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C. Buchbender

Publications and source records attributed to C. Buchbender.

At least 19 recordsLinked to original sources

Molecular cloud dispersal traced by the ionized carbon 158 micron line

Feedback from massive stars in the form of radiation and winds impacts the associated host molecular cloud. Feedback can disperse cloud material and lead to the destruction of the cloud. Recent observations of the ionized carbon CII 158 micron line in high-mass star-forming regions have demonstrated that this line is an excellent tracer of the gas dynamics in such environments. Expanding CII shells have been detected, along with high-velocity gas escaping the natal cloud through low-density channels. Motivated by these results, we conducted a systematic analysis of spectrally resolved CII maps obtained with SOFIA towards ten high-mass star-forming regions hosting at least one O-type star. Across all regions, we identify high-velocity CII line wings with velocities that exceed the cloud escape velocity, indicating that this gas is not gravitationally confined. We show that the high-velocity gas exhibits a complex velocity structure and cannot be attributed solely to a single, coherent expanding CII bubble. The amount of material in these erosion flows depends on the evolutionary stage of the molecular cloud and its associated HII region. Once the initial bubble around the cluster ruptures, typically after 0.1 Myr, gas is expelled from the cloud. The resulting cloud erosion timescales based on these directly observed mass ejection rates typically vary between 2 and 10 Myr after the formation of the first O stars, similar to other indirect measures of molecular cloud life times. These results suggest that stellar feedback is able to remove enough molecular gas to terminate the star formation in the host cloud.

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The SOFIA FEEDBACK Legacy Survey: Rapid molecular cloud dispersal in RCW 79

It has long been discussed whether stellar feedback in the form of winds and/or radiation can shred the nascent molecular cloud, thereby controlling the star formation rate. However, directly probing and quantifying the impact of stellar feedback on the neutral gas of the nascent clouds is challenging. We present an investigation doing exactly that toward the RCW 79 HII region using the ionized carbon line at 158 $\mu$m ([CII]) from the FEEDBACK Legacy Survey. We combine this data with information on the dozen ionizing O stars responsible for the evolution of the region, and observe in [CII] for the first time both blue- and red-shifted mostly neutral high-velocity gas which reaches velocities up to 25 km s$^{-1}$ relative to the bulk emission of the molecular cloud. This high-velocity gas mostly contains neutral gas and partly forms a fragmented shell, similar to recently found shells in a few Galactic HII regions. However, this shell does not account for all of the observed neutral high-velocity gas. We also find high-velocity gas streaming out of the nascent cloud through holes and obtain a range of dynamical timescales below 1.0 Myr for the high-velocity gas which is well below the 2.3$\pm$0.5 Myr age of the OB cluster. This suggests a different scenario for the evolution of RCW 79, where the high-velocity gas is not solely stemming from a spherical expanding bubble, but also from gas recently ablated at the edge of the turbulent molecular cloud into the surrounding interstellar medium through low-pressure holes or chimneys. The resulting mass ejection rate estimate for the cloud is 0.9-3.5$\times$10$^{-2}$ M$_{\odot}$~yr$^{-1}$, which leads to short erosion timescales, i.e. $<$5 Myr, for the nascent molecular cloud. This finding provides direct observational evidence of rapid molecular cloud dispersal.

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SOFIA FEEDBACK survey: PDR diagnostics of stellar feedback in different regions of RCW 49

We quantified the effects of stellar feedback in RCW 49 by determining the physical conditions in different regions using the [CII] 158 $\mu$m and [OI] 63 $\mu$m observations from SOFIA, the $^{12}$CO (3-2) observations from APEX and the H$_2$ line observations from Spitzer telescopes. Large maps of RCW 49 were observed with the SOFIA and APEX telescopes, while the Spitzer observations were only available towards three small areas. From our qualitative analysis, we found that the H$_2$ 0-0 S(2) emission line probes denser gas compared to the H$_2$ 0-0 S(1) line. In four regions ("northern cloud", "pillar", "ridge", and "shell"), we compared our observations with the updated PDR Toolbox models and derived the integrated far-ultraviolet flux between 6-13.6 eV ($G_{\rm 0}$), H nucleus density ($n$), temperatures and pressures. We found the ridge to have the highest $G_{\rm 0}$ (2.4 $\times$ 10$^3$ Habing units), while the northern cloud has the lowest $G_{\rm 0}$ (5 $\times$ 10$^2$ Habing units). This is a direct consequence of the location of these regions with respect to the Wd2 cluster. The ridge also has a high density (6.4 $\times$ 10$^3$ cm$^{-3}$), which is consistent with its ongoing star formation. Among the Spitzer positions, we found the one closest to the Wd2 cluster to be the densest, suggesting an early phase of star formation. Furthermore, the Spitzer position that overlaps with the shell was found to have the highest $G_{\rm 0}$ and we expect this to be a result of its proximity to an O9V star.

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The SOFIA FEEDBACK Legacy Survey: Dynamics and mass ejection in the bipolar HII region RCW 36

We present [CII] 158 $\mu$m and [OI] 63 $\mu$m observations of the bipolar HII region RCW 36 in the Vela C molecular cloud, obtained within the SOFIA legacy project FEEDBACK, which is complemented with APEX $^{12/13}$CO(3-2) and Chandra X-ray (0.5-7 keV) data. This shows that the molecular ring, forming the waist of the bipolar nebula, expands with a velocity of 1 - 1.9 km s$^{-1}$. We also observe an increased linewidth in the ring indicating that turbulence is driven by energy injection from the stellar feedback. The bipolar cavity hosts blue-shifted expanding [CII] shells at 5.2$\pm$0.5$\pm$0.5 km s$^{-1}$ (statistical and systematic uncertainty) which indicates that expansion out of the dense gas happens non-uniformly and that the observed bipolar phase might be relatively short ($\sim$0.2 Myr). The X-ray observations show diffuse emission that traces a hot plasma, created by stellar winds, in and around RCW 36. At least 50 \% of the stellar wind energy is missing in RCW 36. This is likely due to leakage which is clearing even larger cavities around the bipolar RCW 36 region. Lastly, the cavities host high-velocity wings in [CII] which indicates relatively high mass ejection rates ($\sim$5$\times$10$^{-4}$ M$_{\odot}$ yr$^{-1}$). This could be driven by stellar winds and/or radiation pressure, but remains difficult to constrain. This local mass ejection, which can remove all mass within 1 pc of RCW 36 in 1-2 Myr, and the large-scale clearing of ambient gas in the Vela C cloud indicates that stellar feedback plays a significant role in suppressing the star formation efficiency (SFE).

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FEEDBACK from the NGC7538 HII region

Context: How do expanding HII regions interact with their environmental cloud? This is one of the central questions driving the SOFIA legacy program FEEDBACK. Here, we present a case study toward the prototypical H{\sc ii} region NGC7538. Methods: With SOFIA we mapped an area of ~210'^2 around NGC7538 in the [CII] line at 1.9THz. Complementary observed atomic carbon [CI] and high-J CO(8-7) data as well as archival NIR/FIR, cm continuum, CO(3-2) and HI data are folded into the analysis. Results: While the overall [CII] morphology follows the general ionized gas, the channel maps show multiple bubble-like structures with sizes on the order of ~80-100" (~1.0-1.28pc). While at least one of them may be an individual feedback bubble driven by the main exciting sources of the region, the other bubble-morphologies may also be due to the intrinsically porous structure of the HII region. An analysis of the expansion velocities around 10km s^{-1} indicates that thermal expansion is not sufficient but that wind-driving from the central O-stars is required. The most blue-shifted [CII] component has barely any molecular or atomic counterparts. At the interface to the molecular cloud, we find a typical photon-dominated region (PDR) with a bar-shape. Ionized, atomic and molecular carbon show a layered structure in this PDR. The carbon in the PDR is dominated by its ionized form with atomic and molecular masses of ~0.45+-0.1M_{\odot} and ~1.2+-0.1M_{\odot}, respectively, compared to the ionized carbon in the range of 3.6-9.7M_{\odot}. Conclusions: The NGC7538 HII region exhibits a diverse set of sub-structures that interact with each other as well as with the adjacent cloud. Compared to other recent [CII] observations of HII regions (e.g., Orion Veil, RCW120, RCW49), bubble-shape morphologies revealed in [CII] emission, indicative of expanding shells, are recurring structures of PDRs.

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Self-absorption in [CII], $^{12}$CO, and HI in RCW120. Building up a geometrical and physical model of the region

Revealing the 3D dynamics of HII regions and their associated molecular clouds is important for understanding the longstanding problem as to how stellar feedback affects the density structure and kinematics of the interstellar medium. We employed observations of the HII region RCW 120 in [CII], observed within the SOFIA legacy program FEEDBACK, and the $^{12}$CO and $^{13}$CO (3$\to$2) lines, obtained with APEX. In addition we used HI data from the Southern Galactic Plane Survey. Two radiative transfer models were used to fit the observed data. A line profile analysis with the 1D non-LTE radiative transfer code SimLine proves that the CO emission cannot stem from a spherically symmetric molecular cloud configuration. With a two-layer multicomponent model, we then quantified the amount of warm background and cold foreground gas. There is a deficit of CO emission along the line-of-sight toward the center of the HII region which indicates that the HII region is associated with a flattened molecular cloud. Self-absorption in the CO line may hide signatures of infalling and expanding molecular gas. The [CII] emission arises from an expanding [CII] bubble and from the PDRs. A significant part of [CII] emission is absorbed in a cool (~60-100 K), low-density (<500 cm$^{-3}$) atomic foreground layer with a thickness of a few parsec. We propose that the RCW 120 HII region formed in a flattened molecular cloud and is now bursting out of its parental cloud. The compressed surrounding molecular layer formed a torus around the spherically expanding HII bubble. This scenario can possibly be generalized for other HII bubbles and would explain the observed "flat" structure of molecular clouds associated with HII bubbles. We suggest that the [CII] absorption observed in many star-forming regions is at least partly caused by low-density, cool, HI-envelopes surrounding the molecular clouds.

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Globules and pillars in Cygnus X III. Herschel and upGREAT/SOFIA far-infrared spectroscopy of the globule IRAS 20319+3958 inCygnus X

IRAS 20319+3958 in Cygnus X South is a rare example of a free-floating globule (mass ~240 Msun, length ~1.5 pc) with an internal HII region created by the stellar feedback of embedded intermediate-mass stars, in particular, one Herbig Be star. Here, we present a Herschel/HIFI CII 158 mu map of the whole globule and a large set of other FIR lines (mid-to high-J CO lines observed with Herschel/PACS and SPIRE, the OI 63 mu line and the CO 16-15 line observed with upGREAT on SOFIA), covering the globule head and partly a position in the tail. The CII map revealed that the whole globule is probably rotating. Highly collimated, high-velocity CII emission is detected close to the Herbig Be star. We performed a PDR analysis using the KOSMA-tau PDR code for one position in the head and one in the tail. The observed FIR lines in the head can be reproduced with a two-component model: an extended, non-clumpy outer PDR shell and a clumpy, dense, and thin inner PDR layer, representing the interface between the HII region cavity and the external PDR. The modelled internal UV field of ~2500 Go is similar to what we obtained from the Herschel FIR fluxes, but lower than what we estimated from the census of the embedded stars. External illumination from the ~30 pc distant Cyg OB2 cluster, producing an UV field of ~150-600 G0 as an upper limit, is responsible for most of the CII emission. For the tail, we modelled the emission with a non-clumpy component, exposed to a UV-field of around 140 Go.

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Observation and calibration strategies for large-scale multi-beam velocity-resolved mapping of the [CII] emission in the Orion molecular cloud

Context. The [CII] 158micron far-infrared fine-structure line is one of the dominant cooling lines of the star-forming interstellar medium (ISM). Hence [CII] emission originates in and thus can be used to trace a range of ISM processes. Velocity-resolved large-scale mapping of [CII] in star-forming regions provides a unique perspective of the kinematics of these regions and their interactions with the exciting source of radiation. Aims. We explore the scientific applications of large-scale mapping of velocity-resolved [CII] observations. With the [CII] observations, we investigate the effect of stellar feedback on the ISM. We present the details of observation, calibration, and data reduction using a heterodyne array receiver mounted on an airborne observatory. Results. A square-degree [CII] map with a spectral resolution of 0.3 km/s is presented. The scientific potential of this data is summarized with discussion of mechanical and radiative stellar feedback, filament tracing using [CII], [CII] opacity effects, [CII] and carbon recombination lines, and [CII] interaction with the large molecular cloud. The data quality and calibration is discussed in detail, and new techniques are presented to mitigate the effects of unavoidable instrument deficiencies (e.g. baseline stability) and thus to improve the data quality. A comparison with a smaller [CII] map taken with the Herschel/Heterodyne Instrument for the Far-Infrared (HIFI) spectrometer is presented.

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The Dense Warm Ionized Medium in the Inner Galaxy

Ionized interstellar gas is an important component of the interstellar medium and its lifecycle. The recent evidence for a widely distributed highly ionized warm interstellar gas with a density intermediate between the warm ionized medium (WIM) and compact HII regions suggests that there is a major gap in our understanding of the interstellar gas. Here we investigate the properties of the dense warm ionized medium (D-WIM) in the Milky Way using spectrally resolved SOFIA GREAT [NII] 205 micron line emission and Green Bank Telescope hydrogen radio recombination lines (RRL) data, supplemented by Herschel PACS [NII] 122 micron data, and spectrally resolved 12CO. We observed eight lines of sight in the 20deg 50% of the observed [CII] intensity along these LOS. The kinetic temperatures we derive are too low to explain the presence of N+ resulting from electron collisional ionization and/or proton charge transfer of atomic nitrogen. Rather, these regions most likely are ionized by extreme ultraviolet radiation.

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SOFIA FEEDBACK survey: exploring the dynamics of the stellar wind driven shell of RCW 49

We unveil the stellar wind driven shell of the luminous massive star-forming region of RCW 49 using SOFIA FEEDBACK observations of the [CII] 158 $\mu$m line. The complementary dataset of the $^{12}$CO and $^{13}$CO J = 3 - 2 transitions is observed by the APEX telescope and probes the dense gas toward RCW 49. Using the spatial and spectral resolution provided by the SOFIA and APEX telescopes, we disentangle the shell from a complex set of individual components of gas centered around RCW 49. We find that the shell of radius ~ 6 pc is expanding at a velocity of 13 km s$^{-1}$ toward the observer. Comparing our observed data with the ancillary data at X-Ray, infrared, sub-millimeter and radio wavelengths, we investigate the morphology of the region. The shell has a well defined eastern arc, while the western side is blown open and is venting plasma further into the west. Though the stellar cluster, which is ~ 2 Myr old gave rise to the shell, it only gained momentum relatively recently as we calculate the shell's expansion lifetime ~ 0.27 Myr, making the Wolf-Rayet star WR20a a likely candidate responsible for the shell's re-acceleration.

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FEEDBACK: a SOFIA Legacy Program to Study Stellar Feedback in Regions of Massive Star Formation

FEEDBACK is a SOFIA legacy program dedicated to study the interaction of massive stars with their environment. It performs a survey of 11 galactic high mass star forming regions in the 158 $\mu$m (1.9 THz) line of CII and the 63 $\mu$m (4.7 THz) line of OI. We employ the 14 pixel LFA and 7 pixel HFA upGREAT instrument to spectrally resolve (0.24 MHz) these FIR structure lines. With an observing time of 96h, we will cover $\sim$6700 arcmin$^2$ at 14.1$''$ angular resolution for the CII line and 6.3$''$ for the OI line. The observations started in spring 2019 (Cycle 7). Our aim is to understand the dynamics in regions dominated by different feedback processes from massive stars such as stellar winds, thermal expansion, and radiation pressure, and to quantify the mechanical energy injection and radiative heating efficiency. The CII line provides the kinematics of the gas and is one of the dominant cooling lines of gas for low to moderate densities and UV fields. The OI line traces warm and high-density gas, excited in photodissociations regions with a strong UV field or by shocks. The source sample spans a broad range in stellar characteristics from single OB stars, to small groups of O stars, to rich young stellar clusters, to ministarburst complexes. It contains well-known targets such as Aquila, the Cygnus X region, M16, M17, NGC7538, NGC6334, Vela, and W43 as well as a selection of HII region bubbles, namely RCW49, RCW79, and RCW120. These CII maps, together with the less explored OI 63 $\mu$m line, provide an outstanding database for the community. They will be made publically available and will trigger further studies and follow-up observations.

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Dense gas formation in the Musca filament due to the dissipation of a supersonic converging flow

Observations with the Herschel Space Telescope have established that most of the star forming gas is organised in interstellar filaments, a finding that is supported by numerical simulations of the supersonic interstellar medium (ISM) where dense filamentary structures are ubiquitous. We aim to understand the formation of these dense structures by performing observations covering the $^{12}$CO(4-3), $^{12}$CO(3-2), and various CO(2-1) isotopologue lines of the Musca filament, using the APEX telescope. The observed CO intensities and line ratios cannot be explained by PDR (photodissociation region) emission because of the low ambient far-UV field that is strongly constrained by the non-detections of the [C II] line at 158 $\mu$m and the [O I] line at 63 $\mu$m, observed with the upGREAT receiver on SOFIA, as well as a weak [C I] 609 $\mu$m line detected with APEX. We propose that the observations are consistent with a scenario in which shock excitation gives rise to warm and dense gas close to the highest column density regions in the Musca filament. Using shock models, we find that the CO observations can be consistent with excitation by J-type low-velocity shocks. A qualitative comparison of the observed CO spectra with synthetic observations of dynamic filament formation simulations shows a good agreement with the signature of a filament accretion shock that forms a cold and dense filament from a converging flow. The Musca filament is thus found to be dense molecular post-shock gas. Filament accretion shocks that dissipate the supersonic kinetic energy of converging flows in the ISM may thus play a prominent role in the evolution of cold and dense filamentary structures.

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The PDR structure and kinematics around the compact HII regions S235A and S235C with [CII], [13CII], [OI] and HCO+ line profiles

The aim of the present work is to study structure and gas kinematics in the photodissociation regions (PDRs) around the compact HII regions S235A and S235C. We observe the [CII], [13CII] and [OI] line emission, using SOFIA/upGREAT and complement them by data of HCO+ and CO. We use the [13CII] line to measure the optical depth of the [CII] emission, and find that the [CII] line profiles are influenced by self-absorption, while the [13CII] line remains unaffected by these effects. Hence, for dense PDRs, [13CII] emission is a better tracer of gas kinematics. The optical depth of the [CII] line is up to 10 in S235A. We find an expanding motion of the [CII]-emitting layer of the PDRs into the front molecular layer in both regions. Comparison of the gas and dust columns shows that gas components visible neither in the [CII] nor in low-J CO lines may contribute to the total column across S235A. We test whether the observed properties of the PDRs match the predictions of spherical models of expanding HII region + PDR + molecular cloud. Integrated intensities of the [13CII], [CII] and [OI] lines are well-represented by the model, but the models do not reproduce the double-peaked [CII] line profiles due to an insufficient column density of C+. The model predicts that the [OI] line could be a more reliable tracer of gas kinematics, but the foreground self-absorbing material does not allow using it in the considered regions.

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Molecular globules in the Veil bubble of Orion. IRAM 30m 12CO, 13CO, and C18O 2-1 expanded maps of Orion A

Strong winds and ultraviolet (UV) radiation from O-type stars disrupt and ionize their molecular core birthplaces, sweeping up material into parsec-size shells. Owing to dissociation by starlight, the thinnest shells are expected to host low molecular abundances and therefore little star formation. Here, we expand previous maps taken with the IRAM 30m telescope and present square-degree 12CO and 13CO (J=2-1) maps of the wind-driven "Veil bubble'' that surrounds the Trapezium cluster and its natal Orion molecular core (OMC). Although widespread and extended CO emission is largely absent from the Veil, we show that several CO "globules'' exist and are embedded in the [CII]158um-bright shell that confines the bubble. This includes the first detection of quiescent CO at negative LSR velocities in Orion. Given the harsh UV irradiation conditions in this translucent material, the detection of CO globules is surprising. These globules are small (R=7,100 AU), not massive (M=0.3M_Sun), and are moderately dense: n_ H=4x10^4 cm^-3 (median values). They are confined by the external pressure of the shell, P_ext/k~10^7 cm^-3 K, and are likely magnetically supported. They are either transient objects formed by instabilities or have detached from pre-existing molecular structures, sculpted by the passing shock associated with the expanding shell and by UV radiation from the Trapezium. Some represent the first stages in the formation of small pillars, others of isolated small globules. Although their masses do not suggest they will form stars, one globule matches the position of a known YSO. The lack of extended CO in the "Veil shell'' demonstrates that feedback from massive stars expels, agitates, and reprocesses most of the disrupted molecular cloud gas, thereby limiting the star-formation rate in the region. The presence of globules is a result of this feedback.

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The upGREAT dual frequency heterodyne arrays for SOFIA

We present the performance of the upGREAT heterodyne array receivers on the SOFIA telescope after several years of operations. This instrument is a multi-pixel high resolution (R > 10^7) spectrometer for the Stratospheric Observatory for Far-Infrared Astronomy (SOFIA). The receivers use 7-pixel subarrays configured in a hexagonal layout around a central pixel. The low frequency array receiver (LFA) has 2x7 pixels (dual polarization), and presently covers the 1.83-2.06 THz frequency range, which allows to observe the [CII] and [OI] lines at 158 um and 145 um wavelengths. The high frequency array (HFA) covers the [OI] line at 63 um and is equipped with one polarization at the moment (7 pixels, which can be upgraded in the near future with a second polarization array). The 4.7 THz array has successfully flown using two separate quantum-cascade laser local oscillators from two different groups. NASA completed the development, integration and testing of a dual-channel closed-cycle cryocooler system, with two independently operable He compressors, aboard SOFIA in early 2017 and since then, both arrays can be operated in parallel using a frequency separating dichroic mirror. This configuration is now the prime GREAT configuration and has been added to SOFIA's instrument suite since observing cycle 6.

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The upGREAT 1.9 THz multi-pixel high resolution spectrometer for the SOFIA Observatory

We present a new multi-pixel high resolution (R >10^7) spectrometer for the Stratospheric Observatory for Far-Infrared Astronomy (SOFIA). The receiver uses 2 x 7-pixel subarrays in orthogonal polarization, each in an hexagonal array around a central pixel. We present the first results for this new instrument after commissioning campaigns in May and December 2015 and after science observations performed in May 2016 . The receiver is designed to ultimately cover the full 1.8-2.5 THz frequency range but in its first implementation, the observing range was limited to observations of the [CII] line at 1.9 THz in 2015 and extended to 1.83-2.07 THz in 2016. The instrument sensitivities are state-of-the-art and the first scientific observations performed shortly after the commissioning confirm that the time efficiency for large scale imaging is improved by more than an order of magnitude as compared to single pixel receivers. An example of large scale mapping around the Horsehead Nebula is presented here illustrating this improvement. The array has been added to SOFIA's instrument suite already for ongoing observing cycle 4.

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Gas and dust cooling along the major axis of M33 (HerM33es): ISO/LWS CII observations

We aim to better understand the heating of the gas by observing the prominent gas cooling line [CII] at 158um in the low-metallicity environment of the Local Group spiral galaxy M33 at scales of 280pc. In particular, we aim at describing the variation of the photoelectric heating efficiency with galactic environment. In this unbiased study, we used ISO/LWS [CII] observations along the major axis of M33, in combination with Herschel PACS and SPIRE continuum maps, IRAM 30m CO 2-1 and VLA HI data to study the variation of velocity integrated intensities. The ratio of [CII] emission over the far-infrared continuum is used as a proxy for the heating efficiency, and models of photon-dominated regions are used to study the local physical densities, FUV radiation fields, and average column densities of the molecular clouds. The heating efficiency stays constant at 0.8% in the inner 4.5kpc radius of the galaxy where it starts to increase to reach values of ~3% in the outskirts at about 6kpc radial distance. The rise of efficiency is explained in the framework of PDR models by lowered volume densities and FUV fields, for optical extinctions of only a few magnitudes at constant metallicity. In view of the significant fraction of HI emission stemming from PDRs, and for typical pressures found in the Galactic cold neutral medium (CNM) traced by HI emission, the CNM contributes ~15% to the observed [CII] emission in the inner 2kpc radius of M33. The CNM contribution remains largely undetermined in the south, while positions between 2 and 7.3kpc radial distance in the north of M33 show a contribution of ~40%+-20%.

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Dense Gas in M33 (HerM33es)

We aim to better understand the emission of molecular tracers of the diffuse and dense gas in giant molecular clouds and the influence that metallicity, optical extinction, density, far-UV field, and star formation rate have on these tracers. Using the IRAM 30m telescope, we detected HCN, HCO+, 12CO, and 13CO in six GMCs along the major axis of M33 at a resolution of ~ 114pc and out to a radial distance of 3.4kpc. Optical, far-infrared, and submillimeter data from Herschel and other observatories complement these observations. To interpret the observed molecular line emission, we created two grids of models of photon-dominated regions, one for solar and one for M33-type subsolar metallicity. The observed HCO+/HCN line ratios range between 1.1 and 2.5. Similarly high ratios have been observed in the Large Magellanic Cloud. The HCN/CO ratio varies between 0.4% and 2.9% in the disk of M33. The 12CO/13CO line ratio varies between 9 and 15 similar to variations found in the diffuse gas and the centers of GMCs of the Milky Way. Stacking of all spectra allowed HNC and C2H to be detected. The resulting HCO+/HNC and HCN/HNC ratios of ~ 8 and 6, respectively, lie at the high end of ratios observed in a large set of (ultra-)luminous infrared galaxies. HCN abundances are lower in the subsolar metallicity PDR models, while HCO+ abundances are enhanced. For HCN this effect is more pronounced at low optical extinctions. The observed HCO+/HCN and HCN/CO line ratios are naturally explained by subsolar PDR models of low optical extinctions between 4 and 10 mag and of moderate densities of n = 3x10^3 - 3x10^4 cm^-3, while the FUV field strength only has a small effect on the modeled line ratios. The line ratios are almost equally well reproduced by the solar-metallicity models, indicating that variations in metallicity only play a minor role in influencing these line ratios.

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