenic operation of both H2RG detectors. We also outline the next steps in verification of detector performance, as well as integration with the SCALES instrument.

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The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems III: Aperture Masking Interferometric Observations of the star HIP 65426 at 3.8 um

We present aperture masking interferometry (AMI) observations of the star HIP 65426 at $3.8\,\rm{μm}$ as a part of the JWST Direct Imaging Early Release Science (ERS) program obtained using the Near Infrared Imager and Slitless Spectrograph (NIRISS) instrument. This mode provides access to very small inner working angles (even separations slightly below the Michelson limit of $0.5λ/D$ for an interferometer), which are inaccessible with the classical inner working angles of the JWST coronagraphs. When combined with JWST's unprecedented infrared sensitivity, this mode has the potential to probe a new portion of parameter space across a wide array of astronomical observations. Using this mode, we are able to achieve a $5σ$ contrast of $Δm{\sim}7.62{\pm}0.13$ mag relative to the host star at separations ${\gtrsim}0.07{"}$, and the contrast deteriorates steeply at separations ${\lesssim}0.07{"}$. However, we detect no additional companions interior to the known companion HIP 65426 b (at separation ${\sim}0.82{"}$ or, $87^{+108}_{-31}\,\rm{au}$). Our observations thus rule out companions more massive than $10{-}12\,\rm{M_{Jup}}$ at separations ${\sim}10{-}20\,\rm{au}$ from HIP 65426, a region out of reach of ground or space-based coronagraphic imaging. These observations confirm that the AMI mode on JWST is sensitive to planetary mass companions at close-in separations (${\gtrsim}0.07{"}$), even for thousands of more distant stars at $\sim$100 pc, in addition to the stars in the nearby young moving groups as stated in previous works. This result will allow the planning and successful execution of future observations to probe the inner regions of nearby stellar systems, opening an essentially unexplored parameter space.

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Protosolar D-to-H abundance and one part-per-billion PH$_{3}$ in the coldest brown dwarf

The coldest Y spectral type brown dwarfs are similar in mass and temperature to cool and warm ($\sim$200 -- 400 K) giant exoplanets. We can therefore use their atmospheres as proxies for planetary atmospheres, testing our understanding of physics and chemistry for these complex, cool worlds. At these cold temperatures, their atmospheres are cold enough for water clouds to form, and chemical timescales increase, increasing the likelihood of disequilibrium chemistry compared to warmer classes of planets. JWST observations are revolutionizing the characterization of these worlds with high signal-to-noise, moderate resolution near- and mid-infrared spectra. The spectra have been used to measure the abundances of prominent species like water, methane, and ammonia; species that trace chemical reactions like carbon monoxide; and even isotopologues of carbon monoxide and ammonia. Here, we present atmospheric retrieval results using both published fixed-slit (GTO program 1230) and new averaged time series observations (GO program 2327) of the coldest known Y dwarf, WISE 0855-0714 (using NIRSpec G395M spectra), which has an effective temperature of $\sim$ 264 K. We present a detection of deuterium in an atmosphere outside of the solar system via a relative measurement of deuterated methane (CH$_{3}$D) and standard methane. From this, we infer the D/H ratio of a substellar object outside the solar system for the first time. We also present a well-constrained part-per-billion abundance of phosphine (PH$_{3}$). We discuss our interpretation of these results and the implications for brown dwarf and giant exoplanet formation and evolution.

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JADES: Spectroscopic Confirmation and Proper Motion for a T-Dwarf at 2 Kiloparsecs

Large area observations of extragalactic deep fields with the James Webb Space Telescope (JWST) have provided a wealth of candidate low-mass L- and T-class brown dwarfs. The existence of these sources, which are at derived distances of hundreds of parsecs to several kiloparsecs from the Sun, has strong implications for the low-mass end of the stellar initial mass function, and the link between stars and planets at low metallicities. In this letter, we present a JWST/NIRSpec PRISM spectrum of brown dwarf JADES-GS-BD-9, confirming its photometric selection from observations taken as part of the JWST Advanced Deep Extragalactic Survey (JADES) program. Fits to this spectrum indicate that the brown dwarf has an effective temperature of 800-900K (T5 - T6) at a distance of $1.8 - 2.3$kpc from the Sun, with evidence of the source being at low metallicity ([M/H] $\leq -0.5$). Finally, because of the cadence of JADES NIRCam observations of this source, we additionally uncover a proper motion between the 2022 and 2023 centroids, and we measure a proper motion of $20 \pm 4$ mas yr$^{-1}$ (a transverse velocity of 214 km s$^{-1}$ at 2.25 kpc). At this predicted metallicity, distance, and transverse velocity, it is likely that this source belongs either to the edge of the Milky Way thick disk or the galactic halo. This spectral confirmation demonstrates the efficacy of photometric selection of these important sources across deep extragalactic JWST imaging.

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Sensitivity and Performance of LBTI/NOMIC Spectroscopy: Prospects for 10- and 30-meter class Mid-IR Exoplanet Science

Long wavelength infrared (8-13 $μ$m) spectroscopy is invaluable for detecting molecular features in the atmospheres of gas giant and terrestrial exoplanets. The nulling-optimized mid-infrared camera (NOMIC) on the Large Binocular Telescope Interferometer (LBTI) has a low resolution (R$\sim$200) germanium grism that was previously installed but has not been characterized and commissioned for scientific observations. Using a 1.27 mm slit and broadband filter in combination with the grism, the infrared window between 8-13 $μ$m can be captured. We describe initial on sky testing of the LBTI/NOMIC grism mode with adaptive optics to study standard stars and binaries. We discuss the impact of observational strategy and telluric calibration on the spectral reduction process. We infer the impact of existing mid-infrared detectors on NOMIC's spectroscopic mode and discuss requirements to enable higher resolution 8-13 $μ$m spectroscopy on current and future facilities.

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The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems II: A 1 to 20 Micron Spectrum of the Planetary-Mass Companion VHS 1256-1257 b

We present the highest fidelity spectrum to date of a planetary-mass object. VHS 1256 b is a $<$20 M$_\mathrm{Jup}$ widely separated ($\sim$8\arcsec, a = 150 au), young, planetary-mass companion that shares photometric colors and spectroscopic features with the directly imaged exoplanets HR 8799 c, d, and e. As an L-to-T transition object, VHS 1256 b exists along the region of the color-magnitude diagram where substellar atmospheres transition from cloudy to clear. We observed VHS 1256~b with \textit{JWST}'s NIRSpec IFU and MIRI MRS modes for coverage from 1 $μ$m to 20 $μ$m at resolutions of $\sim$1,000 - 3,700. Water, methane, carbon monoxide, carbon dioxide, sodium, and potassium are observed in several portions of the \textit{JWST} spectrum based on comparisons from template brown dwarf spectra, molecular opacities, and atmospheric models. The spectral shape of VHS 1256 b is influenced by disequilibrium chemistry and clouds. We directly detect silicate clouds, the first such detection reported for a planetary-mass companion.

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JWST-TST High Contrast: Achieving direct spectroscopy of faint substellar companions next to bright stars with the NIRSpec IFU

The JWST NIRSpec integral field unit (IFU) presents a unique opportunity to observe directly imaged exoplanets from 3-5 um at moderate spectral resolution (R~2,700) and thereby better constrain the composition, disequilibrium chemistry, and cloud properties of their atmospheres. In this work, we present the first NIRSpec IFU high-contrast observations of a substellar companion that requires starlight suppression techniques. We develop specific data reduction strategies to study faint companions around bright stars, and assess the performance of NIRSpec at high contrast. First, we demonstrate an approach to forward model the companion signal and the starlight directly in the detector images, which mitigates the effects of NIRSpec's spatial undersampling. We demonstrate a sensitivity to planets that are 3e-6 fainter than their stars at 1'', or 3e-5 at 0.3''. Then, we implement a reference star point spread function (PSF) subtraction and a spectral extraction that does not require spatially and spectrally regularly sampled spectral cubes. This allows us to extract a moderate resolution (R~2,700) spectrum of the faint T-dwarf companion HD 19467 B from 2.9-5.2 um with signal-to-noise ratio (S/N)~10 per resolution element. Across this wavelength range, HD~19467~B has a flux ratio varying between 1e-5-1e-4 and a separation relative to its star of 1.6''. A companion paper by Hoch et al. more deeply analyzes the atmospheric properties of this companion based on the extracted spectrum. Using the methods developed here, NIRSpec's sensitivity may enable direct detection and spectral characterization of relatively old (~1 Gyr), cool (~250 K), and closely separated (~3-5 au) exoplanets that are less massive than Jupiter.

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The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems IV: NIRISS Aperture Masking Interferometry Performance and Lessons Learned

We present a performance analysis for the aperture masking interferometry (AMI) mode on board the James Webb Space Telescope Near Infrared Imager and Slitless Spectrograph (JWST/NIRISS). Thanks to self-calibrating observables, AMI accesses inner working angles down to and even within the classical diffraction limit. The scientific potential of this mode has recently been demonstrated by the Early Release Science (ERS) 1386 program with a deep search for close-in companions in the HIP 65426 exoplanetary system. As part of ERS 1386, we use the same data set to explore the random, static, and calibration errors of NIRISS AMI observables. We compare the observed noise properties and achievable contrast to theoretical predictions. We explore possible sources of calibration errors and show that differences in charge migration between the observations of HIP 65426 and point-spread function calibration stars can account for the achieved contrast curves. Lastly, we use self-calibration tests to demonstrate that with adequate calibration NIRISS F380M AMI can reach contrast levels of $\sim9-10$ mag at $\gtrsim λ/D$. These tests lead us to observation planning recommendations and strongly motivate future studies aimed at producing sophisticated calibration strategies taking these systematic effects into account. This will unlock the unprecedented capabilities of JWST/NIRISS AMI, with sensitivity to significantly colder, lower-mass exoplanets than lower-contrast ground-based AMI setups, at orbital separations inaccessible to JWST coronagraphy.

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The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems V: Do Self-Consistent Atmospheric Models Represent JWST Spectra? A Showcase With VHS 1256 b

The unprecedented medium-resolution (R~1500-3500) near- and mid-infrared (1-18um) spectrum provided by JWST for the young (140+/-20Myr) low-mass (12-20MJup) L-T transition (L7) companion VHS1256b gives access to a catalogue of molecular absorptions. In this study, we present a comprehensive analysis of this dataset utilizing a forward modelling approach, applying our Bayesian framework, ForMoSA. We explore five distinct atmospheric models to assess their performance in estimating key atmospheric parameters: Teff, log(g), [M/H], C/O, gamma, fsed, and R. Our findings reveal that each parameter's estimate is significantly influenced by factors such as the wavelength range considered and the model chosen for the fit. This is attributed to systematic errors in the models and their challenges in accurately replicating the complex atmospheric structure of VHS1256b, notably the complexity of its clouds and dust distribution. To propagate the impact of these systematic uncertainties on our atmospheric property estimates, we introduce innovative fitting methodologies based on independent fits performed on different spectral windows. We finally derived a Teff consistent with the spectral type of the target, considering its young age, which is confirmed by our estimate of log(g). Despite the exceptional data quality, attaining robust estimates for chemical abundances [M/H] and C/O, often employed as indicators of formation history, remains challenging. Nevertheless, the pioneering case of JWST's data for VHS1256b has paved the way for future acquisitions of substellar spectra that will be systematically analyzed to directly compare the properties of these objects and correct the systematics in the models.

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The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems I: High Contrast Imaging of the Exoplanet HIP 65426 b from 2-16 $μ$m

We present JWST Early Release Science (ERS) coronagraphic observations of the super-Jupiter exoplanet, HIP 65426 b, with the Near-Infrared Camera (NIRCam) from 2-5 $μ$m, and with the Mid-Infrared Instrument (MIRI) from 11-16 $μ$m. At a separation of $\sim$0.82" (86$^{+116}_{-31}$ au), HIP 65426 b is clearly detected in all seven of our observational filters, representing the first images of an exoplanet to be obtained by JWST, and the first ever direct detection of an exoplanet beyond 5 $μ$m. These observations demonstrate that JWST is exceeding its nominal predicted performance by up to a factor of 10, depending on separation and subtraction method, with measured 5$σ$ contrast limits of $\sim$1$\times10^{-5}$ and $\sim$2$\times10^{-4}$ at 1" for NIRCam at 4.4 $μ$m and MIRI at 11.3 $μ$m, respectively. These contrast limits provide sensitivity to sub-Jupiter companions with masses as low as 0.3$M_\mathrm{Jup}$ beyond separations of $\sim$100 au. Together with existing ground-based near-infrared data, the JWST photometry are well fit by a BT-SETTL atmospheric model from 1-16 $μ$m, and span $\sim$97% of HIP 65426 b's luminous range. Independent of the choice of model atmosphere we measure an empirical bolometric luminosity that is tightly constrained between $\mathrm{log}\!\left(L_\mathrm{bol}/L_{\odot}\right)$=-4.31 to $-$4.14, which in turn provides a robust mass constraint of 7.1$\pm$1.2 $M_\mathrm{Jup}$. In totality, these observations confirm that JWST presents a powerful and exciting opportunity to characterise the population of exoplanets amenable to high-contrast imaging in greater detail.

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Probing the Extent of Vertical Mixing in Brown Dwarf Atmospheres with Disequilibrium Chemistry

Evidence of disequilibrium chemistry due to vertical mixing in the atmospheres of many T and Y-dwarfs has been inferred due to enhanced mixing ratios of CO and reduced NH$_3$. Atmospheric models of planets and brown dwarfs typically parameterize this vertical mixing phenomenon with the vertical eddy diffusion coefficient, $K_{\rm zz}$. While $K_{\rm zz}$ can perhaps be approximated in the convective regions in the atmosphere with mixing length theory, in radiative regions the strength of vertical mixing is uncertain by many orders of magnitude. With a new grid of self-consistent 1D model atmospheres from $T_{\rm eff}$ of 400 - 1000 K, computed with a new radiative-convective equilibrium python code PICASO 3.0, we aim to assess how molecular abundances and corresponding spectra can be used as a probe of depth-dependent $K_{\rm zz}$. At a given surface gravity, we find non-monotonic behavior in the CO abundance as a function of $T_{\rm eff}$, as chemical abundances are sometimes quenched in either of two potential atmospheric convective zones, or quenched in either of two possible radiative zones. The temperature structure and chemical quenching behavior also changes with gravity. We compare our models with available near-infrared and M-band spectroscopy of several T and Y-dwarfs and assess their atmospheric vertical mixing profiles. We also compare to color-magnitude diagrams and make predictions for JWST spectra. This work yields new constraints, and points the way to significant future gains, in determining $K_{\rm zz}$, a fundamental atmospheric parameter in substellar atmospheres, with significant implications for chemistry and cloud modeling.

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