arXiv subjects

C. C. Homes

Publications and source records attributed to C. C. Homes.

At least 19 recordsLinked to original sources

arXiv2026

Optical conductivity of layered topological semimetal TaNiTe$_5$

We present an infrared spectroscopy study of the layered topological semimetal TaNiTe$_5$, a material with a quasi-one-dimensional structure and strong in-plane anisotropy. Despite its structural features, infrared reflectivity and electronic transport measurements along the $a$ and $c$ crystallographic axes show metallic behavior without evidence of reduced dimensionality. Optical conductivity reveals an anisotropic but conventional metallic response with low scattering rates and a single sharp infrared-active phonon mode at $396$ cm$^{-1}$ ($49$ meV). Ab initio calculations closely match the experimental optical data and confirm a three-dimensional electronic structure. Our results demonstrate that TaNiTe$_5$ behaves as a three-dimensional anisotropic semimetal in its electronic and optical properties.

cond-mat.str-el↗

arXiv2026

Quantum control of Hubbard excitons

Quantum control of the many-body wavefunction is a central challenge in quantum materials research, as it could yield a precise control knob to manipulate emergent phenomena. Floquet engineering, the coherent dressing of quantum states with periodic non-resonant optical fields, has become an important strategy for quantum control. Most applications to solid-state systems have targeted weakly interacting or single-ion states, leaving the manipulation of many-body wavefunctions largely unexplored. Here, we use Floquet engineering to achieve quantum control of a strongly correlated Hubbard exciton in the one-dimensional Mott insulator Sr$_2$CuO$_3$. A nonresonant midinfrared optical field coherently dresses the exciton wavefunction, driving its rotation between bright and dark states. We use resonant third-harmonic generation to quantify ultrafast $π/2$ rotations on the Bloch sphere spanned by these exciton states. Our work advances the quest towards programmable control of correlated states and exciton-based quantum sensing.

cond-mat.str-el↗

arXiv2024

Magneto-optical response of magnetic semiconductors EuCd2X2 (X= P, As, Sb)

In this study, we identify EuCd2X2 (for X = P, As, Sb) as a series of magnetic semiconductors. We examine how the band gap of the series responds to X changing from phosphorus (P), to arsenic (As), and finally antimony (Sb). We characterize the samples using electronic transport and magnetization measurements. Based on infrared spectroscopy, we find that the band gap reduces progressively from 1.23 eV in EuCd2P2, to 0.77 eV in EuCd2As2, and finally 0.52 eV in EuCd2Sb2. In a magnetic field, all three systems show a strong response and their band gaps decrease at 4 K. This decrease is non-monotonic as we change X. It is strongest in the phosphorous compound and weakest in the antimony compound. For all the three compositions, EuCd2X2 remains a semiconductor up to the highest magnetic field applied (16 T).

cond-mat.mtrl-sci↗

arXiv2024

Light-Induced Melting of Competing Stripe Orders without Introducing Superconductivity in La$_\mathbf{2-x}$Ba$_\mathbf{x}$CuO$_\mathbf{4}$

The ultrafast manipulation of quantum material has led to many novel and significant discoveries. Among them, the light-induced transient superconductivity in cuprates achieved by melting competing stripe orders represents a highly appealing accomplishment. However, recent investigations have shown that the notion of photoinduced superconductivity remains a topic of controversy, and its elucidation solely through c-axis time-resolved terahertz spectroscopy remains an arduous task. Here, we measure the in-plane and out-of-plane transient terahertz responses simultaneously in the stripe-ordered non-superconducting La$_{2-x}$Ba$_{x}$CuO$_4$ after near-infrared excitations. We find that although a pump-induced reflectivity edge appears in the c-axis reflectance spectrum, the reflectivity along the CuO$_2$ planes decreases simultaneously, indicating an enhancement in the scattering rate of quasiparticles. This in-plane transient response is clearly distinct from the features associated with superconducting condensation. Therefore, we conclude the out-of-plane transient responses cannot be explained by an equivalent of Josephson tunneling. Notably, those pump-induced terahertz responses remain consistent even when we vary the near-infrared optical pump wavelengths and hole concentrations. Our results provide a critical evidence that transient three-dimensional superconductivity cannot be induced by melting the competing stripe orders with pump pulses whose photon energy is much higher than the superconducting gap of cuprates.

cond-mat.supr-con↗

arXiv2024

Revealing the KH2PO4 soft-mode coupling mechanism with infrared spectroscopy under pressure

We measured the far-infrared reflectivity of a KH2PO4 single crystal up to pressures of 2 GPa in the ferroelectric and paraelectric phases. We find that the nu4 vibrational mode of the PO4 tetrahedron is strongly affected by the applied pressure. At ambient pressure this phonon is destabilized by the presence of the H ions and hence shows a highly damped character, beyond the phonon propagation threshold. Applying a pressure close to 0.6 GPa makes this phonon clearly underdamped. Its behavior closely follows the soft-mode behavior observed in Raman spectroscopy. Our results solve a long standing open problem, demonstrating that the nu4 mode is the excitation mediating the coupling of the hydrogen network to the lattice modes that create the ferroelectic polarization in KH2PO4.

cond-mat.mtrl-sci↗

arXiv2023

EuCd$_2$As$_2$: a magnetic semiconductor

EuCd$_2$As$_2$ is now widely accepted as a topological semimetal in which a Weyl phase is induced by an external magnetic field. We challenge this view through firm experimental evidence using a combination of electronic transport, optical spectroscopy and excited-state photoemission spectroscopy. We show that the EuCd$_2$As$_2$ is in fact a semiconductor with a gap of 0.77 eV. We show that the externally applied magnetic field has a profound impact on the electronic band structure of this system. This is manifested by a huge decrease of the observed band gap, as large as 125~meV at 2~T, and consequently, by a giant redshift of the interband absorption edge. However, the semiconductor nature of the material remains preserved. EuCd$_2$As$_2$ is therefore a magnetic semiconductor rather than a Dirac or Weyl semimetal, as suggested by {\em ab initio} computations carried out within the local spin-density approximation.

cond-mat.mtrl-sci↗

arXiv2023

Optical properties and carrier localization in the layered phosphide EuCd$_\mathbf{2}$P$_\mathbf{2}$

The temperature dependence of the complex optical properties of the layered phosphide material EuCd$_2$P$_2$ have been measured over a wide frequency range above and below $T_{\rm N} \simeq 11.5$ K for light polarized in the $a-b$ planes. At room temperature, the optical conductivity is well described by a weak free-carrier component with a Drude plasma frequency of $\simeq 1100$ cm$^{-1}$ and a scattering rate of $1/τ_D\simeq 700$ cm$^{-1}$, with the onset of interband absorptions above $\simeq 2000$ cm$^{-1}$. Two infrared-active $E_u$ modes are observed at $\simeq\,$89 and 239 cm$^{-1}$. As the temperature is reduced the scattering rate decreases and the low-frequency conductivity increases slightly; however, below $\simeq 50$ K the conductivity decreases until at the resistivity maximum at $\simeq 18$ K (just below $2T_{\rm N}$) the spectral weight associated with free carriers is transferred to a localized excitation at $\simeq 500$ cm$^{-1}$. Below $T_{\rm N}$, metallic behavior is recovered. Interestingly, the $E_u$ modes are largely unaffected by these changes, with only the position of the high-frequency mode showing any signs of anomalous behavior. While several scenarios are considered, the prevailing view is that the resistivity maximum and subsequent carrier localization is due to the formation of ferromagnetic domains below $\simeq 2T_{\rm N}$ that result in spin-polarized clusters due to spin-carrier coupling [1].

cond-mat.str-el↗

arXiv2022

Superuid density in overdoped cuprates: thin films versus bulk samples

Recent study of overdoped La$_{2-x}$Sr$_x$CuO$_4$ cuprate superconductor thin films by Božović {\it et al.} has revealed several unexpected findings, most notably the violation of the BCS description which was believed to adequately describe overdoped cuprates. In particular, it was found that the superfluid density in La$_{2-x}$Sr$_x$CuO$_4$ films decreases on the overdoped side as a linear function of critical temperature T$_c$, which was taken as evidence for the violation of the Homes' law. We show explicitly that the law is indeed violated, and as the main reason for violation we find that the superfluid density in Božović's films is suppressed more strongly than in bulk samples. Based on the existing literature data, we show that the superfluid density in bulk cuprate samples does not decrease with doping, but instead tends to saturate on the overdoped side. The result is also supported by our recent measurement of a heavily overdoped bulk La$_{2-x}$Sr$_x$CuO$_4$ sample. Moreover, this saturation of superfluid density might not be limited to cuprates, as we find evidence for similar behavior in two pnictide superconductor families. We argue that quantum phase fluctuations play an important role in suppressing the superfluid density in thin films.

cond-mat.supr-con↗

arXiv2020

Distinguishing the gapped and Weyl semimetal scenario in ZrTe$_5$: insights from an effective two-band model

Here we study the static and dynamic transport properties of a low energy two-band model proposed previously in E. Martino et al. [PRL 122, 217402 (2019), arXiv:1905.00280], with an anisotropic in-plane linear momentum dependence, and a parabolic out-of-plane dispersion. The model is extended to include a negative band gap, which leads to the emergence of a Weyl semimetal (WSM) state, as opposed to the gapped semimetal (GSM) state when the band gap is positive. We calculate and compare the zero and finite frequency transport properties of the GSM and WSM cases. The $dc$ properties that are calculated for the GSM and WSM cases are Drude spectral weight, mobility and resistivity. We determine their dependence on the Fermi energy and crystal direction. The in- and out-of-plane optical conductivities are calculated in the limit of the vanishing interband relaxation rate for both semimetals. The main common features are an $ω^{1/2}$ in-plane and $ω^{3/2}$ out-of-plane frequency dependence of the optical conductivity. We seek particular features related to the charge transport that could unambiguously point to one ground state over the other, based on the comparison with the experiment. Differences between the WSM and GSM are in principle possible only at extremely low carrier concentrations, and at low temperatures.

cond-mat.mes-hall↗

arXiv2020

Optical conductivity of the type-II Weyl semimetal TaIrTe$_4$

TaIrTe$_4$ is an example of a candidate Weyl type-II semimetal with a minimal possible number of Weyl nodes. Four nodes are reported to exist a single plane in $k$-space. The existence of a conical dispersion linked to Weyl nodes has yet to be shown experimentally. Here we use optical spectroscopy as a probe of the band structure on a low-energy scale. Studying optical conductivity allows us to probe intraband and interband transitions with zero momentum. In TaIrTe$_4$, we observe a narrow Drude contribution and an interband conductivity that may be consistent with a tilted linear band dispersion up to 40~meV. The interband conductivity allows us to establish the effective parameters of the conical dispersion; effective velocity $v=1.1\cdot 10^{4}$~m/s and tilt $γ=0.37$. The transport data, Seebeck and Hall coefficients, are qualitatively consistent with conical features in the band structure. Quantitative disagreement may be linked to the multiband nature of TaIrTe$_4$.

cond-mat.mtrl-sci↗

arXiv2019

Optical and photoemission investigation of structural and magnetic transitions in the iron-based superconductor Sr$_\mathbf{0.67}$Na$_\mathbf{0.33}$Fe$_\mathbf{2}$As$_\mathbf{2}$

We report the temperature-dependent optical conductivity and ARPES studies of the iron-based superconductor (SC) Sr$_{0.67}$Na$_{0.33}$Fe$_2$As$_2$ in the high-temperature tetragonal paramagnetic phase; below the structural and magnetic transitions at $T_{\rm N}\simeq$125 K in the orthorhombic spin-density-wave (SDW)-like phase, and $T_r\simeq$42 K in the reentrant tetragonal double-Q magnetic phase where both charge and SDW order exist; and below the SC transition at $T_c\simeq$10 K. The free-carrier component in the optical conductivity is described by two Drude contributions; one strong and broad, the other weak and narrow. The broad Drude component decreases dramatically below $T_{\rm N}$ and $T_r$, with much of its strength being transferred to a bound excitation in the mid-infrared, while the narrow Drude component shows no anomalies at either of the transitions, actually increasing in strength at low temperature while narrowing dramatically. The behavior of an infrared-active mode suggests zone-folding below $T_r$. Below $T_c$ the dramatic decrease in the low-frequency optical conductivity signals the formation of a SC energy gap. ARPES reveals hole-like bands at the center of the Brillouin zone (BZ), with both electron- and hole-like bands at the corners. Below $T_{\rm N}$, the hole pockets at the center of the BZ decrease in size, consistent with the behavior of the broad Drude component; while below $T_r$ the electron-like bands shift and split, giving rise to a low-energy excitation in the optical conductivity at ~20 meV. The magnetic states, with resulting SDW and charge-SDW order, respectively, lead to a significant reconstruction of the Fermi surface that has profound implications for the transport originating from the electron and hole pockets, but appears to have relatively little impact on the SC in this material.

cond-mat.str-el↗

arXiv2019

Probing intraband excitations in ZrTe$_5$: a high-pressure infrared and transport study

Zirconium pentatetelluride, ZrTe5, shows remarkable sensitivity to hydrostatic pressure. In this work we address the high-pressure transport and optical properties of this compound, on samples grown by flux and charge vapor transport. The high-pressure resistivity is measured up to 2 GPa, and the infrared transmission up to 9 GPa. The dc conductivity anisotropy is determined using a microstructured sample. Together, the transport and optical measurements allow us to discern band parameters with and without the hydrostatic pressure, in particular the Fermi level, and the effective mass in the less conducting, out-of-plane direction. The results are interpreted within a simple two-band model characterized by a Dirac-like, linear in-plane band dispersion, and a parabolic out-of-plane dispersion.

cond-mat.mtrl-sci↗

arXiv2019

Two-dimensional conical dispersion in ZrTe5 evidenced by optical spectroscopy

Zirconium pentatelluride was recently reported to be a 3D Dirac semimetal, with a single conical band, located at the center of the Brillouin zone. The cone's lack of protection by the lattice symmetry immediately sparked vast discussions about the size and topological/trivial nature of a possible gap opening. Here we report on a combined optical and transport study of ZrTe5, which reveals an alternative view of electronic bands in this material. We conclude that the dispersion is approximately linear only in the a-c plane, while remaining relatively flat and parabolic in the third direction (along the b axis). Therefore, the electronic states in ZrTe5 cannot be described using the model of 3D Dirac massless electrons, even when staying at energies well above the band gap 6 meV found in our experiments at low temperatures.

cond-mat.mes-hall↗

arXiv2019

Low-energy excitations in type-II Weyl semimetal Td-MoTe2 evidenced through optical conductivity

Molybdenum ditelluride, MoTe2, is a versatile material where the topological phase can be readily tuned by manipulating the associated structural phase transition. The fine details of the band structure of MoTe2, key to understanding its topological properties, have proven difficult to disentangle experientially due to the multi-band character of the material. Through experimental optical conductivity spectra, we detect two strong low-energy interband transitions. Both are linked to excitations between spin-orbit split bands. The lowest interband transition shows a strong thermal shift, pointing to a chemical potential that dramatically decreases with temperature. With the help of ab initio calculations and a simple two-band model, we give qualitative and quantitative explanation of the main features in the temperature-dependent optical spectra up to 400 meV.

cond-mat.mtrl-sci↗

arXiv2019

Perfect separation of intraband and interband excitations in PdCoO$_2$

The temperature dependence of the optical properties of the delafossite PdCoO$_2$ has been measured in the a-b planes over a wide frequency range. The optical conductivity due to the free-carrier (intraband) response falls well below the interband transitions, allowing the plasma frequency to be determined from the $f$-sum rule. Drude-Lorentz fits to the complex optical conductivity yield estimates for the free-carrier plasma frequency and scattering rate. The in-plane plasma frequency has also been calculated using density functional theory. The experimentally-determined and calculated values for the plasma frequencies are all in good agreement; however, at low temperature the optically-determined scattering rate is much larger than the estimate for the transport scattering rate, indicating a strong frequency-dependent renormalization of the optical scattering rate. In addition to the expected in-plane infrared-active modes, two very strong features are observed that are attributed to the coupling of the in-plane carriers to the out-of-plane longitudinal optic modes.

cond-mat.mtrl-sci↗

arXiv2018

Unusual electronic and vibrational properties in the colossal thermopower material FeSb$_2$

The iron antimonide FeSb$_2$ possesses an extraordinarily high thermoelectric power factor at low temperature, making it a leading candidate for cryogenic thermoelectric cooling devices. However, the origin of this unusual behavior is controversial, having been variously attributed to electronic correlations as well as the phonon-drag effect. The optical properties of a material provide information on both the electronic and vibrational properties. The optical conductivity reveals an anisotropic response at room temperature; the low-frequency optical conductivity decreases rapidly with temperature, signalling a metal-insulator transition. One-dimensional semiconducting behavior is observed along the $b$ axis at low temperature, in agreement with first-principle calculations. The infrared-active lattice vibrations are also symmetric and extremely narrow, indicating long phonon relaxation times and a lack of electron-phonon coupling. Surprisingly, there are more lattice modes along the $a$ axis than are predicted from group theory; several of these modes undergo significant changes below about 100 K, hinting at a weak structural distortion or phase transition. While the extremely narrow phonon line shapes favor the phonon-drag effect, the one-dimensional behavior of this system at low temperature may also contribute to the extraordinarily high thermopower observed in this material.

cond-mat.str-el↗

arXiv2018

Non-uniform carrier density in Cd$_3$As$_2$ evidenced by optical spectroscopy

We report the detailed optical properties of Cd$_3$As$_2$ crystals in a wide parameter space: temperature, magnetic field, carrier concentration and crystal orientation. We investigate high-quality crystals synthesized by three different techniques. In all the studied samples, independently of how they were prepared and how they were treated before the optical experiments, our data indicate conspicuous fluctuations in the carrier density (up to 30%). These charge puddles have a characteristic scale of 100 $μ$m, they become more pronounced at low temperatures, and possibly, they become enhanced by the presence of crystal twinning. The Drude response is characterized by very small scattering rates ($\sim 1$ meV) for as-grown samples. Mechanical treatment, such as cutting or polishing, influences the optical properties of single crystals, by increasing the Drude scattering rate and also modifying the high frequency optical response. Magneto-reflectivity and Kerr rotation are consistent with electron-like charge carriers and a spatially non-uniform carrier density.

cond-mat.mtrl-sci↗

arXiv2018

Vibrational anomalies in AFe$_\mathbf{2}$As$_\mathbf{2}$ (A$\,=\,$Ca, Sr, and Ba) single crystals

The detailed behavior of the in-plane infrared-active vibrational modes has been determined in AFe$_2$As$_2$ (A$\,=\,$Ca, Sr, and Ba) above and below the structural and magnetic transition at $T_N=$172, 195 and 138 K, respectively. Above $T_N$, two infrared-active $E_u$ modes are observed. In all three compounds, below $T_N$ the low-frequency $E_u$ mode is observed to split into upper and lower branches; with the exception of the Ba material, the oscillator strength across the transition is conserved. In the Ca and Sr materials, the high-frequency $E_u$ mode splits into an upper and a lower branch; however, the oscillator strengths are quite different. Surprisingly, in both the Sr and Ba materials, below $T_N$ the upper branch appears be either very weak or totally absent, while the lower branch displays an anomalous increase in strength. The frequencies and atomic characters of the lattice modes at the center of the Brillouin zone have been calculated for the high-temperature phase for each of these materials. The high-frequency $E_u$ mode does not change in position or character across this series of compounds. Below $T_N$, the $E_u$ modes are predicted to split into features of roughly equal strength. We discuss the possibility that the anomalous increase in the strength of the lower branch of the high-frequency mode below $T_N$ in the Sr and Ba compounds, and the weak (silent) upper branch, may be related to the orbital ordering and a change in the bonding between the Fe and As atoms in the magnetically-ordered state.

cond-mat.str-el↗