arXiv subjects

C. -Y. Kuo

Publications and source records attributed to C. -Y. Kuo.

27 records · Page 2Linked to original sources

arXiv2017

Intricacies of the Co$^{3+}$ spin state in Sr$_2$Co$_{0.5}$Ir$_{0.5}$O$_4$: an x-ray absorption and magnetic circular dichroism study

We report on a combined soft x-ray absorption and magnetic circular dichroism (XMCD) study at the Co-$L_{3,2}$ on the hybrid 3$d$/5$d$ solid state oxide Sr$_2$Co$_{0.5}$Ir$_{0.5}$O$_4$ with the K$_2$NiF$_4$ structure. Our data indicate unambiguously a pure high spin state $(S=2)$ for the Co$^{3+}$ (3$d^6$) ions with a significant unquenched orbital moment $L_z/2S_z=0.25$ despite the sizeable elongation of the CoO$_6$ octahedra. Using quantitative model calculations based on parameters consistent with our spectra, we have investigated the stability of this high spin state with respect to the competing low spin and intermediate spin states.

cond-mat.str-el↗

arXiv2017

Electronically highly cubic conditions for Ru in alpha-RuCl3

We studied the local Ru 4d electronic structure of alpha-RuCl3 by means of polarization dependent x-ray absorption spectroscopy at the Ru-L2,3 edges. We observed a vanishingly small linear dichroism indicating that electronically the Ru 4d local symmetry is highly cubic. Using full multiplet cluster calculations we were able to reproduce the spectra excellently and to extract that the trigonal splitting of the t2g orbitals is -12 $\pm10$ meV, i.e. negligible as compared to the Ru 4d spin-orbit coupling constant. Consistent with our magnetic circular dichroism measurements, we found that the ratio of the orbital and spin moments is 2.0, the value expected for a Jeff = 1/2 ground state. We have thus shown that as far as the Ru 4d local properties are concerned, alpha-RuCl3 is an ideal candidate for the realization of Kitaev physics.

cond-mat.str-el↗

arXiv2016

Long-range interactions in the effective low energy Hamiltonian of Sr2IrO4: a core level resonant inelastic x-ray scattering study

We have investigated the electronic structure of Sr2IrO4 using core level resonant inelastic x-ray scattering. The experimental spectra can be well reproduced using ab initio density functional theory based multiplet ligand field theory calculations, thereby validating these calculations. We found that the low-energy, effective Ir t2g orbitals are practically degenerate in energy. We uncovered that covalency in Sr2IrO4, and generally in iridates, is very large with substantial oxygen ligand hole character in the Ir t2g Wannier orbitals. This has far reaching consequences, as not only the onsite crystal-field energies are determined by the long range crystal-structure, but, more significantly, magnetic exchange interactions will have long range distance dependent anisotropies in the spin direction. These findings set constraints and show pathways for the design of d^5 materials that can host compass-like magnetic interactions.

cond-mat.str-el↗

arXiv2015

Electronic and Spin States of SrRuO3 Thin Films: an X-ray Magnetic Circular Dichroism Study

We report a study of the local magnetism in thin films of SrRuO3 grown on (111) and (001) oriented SrTiO3 substrates using x-ray magnetic circular dichroism spectroscopy (XMCD) at the Ru-L2,3 edges. The application of the sum rules to the XMCD data gives an almost quenched orbital moment and a spin moment close to the value expected for the low spin state S = 1 . Full-multiplet cluster calculations indicate that the low spin state is quite stable and suggest that the occurrence of a transition to the high spin state S = 2 in strained thin films of SrRuO3 is unlikely as it would be too expensive in energy.

cond-mat.str-el↗

arXiv2014

k=0 magnetic structure and absence of ferroelectricity in SmFeO3

SmFeO3 has attracted considerable attention very recently due to the reported multiferroic properties above room-temperature. We have performed powder and single crystal neutron diffraction as well as complementary polarization dependent soft X-ray absorption spectroscopy measurements on floating-zone grown SmFeO3 single crystals in order to determine its magnetic structure. We found a k=0 G-type collinear antiferromagnetic structure that is not compatible with inverse Dzyaloshinskii-Moriya interaction driven ferroelectricity. While the structural data reveals a clear sign for magneto-elastic coupling at the Néel-temperature of ~675 K, the dielectric measurements remain silent as far as ferroelectricity is concerned.

cond-mat.str-el↗

arXiv2014

Greenland Telescope Project --- Direct Confirmation of Black Hole with Sub-millimeter VLBI

A 12-m diameter radio telescope will be deployed to the Summit Station in Greenland to provide direct confirmation of a Super Massive Black Hole (SMBH) by observing its shadow image in the active galaxy M87. The telescope (Greenland Telescope: GLT) is to become one of the Very Long Baseline Interferometry (VLBI) stations at sub-millimeter (submm) regime, providing the longest baseline > 9,000 km to achieve an exceptional angular resolution of 20 micro arc sec at 350 GHz, which will enable us to resolve the shadow size of ~40 micro arc sec. The triangle with the longest baselines formed by the GLT, the Atacama Large Millimeter/submillimeter Array (ALMA) in Chile, and the Submillimeter Array (SMA) in Hawaii will play a key role for the M87 observations. We have been working on the image simulations based on realistic conditions for a better understanding of the possible observed images. In parallel, retrofitting of the telescope and the site developments are in progress. Based on three years of opacity monitoring at 225 GHz, our measurements indicate that the site is excellent for submm observations, comparable to the ALMA site. The GLT is also expected to make single-dish observations up to 1.5 THz.

astro-ph.IM↗

arXiv2013

Greenland Telescope (GLT) Project: "A Direct Confirmation of Black Hole with Submillimeter VLBI"

The GLT project is deploying a new submillimeter (submm) VLBI station in Greenland. Our primary scientific goal is to image a shadow of the supermassive black hole (SMBH) of six billion solar masses in M87 at the center of the Virgo cluster of galaxies. The expected SMBH shadow size of 40-50 $μ$as requires superbly high angular resolution, suggesting that the submm VLBI would be the only way to obtain the shadow image. The Summit station in Greenland enables us to establish baselines longer than 9,000 km with ALMA in Chile and SMA in Hawaii as well as providing a unique $u$--$v$ coverage for imaging M87. Our VLBI network will achieve a superior angular resolution of about 20 $μ$as at 350 GHz, corresponding to $\sim2.5$ times of the Schwarzschild radius of the supermassive black hole in M87. We have been monitoring the atmospheric opacity at 230 GHz since August. 2011; we have confirmed the value on site during the winter season is comparable to the ALMA site thanks to high altitude of 3,200 m and low temperature of $-50\degr$C. We will report current status and future plan of the GLT project towards our expected first light on 2015--2016.

astro-ph.IM↗

arXiv2013

Spectroscopic evidence for giant orbital moment and magnetic anisotropy induced by local distortions in alpha-CoV2O6

We present a combined experimental and theoretical study on the local magnetism of the Co ions in the spin-chain compound CoV2O6, which crystallizes in two different allotropic phases, alpha- and gamma-CoV2O6. Using x-ray magnetic circular dichroism, we have found a very large and a moderate orbital contribution to the magnetism in alpha- and gamma-CoV2O6, respectively. Full-multiplet calculations indicate that the differences in the magnetic behavior of alpha- and gamma-CoV2O6 phases originate from different local distortions of the CoO6 octahedra. In particular, the strong compression of the CoO6 octahedra in alpha-CoV2O6 lead to a strong mixture of t2g and eg orbitals which, via the local atomic Coulomb and exchange interactions, results in an exceptionally large orbital moment.

cond-mat.str-el↗

arXiv2004

SMA CO(J=3-2) interferometric observations of the central region of M51

We present the first interferometric CO(J=3-2) observations (beam size of 3.9"x1.6" or 160pc x 65pc) with the Submillimeter Array (SMA) toward the center of the Seyfert 2 galaxy M51. The image shows a strong concentration at the nucleus and weak emission from the spiral arm to the northwest. The integrated intensity of the central component in CO(J=3-2) is almost twice as high as that in CO(J=1-0), indicating that the molecular gas within an ~80 pc radius of the nucleus is warm (>~100 K) and dense (~10^4 cm^-3). Similar intensity ratios are seen in shocked regions in our Galaxy, suggesting that these gas properties may be related to AGN or starburst activity. The central component shows a linear velocity gradient (~1.4 km/s/pc) perpendicular to the radio continuum jet, similar to that seen in previous observations and interpreted as a circumnuclear molecular disk/torus around the Seyfert 2 nucleus. In addition, we identify a linear velocity gradient (~0.7 km/s/pc) along the jet. Judging from the energetics, the velocity gradient can be explained by supernova explosions or energy and momentum transfer from the jet to the molecular gas via interaction, which is consistent with the high intensity ratio.

astro-ph↗