arXiv subjects

C. A. Stafford

Publications and source records attributed to C. A. Stafford.

At least 37 records · Page 2Linked to original sources

arXiv2006

Stability and Symmetry Breaking in Metal Nanowires

A general linear stability analysis of simple metal nanowires is presented using a continuum approach which correctly accounts for material-specific surface properties and electronic quantum-size effects. The competition between surface tension and electron-shell effects leads to a complex landscape of stable structures as a function of diameter, cross section, and temperature. By considering arbitrary symmetry-breaking deformations, it is shown that the cylinder is the only generically stable structure. Nevertheless, a plethora of structures with broken axial symmetry is found at low conductance values, including wires with quadrupolar, hexapolar and octupolar cross sections. These non-integrable shapes are compared to previous results on elliptical cross sections, and their material-dependent relative stability is discussed.

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arXiv2006

Comment on "Nonlinear current-voltage curves of gold quantum point contacts" [Appl. Phys. Lett. 87, 103104 (2005)]

In a recent Letter [Appl. Phys. Lett. 87, 103104 (2005)], Yoshida et al. report that nonlinearities in current-voltage curves of gold quantum point contacts occur as a result of a shortening of the distance between electrodes at finite bias, presumably due to thermal expansion. For short wires, the electrode displacement induces a thickening of the wire, as well as nonlinearities of the IV curve, while the radius of long wires is left unchanged, thus resulting in a linear IV curve. We argue here that electron shell effects, which favor wires with certain "magic radii," prevent the thickening of long wires under compression, but have little effect on wires below a critical length.

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arXiv2005

Exactly Solvable Model for the Decay of Superdeformed Nuclei

The history and importance of superdeformation in nuclei is briefly discussed. A simple two-level model is then employed to obtain an elegant expression for the branching ratio for the decay via the E1 process in the normal-deformed band of superdeformed nuclei. From this expression, the spreading width Gamma^downarrow for superdeformed decay is found to be determined completely by experimentally known quantities. The accuracy of the two-level approximation is verified by considering the effects of other normal-deformed states. Furthermore, by using a statistical model of the energy levels in the normal-deformed well, we can obtain a probabilistic expression for the tunneling matrix element V.

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arXiv2005

Controlling quantum transport through a single molecule

We investigate multi-terminal quantum transport through single monocyclic aromatic annulene molecules, and their derivatives, using the nonequilibrium Green function approach in the self-consistent Hartree-Fock approximation. A new device concept, the Quantum Interference Effect Transistor (QuIET) is proposed, exploiting perfect destructive interference stemming from molecular symmetry, and controlling current flow by introducing decoherence and/or elastic scattering that break the symmetry. This approach overcomes the fundamental problems of power dissipation and environmental sensitivity that beset many nanoscale device proposals.

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arXiv2005

Stability of Metal Nanowires at Ultrahigh Current Densities

We develop a generalized grand canonical potential for the ballistic nonequilibrium electron distribution in a metal nanowire with a finite applied bias voltage. Coulomb interactions are treated in the self-consistent Hartree approximation, in order to ensure gauge invariance. Using this formalism, we investigate the stability and cohesive properties of metallic nanocylinders at ultrahigh current densities. A linear stability analysis shows that metal nanowires with certain {\em magic conductance values} can support current densities up to 10^11 A/cm^2, which would vaporize a macroscopic piece of metal. This finding is consistent with experimental studies of gold nanowires. Interestingly, our analysis also reveals the existence of reentrant stability zones--geometries that are stable only under an applied bias.

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arXiv2005

Theory of metastability in simple metal nanowires

Thermally induced conductance jumps of metal nanowires are modeled using stochastic Ginzburg-Landau field theories. Changes in radius are predicted to occur via the nucleation of surface kinks at the wire ends, consistent with recent electron microscopy studies. The activation rate displays nontrivial dependence on nanowire length, and undergoes first- or second-order-like transitions as a function of length. The activation barriers of the most stable structures are predicted to be universal, i.e., independent of the radius of the wire, and proportional to the square root of the surface tension. The reduction of the activation barrier under strain is also determined.

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arXiv2005

On the Stability and Structural Dynamics of Metal Nanowires

This article presents a brief review of the nanoscale free-electron model, which provides a continuum description of metal nanostructures. It is argued that surface and quantum-size effects are the two dominant factors in the energetics of metal nanowires, and that much of the phenomenology of nanowire stability and structural dynamics can be understood based on the interplay of these two competing factors. A linear stability analysis reveals that metal nanocylinders with certain magic conductance values G=1, 3, 6, 12, 17, 23, 34, 42, 51, 67, 78, 96, ... times the conductance quantum are exceptionally stable. A nonlinear dynamical simulation of nanowire structural evolution reveals a universal equilibrium shape consisting of a magic cylinder suspended between unduloidal contacts. The lifetimes of these metastable structures are also computed.

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arXiv2005

The Quantum Interference Effect Transistor

We propose a new type of molecular transistor, the Quantum Interference Effect Transistor (QuIET), based on tunable current suppression due to quantum interference. We show that any aromatic hydrocarbon ring has two-lead configurations for which current at small voltages is suppressed by destructive interference. A transistor can be created by providing phase relaxation or decoherence at a site on the ring. We propose several molecules which could tunably introduce the necessary dephasing or decoherence, as well as a proof of principle using a scanning tunneling microscope tip. Within the self-consistent Hartree-Fock approximation, the QuIET is shown to have characteristics strikingly similar to those of conventional field effect and bipolar junction transistors.

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arXiv2004

Jahn-Teller Distortions and the Supershell Effect in Metal Nanowires

A stability analysis of metal nanowires shows that a Jahn-Teller deformation breaking cylindrical symmetry can be energetically favorable, leading to stable nanowires with elliptic cross sections. The sequence of stable cylindrical and elliptical nanowires allows for a consistent interpretation of experimental conductance histograms for alkali metals, including both the shell and supershell structures. It is predicted that for gold, elliptical nanowires are even more likely to form since their eccentricity is smaller than for alkali metals. The existence of certain metastable ``superdeformed'' nanowires is also predicted.

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arXiv2004

Electronic shell effects and the stability of alkali nanowires

Experimental conductance histograms for Na nanowires are analyzed in detail and compared to recent theoretical results on the stability of cylindrical and elliptical nanowires, using the free-electron model. We find a one-to-one correspondence between the peaks in the histograms and the most stable nanowire geometries, indicating that several of the commonly observed nanowires have elliptical cross sections.

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arXiv2004

Fluctuational Instabilities of Alkali and Noble Metal Nanowires

We introduce a continuum approach to studying the lifetimes of monovalent metal nanowires. By modelling the thermal fluctuations of cylindrical nanowires through the use of stochastic Ginzburg-Landau classical field theories, we construct a self-consistent approach to the fluctuation-induced `necking' of nanowires. Our theory provides quantitative estimates of the lifetimes for alkali metal nanowires in the conductance range 10 < G/G_0 < 100 (where G_0=2e^2/h is the conductance quantum), and allows us to account for qualitative differences in the conductance histograms of alkali vs. noble metal nanowires.

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arXiv2003

Surface Fluctuations and the Stability of Metal Nanowires

The surface dynamics and thermodynamics of metal nanowires are investigated in a continuum model. Competition between surface tension and electron-shell effects leads to a rich stability diagram, with fingers of stability extending to extremely high temperatures for certain magic conductance values. The linearized dynamics of the nanowire's surface are investigated, including both acoustic surface phonons and surface self-diffusion of atoms. On the stability boundary, the surface exhibits critical fluctuations, and the nanowire becomes inhomogeneous. Some stability fingers coalesce at higher temperatures, or exhibit overhangs, leading to reentrant behavior. The nonlinear surface dynamics of unstable nanowires are also investigated in a single-mode approximation. We find evidence that some unstable nanowires do not break, but rather neck down to the next stable radius.

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arXiv2003

Quantum Necking in Stressed Metallic Nanowires

When a macroscopic metallic wire is subject to tensile stress, it necks down smoothly as it elongates. We show that nanowires with radii comparable to the Fermi wavelength display remarkably different behavior. Using concepts from fluid dynamics, a PDE for nanowire shape evolution is derived from a semiclassical energy functional that includes electron-shell effects. A rich dynamics involving movement and interaction of kinks connecting locally stable radii is found, and a new class of universal equilibrium shapes is predicted.

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arXiv2003

How to measure the spreading width for decay of superdeformed nuclei

A new expression for the branching ratio for the decay via the E1 process in the normal-deformed band of superdeformed nuclei is given within a simple two-level model. Using this expression, the spreading or tunneling width Gamma^downarrow for superdeformed decay can be expressed entirely in terms of experimentally known quantities. We show how to determine the tunneling matrix element V from the measured value of Gamma^downarrow and a statistical model of the energy levels. The accuracy of the two-level approximation is verified by considering the effects of the other normal-deformed states.

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arXiv2002

Coherence and Decoherence in Tunneling between Quantum Dots

Coupled quantum dots are an example of the ubiquitous quantum double potential well. In a typical transport experiment, each quantum dot is also coupled to a continuum of states. Our approach takes this into account by using a Green's function formalism to solve the full system. The time-dependent solution is then explored in different limiting cases. In general, a combination of coherent and incoherent behavior is observed. In the case that the coupling of each dot to the macroscopic world is equal, however, the time evolution is purely coherent.

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arXiv2002

Cohesion and Stability of Metal Nanowires: A Quantum Chaos Approach

A remarkably quantitative understanding of the electrical and mechanical properties of metal wires with a thickness on the scale of a nanometer has been obtained within the free-electron model using semiclassical techniques. Convergent trace formulas for the density of states and cohesive force of a narrow constriction in an electron gas, whose classical motion is either chaotic or integrable, are derived. Mode quantization in a metallic point contact or nanowire leads to universal oscillations in its cohesive force, whose amplitude depends only on a dimensionless quantum parameter describing the crossover from chaotic to integrable motion, and is of order 1nN, in agreement with experiments on gold nanowires. A linear stability analysis shows that the classical instability of a long wire under surface tension can be completely suppressed by quantum effects, leading to stable cylindrical configurations whose electrical conductance is a magic number 1, 3, 5, 6,... times the conductance quantum, in accord with recent results on alkali metal nanowires.

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arXiv2002

Metal Nanowires: Quantum Transport, Cohesion, and Stability

Metal nanowires exhibit a number of interesting properties: their electrical conductance is quantized, their shot-noise is suppressed by the Pauli principle, and they are remarkably strong and stable. We show that many of these properties can be understood quantitatively using a nanoscale generalization of the free-electron model. Possible technological applications of nanowires are also discussed.

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arXiv2001

Kondo Resonance in a Mesoscopic Ring Coupled to a Quantum Dot: Exact Results for the Aharonov-Bohm/Casher Effects

We study the persistent currents induced by both the Aharonov-Bohm and Aharonov-Casher effects in a one-dimensional mesoscopic ring coupled to a side-branch quantum dot at Kondo resonance. For privileged values of the Aharonov-Bohm-Casher fluxes, the problem can be mapped onto an integrable model, exactly solvable by a Bethe ansatz. In the case of a pure magnetic Aharonov-Bohm flux, we find that the presence of the quantum dot has no effect on the persistent current. In contrast, the Kondo resonance interferes with the spin-dependent Aharonov-Casher effect to induce a current which, in the strong-coupling limit, is independent of the number of electrons in the ring.

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