arXiv subjects

C. Arnold

Publications and source records attributed to C. Arnold.

7 recordsLinked to original sources

arXiv2023

Photon correlations in the collective emission of hybrid gold-(CdSe/CdS/CdZnS) nanocrystal supraparticles

We investigate the photon statistics of the light emitted by single self-assembled hybrid gold-CdSe/CdS/CdZnS colloidal nanocrystal supraparticles through the detailed analysis of the intensity autocorrelation function $g^{(2)}(\tau)$. We first reveal that, despite the large number of nanocrystals involved in the supraparticle emission, antibunching can be observed. We then present a model based on non-coherent F\"orster energy transfer and Auger recombination that well captures photon antibunching. Finally, we demonstrate that some supraparticles exhibit a bunching effect at short time scales corresponding to coherent collective emission.

cond-mat.mes-hall↗

arXiv2023

Chromatic aberrations correction of attosecond high-order harmonic beams by flat-top spatial shaping of the fundamental beam

Attosecond pulses created by high-order harmonic generation in gases often exhibit strong chromatic aberrations, arising from the broad bandwidth and wavelength-dependent nonlinear light-matter interaction. When the driving laser intensity varies spatially, as for Gaussian driving beams, the apparent source position of the harmonics differs significantly from one order to the next, thus affecting the achievable intensity and duration of the attosecond pulses when they are focused on a target. We show that these chromatic aberrations can be reduced by spatially shaping the fundamental beam to generate high-order harmonics with a driver having a flat-top profile inside the gas medium. By measuring both the intensity profile and wavefront for each harmonic in a plane, we access the extreme ultra-violet (XUV) beam properties and investigate these properties near focus. We observe that controlling chromatic aberrations by flat-top spatial shaping strongly reduces the variation of the XUV spectrum on the beam axis during propagation and, in return, the longitudinal sensitivity of both the temporal profiles and the temporal shifts of the focused attosecond pulses.

physics.optics↗

arXiv2022

Euclid: Modelling massive neutrinos in cosmology -- a code comparison

The measurement of the absolute neutrino mass scale from cosmological large-scale clustering data is one of the key science goals of the Euclid mission. Such a measurement relies on precise modelling of the impact of neutrinos on structure formation, which can be studied with $N$-body simulations. Here we present the results from a major code comparison effort to establish the maturity and reliability of numerical methods for treating massive neutrinos. The comparison includes eleven full $N$-body implementations (not all of them independent), two $N$-body schemes with approximate time integration, and four additional codes that directly predict or emulate the matter power spectrum. Using a common set of initial data we quantify the relative agreement on the nonlinear power spectrum of cold dark matter and baryons and, for the $N$-body codes, also the relative agreement on the bispectrum, halo mass function, and halo bias. We find that the different numerical implementations produce fully consistent results. We can therefore be confident that we can model the impact of massive neutrinos at the sub-percent level in the most common summary statistics. We also provide a code validation pipeline for future reference.

astro-ph.CO↗

arXiv2022

Fluorescence decay enhancement and FRET inhibition in self-assembled hybrid gold CdSe/CdS/CdZnS colloidal nanocrystals supraparticles

We report on the synthesis of hybrid light emitting particles with a diameter ranging between 100 and 500 nm, consisting in a compact semiconductor CdSe/CdS/CdZnS nanocrystal aggregate encapsulated by a controlled nanometric size silica and gold layers. We first characterize the Purcell decay rate enhancement corresponding to the addition of the gold nanoshell as a function of the particle size and find a good agreement with the predictions of numerical simulations. Then, we show that the contribution corresponding to F\"orster resonance energy transfer is inhibited.

cond-mat.mes-hall↗

arXiv2020

RIXS Reveals Hidden Local Transitions of the Aqueous OH Radical

Resonant inelastic x-ray scattering (RIXS) provides remarkable opportunities to interrogate ultrafast dynamics in liquids. Here we use RIXS to study the fundamentally and practically important hydroxyl radical in liquid water, OH(aq). Impulsive ionization of pure liquid water produced a short-lived population of OH(aq), which was probed using femtosecond x-rays from an x-ray free-electron laser. We find that RIXS reveals localized electronic transitions that are masked in the ultraviolet absorption spectrum by strong charge-transfer transitions -- thus providing a means to investigate the evolving electronic structure and reactivity of the hydroxyl radical in aqueous and heterogeneous environments. First-principles calculations provide interpretation of the main spectral features.

physics.chem-ph↗

arXiv2017

Once in a blue moon: detection of 'bluing' during debris transits in the white dwarf WD1145+017

The first transiting planetesimal orbiting a white dwarf was recently detected in K2 data of WD1145+017 and has been followed up intensively. The multiple, long, and variable transits suggest the transiting objects are dust clouds, probably produced by a disintegrating asteroid. In addition, the system contains circumstellar gas, evident by broad absorption lines, mostly in the u'-band, and a dust disc, indicated by an infrared excess. Here we present the first detection of a change in colour of WD1145+017 during transits, using simultaneous multi-band fast-photometry ULTRACAM measurements over the u'g'r'i'-bands. The observations reveal what appears to be 'bluing' during transits; transits are deeper in the redder bands, with a u'-r' colour difference of up to ~-0.05 mag. We explore various possible explanations for the bluing. 'Spectral' photometry obtained by integrating over bandpasses in the spectroscopic data in- and out-of-transit, compared to the photometric data, shows that the observed colour difference is most likely the result of reduced circumstellar absorption in the spectrum during transits. This indicates that the transiting objects and the gas share the same line-of-sight, and that the gas covers the white dwarf only partially, as would be expected if the gas, the transiting debris, and the dust emitting the infrared excess, are part of the same general disc structure (although possibly at different radii). In addition, we present the results of a week-long monitoring campaign of the system.

astro-ph.EP↗

arXiv2015

Storage and retrieval of vector beams of light in a multiple-degree-of-freedom quantum memory

The full structuration of light in the transverse plane, including intensity, phase and polarization, holds the promise of unprecedented capabilities for applications in classical optics as well as in quantum optics and information sciences. Harnessing special topologies can lead to enhanced focusing, data multiplexing or advanced sensing and metrology. Here we experimentally demonstrate the storage of such spatio-polarization-patterned beams into an optical memory. A set of vectorial vortex modes is generated via liquid crystal cell with topological charge in the optic axis distribution, and preservation of the phase and polarization singularities is demonstrated after retrieval, at the single-photon level. The realized multiple-degree-of-freedom memory can find applications in classical data processing but also in quantum network scenarios where structured states have been shown to provide promising attributes, such as rotational invariance.

quant-ph↗