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C. Codella

Publications and source records attributed to C. Codella.

At least 91 records · Page 5Linked to original sources

ALMA discovery of a rotating SO/SO$_2$ flow in HH212. A possible MHD disk wind?

We wish to constrain the possible contribution of a magnetohydrodynamic disk wind (DW) to the HH212 molecular jet. We mapped the flow base with ALMA Cycle 4 at 0.13"$\sim$ 60 au resolution and compared these observations with synthetic DW predictions. We identified, in SO/SO$_2$, a rotating flow that is wider and slower than the axial SiO jet. The broad outflow cavity seen in C$^{34}$S is not carved by a fast wide-angle wind but by this slower agent. Rotation signatures may be fitted by a DW of a moderate lever arm launched out to $\sim$ 40 au with SiO tracing dust-free streamlines from 0.05-0.3 au. Such a DW could limit the core-to-star efficiency to $\leq$50%.

astro-ph.SR

Seeds Of Life In Space (SOLIS): The organic composition diversity at 300--1000 au scale in Solar-type star forming regions

Complex organic molecules have been observed for decades in the interstellar medium. Some of them might be considered as small bricks of the macromolecules at the base of terrestrial life. It is hence particularly important to understand organic chemistry in Solar-like star forming regions. In this article, we present a new observational project: SOLIS (Seeds Of Life In Space). This is a Large Project at the IRAM-NOEMA interferometer, and its scope is to image the emission of several crucial organic molecules in a sample of Solar-like star forming regions in different evolutionary stage and environments. Here, we report the first SOLIS results, obtained from analysing the spectra of different regions of the Class 0 source NGC1333-IRAS4A, the protocluster OMC-2 FIR4, and the shock site L1157-B1. The different regions were identified based on the images of formamide (NH2CHO) and cyanodiacetylene (HC5N) lines. We discuss the observed large diversity in the molecular and organic content, both on large (3000-10000 au) and relatively small (300-1000 au) scales. Finally, we derive upper limits to the methoxy fractional abundance in the three observed regions of the same order of magnitude of that measured in few cold prestellar objects, namely ~10^-12-10^-11 with respect to H2 molecules.

astro-ph.SR

Deuterated methanol on Solar System scale around the HH212 protostar

Context: Methanol is thought to be mainly formed during the prestellar phase and its deuterated form keeps memory of the conditions at that epoch. Thanks to the unique combination of high angular resolution and sensitivity provided by ALMA, we wish to measure methanol deuteration in the planet formation region around a Class 0 protostar and to understand its origin. Aims: We mapped both the $^{13}$CH$_3$OH and CH$_2$DOH distribution in the inner regions ($\sim$100 au) of the HH212 system in Orion B. To this end, we used ALMA Cycle 1 and Cycle 4 observations in Band 7 with angular resolution down to $\sim$0.15$"$. Results: We detected 6 lines of $^{13}$CH$_3$OH and 13 lines of CH$_2$DOH with upper level energies up to 438 K in temperature units. We derived a rotational temperature of (171 $\pm$ 52) K and column densities of 7$\times$10$^{16}$ cm$^{-2}$ ($^{13}$CH$_3$OH) and 1$\times$10$^{17}$ cm$^{-2}$ (CH$_2$DOH), respectively. Consequently, the D/H ratio is (2.4 $\pm$ 0.4)$\times$10$^{-2}$, a value lower by an order of magnitude with respect to what was previously measured using single dish telescopes toward protostars located in Perseus. Our findings are consistent with the higher dust temperatures in Orion B with respect to that derived for the Perseus cloud. The emission is tracing a rotating structure extending up to 45 au from the jet axis and elongated by 90 au along the jet axis. So far, the origin of the observed emission appears to be related with the accretion disk. Only higher spatial resolution measurements however, will be able to disentangle between different possible scenarios: disk wind, disk atmosphere, or accretion shocks.

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Seeds of Life in Space (SOLIS) III. Formamide in protostellar shocks: evidence for gas-phase formation

Context: Modern versions of the Miller-Urey experiment claim that formamide (NH$_2$CHO) could be the starting point for the formation of metabolic and genetic macromolecules. Intriguingly, formamide is indeed observed in regions forming Solar-type stars as well as in external galaxies. Aims: How NH$_2$CHO is formed has been a puzzle for decades: our goal is to contribute to the hotly debated question of whether formamide is mostly formed via gas-phase or grain surface chemistry. Methods: We used the NOEMA interferometer to image NH$_2$CHO towards the L1157-B1 blue-shifted shock, a well known interstellar laboratory, to study how the components of dust mantles and cores released into the gas phase triggers the formation of formamide. Results: We report the first spatially resolved image (size $\sim$ 9", $\sim$ 2300 AU) of formamide emission in a shocked region around a Sun-like protostar: the line profiles are blueshifted and have a FWHM $\simeq$ 5 km s$^{-1}$. A column density of $N_{\rm NH_2CHO}$ = 8 $\times$ 10$^{12}$ cm$^{-1}$, and an abundance (with respect to H-nuclei) of 4 $\times$ 10$^{-9}$ are derived. We show a spatial segregation of formamide with respect to other organic species. Our observations, coupled with a chemical modelling analysis, indicate that the formamide observed in L1157-B1 is formed by gas-phase chemical process, and not on grain surfaces as previously suggested. Conclusions: The SOLIS interferometric observations of formamide provide direct evidence that this potentially crucial brick of life is efficiently formed in the gas-phase around Sun-like protostars.

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The L1157-B1 astrochemical laboratory: testing the origin of DCN

L1157-B1 is the brightest shocked region of the large-scale molecular outflow, considered the prototype of chemically rich outflows, being the ideal laboratory to study how shocks affect the molecular gas. Several deuterated molecules have been previously detected with the IRAM 30m, most of them formed on grain mantles and then released into the gas phase due to the shock. We aim to observationally investigate the role of the different chemical processes at work that lead to formation the of DCN and test the predictions of the chemical models for its formation. We performed high-angular resolution observations with NOEMA of the DCN(2-1) and H13CN(2-1) lines to compute the deuterated fraction, Dfrac(HCN). We detected emission of DCN(2-1) and H13CN(2-1) arising from L1157-B1 shock. Dfrac(HCN) is ~4x10$^{-3}$ and given the uncertainties, we did not find significant variations across the bow-shock. Contrary to HDCO, whose emission delineates the region of impact between the jet and the ambient material, DCN is more widespread and not limited to the impact region. This is consistent with the idea that gas-phase chemistry is playing a major role in the deuteration of HCN in the head of the bow-shock, where HDCO is undetected as it is a product of grain-surface chemistry. The spectra of DCN and H13CN match the spectral signature of the outflow cavity walls, suggesting that their emission result from shocked gas. The analysis of the time dependent gas-grain chemical model UCL-CHEM coupled with a C-type shock model shows that the observed Dfrac(HCN) is reached during the post-shock phase, matching the dynamical timescale of the shock. Our results indicate that the presence of DCN in L1157-B1 is a combination of gas-phase chemistry that produces the widespread DCN emission, dominating in the head of the bow-shock, and sputtering from grain mantles toward the jet impact region.

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SOLIS II. Carbon-chain growth in the Solar-type protocluster OMC2-FIR4

The interstellar delivery of carbon atoms locked into molecules might be one of the key ingredients for the emergence of life. Cyanopolyynes are carbon chains delimited at their two extremities by an atom of hydrogen and a cyano group, so that they might be excellent reservoirs of carbon. The simplest member, HC3N, is ubiquitous in the galactic interstellar medium and found also in external galaxies. Thus, understanding the growth of cyanopolyynes in regions forming stars similar to our Sun, and what affects it, is particularly relevant. In the framework of the IRAM/NOEMA Large Program SOLIS (Seeds Of Life In Space), we have obtained a map of two cyanopolyynes, HC3N and HC5N, in the protocluster OMC2-FIR4. Because our Sun is thought to be born in a rich cluster, OMC2-FIR4 is one of the closest and best known representatives of the environment in which the Sun may have been born. We find a HC3N/HC5N abundance ratio across the source in the range ~ 1 - 30, with the smallest values (< 10) in FIR5 and in the Eastern region of FIR4. The ratios < 10 can be reproduced by chemical models only if: (1) the cosmic-ray ionisation rate $ζ$ is ~ $4 \times 10^{-14}$ s$^{-1}$; (2) the gaseous elemental ratio C/O is close to unity; (3) O and C are largely depleted. The large $ζ$ is comparable to that measured in FIR4 by previous works and was interpreted as due to a flux of energetic (> 10 MeV) particles from embedded sources. We suggest that these sources could lie East of FIR4 and FIR5. A temperature gradient across FIR4, with T decreasing by about 10 K, could also explain the observed change in the HC3N/HC5N line ratio, without the need of a cosmic ray ionisation rate gradient. However, even in this case, a high constant cosmic-ray ionisation rate (of the order of $10^{-14}$ s$^{-1}$) is necessary to reproduce the observations.

astro-ph.GA

NH_3(1_0-0_0) in the pre-stellar core L1544

Pre-stellar cores represent the initial conditions in the process of star and planet formation, therefore it is important to study their physical and chemical structure. Because of their volatility, nitrogen-bearing molecules are key to study the dense and cold gas present in pre-stellar cores. The NH_3 rotational transition detected with Herschel-HIFI provides a unique combination of sensitivity and spectral resolution to further investigate physical and chemical processes in pre-stellar cores. Here we present the velocity-resolved Herschel-HIFI observations of the ortho-NH_3(1_0-0_0) line at 572 GHz and study the abundance profile of ammonia across the pre-stellar core L1544 to test current theories of its physical and chemical structure. Recently calculated collisional coefficients have been included in our non-LTE radiative transfer code to reproduce Herschel observations. A gas-grain chemical model, including spin-state chemistry and applied to the (static) physical structure of L1544 is also used to infer the abundance profile of ortho-NH_3 . The hyperfine structure of ortho-NH_3(1_0-0_0) is resolved for the first time in space. All the hyperfine components are strongly self-absorbed. The profile can be reproduced if the core is contracting in quasi-equilibrium, consistent with previous work, and if the NH_3 abundance is slightly rising toward the core centre, as deduced from previous interferometric observations of para-NH_3(1,1). The chemical model overestimates the NH_3 abundance at radii between ~ 4000 and 15000 AU by about two orders of magnitude and underestimates the abundance toward the core centre by more than one order of magnitude. Our observations show that chemical models applied to static clouds have problems in reproducing NH_3 observations.

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Silicon-bearing molecules in the shock L1157-B1: first detection of SiS around a Sun-like protostar

The shock L1157-B1 driven by the low-mass protostar L1157-mm is an unique environment to investigate the chemical enrichment due to molecules released from dust grains. IRAM-30m and Plateau de Bure Interferometer observations allow a census of Si-bearing molecules in L1157-B1. We detect SiO and its isotopologues and, for the first time in a shock, SiS. The strong gradient of the [SiO/SiS] abundance ratio across the shock (from >=180 to ~25) points to a different chemical origin of the two species. SiO peaks where the jet impacts the cavity walls ([SiO/H2] ~ 1e-6), indicating that SiO is directly released from grains or rapidly formed from released Si in the strong shock occurring at this location. In contrast, SiS is only detected at the head of the cavity opened by previous ejection events ([SiS/H2] ~ 2e-8). This suggests that SiS is not directly released from the grain cores but instead should be formed through slow gas-phase processes using part of the released silicon. This finding shows that Si-bearing molecules can be useful to distinguish regions where grains or gas-phase chemistry dominates.

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L1157-B1, a factory of complex organic molecules in a Solar-type star forming region

We report on a systematic search for oxygen-bearing Complex Organic Molecules (COMs) in the Solar-like protostellar shock region L1157-B1, as part of the IRAM Large Program "Astrochemical Surveys At IRAM" (ASAI). Several COMs are unambiguously detected, some for the first time, such as ketene H$_2$CCO, dimethyl ether (CH$_3$OCH$_3$) and glycolaldehyde (HCOCH$_2$OH), and others firmly confirmed, such as formic acid (HCOOH) and ethanol (C$_2$H$_5$OH). Thanks to the high sensitivity of the observations and full coverage of the 1, 2 and 3mm wavelength bands, we detected numerous (10--125) lines from each of the detected species. Based on a simple rotational diagram analysis, we derive the excitation conditions and the column densities of the detected COMs. Combining our new results with those previously obtained towards other protostellar objects, we found a good correlation between ethanol, methanol and glycolaldehyde. We discuss the implications of these results on the possible formation routes of ethanol and glycolaldehyde.

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Nature of shocks revealed by SOFIA OI observations in the Cepheus E protostellar outflow

Protostellar jets and outflows are key features of the star-formation process, and primary processes of the feedback of young stars on the interstellar medium. Understanding the underlying shocks is necessary to explain how jets and outflows are launched, and to quantify their chemical and energetic impacts on the surrounding medium. We performed a high-spectral resolution study of the [OI]$_{\rm 63 μm}$ emission in the outflow of the intermediate-mass Class 0 protostar Cep E-mm. We present observations of the OI $^3$P$_1 \rightarrow$ $^3$P$_2$, OH between $^2Π_{1/2}$ $J = 3/2$ and $J = 1/2$ at 1837.8 GHz, and CO (16-15) lines with SOFIA-GREAT at three positions in the Cep E outflow: mm (the driving protostar), BI (in the southern lobe), and BII (the terminal position in the southern lobe). The CO line is detected at all three positions. The OI line is detected in BI and BII, whereas the OH line is not detected. In BII, we identify three kinematical components in OI and CO, already detected in CO: the jet, the HH377 terminal bow-shock, and the outflow cavity. The OI column density is higher in the outflow cavity than in the jet, which itself is higher than in the terminal shock. The terminal shock is where the abundance ratio of OI to CO is the lowest (about 0.2), whereas the jet component is atomic (ratio $\sim$2.7). In the jet, we compare the OI observations with shock models that successfully fit the integrated intensity of 10 CO lines: these models do not fit the OI data. The high intensity of OI emission points towards the propagation of additional dissociative or alternative FUV-irradiated shocks, where the illumination comes from the shock itself. From the sample of low-to-high mass protostellar outflows where similar observations have been performed, the effects of illumination seem to increase with the mass of the protostar.

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Decrease of the organic deuteration during the evolution of Sun-like protostars: the case of SVS13-A

We present the results of formaldehyde and methanol deuteration measurements towards the Class I low-mass protostar SVS13-A, in the framework of the IRAM 30-m ASAI (Astrochemical Surveys At IRAM) project. We detected emission lines of formaldehyde, methanol, and their deuterated forms (HDCO, D2CO, CHD2OH, CH3OD) with Eup up to 276 K. The formaldehyde analysis indicates Tkin = 15 - 30 K, n (H2) >= 10^6 cm^-3, and a size of about 1200 AU suggesting an origin in the protostellar envelope. For methanol we find two components: (i) a high temperature (Tkin = 80 K) and very dense (> 10^8 cm^-3}) gas from a hot corino (radius about 35 AU), and (ii) a colder Tkin <= 70 K) and more extended (radius about 350 AU) region. The deuterium fractionation is 9 10^-2 for HDCO, 4 10^-3 for D2CO, and 2 - 7 10^-3 for CH2DOH, up to two orders of magnitude lower than the values measured in Class 0 sources. We derive also formaldehyde deuteration in the outflow: 4 10^-3, in agreement with what found in the L1157-B1 protostellar shock. Finally, we estimate [CH2DOH]/[CH3OD] about 2. The decrease of deuteration in the Class I source SVS13-A with respect to Class 0 sources can be explained by gas-phase processes. Alternatively, a lower deuteration could be the effect of a gradual collapse of less deuterated external shells of the protostellar evelope. The present measurements fill in the gap between prestellar cores and protoplanetary disks in the context of organics deuteration measurements.

astro-ph.SR

The shocked gas of the BHR71 outflow observed by Herschel: indirect evidence for an atomic jet

In the BHR71 region, two low-mass protostars drive two distinguishable outflows. They constitute an ideal laboratory to investigate the effects of shock chemistry and the mechanisms that led to their formation. We aim to define the morphology of the warm gas component of the BHR 71 outflow and at modelling its shocked component. We present the first far infrared Herschel images of the BHR71 outflow in the CO(14-13), H$_2$O (2$_{21}$-1$_{10}$), H$_2$O (2$_{12}$-1$_{01}$) and [OI] 145 $μ$m, lines, revealing the presence of several knots of warm, shocked gas associated with fast outflowing gas. In two of these knots we performed a detailed study of the physical conditions by comparing a large set of transitions from several molecules to a grid of shock models. Herschel lines ratios in the outflow knots are quite similar, showing that the excitation conditions of the fast moving gas do not change significantly within the first $\sim$ 0.068 pc of the outflow, apart at the extremity of the southern blue-shifted lobe that is expanding outside the molecular cloud. Rotational diagram, spectral line profile and LVG analysis of the CO lines in knot A show the presence of two gas components: one extended, cold ($T\sim$80 K) and dense ($n$(H$_2$) = 3$\times$10$^5$-4$\times$10$^6$ cm$^{-3}$) and another compact (18 arcsec), warm ($T$ = 1700-2200 K) with slightly lower density ($n$(H$_2$) = (2-6)$\times$10$^4$ cm$^{-3}$). In the two brightest knots (where we performed shock modelling) we found that H$_2$ and CO are well fitted with non-stationary (young) shocks. These models, however, significantly underestimate the observed fluxes of [OI] and OH lines, but are not too far off those of H$_2$O, calling for an additional, possibly dissociative, J-type shock component. Our modelling indirectly suggests that an additional shock component exists, possibly a remnant of the primary jet

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Glycolaldehyde in Perseus young solar analogs

Aims: In this paper we focus on the occurrence of glycolaldehyde (HCOCH2OH) in young solar analogs by performing the first homogeneous and unbiased study of this molecule in the Class 0 protostars of the nearby Perseus star forming region. Methods: We obtained sub-arcsec angular resolution maps at 1.3mm and 1.4mm of glycolaldehyde emission lines using the IRAM Plateau de Bure (PdB) interferometer in the framework of the CALYPSO IRAM large program. Results: Glycolaldehyde has been detected towards 3 Class 0 and 1 Class I protostars out of the 13 continuum sources targeted in Perseus: NGC1333-IRAS2A1, NGC1333-IRAS4A2, NGC1333-IRAS4B1, and SVS13-A. The NGC1333 star forming region looks particularly glycolaldehyde rich, with a rate of occurrence up to 60%. The glycolaldehyde spatial distribution overlaps with the continuum one, tracing the inner 100 au around the protostar. A large number of lines (up to 18), with upper-level energies Eu from 37 K up to 375 K has been detected. We derived column densities > 10^15 cm^-2 and rotational temperatures Trot between 115 K and 236 K, imaging for the first time hot-corinos around NGC1333-IRAS4B1 and SVS13-A. Conclusions: In multiple systems glycolaldehyde emission is detected only in one component. The case of the SVS13-A+B and IRAS4-A1+A2 systems support that the detection of glycolaldehyde (at least in the present Perseus sample) indicates older protostars (i.e. SVS13-A and IRAS4-A2), evolved enough to develop the hot-corino region (i.e. 100 K in the inner 100 au). However, only two systems do not allow us to firmly conclude whether the primary factor leading to the detection of glycolaldehyde emission is the environments hosting the protostars, evolution (e.g. low value of Lsubmm/Lint), or accretion luminosity (high Lint).

astro-ph.SR

Hot methanol from the inner region of the HH 212 protostellar system

The mechanisms leading to the formation of disks around young stellar objects (YSOs) and to the launching of the associated jets are crucial to the understanding of the earliest stages of star and planet formation. HH 212 is a privileged laboratory to study a pristine jet-disk system. Therefore we investigate the innermost region ($<100$ AU) around the HH 212-MM1 protostar through ALMA band\,7 observations of methanol. The 8 GHz bandwidth spectrum towards the peak of the continuum emission of the HH 212 system reveals at least 19 transitions of methanol. Several of these lines (among which several vibrationally excited lines in the v$_{\rm t}=1,2$ states) have upper energies above 500 K. They originate from a compact ($<135$ AU in diameter), hot ($\sim 295$ K) region elongated along the direction of the SiO jet. We performed a fit in the $uv$ plane of various velocity channels of the strongest high-excitation lines. The blue- and red-shifted velocity centroids are shifted roughly symmetrically on either side of the jet axis, indicating that the line-of-sight velocity beyond 0.7 km s$^{-1}$ from systemic is dominated by rotational motions. The velocity increases moving away from the protostar further indicating that the emission of methanol is not associated with a Keplerian disk or rotating-infalling cavity, and it is more likely associated with outflowing gas. We speculate that CH$_3$OH traces a disk wind gas accelerated at the base. The launching region would be at a radius of a few astronomical units from the YSO.

astro-ph.GA

The formation of ethylene glycol and other complex organic molecules in star-forming regions

We study the molecular abundance and spatial distribution of the simplest sugar alcohol, ethylene glycol (EG), the simplest sugar glycoladehyde (GA), and other chemically related complex organic species towards the massive star-forming region G31.41+0.31. We have analyzed multiple single dish and interferometric data, and obtained excitation temperatures and column densities using an LTE analysis. We have reported for the first time the presence of EG towards G31.41+0.31, and we have also detected multiple transitions of other complex organic molecules such as GA, methyl formate (MF), dimethyl ether (DME) and ethanol (ET). The high angular resolution images show that the EG emission is very compact, peaking towards the maximum of the continuum. These observations suggest that low abundance complex organic molecules, like EG or GA, are good probes of the gas located closer to the forming stars. Our analysis confirms that EG is more abundant than GA in G31.41+0.31, as previously observed in other interstellar regions. Comparing different star-forming regions we find evidence of an increase of the EG/GA abundance ratio with the luminosity of the source. The DME/MF and EG/ET ratios are nearly constant with luminosity. We have also found that the abundance ratios of pairs of isomers GA/MF and ET/DME decrease with the luminosity of the sources. The most likely explanation for the behavior of the EG/GA ratio is that these molecules are formed by different chemical formation routes not directly linked; although warm-up timescales effects and different formation and destruction efficiencies in the gas phase cannot be ruled out. The most likely formation route of EG is by combination of two CH$_{2}$OH radicals on dust grains. We also favor that GA is formed via the solid-phase dimerization of the formyl radical HCO, and a chemical link between MF and DME.

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First image of the L1157 molecular jet by the CALYPSO IRAM-PdBI survey

Fast jets are thought to be a crucial ingredient of star formation because they might extract angular momentum from the disk and thus allow mass accretion onto the star. However, it is unclear whether jets are ubiquitous, and likewise, their contribution to mass and angular momentum extraction during protostar formation remains an open question. Our aim is to investigate the ejection process in the low-mass Class 0 protostar L1157. This source is associated with a spectacular bipolar outflow, and the recent detection of high-velocity SiO suggests the occurrence of a jet. Observations of CO 2-1 and SiO 5-4 at 0.8" resolution were obtained with the IRAM Plateau de Bure Interferometer as part of the CALYPSO large program. The jet and outflow structure were fit with a precession model. We derived the column density of CO and SiO, as well as the jet mass-loss rate and mechanical luminosity. High-velocity CO and SiO emission resolve for the first time the first 200 au of the outflow-driving molecular jet. The jet is strongly asymmetric, with the blue lobe 0.65 times slower than the red lobe. This suggests that the large-scale asymmetry of the outflow is directly linked to the jet velocity and that the asymmetry in the launching mechanism has been at work for the past 1800 yr. Velocity asymmetries are common in T Tauri stars, which suggests that the jet formation mechanism from Class 0 to Class II stages might be similar. Our model simultaneously fits the inner jet and the clumpy 0.2 pc scale outflow by assuming that the jet precesses counter-clockwise on a cone inclined by 73 degree to the line of sight with an opening angle of 8 degree on a period of 1640 yr. The estimated jet mass flux and mechanical luminosity are 7.7e-7 Msun/yr, and 0.9 Lsun, indicating that the jet could extract at least 25% of the gravitational energy released by the forming star.

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Phosphorus-bearing molecules in solar-type star forming regions: First PO detection

As part of the Large Program ASAI (Astrochemical Surveys At IRAM), we have used the IRAM 30m telescope to lead a systematic search for the emission of rotational transitions of P-bearing species between 80 and 350 GHz towards L1157-B1, a shock position in the solar-type star forming region L1157. We report the detection of several transitions of PN and, for the first time, of prebiotic molecule PO. None of these species are detected towards the driving protostar of the outflow L1157-mm. Analysis of the line profiles shows that PN arises from the outflow cavity, where SiO, a strong shock tracer, is produced. Radiative transfer analysis yields an abundance of 2.5e-9 and 0.9e-9 for PO and PN, respectively. These results imply a strong depletion (approx 100) of Phosphorus in the quiescent cloud gas. Shock modelling shows that atomic N plays a major role in the chemistry of PO and PN. The relative abundance of PO and PN brings constraints both on the duration of the pre-shock phase, which has to be about 1 Myr, and on the shock parameters. The maximum temperature in the shock has to be larger than 4000K, which implies a shock velocity of 40 km/s.

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Diagnosing shock temperature with NH$_3$ and H$_2$O profiles

In a previous study of the L1157 B1 shocked cavity, a comparison between NH$_3$(1$_0$-$0_0$) and H$_2$O(1$_{\rm 10}$--1$_{\rm 01}$) transitions showed a striking difference in the profiles, with H$_2$O emitting at definitely higher velocities. This behaviour was explained as a result of the high-temperature gas-phase chemistry occurring in the postshock gas in the B1 cavity of this outflow. If the differences in behaviour between ammonia and water are indeed a consequence of the high gas temperatures reached during the passage of a shock, then one should find such differences to be ubiquitous among chemically rich outflows. In order to determine whether the difference in profiles observed between NH$_3$ and H$_2$O is unique to L1157 or a common characteristic of chemically rich outflows, we have performed Herschel-HIFI observations of the NH$_3$(1$_0$-0$_0$) line at 572.5 GHz in a sample of 8 bright low-mass outflow spots already observed in the H$_2$O(1$_{\rm 10}$--1$_{\rm 01}$) line within the WISH KP. We detected the ammonia emission at high-velocities at most of the outflows positions. In all cases, the water emission reaches higher velocities than NH$_3$, proving that this behaviour is not exclusive of the L1157-B1 position. Comparisons with a gas-grain chemical and shock model confirms, for this larger sample, that the behaviour of ammonia is determined principally by the temperature of the gas.

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