arXiv subjects

C. Cecchi-Pestellini

Publications and source records attributed to C. Cecchi-Pestellini.

16 recordsLinked to original sources

arXiv2026

Nano-particle Transition Matrix code implementation

Electromagnetic scattering and absorption by material particles is a fundamental physical problem with a broad range of applications, going from laboratory experiments, biology and material sciences, all the way up to environmental studies and astrophysical investigations. In spite of its primary importance, an exact theoretical treatment is only possible for a limited range of ideal cases, while realistic situations require the development of numerical solutions. In the course of the years, several techniques were developed to model the effects of scattering and absorption in more general cases, using approaches such as the Discrete Dipole Approximation (DDA), the Finite Difference Time Domain (FDTD) method, the Transition Matrix formalism (T-matrix) or the Mean Field Theory (MFT). Among these possibilities, the T-matrix approach grants the highest degree of flexibility in modeling aggregates of spherically symmetric particles with arbitrary overall morphology and composition, but its application has been limited by the challenging computational requirements of the method in realistic cases. This paper describes the Nano-Particle Transition Matrix Code project (NP_TMcode), a new implementation of the T-matrix formalism that, taking advantage of high performance parallel hardware architectures, allows the solution of increasingly complex models, while substantially reducing the computing time. The paper describes the code structure, with a particular focus on the algorithm optimization, and it presents the results of the performance analysis for a set of development applications.

astro-ph.IM↗

arXiv2025

Interstellar dust as a dynamic environment

In spite of accounting for only a small fraction of the mass of the Interstellar Medium (ISM), dust plays a primary role in many physical and chemical processes in the Universe. It is the main driver of extinction of radiation in the UV/optical wavelength range and a primary source of thermal IR emission. Dust grains contain most of the refractory elements of the ISM and they host chemical processes that involve complex molecular compounds. However, observational evidence suggests that grain structure is highly non-trivial and that dust particles are characterized by granularity, asymmetry and stratification, which significantly affect their interaction with radiation fields. Accurate modeling of such interaction is fundamental to properly explain observational results, but it is a computationally demanding task. Here we present the possibility to investigate the effects of radiation/particle interactions in non-spherically symmetric conditions using a novel implementation of the Transition Matrix formalism, designed to run on scalable parallel hardware facilities.

astro-ph.GA↗

arXiv2023

EWOCS-I: The catalog of X-ray sources in Westerlund 1 from the Extended Westerlund 1 and 2 Open Clusters Survey

Context. With a mass exceeding several 10^4 solar masses and a rich and dense population of massive stars, supermassive young star clusters represent the most massive star-forming environment that is dominated by the feedback from massive stars and gravitational interactions among stars. Aims. In this paper we present the "Extended Westerlund 1 and 2 Open Clusters Survey" (EWOCS) project, which aims to investigate the influence of the starburst environment on the formation of stars and planets, and on the evolution of both low and high mass stars. The primary targets of this project are Westerlund 1 and 2, the closest supermassive star clusters to the Sun. Methods. The project is based primarily on recent observations conducted with the Chandra and JWST observatories. Specifically, the Chandra survey of Westerlund 1 consists of 36 new ACIS-I observations, nearly co-pointed, for a total exposure time of 1 Msec. Additionally, we included 8 archival Chandra/ACIS-S observations. This paper presents the resulting catalog of X-ray sources within and around Westerlund 1. Sources were detected by combining various existing methods, and photon extraction and source validation were carried out using the ACIS-Extract software. Results. The EWOCS X-ray catalog comprises 5963 validated sources out of the 9420 initially provided to ACIS-Extract, reaching a photon flux threshold of approximately 2x10^-8 photons/cm^2/s. The X-ray sources exhibit a highly concentrated spatial distribution, with 1075 sources located within the central 1 arcminute. We have successfully detected X-ray emissions from 126 out of the 166 known massive stars of the cluster, and we have collected over 71000 photons from the magnetar CXO J164710.20-455217

astro-ph.SR↗

arXiv2021

The GAPS Programme at TNG. XXXII. The revealing non-detection of metastable HeI in the atmosphere of the hot Jupiter WASP-80b

The hot Jupiter WASP-80b has been identified as a possible excellent target for detecting and measuring HeI absorption in the upper atmosphere. We observed 4 primary transits of WASP-80b in the optical and near-IR using the HARPS-N and GIANO-B high-resolution spectrographs, focusing on the HeI triplet. We further employed a three-dimensional hydrodynamic aeronomy model to understand the observational results. We did not find any signature of planetary absorption at the position of the HeI triplet with an upper limit of 0.7% (i.e. 1.11 planetary radii; 95% confidence level). We re-estimated the stellar high-energy emission that we combined with a stellar photospheric model to generate the input for the hydrodynamic modelling. We obtained that, assuming a solar He to H abundance ratio, HeI absorption should have been detected. Considering a stellar wind 25 times weaker than solar, we could reproduce the non-detection only assuming a He to H abundance ratio about 16 times smaller than solar. Instead, considering a stellar wind 10 times stronger than solar, we could reproduce the non-detection only with a He to H abundance ratio about 10 times smaller than solar. We attempted to understand this result by collecting all past HeI measurements looking for correlations with stellar high-energy emission and planetary gravity, but without finding any. WASP-80b is not the only planet with a sub-solar estimated He to H abundance ratio, suggesting the presence of efficient physical mechanisms (e.g. phase separation, magnetic fields) capable of significantly modifying the He to H content in the upper atmosphere of hot Jupiters. The planetary macroscopic properties and the shape of the stellar spectral energy distribution are not sufficient for predicting the presence or absence of detectable metastable He in a planetary atmosphere, as also the He abundance appears to play a major role.

astro-ph.EP↗

arXiv2021

Optical tweezers in a dusty universe

Optical tweezers are powerful tools based on focused laser beams. They are able to trap, manipulate and investigate a wide range of microscopic and nanoscopic particles in different media, such as liquids, air, and vacuum. Key applications of this contactless technique have been developed in many fields. Despite this progress, optical trapping applications to planetary exploration is still to be developed. Here we describe how optical tweezers can be used to trap and characterize extraterrestrial particulate matter. In particular, we exploit light scattering theory in the T-matrix formalism to calculate radiation pressure and optical trapping properties of a variety of complex particles of astrophysical interest. Our results open perspectives in the investigation of extraterrestrial particles on our planet, in controlled laboratory experiments, aiming for space tweezers applications: optical tweezers used to trap and characterize dust particles in space or on planetary bodies surface.

physics.space-ph↗

arXiv2020

A systematic study of \ce{CO2} planetary atmospheres and their link to the stellar environment

The Milky Way Galaxy is literally teeming with exoplanets; thousands of planets have been discovered, with thousands more planet candidates identified. Terrestrial-like planets are quite common around other stars, and are expected to be detected in large numbers in the future. Such planets are the primary targets in the search for potentially habitable conditions outside the solar system. Determining the atmospheric composition of exoplanets is mandatory to understand their origin and evolution, as atmospheric processes play crucial roles in many aspects of planetary architecture. In this work we construct and exploit a 1D radiative transfer model based on the discrete-ordinates method in plane-parallel geometry. Radiative results are linked to a convective flux that redistributes energy at any altitude producing atmospheric profiles in radiative-convective equilibrium. The model has been applied to a large number (6250) of closely dry synthetic \ce{CO2} atmospheres, and the resulting pressure and thermal profiles have been interpreted in terms of parameter variability. Although less accurate than 3D general circulation models, not properly accounting for e.g., clouds and atmospheric and ocean dynamics, 1D descriptions are computationally inexpensive and retain significant value by allowing multidimensional parameter sweeps with relative ease.

astro-ph.EP↗

arXiv2019

Effects of $150-1000$ eV Electron Impacts on Pure Carbon Monoxide Ices using the Interstellar Energetic-Process System (IEPS)

Pure CO ice has been irradiated with electrons of energy in the range $150-1000$~eV with the Interstellar Energetic-Process System (IEPS). The main products of irradiation are carbon chains C$_n$ ($n=3$, 5, 6, 8, 9, 10, 11, 12), suboxides, C$_n$O ($n=2$, 3, 4, 5, 6, 7), and C$_n$O$_2$ ($n=1$, 3, 4, 5, 7) species. \ce{CO2} is by far the most abundant reaction product in all the experiments. The destruction cross-section of CO peaks at about 250 eV, decreases with the energy of the electrons and is more than one order of magnitude higher than for gas-phase CO ionization. The production cross-section of carbon dioxide has been also derived and is characterized by the competition between chemistry and desorption. Desorption of CO and of new species during the radiolysis follows the electron distribution in the ice. Low energy electrons having short penetration depths induce significant desorption. Finally, as the ice thickness approaches the electron penetration depth the abundance of the products starts to saturate. Implications on the atmospheric photochemistry of cold planets hosting surface CO ices are also discussed.

astro-ph.IM↗

arXiv2019

Synthesis of complex organic molecules in soft x-ray irradiated ices

We study the chemical evolution of H2O:CO:NH3 ice mixtures irradiated with soft X-rays, in the range 250-1250 eV. We identify many nitrogen-bearing molecules such as e.g., OCN-, NH4+ , HNCO, CH3CN, HCONH2, and NH2COCONH2. Several infrared features are compatible with glycine or its isomers. During the irradiation, we detected through mass spectroscopy many species desorbing the ice. Such findings support either the infrared identifications and reveal less abundant species with not clear infrared features. Among them, m/z = 57 has been ascribed to methyl isocyanate (CH3NCO), a molecule of prebiotic relevance, recently detected in protostellar environments. During the warm up after the irradiation, several infrared features including 2168 cm-1 band of OCN-, 1690 cm-1 band of formamide, and the 1590 cm-1 band associated to three different species, HCOO-, CH3NH2 and NH3+CH2COO survive up to room temperature. Interestingly, many high masses have been also detected. Possible candidates are methyl-formate, (m/z = 60, HCOOCH3), ethanediamide (m/z = 88, NH2COCONH2), and N-acetyl-L-aspartic acid (m=z = 175). This latter species is compatible with the presence of the m/z = 43, 70 and 80 fragments. Photo-desorption of organics is relevant for the detection of such species in the gas-phase of cold environments, where organic synthesis in ice mantles should dominate. We estimate the gas-phase enrichment of some selected species in the light of a protoplanetary disc model around young solar-type stars.

astro-ph.GA↗

arXiv2018

Photo-desorption of H2O:CO:NH3 circumstellar ice analogs: Gas-phase enrichment

We study the photo-desorption occurring in H$_2$O:CO:NH$_3$ ice mixtures irradiated with monochromatic (550 and 900 eV) and broad band (250--1250 eV) soft X-rays generated at the National Synchrotron Radiation Research Center (Hsinchu, Taiwan). We detect many masses photo-desorbing, from atomic hydrogen (m/z = 1) to complex species with m/z = 69 (e.g., C$_3$H$_3$NO, C$_4$H$_5$O, C$_4$H$_7$N), supporting the enrichment of the gas phase. At low number of absorbed photons, substrate-mediated exciton-promoted desorption dominates the photo-desorption yield inducing the release of weakly bound (to the surface of the ice) species; as the number of weakly bound species declines, the photo-desorption yield decrease about one order of magnitude, until porosity effects, reducing the surface/volume ratio, produce a further drop of the yield. We derive an upper limit to the CO photo-desorption yield, that in our experiments varies from 1.4 to 0.007 molecule photon$^{-1}$ in the range $\sim 10^{15} - 10^{20}$~absorbed photons cm$^{-2}$. We apply these findings to a protoplanetary disk model irradiated by a central T~Tauri star.

astro-ph.GA↗

arXiv2016

Soft X-ray Irradiation of Silicates: Implications on Dust Evolution in Protoplanetary Disks

The processing of energetic photons on bare silicate grains was simulated experimentally on silicate films submitted to soft X-rays of energies up to 1.25 keV. The silicate material was prepared by means of a microwave assisted solgel technique. Its chemical composition reflects the Mg2SiO4 stoichiometry with residual impurities due to the synthesis method. The experiments were performed using the spherical grating monochromator beamline at the National Synchrotron Radiation Research Center in Taiwan. We found that soft X-ray irradiation induces structural changes that can be interpreted as an amorphization of the processed silicate material. The present results may have relevant implications in the evolution of silicate materials in X-ray irradiated protoplanetary disks.

astro-ph.GA↗

arXiv2015

Redshifted Diffuse Interstellar Bands in Orion OB1 association

The wavelength displacement of the Diffuse Interstellar Bands at 4502, 5705, 5780, 6284, and 7224 Å with respect to the well known, narrow atomic/molecular interstellar lines (of Ca{\sc ii} and Na{\sc i}) have been measured in the spectra of the 2 Orion Trapezium stars HD 37022 and HD 37020, using the HARPS\textendash N spectrograph, fed with the 3.5 m Telescopio Nazionale Galileo, and the BOES spectrograph, fed with the 1.8m Korean telescope. The red shift is $\sim$25 km/s for all these DIBs. We discuss the various possible origins of this very peculiar wavelength shift in the light of the particular physical conditions in the Orion Trapezium. The above mentioned shift is seemingly absent in the DIBs at 6196 and 6993 Å.

astro-ph.GA↗

arXiv2013

A radical route to interstellar propylene formation

Complex organic molecules, such as propylene (CH3CHCH2), are detected in molecular clouds (such as TMC1) with high fractional abundances (~2.10^{-9}, relative to hydrogen) that cannot be explained by gas-phase chemical reactions under normal dark cloud conditions. To obtain such high abundances requires an efficient grain-driven chemistry to be operating, coupled with effective desorption of the complex organics back into the gas-phase. We propose that the mechanism that we have previously described; rapid high density gas-phase chemistry in the gas released following sudden, total, ice mantle sublimation - can explain the high abundances, without recourse to ill-defined surface chemical pathways. Our model provides a natural explanation for why it is that some sources harbour high abundances of propylene, whilst others do not; based on the age and level of dynamical activity within the source (which affects the ice composition) and the chemical composition of the ambient gas.

astro-ph.GA↗

arXiv2013

Episodic Explosions in Interstellar Ices

We present a model for the formation of large organic molecules in dark clouds. The molecules are produced in the high density gas-phase that exists immediately after ice mantles are explosively sublimated. The explosions are initiated by the catastrophic recombination of trapped atomic hydrogen. We propose that, in molecular clouds, the processes of freeze-out onto ice mantles, accumulation of radicals, explosion and then rapid (three-body) gas-phase chemistry occurs in a cyclic fashion. This can lead to a cumulative molecular enrichment of the interstellar medium. A model of the time-dependent chemistries, based on this hypothesis, shows that significant abundances of large molecular species can be formed, although the complexity of the species is limited by the short expansion timescale in the gas, immediately following mantle explosion. We find that this mechanism may be an important source of smaller organic species, such as methanol and formaldehyde, as well as precursors to bio-molecule formation. Most significantly, we predict the gas-phase presence of these larger molecular species in quiescent molecular clouds and not just dynamically active regions, such as hot cores. As such the mechanism that we propose complements alternative methods of large molecule formation, such as those that invoke solid-state chemistry within activated ice mantles.

astro-ph.GA↗

arXiv2008

Dehydrogenated polycyclic aromatic hydrocarbons and UV bump

Recent calculations have shown that the UV bump at about 217.5 nm in the extinction curve can be explained by a complex mixture of PAHs in several charge states. Other studies proposed that the carriers are a restricted population made of neutral and singly-ionised dehydrogenated coronene molecules (C24Hn, n less than 3), in line with models of the hydrogenation state of interstellar PAHs predicting that medium-sized species are highly dehydrogenated. To assess the observational consequences of the latter hypothesis we have undertaken a systematic study of the electronic spectra of dehydrogenated PAHs. We use our first results to see whether such spectra show strong general trends upon dehydrogenation. We used state-of-the-art techniques in the framework of the density functional theory (DFT) to obtain the electronic ground-state geometries, and of the time- dependent DFT to evaluate the electronic excited-state properties. We computed the absorption cross-section of the species C24Hn (n=12,10,8,6,4,2,0) in their neutral and cationic charge-states. Similar calculations were performed for other PAHs and their fullydehydrogenated counterparts. pi electron energies are always found to be strongly affected by dehydrogenation. In all cases we examined, progressive dehydrogenation translates into a correspondingly progressive blue shift of the main electronic transitions. In particular, the pi-pi* collective resonance becomes broader and bluer with dehydrogenation. Its calculated energy position is therefore predicted to fall in the gap between the UV bump and the far-UV rise of the extinction curve. Since this effect appears to be systematic, it poses a tight observational limit on the column density of strongly dehydrogenated medium-sized PAHs.

astro-ph↗

arXiv2008

The role of the charge state of PAHs in ultraviolet extinction

Aims: We explore the relation between charge state of polycyclic aromatic hydrocarbons (PAHs) and extinction curve morphology. Methods: We fit extinction curves with a dust model including core-mantle spherical particles of mixed chemical composition (silicate core, $sp^2$ and $sp^3$ carbonaceous layers), and an additional molecular component. We use exact methods to calculate the extinction due to classical particles and accurate computed absorption spectra of PAHs in different charge states, for the contribution due to the molecular component, along a sample of five rather different lines of sight. Results: A combination of classical dust particles and mixtures of real PAHs satisfactorily matches the observed interstellar extinction curves. Variations of the spectral properties of PAHs in different charge states produce changes consistent with the varying relative strengths of the bump and non-linear far-UV rise.

astro-ph↗

arXiv2002

The Far Ultraviolet Spectroscopic picture of the Missing Baryons in the Local Group

The number of detected baryons in the low-redshift Universe (z < 1) is far small er than the corresponding number of baryons observed at higher redshift. According to hydrodynamical simulations for the formation of structure in the Universe, up to 2/3 of the 'missing baryons' may have escaped identification so far, due to their high temperature and low density. One of the few ways to detect this matter is to look for its UV absorption signature on the light from background sources. Here we show that the amplitude of the average velocity vector of 'high velocity' OVI absorbers detected in a UV survey of AGN decreases significantly in moving from the Local Standard of Rest, to the Galactic Standard of Rest and Local Group frames. At least 82 % of these absorbers are not associated with any 'high velocity' HI complex (HV-HI) in our Galaxy, and so are strongly implicated as being due to primordial Warm-Hot Intergalactic Medium (WHIM) pervading an extended Galactic Corona or our Local Group. We estimate that the total baryonic mass contained in this medium is as large as ~ 1e12 solar masses, similar to the combined mass of the two most massive virialized constituents of the Local Group (the Andromeda and the Milky Way galaxies), and of the order of the mass required to dynamically stabilize the Local Group.

astro-ph↗