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Bruno Bézard

Publications and source records attributed to Bruno Bézard.

18 recordsLinked to original sources

Next-generation Exo-REM atmospheric models: application to VHS 1256 b to emulate patchy clouds

Condensate clouds are a defining feature of brown dwarf and exoplanet atmospheres, producing a broad range of colours on the CMD and giving rise to spectral features such as the distinct $\sim 10 μ$m spectral imprint. Cloud cover is likely to be heterogeneous in many objects, with observed rotational variability providing evidence for the presence of thick and thin cloud regions rotating in and out of view. Yet current 1D atmosphere models often fail to reproduce the spectra of highly cloudy substellar objects, especially those with complex cloud structures. We address these limitations by upgrading the Exo-REM atmosphere model, and by devising a more nuanced approach to describe heterogeneous cloud cover with pre-computed 1D grids. We present new Exo-REM grids, hereafter Exo-REM k26, featuring critical updates: (1) the incorporation of a cloud sedimentation parameter, $f_{sed}$, to govern cloud opacity, thereby enabling even the reddest of objects to be accessed on a CMD, revealing a trend of decreasing $f_{sed}$ along the L--T transition (2) the substantial update of molecular opacities and abundances used, including new experimentally validated alkali line lists, and (3) the implementation of strict convergence criteria that entirely avoid unstable model solutions. Correcting an erroneous $\text{CH}_3\text{D}$ abundance leads to spectral changes for low-$T_{eff}$ objects. Applying Exo-REM k26 to the cool GJ 504 b thus leads to a revision of its parameters ($T_{eff} = 473^{+14}_{-12}$ K, $\log g = 4.0 \pm 0.1$ dex). For the variable VHS 1256 b, a two-column framework that emulates cloud heterogeneities achieves an improved global fit over a single 1D model. A ~60-40% split of thick and thin clouds best describes its atmosphere, further confirming the presence of patchy clouds. This reproduces the strong $10 μ$m silicate absorption in the JWST data of VHS 1256 b.

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X-SHYNE: X-Shooter spectra of young exoplanet analogs II. Presentation and analysis of the full library

The X-SHYNE library is a homogeneous sample of 43 medium-resolution (R=8000) infrared (0.3-2.5um) spectra of young (<500Myr), low-mass (<20Mjup), and cold (Teff=600-2000K) isolated brown dwarfs and wide-separation companions observed with the VLT/X-Shooter instrument. To characterize our targets, we performed a global comparative analysis. We first applied a semi-empirical approach. By refining their age and bolometric luminosity, we derived key atmospheric and physical properties, such as Teff, mass, surface gravity (g), and radius, using the evolutionary model COND03. These results were then compared with the results from a synthetic analysis based on three self-consistent atmospheric models. To compare our spectra with these grids we used the Bayesian inference code ForMoSA. We found similar Lbol estimates between both approaches, but an underestimated Teff from the cloudy models, likely due to a lack of absorbers that could dominate the J and H bands of early L. We also observed a discrepancy in the log(g) estimates, which are dispersed between 3.5 and 5.5 dex for mid-L objects. We interpreted this as a bias caused by a range of rotational velocities leading to cloud migration toward equatorial latitudes, combined with a variety of viewing angles that result in different observed atmospheric properties (cloud column densities, atmospheric pressures, etc.). Finally, while providing robust estimates of [M/H] and C/O for individual objects remains challenging, the X-SHYNE library globally suggests solar values, which are consistent with a formation via stellar formation mechanisms. This study highlights the strength of homogeneous datasets in performing comparative analyses, reducing the impact of systematics, and ensuring robust conclusions while avoiding over-interpretation.

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The Atmosphere of Titan in Late Northern Summer from JWST and Keck Observations

Saturn's moon Titan undergoes a long annual cycle of 29.45 Earth years. Titan's northern winter and spring were investigated in detail by the Cassini-Huygens spacecraft (2004-2017), but the northern summer season remains sparsely studied. Here we present new observations from the James Webb Space Telescope (JWST) and Keck II telescope made in 2022 and 2023 during Titan's late northern summer. Using JWST's mid-infrared instrument, we spectroscopically detected the methyl radical, the primary product of methane break-up and key to the formation of ethane and heavier molecules. Using the near-infrared spectrograph onboard JWST, we detected several non-local thermodynamic equilibrium CO and CO2 emission bands, which allowed us to measure these species over a wide altitude range. Lastly, using the near-infrared camera onboard JWST and Keck II, we imaged northern hemisphere tropospheric clouds evolving in altitude, which provided new insights and constraints on seasonal convection patterns. These observations pave the way for new observations and modelling of Titan's climate and meteorology as it progresses through the northern fall equinox, when its atmosphere is expected to show notable seasonal changes.

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The radiative and dynamical impact of clouds in the atmosphere of the hot Jupiter WASP-43 b

Hot Jupiters exhibit large day-night temperature contrasts. Their cooler nightsides are thought to host clouds. However, the exact nature of these clouds, their spatial distribution, and their impact on atmospheric dynamics, thermal structure, and spectra is still unclear. We investigate the atmosphere of WASP-43 b, a short period hot Jupiter recently observed with JWST, to understand the radiative and dynamical impact of clouds on the atmospheric circulation and thermal structure. We aim to understand the impact of different kinds of condensates potentially forming in WASP-43 b, with various sizes and atmospheric metallicities. We used a 3D global climate model (GCM) with a new temperature-dependent cloud model that includes radiative feed-backs coupled with hydrodynamical integrations to study the atmospheric properties of WASP-43 b. We produced observables from our simulations and compared them to spectral phase curves from various observations. We show that clouds have a net warming effect, meaning that the greenhouse effect caused by clouds is stronger than the albedo cooling effect. We show that the radiative effect of clouds has various impacts on the dynamical and thermal structure of WASP-43 b. Depending on the type of condensates and their sizes, the radiative-dynamical feedback will modify the horizontal and vertical temperature gradient and reduce the wind speed. For super-solar metallicity atmospheres, fewer clouds form in the atmosphere, leading to a weaker feedback. Comparisons with spectral phase curves observed with HST, Spitzer, and JWST indicate that WASP-43 b s nightside is cloudy and rule out sub-micron Mg2SiO4 cloud particles as the main opacity source. Distinguishing between cloudy solar and cloudy super-solar-metallicity atmospheres is not straightforward, and further observations of both reflected light and thermal emission are needed.

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Methane as a dominant absorber in the habitable-zone sub-Neptune K2-18 b

In their Letter, Tsiaras et al. reported the detection of water vapour in the atmosphere of K2-18 b, an exoplanet of 7 to 10 Earth masses located in the habitable zone of an M-dwarf star. The detection is based on an absorption feature seen at 1.4 $μ$m in observations of the transiting exoplanet with the Hubble Space Telescope/Wide Field Camera 3. We have simulated the mean temperature structure and composition of K2-18b using a radiative-convective equilibrium model and we present here the corresponding transit spectroscopy calculations. We argue that the reported absorption is most likely due to methane, a gas expected to be abundant in the hydrogen-helium atmosphere of cold sub-Neptunes. More generally, we show that the 1.4-$μ$m absorption seen in transit spectra is not diagnostic of the presence of water vapour for sub-Neptunes having an effective temperature less than 600 K and that water vapour dominates over methane at this wavelength only at larger temperatures.

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Trajectory-based simulation of far-infrared CIA profiles of CH$_4-$N$_2$ for modeling Titan's atmosphere

We report the results of the trajectory-based simulation of far-infrared collision-induced absorption (CIA) due to CH$_4-$N$_2$ pairs at temperatures between 70 and 400 K. Our analysis utilizes recently calculated high-level potential energy (PES) and induced dipole surfaces (IDS) [Finenko, A. A., Chistikov, D. N., Kalugina, Y. N., Conway E. K., Gordon, I. E., Phys. Chem. Chem. Phys., 2021, doi: 10.1039/d1cp02161c]. Treating collision partners as rigid rotors, the time evolution of interaction-induced dipole is accumulated over a vast ensemble of classical trajectories and subsequently transformed into CIA spectrum via Fourier transform. In our calculations, both bound and unbound states are properly accounted for, and the rigorous theory of lower-order spectral moments is addressed to check the accuracy of simulated profiles. Classically derived trajectory-based profiles are subject to two approximate desymmetrization procedures so that resulting profiles conform to the quantum principle of detailed balance. The simulated profiles are compared to laboratory measurements and employed for modeling Titan's spectra in the 50-500 cm$^{-1}$ range. Based on the desymmetrized simulated profiles, a new semi-empirical model for CH$_4-$N$_2$ CIA is proposed for modeling Titan's infrared spectra. Synthetic spectra derived using this model yield an excellent agreement with the data recorded by the Composite Infrared Spectrometer (CIRS) aboard the Cassini spacecraft at low and high emission angles.

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Science goals and new mission concepts for future exploration of Titan's atmosphere geology and habitability: Titan POlar Scout/orbitEr and In situ lake lander and DrONe explorer (POSEIDON)

In response to ESA Voyage 2050 announcement of opportunity, we propose an ambitious L-class mission to explore one of the most exciting bodies in the Solar System, Saturn largest moon Titan. Titan, a "world with two oceans", is an organic-rich body with interior-surface-atmosphere interactions that are comparable in complexity to the Earth. Titan is also one of the few places in the Solar System with habitability potential. Titan remarkable nature was only partly revealed by the Cassini-Huygens mission and still holds mysteries requiring a complete exploration using a variety of vehicles and instruments. The proposed mission concept POSEIDON (Titan POlar Scout/orbitEr and In situ lake lander DrONe explorer) would perform joint orbital and in situ investigations of Titan. It is designed to build on and exceed the scope and scientific/technological accomplishments of Cassini-Huygens, exploring Titan in ways that were not previously possible, in particular through full close-up and in situ coverage over long periods of time. In the proposed mission architecture, POSEIDON consists of two major elements: a spacecraft with a large set of instruments that would orbit Titan, preferably in a low-eccentricity polar orbit, and a suite of in situ investigation components, i.e. a lake lander, a "heavy" drone (possibly amphibious) and/or a fleet of mini-drones, dedicated to the exploration of the polar regions. The ideal arrival time at Titan would be slightly before the next northern Spring equinox (2039), as equinoxes are the most active periods to monitor still largely unknown atmospheric and surface seasonal changes. The exploration of Titan northern latitudes with an orbiter and in situ element(s) would be highly complementary with the upcoming NASA New Frontiers Dragonfly mission that will provide in situ exploration of Titan equatorial regions in the mid-2030s.

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Formation and dynamics of water clouds on temperate sub-Neptunes: The example of K2-18b

Hubble (HST) spectroscopic transit observations of the temperate sub-Neptune K2-18b were interpreted as the presence of water vapour with potential water clouds. 1D modelling studies also predict the formation of water clouds at some conditions. However, such models cannot predict the cloud cover, driven by atmospheric dynamics and thermal contrasts, and thus their real impact on spectra. The main goal of this study is to understand the formation, distribution and observational consequences of water clouds on K2-18b and other temperate sub-Neptunes. We simulated the atmospheric dynamics, water cloud formation and spectra of K2-18b for H2-dominated atmosphere using a 3D GCM. We analysed the impact of atmospheric composition (with metallicity from 1*solar to 1000*solar), concentration of cloud condensation nuclei and planetary rotation rate. Assuming that K2-18b has a synchronous rotation, we show that the atmospheric circulation in the upper atmosphere essentially corresponds to a symmetric day-to-night circulation. This regime preferentially leads to cloud formation at the substellar point or at the terminator. Clouds form for metallicity >100*solar with relatively large particles. For 100-300*solar metallicity, the cloud fraction at the terminators is small with a limited impact on transit spectra. For 1000*solar metallicity, very thick clouds form at the terminator. The cloud distribution appears very sensitive to the concentration of CCN and to the planetary rotation rate. Fitting HST transit data with our simulated spectra suggests a metallicity of ~100-300*solar. In addition, we found that the cloud fraction at the terminator can be highly variable, leading to a potential variability in transit spectra. This effect could be common on cloudy exoplanets and could be detectable with multiple transit observations.

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1D atmospheric study of the temperate sub-Neptune K2-18b

The atmospheric composition of exoplanets with masses between 2 and 10 M$_\oplus$ is poorly understood. In that regard, the sub-Neptune K2-18b, which is subject to Earth-like stellar irradiation, offers a valuable opportunity for the characterisation of such atmospheres. Previous analyses of its transmission spectrum from the Kepler, Hubble (HST), and Spitzer space telescopes data using both retrieval algorithms and forward-modelling suggest the presence of H$_2$O and an H$_2$--He atmosphere, but have not detected other gases, such as CH$_4$. We present simulations of the atmosphere of K2-18 b using Exo-REM, our self-consistent 1D radiative-equilibrium model, using a large grid of atmospheric parameters to infer constraints on its chemical composition. We show that our simulations favour atmospheric metallicities between 40 and 500 times solar and indicate, in some cases, the formation of H$_2$O-ice clouds, but not liquid H$_2$O clouds. We also confirm the findings of our previous study, which showed that CH$_4$ absorption features nominally dominate the transmission spectrum in the HST spectral range. We compare our results with results from retrieval algorithms and find that the H$_2$O-dominated spectrum interpretation is either due to the omission of CH$_4$ absorptions or a strong overfitting of the data. Finally, we investigated different scenarios that would allow for a CH$_4$-depleted atmosphere. We were able to fit the data to those scenarios, finding, however, that it is very unlikely for K2-18b to have a high internal temperature. A low C/O ratio ($\approx$ 0.01--0.1) allows for H$_2$O to dominate the transmission spectrum and can fit the data but so far, this set-up lacks a physical explanation. Simulations with a C/O ratio $<$ 0.01 are not able to fit the data satisfactorily.

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Seasonal changes in the middle atmosphere of Titan from Cassini/CIRS observations: temperature and trace species abundance profiles from 2004 to 2017

The Cassini/Composite InfraRed Spectrometer (CIRS) instrument has been observing the middle atmosphere of Titan over almost half a Saturnian year. We used the CIRS dataset processed through the up-to-date calibration pipeline to characterize seasonal changes of temperature and abundance profiles in the middle atmosphere of Titan, from mid-northern winter to early northern summer all around the satellite. We used limb spectra from 590 to 1500 cm$^{-1}$ at 0.5-cm$^{-1}$ spectral resolution, which allows us to probe different altitudes. We averaged the limb spectra recorded during each flyby on a fixed altitude grid to increase the signal-to-noise ratio. These thermal infrared data were analyzed by means of a radiative transfer code coupled with an inversion algorithm, in order to retrieve vertical temperature and abundance profiles. These profiles cover an altitude range of approximately 100 to 600 km, at 10- or 40-km vertical resolution (depending on the observation). Strong changes in temperature and composition occur in both polar regions where a vortex is in place during the winter. At this season, we observe a global enrichment in photochemical compounds in the mesosphere and stratosphere and a hot stratopause located around 0.01 mbar, both linked to downwelling in a pole-to-pole circulation cell. After the northern spring equinox, between December 2009 and April 2010, a stronger enhancement of photochemical compounds occurred at the north pole above the 0.01-mbar region, likely due to combined photochemical and dynamical effects. During the southern autumn in 2015, above the South pole, we also observed a strong enrichment in photochemical compounds that contributed to the cooling of the stratosphere above 0.2 mbar. Close to the northern spring equinox, in December 2009, the thermal profile at 74°N exhibits an oscillation that we interpret in terms of an inertia-gravity wave.

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On the H$_2$ abundance and ortho-to-para ratio in Titan's troposphere

We have analyzed spectra recorded between 50 and 650 cm$^{-1}$ by the Composite Infrared Spectrometer (CIRS) aboard the Cassini spacecraft at low and high emission angles to determine simultaneously the H$_2$ mole fraction and ortho-to-para ratio in Titan's troposphere. We used constraints from limb spectra between 50 and 900 cm$^{-1}$ and from in situ measurements by the Huygens probe to characterize the temperature, haze and gaseous absorber profiles. We confirm that the N$_2$-CH$_4$ collision-induced absorption (CIA) coefficients used up to now need to be increased by about 52% at temperatures of 70-85 K. We find that the N$_2$-N$_2$ CIA coefficients are also too low in the N$_2$ band far wing, beyond 110 cm$^{-1}$, in agreement with recent quantum mechanical calculations. We derived a H$_2$ mole fraction equal to (0.88 $\pm$ 0.13) $\times$ 10$^{-3}$, which pertains to the $\sim$1-34 km altitude range probed by the S$_0$(0) and S$_0$(1) lines. The H$_2$ para fraction is close to equilibrium in the 20-km region. We have investigated different mechanisms that may operate in Titan's atmosphere to equilibrate the H$_2$ o-p ratio and we have developed a one-dimensional model that solves the continuity equation in presence of such conversion mechanisms. We conclude that exchange with H atoms in the gas phase or magnetic interaction of H$_2$ in a physisorbed state on the surface of aerosols are too slow compared with atmospheric mixing to play a significant role. On the other hand, magnetic interaction of H$_2$ with CH$_4$, and to a lesser extent N$_2$, can operate on a timescale similar to the vertical mixing time in the troposphere. This process is thus likely responsible for the o-p equilibration of H$_2$ in the mid-troposphere implied by CIRS measurements.

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Detection of Propadiene on Titan

The atmosphere of Titan, the largest moon of Saturn, is rich in organic molecules, and it has been suggested that the moon may serve as an analog for the pre-biotic Earth due to its highly reducing chemistry and existence of global hazes. Photochemical models of Titan have predicted the presence of propadiene (historically referred to as allene), CH$_{2}$CCH$_{2}$, an isomer of the well-measured propyne (also called methylacetylene) CH$_{3}$CCH, but its detection has remained elusive due to insufficient spectroscopic knowledge of the molecule - which has recently been remedied with an updated spectral line list. Here we present the first unambiguous detection of the molecule in any astronomical object, observed with the Texas Echelle Cross Echelle Spectrograph (TEXES) on the NASA Infrared Telescope Facility (IRTF) in July 2017. We model its emission line near 12 $μ$m and measure a volume mixing ratio (VMR) of (6.9 $\pm$ 0.8) $\times$10$^{-10}$ at 175 km, assuming a vertically increasing abundance profile as predicted in photochemical models. Cassini measurements of propyne made during April 2017 indicate that the abundance ratio of propyne to propadiene is 8.2$\pm$1.1 at the same altitude. This initial measurement of the molecule in Titan's stratosphere paves the way towards constraining the amount of atomic hydrogen available on Titan, as well as future mapping of propadiene on Titan from 8 meter and larger ground based observatories, and future detection on other planetary bodies.

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Probable detection of hydrogen sulphide (H$_2$S) in Neptune's atmosphere

Recent analysis of Gemini-North/NIFS H-band (1.45 - 1.8 $μ$m) observations of Uranus, recorded in 2010, with recently updated line data has revealed the spectral signature of hydrogen sulphide (H$_2$S) in Uranus's atmosphere (Irwin et al., 2018). Here, we extend this analysis to Gemini-North/NIFS observations of Neptune recorded in 2009 and find a similar detection of H$_2$S spectral absorption features in the 1.57 - 1.58 $μ$m range, albeit slightly less evident, and retrieve a mole fraction of $\sim1-3$ ppm at the cloud tops. We find a much clearer detection (and much higher retrieved column abundance above the clouds) at southern polar latitudes compared with equatorial latitudes, which suggests a higher relative humidity of H$_2$S here. We find our retrieved H$_2$S abundances are most consistent with atmospheric models that have reduced methane abundance near Neptune's south pole, consistent with HST/STIS determinations (Karkoschka and Tomasko, 2011). We also conducted a Principal Component Analysis (PCA) of the Neptune and Uranus data and found that in the 1.57 - 1.60 $μ$m range, some of the Empirical Orthogonal Functions (EOFs) mapped closely to physically significant quantities, with one being strongly correlated with the modelled H$_2$S signal and clearly mapping the spatial dependence of its spectral detectability. Just as for Uranus, the detection of H$_2$S at the cloud tops constrains the deep bulk sulphur/nitrogen abundance to exceed unity (i.e. $ > 4.4 - 5.0$ times the solar value) in Neptune's bulk atmosphere, provided that ammonia is not sequestered at great depths, and places a lower limit on its mole fraction below the observed cloud of (0.4 - 1.3) $\times 10^{-5}$. The detection of gaseous H$_2$S at these pressure levels adds to the weight of evidence that the principal constituent of the 2.5 - 3.5-bar cloud is likely to be H$_2$S ice.

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Mapping of Jupiter's tropospheric NH$_3$ abundance using ground-based IRTF/TEXES observations at 5 $μ$m

We report on results of an observing campaign to support the Juno mission. At the beginning of 2016, using TEXES (Texas Echelon cross-dispersed Echelle Spectrograph), mounted on the NASA Infrared Telescope Facility (IRTF), we obtained data cubes of Jupiter in the 1930--1943 cm$^{-1}$ spectral ranges (around 5 $μ$m), which probe the atmosphere in the 1--4 bar region, with a spectral resolution of $\approx$ 0.15 cm$^{-1}$ and an angular resolution of $\approx$ 1.4". This dataset is analysed by a code that combines a line-by-line radiative transfer model with a non-linear optimal estimation inversion method. The inversion retrieves the vertical abundance profiles of NH$_3$ - which is the main contributor at these wavelengths - with a maximum sensitivity at $\approx$ 1--3 bar, as well as the cloud transmittance. This retrieval is performed on over more than one thousand pixels of our data cubes, producing maps of the disk, where all the major belts are visible. We present our retrieved NH$_3$ abundance maps which can be compared with the distribution observed by Juno's MWR (Bolton et al., 2017; Li et al., 2017) in the 2 bar region and discuss their significance for the understanding of Jupiter's atmospheric dynamics. We are able to show important latitudinal variations - such as in the North Equatorial Belt (NEB), where the NH$_3$ abundance is observed to drop down to 60 ppmv at 2 bar - as well as longitudinal variability. In the zones, we find the NH$_3$ abundance to increase with depth, from 100 $\pm$ 15 ppmv at 1 bar to 500 $\pm$ 30 ppmv at 3 bar. We also display the cloud transmittance--NH$_3$ abundance relationship, and find different behaviour for the NEB, the other belts and the zones. Using a simple cloud model, we are able to fit this relationship, at least in the NEB, including either NH$_3$-ice or NH$_4$SH particles with sizes between 10 and 100 $μ$m.

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Simultaneous, Multi-Wavelength Variability Characterization of the Free-Floating Planetary Mass Object PSO J318.5-22

We present simultaneous HST WFC3 + Spitzer IRAC variability monitoring for the highly-variable young ($\sim$20 Myr) planetary-mass object PSO J318.5-22. Our simultaneous HST + Spitzer observations covered $\sim$2 rotation periods with Spitzer and most of a rotation period with HST. We derive a period of 8.6$\pm$0.1 hours from the Spitzer lightcurve. Combining this period with the measured $v sin i$ for this object, we find an inclination of 56.2$\pm 8.1^{\circ}$. We measure peak-to-trough variability amplitudes of 3.4$\pm$0.1$\%$ for Spitzer Channel 2 and 4.4 - 5.8$\%$ (typical 68$\%$ confidence errors of $\sim$0.3$\%$) in the near-IR bands (1.07-1.67 $μ$m) covered by the WFC3 G141 prism -- the mid-IR variability amplitude for PSO J318.5-22 one of the highest variability amplitudes measured in the mid-IR for any brown dwarf or planetary mass object. Additionally, we detect phase offsets ranging from 200--210$^{\circ}$ (typical error of $\sim$4$^{\circ}$) between synthesized near-IR lightcurves and the Spitzer mid-IR lightcurve, likely indicating depth-dependent longitudinal atmospheric structure in this atmosphere. The detection of similar variability amplitudes in wide spectral bands relative to absorption features suggests that the driver of the variability may be inhomogeneous clouds (perhaps a patchy haze layer over thick clouds), as opposed to hot spots or compositional inhomogeneities at the top-of-atmosphere level.

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A self-consistent cloud model for brown dwarfs and young giant exoplanets: comparison with photometric and spectroscopic observations

We developed a simple, physical and self-consistent cloud model for brown dwarfs and young giant exoplanets. We compared different parametrisations for the cloud particle size, by either fixing particle radii, or fixing the mixing efficiency (parameter fsed) or estimating particle radii from simple microphysics. The cloud scheme with simple microphysics appears as the best parametrisation by successfully reproducing the observed photometry and spectra of brown dwarfs and young giant exoplanets. In particular, it reproduces the L-T transition, due to the condensation of silicate and iron clouds below the visible/near-IR photosphere. It also reproduces the reddening observed for low-gravity objects, due to an increase of cloud optical depth for low gravity. In addition, we found that the cloud greenhouse effect shifts chemical equilibriums, increasing the abundances of species stable at high temperature. This effect should significantly contribute to the strong variation of methane abundance at the L-T transition and to the methane depletion observed on young exoplanets. Finally, we predict the existence of a continuum of brown dwarfs and exoplanets for absolute J magnitude=15-18 and J-K color=0-3, due to the evolution of the L-T transition with gravity. This self-consistent model therefore provides a general framework to understand the effects of clouds and appears well-suited for atmospheric retrievals.

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A radiative-convective equilibrium model for young giant exoplanets: Application to beta Pictoris b

We present a radiative-convective equilibrium model for young giant exoplanets. Model predictions are compared with the existing photometric measurements of planet beta Pictoris b in the J, H, Ks, L', NB 4.05, M' bands . This model will be used to interpret future photometric and spectroscopic observations of exoplanets with SPHERE, mounted at the VLT with a first light expected mid-2014.

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Upper limits for undetected trace species in the stratosphere of Titan

In this paper we describe a first quantitative search for several molecules in Titan's stratosphere in Cassini CIRS infrared spectra. These are: ammonia (NH3), methanol (CH3OH), formaldehyde (H2CO), and acetonitrile (CH3CN), all of which are predicted by photochemical models but only the last of which observed, and not in the infrared. We find non-detections in all cases, but derive upper limits on the abundances from low-noise observations at 25°S and 75°N. Comparing these constraints to model predictions, we conclude that CIRS is highly unlikely to see NH3 or CH3OH emissions. However, CH3CN and H2CO are closer to CIRS detectability, and we suggest ways in which the sensitivity threshold may be lowered towards this goal.

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