arXiv subjects

C. Capan

Publications and source records attributed to C. Capan.

At least 19 recordsLinked to original sources

arXiv2019

Site Specific Knight Shift Measurements of the Dilute Kondo lattice System Ce$_{1-x}$La$_x$CoIn$_5$

$^{115}$In Nuclear magnetic resonance data are presented for a series of Ce$_{1-x}$La$_x$CoIn$_5$ crystals with different La dilutions, $x$. Multiple In(1) sites associated with different numbers of nearest-neighbor cerium atoms exhibit different Knight shifts and spin lattice relaxation rates. Analysis of the temperature dependence of these sites reveals both an evolution of the heavy electron coherence as a function of dilution, as well as spatial inhomogeneity associated with a complete suppression of antiferromagnetic fluctuations in the vicinity of the La sites. Quantum critical fluctuations persist within disconnected Ce clusters with dilution levels up to 75%, despite the fact that specific heat shows Fermi liquid behavior in dilute samples.

cond-mat.str-el↗

arXiv2015

Tuning electronic correlations in transition metal pnictides: chemistry beyond the valence count

The effects of electron-electron correlations on the low-energy electronic structure and their relationship with unconventional superconductivity are central aspects in the research on the iron-based pnictide superconductors. Here we use soft X-ray angle-resolved photoemission spectroscopy (SX-ARPES) to study how electronic correlations evolve in different chemically substituted iron pnictides. We find that correlations are intrinsically related to the effective filling of the correlated orbitals, rather than to the filling obtained by valence counting. Combined density functional theory (DFT) and dynamical mean-field theory (DMFT) calculations capture these effects, reproducing the experimentally observed trend in the correlation strength. The occupation-driven trend in the electronic correlation reported in our work supports the recently proposed connection between cuprate and pnictides phase diagrams.

cond-mat.supr-con↗

arXiv2014

Magnetic, thermodynamic, and electrical transport properties of the noncentrosymmetric B20 germanides MnGe and CoGe

We present magnetization, specific heat, resistivity, and Hall effect measurements on the cubic B20 phase of MnGe and CoGe and compare to measurements of isostructural FeGe and electronic structure calculations. In MnGe, we observe a transition to a magnetic state at $T_c=275$ K as identified by a sharp peak in the ac magnetic susceptibility, as well as second phase transition at lower temperature that becomes apparent only at finite magnetic field. We discover two phase transitions in the specific heat at temperatures much below the Curie temperature one of which we associate with changes to the magnetic structure. A magnetic field reduces the temperature of this transition which corresponds closely to the sharp peak observed in the ac susceptibility at fields above 5 kOe. The second of these transitions is not affected by the application of field and has no signature in the magnetic properties or our crystal structure parameters. Transport measurements indicate that MnGe is metal with a negative magnetoresistance similar to that seen in isostructural FeGe and MnSi. Hall effect measurements reveal a carrier concentration of about 0.5 carriers per formula unit also similar to that found in FeGe and MnSi. CoGe is shown to be a low carrier density metal with a very small, nearly temperature independent diamagnetic susceptibility.

cond-mat.str-el↗

arXiv2014

Fermi-surface topology of the iron pnictide LaFe$_2$P$_2$

We report on a comprehensive de Haas--van Alphen (dHvA) study of the iron pnictide LaFe$_2$P$_2$. Our extensive density-functional band-structure calculations can well explain the measured angular-dependent dHvA frequencies. As salient feature, we observe only one quasi-two-dimensional Fermi-surface sheet, i.e., a hole-like Fermi-surface cylinder around $Γ$, essential for $s_\pm$ pairing, is missing. In spite of considerable mass enhancements due to many-body effects, LaFe$_2$P$_2$ shows no superconductivity. This is likely caused by the absence of any nesting between electron and hole bands.

cond-mat.supr-con↗

arXiv2013

Angle-resolved photoemission spectroscopy observation of anomalous electronic states in EuFe$_2$As$_{2-x}$P$_x$

We used angle-resolved photoemission spectroscopy to investigate the electronic structure of EuFe$_2$As$_2$, EuFe$_2$As$_{1.4}$P$_{0.6}$ and EuFe$_2$P$_2$. We observed doubled core level peaks associated to the pnictide atoms, which are related to a surface state. Nevertheless, strong electronic dispersion along the $c$ axis, especially pronounced in EuFe$_2$P$_2$, is observed for at less one band, thus indicated that the Fe states, albeit probably affected at the surface, do not form pure two-dimensional surface states. However, this latter material shows reduced spectral weight near the Fermi level as compared to EuFe$_2$As$_2$ and EuFe$_2$As$_{1.4}$P$_{0.6}$. An anomalous jump is also found in the electronic states associated with the Eu$^{2+}$ $f$ states in EuFe$_2$P$_2$.

cond-mat.supr-con↗

arXiv2011

Electronic inhomogeneity in a Kondo lattice

Inhomogeneous electronic states resulting from entangled spin, charge, and lattice degrees of freedom are hallmarks of strongly correlated electron materials; such behavior has been observed in many classes of d-electron materials, including the high-Tc copper-oxide superconductors, manganites, and most recently the iron-pnictide superconductors. The complexity generated by competing phases in these materials constitutes a considerable theoretical challenge-one that still defies a complete description. Here, we report a new manifestation of electronic inhomogeneity in a strongly correlated f-electron system, using CeCoIn5 as an example. A thermodynamic analysis of its superconductivity, combined with nuclear quadrupole resonance measurements, shows that nonmagnetic impurities (Y, La, Yb, Th, Hg and Sn) locally suppress unconventional superconductivity, generating an inhomogeneous electronic "Swiss cheese" due to disrupted periodicity of the Kondo lattice. Our analysis may be generalized to include related systems, suggesting that electronic inhomogeneity should be considered broadly in Kondo lattice materials.

cond-mat.str-el↗

arXiv2010

Wilson ratio in Yb-substituted CeCoIn5

We have investigated the effect of Yb substitution on the Pauli limited, heavy fermion superconductor, CeCoIn$_5$. Yb acts as a non-magnetic divalent substituent for Ce throughout the entire doping range, equivalent to hole doping on the rare earth site. We found that the upper critical field in (Ce,Yb)CoIn$_5$ is Pauli limited, yet the reduced (H,T) phase diagram is insensitive to disorder, as expected in the purely orbitally limited case. We use the Pauli limiting field, the superconducting condensation energy and the electronic specific heat coefficient to determine the Wilson ratio ($R_{W}$), the ratio of the specific heat coefficient to the Pauli susceptibility in CeCoIn$_5$. The method is applicable to any Pauli limited superconductor in the clean limit.

cond-mat.str-el↗

arXiv2010

Unusual metamagnetism in CeIrIn$_5$

We report a high field investigation (up to 45 T) of the metamagnetic transition in CeIrIn$_5$ with resistivity and de-Haas-van-Alphen (dHvA) effect measurements in the temperature range 0.03-1 K. As the magnetic field is increased the resistivity increases, reaches a maximum at the metamagnetic critical field, and falls precipitously for fields just above the transition, while the amplitude of all measurable dHvA frequencies are significantly attenuated near the metamagnetic critical field. However, the dHvA frequencies and cyclotron masses are not substantially altered by the transition. In the low field state, the resistivity is observed to increase toward low temperatures in a singular fashion, a behavior that is rapidly suppressed above the transition. Instead, in the high field state, the resistivity monotonically increases with temperature with a dependence that is more singular than the iconic Fermi-liquid, temperature-squared, behavior. Both the damping of the dHvA amplitudes and the increased resistivity near the metamagnetic critical field indicate an increased scattering rate for charge carriers consistent with critical fluctuation scattering in proximity to a phase transition. The dHvA amplitudes do not uniformly recover above the critical field, with some hole-like orbits being entirely suppressed at high fields. These changes, taken as a whole, suggest that the metamagnetic transition in CeIrIn$_5$ is associated with the polarization and localization of the heaviest of quasiparticles on the hole-like Fermi surface.

cond-mat.str-el↗

arXiv2010

Magnetic, thermal and transport properties of Cd doped CeIn$_3$

We have investigated the effect of Cd substitution on the archetypal heavy fermion antiferromagnet CeIn$_3$ via magnetic susceptibility, specific heat and resistivity measurements. The suppression of the Neel temperature, T$_{N}$, with Cd doping is more pronounced than with Sn. Nevertheless, a doping induced quantum critical point does not appear to be achievable in this system. The magnetic entropy at $T_N$ and the temperature of the maximum in resistivity are also systematically suppressed with Cd, while the effective moment and the Curie-Weiss temperature in the paramagnetic state are not affected. These results suggest that Cd locally disrupts the AFM order on its neighboring Ce moments, without affecting the valence of Ce. Moreover, the temperature dependence of the specific heat below $T_N$ is not consistent with 3D magnons in pure as well as in Cd-doped CeIn$_3$, a point that has been missed in previous investigations of CeIn$_3$ and that has bearing on the type of quantum criticality in this system.

cond-mat.str-el↗

arXiv2010

Fermi surface evolution through a heavy fermion superconductor-to-antiferromagnet transition: de Haas-van Alphen effect in Cd-substituted CeCoIn$_5$

We report the results of de-Haas-van-Alphen (dHvA) measurements in Cd doped CeCoIn$_5$ and LaCoIn$_5$. Cd doping is known to induce an antiferromagnetic order in the heavy fermion superconductor CeCoIn$_5$, whose effect can be reversed with applied pressure. We find a slight but systematic change of the dHvA frequencies with Cd doping in both compounds, reflecting the chemical potential shift due to the addition of holes. The frequencies and effective masses are close to those found in the nominally pure compounds with similar changes apparent in the Ce and La compounds with Cd substitution. We observe no abrupt changes to the Fermi surface in the high field paramagnetic state for $x \sim x_c$ corresponding to the onset of antiferromagnetic ordering at H=0 in CeCo(In$_{1-x}$Cd$_x$)$_5$. Our results rule out $f-$electron localization as the mechanism for the tuning of the ground state in CeCoIn$_5$ with Cd doping.

cond-mat.str-el↗

arXiv2009

Superconductivity without Fe or Ni in the phosphides BaIr2P2 and BaRh2P2

Heat capacity, resistivity, and magnetic susceptibility measurements confirm bulk superconductivity in single crystals of BaIr$_2$P$_2$ (T$_c$=2.1K) and BaRh$_2$P$_2$ (T$_c$ = 1.0 K). These compounds form in the ThCr$_2$Si$_2$ (122) structure so they are isostructural to both the Ni and Fe pnictides but not isoelectronic to either of them. This illustrates the importance of structure for the occurrence of superconductivity in the 122 pnictides. Additionally, a comparison between these and other ternary phosphide superconductors suggests that the lack of interlayer $P-P$ bonding favors superconductivity. These stoichiometric and ambient pressure superconductors offer an ideal playground to investigate the role of structure for the mechanism of superconductivity in the absence of magnetism.

cond-mat.supr-con↗

arXiv2009

Local structure and site occupancy of Cd and Hg substitutions in CeTIn5 (T=Co, Rh, Ir)

The CeTIn5 superconductors (T=Co, Rh, or Ir) have generated great interest due to their relatively Tc's, NFL behavior, and their proximity to AF order and quantum critical points. In contrast to small changes with the T-species, electron doping in CeT(In{1-x}Mx)5 with M=Sn and hole doping with Cd or Hg have a dramatic effect on the electronic properties at very low concentrations. The present work reports EXAFS measurements that address the substituent atom distribution as a function of T, M, and x, near the superconducting phase. Together with previous measurements for M=Sn, the proportion of the M atom residing on the In(1) site, f{In(1)}, increases in the order M=Cd, Sn, and Hg, ranging from about 40% to 70%, showing a strong preference for these substituents to occupy the In(1) site (random=20%). In addition, f{In(1)} ranges from 70% to 100% for M=Hg in the order T=Co, Rh, and Ir. These fractions track the changes in the atomic radii of the various species, and help explain the sharp dependence of Tc on substituting into the In site. However, it is difficult to reconcile the small concentrations of M with the dramatic changes in the ground state in the hole-doped materials with only an impurity scattering model. These results therefore indicate that while such substitutions have interesting local atomic structures with important electronic and magnetic consequences, other local changes in the electronic and magnetic structure are equally important in determining the bulk properties of these materials.

cond-mat.str-el↗

arXiv2008

The role of f -electrons in the Fermi surface of the heavy fermion superconductor beta-YbAlB4

We present a detailed quantum oscillation study of the Fermi surface of the recently discovered Yb-based heavy fermion superconductor beta-YbAlB4 . We compare the data, obtained at fields from 10 to 45 Tesla, to band structure calculations performed using the local density approximation. Analysis of the data suggests that f-holes participate in the Fermi surface up to the highest magnetic fields studied. We comment on the significance of these findings for the unconventional superconducting properties of this material.

cond-mat.str-el↗

arXiv2006

Magnetic Excitations of the 2-D Sm Spin Layers in Sm(La,Sr)CuO4

We present specific heat and susceptibility data on Sm(La,Sr)CuO4 in magnetic fields up to 9 T and temperatures down to 100 mK. We find a broad peak in specific heat which is insensitive to magnetic field at a temperature of 1.5 K with a value of 2.65 J/mol K. The magnetic susceptibility at 5 T continues to increase down to 2 K, the lowest temperature measured. The data suggest that the Sm spin system may be an ideal realization of the frustrated Heisenberg antiferromagnet on the square lattice.

cond-mat.str-el↗

arXiv2006

Pressure Study of Quantum Criticality in CeCoIn5

We report resistivity measurements in the normal state of CeCoIn5 down to 40 mK and simultaneously in magnetic fields up to 9 T in the [001] crystallographic direction and under pressures up to 1.3 GPa. At ambient pressure the data are consistent with a field tuned quantum critical point coincident with the superconducting upper critical field H_{c2}, as observed previously. We find that with increasing pressure the quantum critical point moves inside the superconducting dome to lower fields. Thus, we can rule out that superconductivity is directly responsible for the non-Fermi liquid behavior in CeCoIn5. Instead, the data point toward an antiferromagnetic quantum critical point scenario.

cond-mat.str-el↗

arXiv2005

c-axis magnetotransport in CeCoIn$_{5}$

We present the results of out-of-plane electrical transport measurements on the heavy fermion superconductor CeCoIn$_{5}$ at temperatures from 40 mK to 400 K and in magnetic field up to 9 T. For $T <$ 10 K transport measurements show that the zero-field resistivity $ρ_{c}$ changes linearly with temperature and extrapolates nearly to zero at 0 K, indicative of non-Fermi-liquid (nFL) behavior associated with a quantum critical point (QCP). The longitudinal magnetoresistance (LMR) of CeCoIn$_{5}$ for fields applied parallel to the c-axis is negative and scales as $B/(T+T^{*})$ between 50 and 100 K, revealing the presence of a single-impurity Kondo energy scale $T^{*} \sim 2$ K. Beginning at 16 K a small positive LMR feature is evident for fields less than 3 tesla that grows in magnitude with decreasing temperature. For higher fields the LMR is negative and increases in magnitude with decreasing temperature. This sizable negative magnetoresistance scales as $B{^2}/T$ from 2.6 K to roughly 8 K, and it arises from an extrapolated residual resistivity that becomes negative and grows quadratically with field in the nFL temperature regime. Applying a magnetic field along the c-axis with B $>$ B$_{c2}$ restores Fermi-liquid behavior in $ρ_{c}(T)$ at $T$ less than 130 mK. Analysis of the $T{^2}$ resistivity coefficient's field-dependence suggests that the QCP in CeCoIn$_{5}$ is located \emph{below} the upper critical field, inside the superconducting phase. These data indicate that while high-$T$ c-axis transport of CeCoIn$_{5}$ exhibits features typical for a heavy fermion system, low-$T$ transport is governed both by spin fluctuations associated with the QCP and Kondo interactions that are influenced by the underlying complex electronic structure intrinsic to the anisotropic CeCoIn$_{5}$ crystal structure.

cond-mat.str-el↗

arXiv2004

Field-Tuned Quantum Critical Point in CeCoIn$_5$ Near the Superconducting Upper Critical Field

We report a systematic study of high magnetic field specific heat and resistivity in single crystals of CeCoIn_5 for the field oriented in the basal plane (H//ab) of this tetragonal heavy fermion superconductor. We observe a divergent electronic specific heat as well as an enhanced A coefficient of the T^{2} law in resistivity at the lowest temperatures, as the field approaches the upper critical field of the superconducting transition. Together with the results for field along the tetragonal axis (H//c), the emergent picture is that of a magnetic field tuned quantum critical point which exists in the vicinity of the superconducting H_{c2} despite a variation of a factor of 2.4 in H_{c2} for different field orientations. This suggests an underlying physical reason exists for the superconducting H_{c2} to coincide with the quantum critical field. Moreover, we show that the recovery of a Fermi Liquid ground state with increasing magnetic field is more gradual, meaning that the fluctuations responsible for the observed quantum critical phenomena are more robust with respect to magnetic field, when the magnetic field is applied in-plane. Together with the close proximity of the quantum critical point and H_{c2} in CeCoIn_5 for both field orientation, the anisotropy in the recovery of the Fermi liquid state might constitute an important piece of information in identifying the nature of the fluctuations that become critical.

cond-mat.str-el↗

arXiv2004

Superconductivity in CeCoIn5-xSnx: Veil Over an Ordered State or Novel Quantum Critical Point?

Measurements of specific heat and electrical resistivity in magnetic fields up to 9 T along [001] and temperatures down to 50 mK of Sn-substituted CeCoIn5 are reported. The maximal -ln(T) divergence of the specific heat at the upper critical field H_{c2} down to the lowest temperature characteristic of non-Fermi liquid systems at the quantum critical point (QCP), the universal scaling of the Sommerfeld coefficient, and agreement of the data with spin-fluctuation theory, provide strong evidence for quantum criticality at H_{c2} for all x < 0.12 in CeCoIn5-xSnx. These results indicate the "accidental" coincidence of the QCP located near H_{c2} in pure CeCoIn5, in actuality, constitute a novel quantum critical point associated with unconventional superconductivity.

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