arXiv subjects

C. A. Murray

Publications and source records attributed to C. A. Murray.

22 records · Page 2Linked to original sources

arXiv2020

Photometry and Performance of SPECULOOS-South

SPECULOOS-South, an observatory composed of four independent 1m robotic telescopes, located at ESO Paranal, Chile, started scientific operation in January 2019. This Southern Hemisphere facility operates as part of SPECULOOS, an international network of 1m-class telescopes surveying for transiting terrestrial planets around the nearest and brightest ultra-cool dwarfs. To automatically and efficiently process the observations of SPECULOOS-South, and to deal with the specialised photometric requirements of ultra-cool dwarf targets, we present our automatic pipeline. This pipeline includes an algorithm for automated differential photometry and an extensive correction technique for the effects of telluric water vapour, using ground measurements of the precipitable water vapour. Observing very red targets in the near-infrared can result in photometric systematics in the differential lightcurves, related to the temporally-varying, wavelength-dependent opacity of the Earth's atmosphere. These systematics are sufficient to affect the daily quality of the lightcurves, the longer time-scale variability study of our targets and even mimic transit-like signals. Here we present the implementation and impact of our water vapour correction method. Using the 179 nights and 98 targets observed in the I+z' filter by SPECULOOS-South since January 2019, we show the impressive photometric performance of the facility (with a median precision of ~1.5 mmag for 30-min binning of the raw, non-detrended lightcurves) and assess its detection potential. We compare simultaneous observations with SPECULOOS-South and TESS, to show that we readily achieve high-precision, space-level photometry for bright, ultra-cool dwarfs, highlighting SPECULOOS-South as the first facility of its kind.

astro-ph.EP↗

arXiv2017

Properties of CO$_2$ clathrate hydrates formed in the presence of MgSO$_4$ solutions with implications for icy moons

There is evidence to suggest that clathrate hydrates have a significant effect on the surface geology of icy bodies in the Solar System. However the aqueous environments believed to be present on these bodies are likely to be saline rather than pure water. Laboratory work to underpin the properties of clathrates in such environments is lacking. We fill this gap by carrying out a laboratory investigation of the physical properties of CO$_2$ clathrates produced in weak aqueous solutions of MgSO$_4$. We use synchrotron X-ray powder diffraction to investigate clathrates formed at high CO$_2$ pressure in ice that has formed from aqueous solutions of MgSO$_4$. We measure the thermal expansion, density and dissociation properties of the clathrates under temperature conditions similar to those on icy Solar System bodies. We find that the sulphate solution inhibits the formation of clathrates by lowering their dissociation temperatures. Hysteresis is found in the thermal expansion coefficients as clathrates are cooled and heated; we attribute this to the presence of the salt in solution. The density derived from X-ray powder diffraction is temperature and pressure dependent. When comparing the density of CO$_2$ clathrates to that of the solution in which they formed, we conclude that they sink in the oceans in which they form. We also find that the polymorph of ice present at low temperatures is Ih rather than Ic, which we attribute to the presence of the MgSO$_4$. We 1) conclude that the clathrate density has implications for their behaviour in satellite oceans as their sinking and floating capabilities are temperature and pressure dependent, 2) conclude that the presence of MgSO$_4$ inhibits the formation of clathrates and in some cases may even affect their structure and 3) report the dominance of Ih throughout the experimental procedure despite Ic being the stable phase at low temperature.

astro-ph.EP↗

arXiv2016

Spontaneous structural distortion of metallic Shastry-Sutherland system DyB4 by quadrupole-spin-lattice coupling

DyB4 has a two-dimensional Shastry-Sutherland (Sh-S) lattice with strong Ising character of the Dy ions. Despite the intrinsic frustrations, surprisingly, it undergoes two successive transitions: a magnetic ordering at TN = 20K, and a quadrupole ordering at TQ=12.5 K. From high-resolution neutron and synchrotron X-ray powder diffraction studies, we have obtained full structural information on this material in all phases, and demonstrate that structural modifications occurring at quadrupolar transition lead to the lifting of frustrations inherent in the Sh-S model. Our study thus provides a complete experimental picture of how the intrinsic frustration of the Sh-S lattice can be lifted by the coupling to quadrupole moments. We show that two other factors, i.e. strong spin-orbit coupling and long-range RKKY interaction in metallic DyB4, play an important role in this behavior.

cond-mat.str-el↗

arXiv2008

Metal-Insulator Transition and Orbital Order in PbRuO3

Anomalous low temperature electronic and structural behaviour has been discovered in PbRuO3. The structure (space group Pnma, a = 5.56314(1), b = 7.86468(1), c = 5.61430(1) A) and metallic conductivity at 290 K are similar to those of SrRuO3 and other ruthenate perovskites, but a sharp metal-insulator transition at which the resistivity increases by four orders of magnitude is discovered at 90 K. This is accompanied by a first order structural transition to an Imma phase (a = 5.56962(1), b = 7.74550(1), c = 5.66208(1) A at 25 K) that shows a coupling of Ru4+ 4d orbital order to distortions from Pb2+ 6s6p orbital hybridization. The Pnma to Imma transition is an unconventional reversal of the group-subgroup symmetry relationship. No long range magnetic order is evident down to 1.5 K. Electronic structure calculations show that hybridization of Pb 6s6p and Ru 4d orbitals and strong spin-orbit coupling stabilise this previously hidden ground state for ruthenate perovskites

cond-mat.str-el↗