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C. C. Homes

Publications and source records attributed to C. C. Homes.

At least 73 records · Page 4Linked to original sources

Optical determination of the superconducting energy gap in electron-doped Pr_{1.85}Ce_{0.15}CuO_4

The optical properties of single crystal Pr_{1.85}Ce_{0.15}CuO_4 have been measured over a wide frequency range above and below the critical temperature (T_c \simeq 20 K). In the normal state the coherent part of the conductivity is described by the Drude model, from which the scattering rate just above T_c is determined to be 1/τ\simeq 80 cm^{-1}. The condition that \hbar/τ\approx 2k_B T near T_c appears to be a general result in many of the cuprate superconductors. Below T_c the formation of a superconducting energy gap is clearly visible in the reflectance, from which the gap maximum is estimated to be Δ_0 \simeq 35 cm^{-1} (4.3 meV). The ability to observe the superconducting energy gap in the optical properties favors the nonmonotonic over the monotonic description of the d-wave gap. The penetration depth for T\ll T_c is λ\simeq 2000 Å, which when taken with the estimated value for the dc conductivity just above T_c of σ_{dc} \simeq 35 \times 10^3 Ω^{-1}cm^{-1} places this material on the general scaling line for the cuprates defined by 1/λ^2 \propto σ_{dc}(T\simeq T_c) \times T_c. This result is consistent with the observation that 1/τ\approx 2Δ_0, which implies that the material is not in the clean limit.

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Optical and thermodynamic properties of the high-temperature superconductor HgBa_2CuO_4+delta

In- and out-of-plane optical spectra and specific heat measurements for the single layer cuprate superconductor Hg-1201 at optimal doping (Tc = 97 K) are presented. Both the in-plane and out-of-plane superfluid density agree well with a recently proposed scaling relation rho_{s}=sigma_{dc}T_{c}. It is shown that there is a superconductivity induced increase of the in-plane low frequency spectral weight which follows the trend found in underdoped and optimally doped Bi-2212 and optimally doped Bi-2223. We observe an increase of optical spectral weight which corresponds to a change in kinetic energy of approximately 0.5 meV/Cu which is more than enough to explain the condensation energy. The specific heat anomaly is 10 times smaller than in YBCO and 3 times smaller than in Bi-2212. The shape of the anomaly is similar to the one observed in YBCO showing that the superconducting transition is governed by thermal fluctuations.

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Charge order, metallic behavior and superconductivity in La_{2-x}Ba_xCuO_4 with x=1/8

The ab-plane optical properties of a cleaved single crystal of La_{2-x}Ba_xCuO_4 for x=1/8 (T_c ~ 2.4 K) have been measured over a wide frequency and temperature range. The low-frequency conductivity is Drude-like and shows a metallic response with decreasing temperature. However, below ~ 60 K, corresponding to the onset of charge-stripe order, there is a rapid loss of spectral weight below about 40 meV. The gapping of single-particle excitations looks surprisingly similar to that observed in superconducting La_{2-x}Sr_{x}CuO_4, including the presence of a residual Drude peak with reduced weight; the main difference is that the lost spectral weight moves to high, rather than zero, frequency, reflecting the absence of a bulk superconducting condensate.

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Separation of orbital contributions to the optical conductivity of BaVS$_3$

The correlation-driven metal-insulator transition (MIT) of BaVS$_3$ was studied by polarized infrared spectroscopy. In the metallic state two types of electrons coexist at the Fermi energy: The quasi 1D metallic transport of $A_{1g}$ electrons is superimposed on the isotropic hopping conduction of localized $E_g$ electrons. The "bad-metal" character and the weak anisotropy are the consequences of the large effective mass $m_{eff}\approx7m_e$ and scattering rate $Γ\geq160$ meV of the quasi-particles in the $A_{1g}$ band. There is a pseudo-gap above $T_{MI}=69$ K, and in the insulating phase the gap follows the BCS-like temperature dependence of the structural order parameter with $Δ_{ch}\approx42$ meV in the ground state. The MIT is described in terms of a weakly coupled two-band model.

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Strong-coupling Effects in cuprate High-$T_{c}$ Superconductors by magnetooptical studies

Signatures of strong coupling effects in cuprate high-$T_{c}$ superconductors have been authenticated through a variety of spectroscopic probes. However, the microscopic nature of relevant excitations has not been agreed upon. Here we report on magneto-optical studies of the CuO$_{2}$ plane carrier dynamics in a prototypical high-$T_{c}$ superconductor YBa$%_{2} $Cu$_{3}$O$_{y}$ (YBCO). Infrared data are directly compared with earlier inelastic neutron scattering results by Dai \textit{et al}. [Nature (London) \textbf{406}, 965 (2000)] revealing a characteristic depression of the magnetic resonance in H $\parallel $ \textit{c} field less than 7 T. This analysis has allowed us to critically assess the role of magnetic degrees of freedom in producing strong coupling effects for YBCO system.

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Electrodynamics of the Nodal Metal in Weakly Doped High-$T_{c}$ Cuprates

We report on the detailed analysis of the infrared (IR) conductivity of two prototypical high-$T_{c}$ systems YBa$_{2}$Cu$_{3}$O$_{y}$ and La$_{2-x}$Sr$%_{x}$CuO$_{4}$ throughout the complex phase diagram of these compounds. Our focus in this work is to thoroughly document the electromagnetic response of the nodal metal state which is initiated with only few holes doped in parent antiferromagnetic systems and extends up to the pseudogap boundary in the phase diagram. The key signature of the nodal metal is the two-component conductivity: the Drude mode at low energies followed by a resonance in mid-IR. The Drude component can be attributed to the response of coherent quasiparticles residing on the Fermi arcs detected in photoemission experiments. The microscopic origin of the mid-IR band is yet to be understood. A combination of transport and IR data uncovers fingerprints of the Fermi liquid behavior in the response of the nodal metal. The comprehensive nature of the data sets presented in this work allows us to critically re-evaluate common approaches to the interpretation of the optical data. Specifically we re-examine the role of magnetic excitations in generating electronic self energy effects through the analysis of the IR data in high magnetic field.

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Scaling of the superfluid density in high-temperature superconductors

A scaling relation ρ_s \simeq 35σ_{dc}T_c has been observed in the copper-oxide superconductors, where ρ_s is the strength of the superconducting condensate, T_c is the critical temperature, and σ_{dc} is the normal-state dc conductivity close to T_c. This scaling relation is examined within the context of a clean and dirty-limit BCS superconductor. These limits are well established for an isotropic BCS gap 2Δand a normal-state scattering rate 1/τ; in the clean limit 1/τ\ll 2Δ, and in the dirty limit 1/τ> 2Δ. The dirty limit may also be defined operationally as the regime where ρ_s varies with 1/τ. It is shown that the scaling relation ρ_s \propto σ_{dc}T_c is the hallmark of a BCS system in the dirty-limit. While the gap in the copper-oxide superconductors is considered to be d-wave with nodes and a gap maximum Δ_0, if 1/τ> 2Δ_0 then the dirty-limit case is preserved. The scaling relation implies that the copper-oxide superconductors are likely to be in the dirty limit, and that as a result the energy scale associated with the formation of the condensate is scaling linearly with T_c. The a-b planes and the c axis also follow the same scaling relation. It is observed that the scaling behavior for the dirty limit and the Josephson effect (assuming a BCS formalism) are essentially identical, suggesting that in some regime these two effects may be viewed as equivalent. This raises the possibility that electronic inhomogeneities in the copper-oxygen planes may play an important role in the nature of the superconductivity in the copper-oxide materials.

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Coherence, incoherence and scaling along the c axis of YBa_2Cu_3O_{6+x}

The optical properties of single crystals of YBa_2Cu_3O_{6+x} have been examined along the c axis above and below the critical temperature (T_c) for a wide range of oxygen dopings. The temperature dependence of the optically-determined value of the dc conductivity (σ_{dc}) in the normal state suggests a crossover from incoherent (hopping-type) transport at lower oxygen dopings (x \lesssim 0.9) to more coherent anisotropic three-dimensional behavior in the overdoped (x \approx 0.99) material at temperatures close to T_c. The assumption that superconductivity occurs along the c axis through the Josephson effect yields a scaling relation between the strength of the superconducting condensate (ρ_{s,c}, a measure of the number of superconducting carriers), the critical temperature, and the normal-state c-axis value for σ_{dc} just above T_c; ρ_{s,c} \propto σ_{dc} T_c. This scaling relation is observed along the c axis for all oxygen dopings, as well as several other cuprate materials. However, the agreement with the Josephson coupling model does not necessarily imply incoherent transport, suggesting that these materials may indeed be tending towards coherent behavior at the higher oxygen dopings.

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Marginal Fermi liquid analysis of 300 K reflectance of Bi2Sr2CaCu2O8+x

We use 300 K reflectance data to investigate the normal-state electrodynamics of the high temperature superconductor Bi$_{2}$Sr$_{2}$CaCu$_{2}$O$_{8+δ}$ over a wide range of doping levels. The data show that at this temperature the free carriers are coupled to a continuous spectrum of fluctuations. Assuming the Marginal Fermi Liquid (MFL) form as a first approximation for the fluctuation spectrum, the doping-dependent coupling constant $λ(p)$ can be estimated directly from the slope of the reflectance spectrum. We find that $λ(p)$ decreases smoothly with the hole doping level, from underdoped samples with $ p=0.103$ ($T_c = 67$ K) where $λ(p)= 0.93$ to overdoped samples with $p=0.226$, ($T_c= 60$ K) where $λ(p)= 0.53$. An analysis of the intercept and curvature of the reflectance spectrum shows deviations from the MFL spectrum symmetrically placed at the optimal doping point $p=0.16$. The Kubo formula for the conductivity gives a better fit to the experiments with the MFL spectrum up to 2000 cm$^{-1}$ and with an additional Drude component or an additional Lorentz component up to 7000 cm$^{-1}$. By comparing three different model fits we conclude that the MFL channel is necessary for a good fit to the reflectance data. Finally, we note that the monotonic variation of the reflectance slope with doping provides us with an independent measure of the doping level for the Bi-2212 system.

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Extracting the electron--boson spectral function $α^2$F($ω$) from infrared and photoemission data using inverse theory

We present a new method of extracting electron-boson spectral function $α^2$F($ω$) from infrared and photoemission data. This procedure is based on inverse theory and will be shown to be superior to previous techniques. Numerical implementation of the algorithm is presented in detail and then used to accurately determine the doping and temperature dependence of the spectral function in several families of high-T$_c$ superconductors. Principal limitations of extracting $α^2$F($ω$) from experimental data will be pointed out. We directly compare the IR and ARPES $α^2$F($ω$) and discuss the resonance structure in the spectra in terms of existing theoretical models.

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Optical spectroscopy study on the electronic structure of $Eu_{1-x} Ca_x B_6$

The optical conductivity $σ_{1}(ω)$ of Eu$_{1-x}$Ca$_{x}$B$_{6}$ has been obtained from reflectivity and ellipsometry measurements for series of compositions, $0\leq x\leq 1$. The interband part of $σ_{1}(ω) $ shifts continuously to higher frequency as Ca-content $x$ increases. Also the intraband spectral weight of $σ_{1}(ω)$ decreases rapidly and essentially vanishes for $x\geq x_{c}=0.35$. These results show that the valence band and the conduction band of Eu$_{1-x}$Ca$_{x}$B$_{6}$ move away from each other such that their band overlap decreases with increasing Ca-substitution. As a result, the electronic state evolves from the semimetallic structure of EuB$_{6}$ to the insulating CaB$_{6}$ where the two bands are separated to open a finite gap ($\simeq 0.25$ eV) at the X-point of the Brillouin zone.

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Infrared Properties of Electron Doped Cuprates: Tracking Normal State Gaps and Quantum Critical Behavior in Pr(2-x)Ce(x)CuO(4)

We report the temperature dependence of the infrared-visible conductivity of Pr(2-x)Ce(x)CuO(4) thin films. When varying the doping from a non-superconducting film (x = 0.11) to a superconducting overdoped film (x = 0.17), we observe, up to optimal doping (x = 0.15), a partial gap opening. A model combining a spin density wave gap and a frequency and temperature dependent self energy reproduces our data reasonably well. The magnitude of this gap extrapolates to zero for x ~ 0.17 indicating the coexistence of magnetism and superconductivity in this material and the existence of a quantum critical point at this Ce concentration.

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Infrared Signature of the Superconducting State in Pr(2-x)Ce(x)CuO(4)

We measured the far infrared reflectivity of two superconducting Pr(2-x)Ce(x)CuO(4) films above and below Tc. The reflectivity in the superconducting state increases and the optical conductivity drops at low energies, in agreement with the opening of a (possibly) anisotropic superconducting gap. The maximum energy of the gap scales roughly with Tc as 2 Delta_{max} / kB Tc ~ 4.7. We determined absolute values of the penetration depth at 5 K as lambda_{ab} = (3300 +/- 700) A for x = 0.15 and lambda_{ab} = (2000 +/- 300) A for x = 0.17. A spectral weight analysis shows that the Ferrell-Glover-Tinkham sum rule is satisfied at conventional low energy scales \~ 4 Delta_{max}.

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Optical properties of (Pr,Ce)2CuO4

We studied the optical conductivity of electron doped Pr{1-x)Ce(x)CuO(4) from the underdoped to the overdoped regime. The observation of low to high frequency spectral weight transfer reveals the presence of a gap, except in the overdoped regime. A Drude peak at all temperatures shows the partial nature of this gap. The close proximity of the doping at which the gap vanishes to the antiferromagnetic phase boundary leads us to assign this partial gap to a spin density wave.

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Universal scaling relation in high-temperature superconductors

Scaling laws express a systematic and universal simplicity among complex systems in nature. For example, such laws are of enormous significance in biology. Scaling relations are also important in the physical sciences. The seminal 1986 discovery of high transition-temperature (high-T_c) superconductivity in cuprate materials has sparked an intensive investigation of these and related complex oxides, yet the mechanism for superconductivity is still not agreed upon. In addition, no universal scaling law involving such fundamental properties as T_c and the superfluid density ρ_s, a quantity indicative of the number of charge carriers in the superconducting state, has been discovered. Here we demonstrate that the scaling relation ρ_s \propto σ_{dc} T_c, where the conductivity σ_{dc} characterizes the unidirectional, constant flow of electric charge carriers just above T_c, universally holds for a wide variety of materials and doping levels. This surprising unifying observation is likely to have important consequences for theories of high-T_c superconductivity.

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Doping of a One-Dimensional Mott Insulator: Photoemision and Optical Studies of Sr$_2$CuO$_{3+δ}$

The spectral properties of a one-dimensional (1D) single-chain Mott insulator Sr$_2$CuO$_{3}$ have been studied in angle-resolved photoemission and optical spectroscopy, at half filling and with small concentrations of extra charge doped into the chains via high oxygen pressure growth. The single- particle gap is reduced with oxygen doping, but the metallic state is not reached. The bandwidth of the charge-transfer band increases with doping, while the state becomes narrower, allowing unambiguous observation of separated spinon and holon branches in the doped system. The optical gap is not changed upon doping, indicating that a shift of chemical potential rather than decrease of corelation gap is responsible for the apparent reduction of the photoemission gap.

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Pressure induced suppression of the singlet insulator phase in BaVS$_3$: infrared optical study

The metal-insulator (MI) transition in BaVS$_3$ has been studied at ambient pressure and under hydrostatic pressure up to $p=26 $kbar in the frequency range of $20-3000 $cm$^{-1}$. The charge gap determined from the optical reflectivity is enhanced, $Δ_{ch}(p)/k_BT_{MI}(p)\sim 12$. This ratio is independent of pressure indicating that the character of the transition does not vary along the $p-T$ phase boundary. Above the critical pressure, $p_{cr}\sim20$ kbar, metallic spectra were recorded in the whole temperature range, as expected from the shape of the phase diagram. Our results exclude the opening of a pseudogap above $T_{MI}$ at any pressure. Below $T_{MI}$ an unusually strong temperature dependence of the charge gap was observed, resulting in a $Δ_{ch}(T)$ deviating strongly from the mean field-like variation of the structural order parameter.

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Sum rules and energy scales in the high-temperature superconductor YBa2Cu3O6+x

The Ferrell-Glover-Tinkham (FGT) sum rule has been applied to the temperature dependence of the in-plane optical conductivity of optimally-doped YBa_2Cu_3O_{6.95} and underdoped YBa_2Cu_3O_{6.60}. Within the accuracy of the experiment, the sum rule is obeyed in both materials. However, the energy scale ω_c required to recover the full strength of the superfluid ρ_s in the two materials is dramatically different; ω_c \simeq 800 cm^{-1} in the optimally doped system (close to twice the maximum of the superconducting gap, 2Δ_0), but ω_c \gtrsim 5000 cm^{-1} in the underdoped system. In both materials, the normal-state scattering rate close to the critical temperature is small, Γ< 2Δ_0, so that the materials are not in the dirty limit and the relevant energy scale for ρ_s in a BCS material should be twice the energy gap. The FGT sum rule in the optimally-doped material suggests that the majority of the spectral weight of the condensate comes from energies below 2Δ_0, which is consistent with a BCS material in which the condensate originates from a Fermi liquid normal state. In the underdoped material the larger energy scale may be a result of the non-Fermi liquid nature of the normal state. The dramatically different energy scales suggest that the nature of the normal state creates specific conditions for observing the different aspects of what is presumably a central mechanism for superconductivity in these materials.

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