arXiv subjects

C. Bertram

Publications and source records attributed to C. Bertram.

2 recordsLinked to original sources

arXiv2021

The ambivalent competition of Coulomb and van-der-Waals interactions in Xe-Cs+ aggregates on Cu(111) surfaces

Microscopic insight into interactions is a key for understanding the properties of heterogenous interfaces. We analyze local attraction in non-covalently bonded Xe{Cs+ aggregates and monolayers on Cu(111) as well as repulsion upon electron transfer. Using two-photon photoemission spectroscopy, scanning tunneling microscopy, and coupled cluster calculations combined with an image-charge model we explain the intricate impact Xe has on Cs+/Cu(111). We find that attraction between Cs+ and Xe counterbalances the screened Coulomb repulsion between Cs+ ions on Cu(111). Furthermore, we observe that the Cs 6s electron is repelled from Cu(111) due to xenon's electron density. Together, this yields a dual, i.e., attractive or repulsive, response of Xe depending on the positive or negative charge of the respective counterparticle, which emphasizes the importance of the Coulomb interaction in these systems.

cond-mat.mes-hall↗

arXiv2016

How Atomic Steps Modify Diffusion and Inter-adsorbate Forces: Empirical Evidence From Hopping Dynamics in Na/Cu(115)

We followed the collective atomic-scale motion of Na atoms on a vicinal Cu(115) surface within a time scale of pico to nano-seconds using helium spin echo spectroscopy. The well defined stepped structure of Cu(115) allows us to study the effect that atomic steps have on the adsorption properties, the rate for motion parallel and perpendicular to the step edge and the interaction between the Na atoms. With the support of a molecular dynamics simulation we show that the Na atoms perform strongly anisotropic one dimensional hopping motion parallel to the step edges. Furthermore, we observe that the spatial and temporal correlations between the Na atoms which lead to collective motion are also anisotropic, suggesting the steps efficiently screen the lateral interaction between Na atoms residing on different terraces.

cond-mat.mtrl-sci↗