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Bruno Neumann

Publications and source records attributed to Bruno Neumann.

3 recordsLinked to original sources

Thermoelastic Harvesting Outperforming Thermoelectric Generators Below 100 {\deg}C

Low-grade waste heat below 100 degC is one of the largest untapped opportunities in solid-state energy conversion. Three ferroic routes are candidates for recovering this resource: thermomagnetic, pyroelectric, and thermoelastic harvesters. The last has remained the most unexplored, despite decades of progress on the underlying NiTi shape-memory alloy wires. Three system-design changes close this gap: a protagonist-antagonist architecture that recovers the energy for prestraining, a continuously tunable prestrain mechanism that sets the force-strain balance, and transversal water flow that decouples cycle frequency from wire length. The resulting harvester delivers a directly measured power density of 366 mW/cm^3 with respect to the active material, about 1.7 times the next-best thermoelastic device, ahead of every reported thermomagnetic and pyroelectric generator, and outperforming the best thermoelectric generators in this temperature range also with respect to power per material cost. The system maps the parameter space directly through force and displacement measurements, without using material-property estimates, giving a quantitative picture of how the alloy responds while the device is doing work.

cond-mat.mtrl-sci

Understanding Energy Flow and Inefficiency of a Thermomagnetic Generator by Transient Multi-Physics Modelling

Waste heat recovery improves energy efficiency and reduces greenhouse gas emissions; however, much industrial and environmental heat is wasted at low temperature. Thermomagnetic recovery of waste heat has a high potential for sustainable production of electric energy, especially for low-grade waste heat where conventional technology is inefficient or infeasible. Of particular interest are thermomagnetic generators (TMG) as they require almost no mechanically moving parts, which is beneficial for high reliability. However, all existing prototypes have two remaining challenges: low efficiency and low cycle frequency. In this work, we develop a digital twin of a recent TMG with genus 3 by using multi-physics simulations. We identify shortcomings of previous simulation approaches, and describe why simulations in three dimensions are necessary, which consider coupling between magnetic, thermal, fluid flow, and electrical physics domains. We validate our model, which only uses known geometry and material parameters, by experimental data of the TMG with highest power density today, and attain 96% accuracy in open-circuit voltage and 95% accuracy in power output. This high accuracy allows us to identify the origin of both challenges for TMGs, which are not accessible by experiments. First, we uncover inefficiencies by analyzing the energy flow within a Sankey diagram. Second, we trace the transient heat flow through the generator, which identifies the factors limiting frequency. This paves the way for more efficient and faster TMGs, and their development will be accelerated by our validated digital twin.

physics.app-ph

Sub-nanosecond structural dynamics of the martensitic transformation in Ni-Mn-Ga

Martensitic transformations drive a multitude of emerging applications, which range from high stroke actuation and, mechanocaloric refrigeration, to thermoelastic energy harvesting. All these applications benefit from faster transformations, as a high cycle frequency is essential for achieving high power density. However, systematic investigations of the fast dynamics and fundamental speed limits of martensitic transformations are scarce. Especially for ultrashort time transformations, the temperature evolution throughout the transformation is not measured, which is a substantial shortcoming as temperature is the intrinsic force driving the transformation. Here, we present a synchrotron-based time-resolved X-ray diffraction study of a 270 fs laser-induced martensitic transformation in a Ni-Mn-Ga-based epitaxial thin film. We observe the transformation from martensite to austenite within about 100 ps, just limited by the synchrotron probe pulse duration. Furthermore, a full transformation cycle from martensite to austenite and back to martensite can almost be finished within 5 ns, which is the fastest martensitic transformation reported so far. Measurements and calculations of the temperature evolution allow us to analyse the influence of temperature on transformation time. By time-resolved strain measurements we demonstrate that in addition to temperature, thermal film stress must be considered as a competing influence on the martensitic transformation. Our experimental findings are supported by molecular dynamics simulations with machine learned force fields adapted to density functional theory calculations. These reveal that the huge distortion during a martensitic transformation requires the collective movement of many atoms within the microstructure, which delays the transformation.

cond-mat.mtrl-sci