arXiv subjects

C. Castelnovo

Publications and source records attributed to C. Castelnovo.

17 recordsLinked to original sources

arXiv2025

Intrinsic disorder in the candidate quantum spin ice Pr$_2$Zr$_2$O$_7$

Quantum spin liquids with long-range entanglement are of great interest for applications in quantum technology. The quantum spin ice Pr$_2$Zr$_2$O$_7$ is a promising example, where it is believed that structural disorder plays a key role in enhancing quantum mechanical effects by introducing strains that split the ground state doublet akin to the effect of a local disordered transverse field. However, the precise defect structure responsible for this behaviour is unknown. Here we have determined the intrinsic defect structure of Pr$_2$Zr$_2$O$_7$ using neutron and x-ray scattering techniques supported by density functional theory. We find the main defect is the stuffing of Zr$^{4+}$ sites by Pr$^{3+}$ ions, accompanied by charge compensating O$^{2-}$ vacancies, and the relaxation of a neighbouring O$^{2-}$ ion to an interstitial site. Our results explain the single-ion magnetism by considering the non-magnetic singlets that arise on neighbouring sites as a result of the defect structure. These singlets account for additional features in the crystal electric field excitations. The effects caused by this low level of structural disorder are magnified since several neighbouring Pr sites are affected. This makes a significant contribution towards the observed broadening of pinch points in the magnetic diffuse scattering, which was previously attributed purely to quantum effects.

cond-mat.str-el↗

arXiv2024

Magnetotransport of single crystal Sm$_2$Ir$_2$O$_7$ across the pressure-induced quantum-critical phase boundary

Rare-earth pyrochlore iridates host two interlocking magnetic sublattices of corner-sharing tetrahedra and can harbour a unique combination of frustrated moments, exotic excitations and highly correlated electrons. They are also the first systems predicted to display both topological Weyl semimetal and axion insulator phases. We have measured the transport and magnetotransport properties of single-crystal Sm$_2$Ir$_2$O$_7$ up to and beyond the pressure-induced quantum critical point for all-in-all-out (AIAO) Ir order at $p_{\rm c}$ = 63 kbar previously identified by resonant X-ray scattering and close to which Weyl semimetallic behavior has been previously predicted. Our findings overturn the accepted expectation that the suppression of AIAO order should lead to metallic conduction persisting down to zero temperature. Instead, the resistivity-minimum temperature, which tracks the decrease in the AIAO ordering temperature for pressures up to 30~kbar, begins to increase under further application of pressure, pointing to the presence of a second as-yet unidentified mechanism leading to non-metallic behavior. The magnetotransport does track the suppression of Ir magnetism, however, with a strong hysteresis observed only within the AIAO phase boundary, similar to that found for Ho$_2$Ir$_2$O$_7$ and attributed to plastic deformation of Ir domains. Around $p_{\rm c}$ we find the emergence of a new type of electronic phase, characterized by a negative magnetoresistance with small hysteresis at the lowest temperatures, and hysteresis-free positive magnetoresistance above approximately 5 K. The temperature dependence of our low-temperature transport data are found to be best described by a model consistent with a Weyl semimetal across the entire pressure range.

cond-mat.str-el↗

arXiv2021

Monopole density and antiferromagnetic domain control in spin-ice iridates

Frustration in magnetic systems is fertile ground for complex behaviour, including unconventional ground states with emergent symmetries, topological properties, and exotic excitations. A canonical example is the emergence of magnetic-charge-carrying quasiparticles in spin-ice compounds. Despite extensive work, a reliable experimental indicator of the density of these magnetic monopoles in spin-ice systems is yet to be found. Here, using measurements on single crystals of Ho$_{2}$Ir$_{2}$O$_{7}$ in combination with dipolar Monte Carlo simulations, we show that the magnetoresistance is highly sensitive to the density of monopoles. Moreover, we find that for the orientations of magnetic field in which the monopole density is enhanced, a strong coupling emerges between the magnetic charges on the holmium sublattice and the antiferromagnetically ordered iridium ions, leading to an ability to manipulate the antiferromagnetic domains via a uniform external field. Our results pave the way to a quantitative experimental measure of monopole density and provide a powerful illustration of the interplay between the various magnetic and electronic degrees of freedom in the frustrated pyrochlore iridates. This interdependence holds promise for potential functional properties arising from the link between magnetic and electric charges, as well as for the control of antiferromagnetic domain walls, a key goal in the design of next-generation spintronic devices.

cond-mat.str-el↗

arXiv2019

Role of defects in determining the magnetic ground state of ytterbium titanate

Pyrochlore systems are ideally suited to the exploration of geometrical frustration in three dimensions, and their rich phenomenology encompasses topological order and fractional excitations. Classical spin ices provide the first context in which it is possible to control emergent magnetic monopoles, and anisotropic exchange leads to even richer behaviour associated with large quantum fluctuations. Whether the magnetic ground state of Yb2Ti2O7 is a quantum spin liquid or a ferromagnetic phase induced by a Higgs transition appears to be sample dependent. Here we have determined the role of structural defects on the magnetic ground state via the diffuse scattering of neutrons. We find that oxygen vacancies stabilise the spin liquid phase and the stuffing of Ti sites by Yb suppresses it. Samples in which the oxygen vacancies have been eliminated by annealing in oxygen exhibit a transition to a ferromagnetic phase, and this is the true magnetic ground state.

cond-mat.str-el↗

arXiv2016

Semi-classical Approach to Quantum Spin Ice

We propose a semi-classical description of the low-energy properties of quantum spin ice in the strong Ising limit. Within the framework of a semiclassical, perturbative Villain expansion, that can be truncated at arbitrary order, we give an analytic and quantitative treatment of the deconfining phase. We find that photon-photon interactions significantly renormalise the speed of light and split the two transverse photon polarisations at intermediate wavevectors. We calculate the photon velocity and the ground state energy to first and second order in perturbation theory, respectively. The former is in good agreement with recent numerical simulations.

cond-mat.str-el↗

arXiv2015

Vacancy defects and monopole dynamics in oxygen-deficient pyrochlores

The idea of magnetic monopoles in spin ice has enjoyed much success at intermediate temperatures, but at low temperatures a description in terms of monopole dynamics alone is insufficient. Recently, numerical simulations were used to argue that magnetic impurities account for this discrepancy by introducing a magnetic equivalent of residual resistance in the system. Here we propose that oxygen deficiency is the leading cause of magnetic impurities in as-grown samples, and we determine the defect structure and magnetism in Y2Ti2O(7-δ) using diffuse neutron scattering and magnetization measurements. These defects are eliminated by oxygen annealing. The introduction of oxygen vacancies causes Ti4+ to transform to magnetic Ti3+ with quenched orbital magnetism, but the concentration is anomalously low. In the spin-ice material Dy2Ti2O7 we find that the same oxygen-vacancy defects suppress moments on neighbouring rare-earth sites, and that these magnetic distortions dramatically slow down the long-time monopole dynamics at sub-Kelvin temperatures.

cond-mat.str-el↗

arXiv2012

High temperature onset of field-induced transitions in the spin-ice compound Dy2Ti2O7

We have studied the field-dependent ac magnetic susceptibility of single crystals of Dy2Ti2O7 spin ice along the [111] direction in the temperature range 1.8 K - 7 K. Our data reflect the onset of local spin ice order in the appearance of different field regimes. In particular, we observe a prominent feature at approximately 1.0 T that is a precursor of the low-temperature metamagnetic transition out of field-induced kagome ice, below which the kinetic constraints imposed by the ice rules manifest themselves in a substantial frequency-dependence of the susceptibility. Despite the relatively high temperatures, our results are consistent with a monopole picture, and they demonstrate that such a picture can give physical insight to the spin ice systems even outside the low-temperature, low-density limit where monopole excitations are well-defined quasiparticles.

cond-mat.str-el↗

arXiv2012

A field trip through spin ice

Fractionalisation -- the breaking up of an apparently indivisible microscopic degree of freedom -- is one of the most counterintuitive phenomena in many-body physics. Here we study its most fundamental manifestation in spin ice, the only known fractionalised magnetic compound in 3D: we directly visualise the $1/r^2$ magnetic Coulomb field of monopoles which emerge as the atomic magnetic dipoles fractionalise. We analyse the internal magnetic field distribution, relevant for local experimental probes. In particular, we present new zero-field NMR measurements which exhibit excellent agreement with the calculated lineshapes, noting that this experimental technique can in principle measure directly the monopole density in spin ice. The distribution of field strengths is captured by a simple analytical form which exhibits a low density of low-field sites---in apparent disagreement with reported $μ$SR results. Counterintuitively, the density of low-field locations decreases as the local ferromagnetic correlations imposed by the ice rules weaken.

cond-mat.str-el↗

arXiv2011

Spin Ice, Fractionalization and Topological Order

The spin ice compounds {\dys} and {\holm} are highly unusual magnets which epitomize a set of concepts of great interest in modern condensed matter physics: their low-energy physics exhibits an emergent gauge field and their excitations are magnetic monopoles which arise from the fractionalization of the microscopic magnetic spin degrees of freedom. In this review, we provide an elementary introduction to these concepts and we survey the thermodynamics, statics and dynamics---in and out of equilibrium---of spin ice from these vantage points. Along the way, we touch on topics such as emergent Coulomb plasmas, observable "Dirac strings", and irrational charges. We close with the outlook for these unique materials.

cond-mat.str-el↗

arXiv2011

Interplay of Topological Order and Spin Glassiness in the Toric Code under Random Magnetic Fields

We analyze the toric code model in the presence of quenched disorder, which is introduced via different types of random magnetic fields. In general, close to a quantum phase transition between a spin polarized phase and a topologically ordered one, we find that increasing the amount of disorder favors the topological phase. For some realizations of disorder, topological order can be robust against arbitrarily strong magnetic fields. In the case of the toric code in a random \pm h field, we show that the system exhibits a quantum phase transition to a spin glass phase in an appropriate dual variables description. The survival of topological order in the spin glass phase is directly related to the percolation properties of the rigid lattice in the Edwards-Anderson bimodal spin glass model. According to recent numerical results for this model [Phys. Rev. B 82, 214401 (2010)], it is likely that the rigid lattice does not percolate and, as a result, a new intermediate quantum phase appears in the random-field toric code. In this intermediate quantum phase, topological order coexists with spin glassiness.

quant-ph↗

arXiv2010

Dirac Strings and Magnetic Monopoles in Spin Ice Dy2Ti2O7

While sources of magnetic fields - magnetic monopoles - have so far proven elusive as elementary particles, several scenarios have been proposed recently in condensed matter physics of emergent quasiparticles resembling monopoles. A particularly simple proposition pertains to spin ice on the highly frustrated pyrochlore lattice. The spin ice state is argued to be well-described by networks of aligned dipoles resembling solenoidal tubes - classical, and observable, versions of a Dirac string. Where these tubes end, the resulting defect looks like a magnetic monopole. We demonstrate, by diffuse neutron scattering, the presence of such strings in the spin-ice Dy2Ti2O7. This is achieved by applying a symmetry-breaking magnetic field with which we can manipulate density and orientation of the strings. In turn, heat capacity is described by a gas of magnetic monopoles interacting via a magnetic Coulomb interaction.

cond-mat.mtrl-sci↗

arXiv2010

Unconventional magnetization processes and thermal runaway in spin-ice Dy$_2$Ti$_2$O$_7$

We investigate the non-equilibrium behavior of the spin-ice material Dy$_2$Ti$_2$O$_7$ by studying its magnetization as a function of the rate at which an external field is swept. At temperatures below the enigmatic "freezing" temperature $T_{\rm equil}\approx600$ mK, we find that even the slowest sweeps fail to yield the equilibrium magnetization curve and instead give a smooth, initially much flatter curve. For higher sweep rates, the magnetization develops sharp steps accompanied by similarly sharp peaks in the temperature of the sample. We ascribe the former behavior to the energy barriers encountered in the magnetization process, which proceeds via flipping of spins on filaments traced out by the field-driven motion of the gapped, long-range interacting magnetic monopole excitations. In contrast, the peaks in temperature result from the released Zeeman energy not being carried away efficiently into the bath, with the resulting heating triggering a chain reaction.

cond-mat.mtrl-sci↗

arXiv2010

Thermal quenches in spin ice

We study the diffusion annihilation process which occurs when spin ice is quenched from a high temperature paramagnetic phase deep into the spin ice regime, where the excitations -- magnetic monopoles -- are sparse. We find that due to the Coulomb interaction between the monopoles, a dynamical arrest occurs, in which `non-universal' lattice-scale constraints impede the complete decay of charge fluctuations. This phenomenon is outside the reach of universal mean-field theory for a two-component Coulomb liquid. We identify the relevant timescales for the dynamical arrest and propose an experiment for detecting monopoles and their dynamics in spin ice based on this non-equilibrium phenomenon.

cond-mat.str-el↗

arXiv2008

A quantum topological phase transition at the microscopic level

We study a quantum phase transition between a phase which is topologically ordered and one which is not. We focus on a spin model, an extension of the toric code, for which we obtain the exact ground state for all values of the coupling constant that takes the system across the phase transition. We compute the entanglement and the topological entropy of the system as a function of this coupling constant, and show that the topological entropy remains constant all the way up to the critical point, and jumps to zero beyond it. Despite the jump in the topological entropy, the transition is second order as detected via any local observable.

cond-mat.str-el↗

arXiv2007

Entanglement and topological entropy of the toric code at finite temperature

We calculate exactly the von Neumann and topological entropies of the toric code as a function of system size and temperature. We do so for systems with infinite energy scale separation between magnetic and electric excitations, so that the magnetic closed loop structure is fully preserved while the electric loop structure is tampered with by thermally excited electric charges. We find that the entanglement entropy is a singular function of temperature and system size, and that the limit of zero temperature and the limit of infinite system size do not commute. From the entanglement entropy we obtain the topological entropy, which is shown to drop to half its zero-temperature value for any infinitesimal temperature in the thermodynamic limit, and remains constant as the temperature is further increased. Such discontinuous behavior is replaced by a smooth decreasing function in finite-size systems. If the separation of energy scales in the system is large but finite, we argue that our results hold at small enough temperature and finite system size, and a second drop in the topological entropy should occur as the temperature is raised so as to disrupt the magnetic loop structure by allowing the appearance of free magnetic charges. We interpret our results as an indication that the underlying magnetic and electric closed loop structures contribute equally to the topological entropy (and therefore to the topological order) in the system. Since each loop structure \emph{per se} is a classical object, we interpret the quantum topological order in our system as arising from the ability of the two structures to be superimposed and appear simultaneously.

cond-mat.str-el↗

arXiv2005

Fractal analysis of Sampled Profiles: Systematic Study

A quantitative evaluation of the influence of sampling on the numerical fractal analysis of experimental profiles is of critical importance. Although this aspect has been widely recognized, a systematic analysis of the sampling influence is still lacking. Here we present the results of a systematic analysis of synthetic self-affine profiles in order to clarify the consequences of the application of a poor sampling (up to 1000 points) typical of Scanning Probe Microscopy for the characterization of real interfaces and surfaces. We interprete our results in term of a deviation and a dispersion of the measured exponent with respect to the ``true'' one. Both the deviation and the dispersion have always been disregarded in the experimental literature, and this can be very misleading if results obtained from poorly sampled images are presented. We provide reasonable arguments to assess the universality of these effects and we propose an empirical method to take them into account. We show that it is possible to correct the deviation of the measured Hurst exponent from the 'true' one and give a reasonable estimate of the dispersion error. The last estimate is particularly important in the experimental results since it is an intrinsic error that depends only on the number of sampling points and can easily overwhelm the statistical error. Finally, we test our empirical method calculating the Hurst exponent for the well-known 1+1 dimensional directed percolation profiles, with a 512-point sampling.

cond-mat.stat-mech↗

arXiv2003

Dynamical obstruction in a constrained system and its realization in lattices of superconducting devices

Hard constraints imposed in statistical mechanics models can lead to interesting thermodynamical behaviors, but may at the same time raise obstructions in the thoroughfare to thermal equilibration. Here we study a variant of Baxter's 3-color model in which local interactions and defects are included, and discuss its connection to triangular arrays of Josephson junctions of superconductors and \textit{kagomé} networks of superconducting wires. The model is equivalent to an Ising model in a hexagonal lattice with the constraint that the magnetization of each hexagon is $\pm 6$ or 0. For ferromagnetic interactions, we find that the system is critical for a range of temperatures (critical line) that terminates when it undergoes an exotic first order phase transition with a jump from a zero magnetization state into the fully magnetized state at finite temperature. Dynamically, however, we find that the system becomes frozen into domains. The domain walls are made of perfectly straight segments, and domain growth appears frozen within the time scales studied with Monte Carlo simulations. This dynamical obstruction has its origin in the topology of the allowed reconfigurations in phase space, which consist of updates of closed loops of spins. As a consequence of the dynamical obstruction, there exists a dynamical temperature, lower than the (avoided) static critical temperature, at which the system is seen to jump from a ``supercooled liquid'' to a ``polycrystalline'' phase. In contrast, for antiferromagnetic interactions, we argue that the system orders for infinitesimal coupling because of the constraint, and we observe no interesting dynamical effects.

cond-mat.stat-mech↗