arXiv subjects

C. Comito

Publications and source records attributed to C. Comito.

At least 19 recordsLinked to original sources

arXiv2021

Herschel observations of extraordinary sources: Full Herschel/HIFI molecular line survey of Sagittarius B2(M)

We present a full analysis of a broadband spectral line survey of Sagittarius B2 (Main), one of the most chemically rich regions in the Galaxy located within the giant molecular cloud complex Sgr B2 in the Central Molecular Zone. Our goal is to derive the molecular abundances and temperatures of the high-mass star-forming region Sgr B2(M) and thus its physical and astrochemical conditions. Sgr B2(M) was observed using the Heterodyne Instrument for the Far-Infrared (HIFI) on board the Herschel Space Observatory in a spectral line survey from 480 to 1907 GHz at a spectral resolution of 1.1 MHz, which provides one of the largest spectral coverages ever obtained toward this high-mass star-forming region in the submillimeter with high spectral resolution and includes frequencies > 1 THz unobservable from the ground. We model the molecular emission from the submillimeter to the far-IR using the XCLASS program. For each molecule, a quantitative description was determined taking all emission and absorption features of that species across the entire spectral range into account. Additionally, we derive velocity resolved ortho / para ratios for those molecules for which ortho and para resolved molecular parameters are available. Finally, the temperature and velocity distributions are analyzed and the derived abundances are compared with those obtained for Sgr B2(N) from a similar HIFI survey. A total of 92 isotopologues were identified, arising from 49 different molecules, ranging from free ions to complex organic compounds and originating from a variety of environments from the cold envelope to hot and dense gas within the cores. Sulfur dioxide, methanol, and water are the dominant contributors. For the ortho / para ratios we find deviations from the high temperature values between 13 and 27 %. In total 14 % of all lines remain unidentified.

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arXiv2017

The physical and chemical structure of Sagittarius B2. II. Continuum millimeter emission of SgrB2(M) and SgrB2(N) with ALMA

The high-mass star forming sites SgrB2(M) and SgrB2(N) have been the target of numerous studies, revealing e.g. a rich chemistry. We want to characterize their physical and chemical structure using ALMA high-angular resolution observations at mm wavelengths, reaching spatial scales of about 4000 au, and covering the whole band 6 (from 211 to 275 GHz). In order to determine the continuum emission in line-rich sources, we use a new statistical method: STATCONT. We detect 27 continuum sources in SgrB2(M) and 20 in SgrB2(N). We study the continuum emission across the ALMA band 6, and compare it with previous SMA 345 GHz and VLA 40 GHz observations, to study the nature of the sources detected. The brightest sources are dominated by (partially optically thick) dust emission, while there is an important degree of contamination from ionized gas free-free emission in weaker sources. While the total mass in SgrB2(M) is distributed in many fragments, most of the mass in SgrB2(N) arises from a single object, with filamentary-like structures converging towards the center. There seems to be a lack of low-mass dense cores in both regions. We determine H2 volume densities for the cores of about 10^5-10^7 Msun pc^-3, one to two orders of magnitude higher than the stellar densities of super star clusters. In general, SgrB2(N) is chemically richer than SgrB2(M). There seems to be a correlation between the chemical richness and the mass of the fragments, with more massive clumps being more chemically rich. Both SgrB2(N) and SgrB2(M) harbour a cluster of hot molecular cores. We compare the continuum images with predictions from a detailed 3D radiative transfer model that reproduces the structure of SgrB2 from 45 pc down to 100 au. This dataset, together with ongoing projects in the range 5 to 200 GHz, better constrain the 3D structure of SgrB2, and allow us to understand its physical and chemical structure.

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arXiv2016

The physical and chemical structure of Sagittarius B2, I. Three-dimensional thermal dust and free-free continuum modeling on 100 au to 45 pc scales

We model the dust and free-free continuum emission in the high-mass star-forming region Sagittarius B2 in order to reconstruct the three-dimensional density and dust temperature distribution, as a crucial input to follow-up studies of the gas velocity field and molecular abundances. We employ the three-dimensional radiative transfer program RADMC-3D to calculate the dust temperature self-consistently, provided a given initial density distribution. This density distribution of the entire cloud complex is then recursively reconstructed based on available continuum maps, including both single-dish and high-resolution interferometric maps covering a wide frequency range (40 GHz - 4 THz). The model covers spatial scales from 45 pc down to 100 au, i.e. a spatial dynamic range of 10^5. We find that the density distribution of Sagittarius B2 can be reasonably well fitted by applying a superposition of spherical cores with Plummer-like density profiles. In order to reproduce the spectral energy distribution, we position Sgr B2(N) along the line of sight behind the plane containing Sgr B2(M). We find that the entire cloud complex comprises a total gas mass of 8.0 x 10^6 Msun within a diameter of 45 pc, corresponding to an averaged gas density of 170 Msun/pc^3. We estimate stellar masses of 2400 Msun and 20700 Msun and luminosities of 1.8 x 10^6 Lsun and 1.2 x 10^7 Lsun for Sgr B2(N) and Sgr B2(M), respectively. We report H_2 column densities of 2.9 x 10^24 cm^-2 for Sgr B2(N) and 2.5 x 10^24 cm^-2 for Sgr B2(M) in a 40" beam. For Sgr B2(S), we derive a stellar mass of 1100 Msun, a luminosity of 6.6 x 10^5 Lsun and a H_2 column density of 2.2 x 10^24 cm^-2 in a 40" beam. We calculate a star formation efficiency of 5% for Sgr B2(N) and 50% for Sgr B2(M), indicating that most of the gas content in Sgr B2(M) has already been converted to stars or dispersed.

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arXiv2014

Water emission from the high-mass star-forming region IRAS 17233-3606. High water abundances at high velocities

We investigate the physical and chemical processes at work during the formation of a massive protostar based on the observation of water in an outflow from a very young object previously detected in H2 and SiO in the IRAS 17233-3606 region. We estimated the abundance of water to understand its chemistry, and to constrain the mass of the emitting outflow. We present new observations of shocked water obtained with the HIFI receiver onboard Herschel. We detected water at high velocities in a range similar to SiO. We self-consistently fitted these observations along with previous SiO data through a state-of-the-art, one-dimensional, stationary C-shock model. We found that a single model can explain the SiO and H2O emission in the red and blue wings of the spectra. Remarkably, one common area, similar to that found for H2 emission, fits both the SiO and H2O emission regions. This shock model subsequently allowed us to assess the shocked water column density, N(H2O)=1.2x10^{18} cm^{-2}, mass, M(H2O)=12.5 M_earth, and its maximum fractional abundance with respect to the total density, x(H2O)=1.4x10^{-4}. The corresponding water abundance in fractional column density units ranges between 2.5x10^{-5} and 1.2x10^{-5}, in agreement with recent results obtained in outflows from low- and high-mass young stellar objects.

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arXiv2014

Widespread Rotationally-Hot Hydronium Ion in the Galactic Interstellar Medium

We present new observations of the (6,6) and (9,9) inversion transitions of the hydronium ion toward Sagittarius B2(N) and W31C. Sensitive observations toward Sagittarius B2(N) show that the high, ~ 500 K, rotational temperatures characterizing the population of the highly-excited metastable H3O+ rotational levels are present over a wide range of velocities corresponding to the Sagittarius B2 envelope, as well as the foreground gas clouds between the Sun and the source. Observations of the same lines toward W31C, a line of sight that does not intersect the Central Molecular Zone, but instead traces quiescent gas in the Galactic disk, also imply a high rotational temperature of ~ 380 K, well in excess of the kinetic temperature of the diffuse Galactic interstellar medium. While it is plausible that some fraction of the molecular gas may be heated to such high temperatures in the active environment of the Galactic center, characterized by high X-ray and cosmic ray fluxes, shocks and high degree of turbulence, this is unlikely in the largely quiescent environment of the Galactic disk clouds. We suggest instead that the highly-excited states of the hydronium ion are populated mainly by exoergic chemical formation processes and temperature describing the rotational level population does not represent the physical temperature of the medium. The same arguments may be applicable to other symmetric top rotors, such as ammonia. This offers a simple explanation to the long-standing puzzle of the presence of a pervasive, hot molecular gas component in the central region of the Milky Way. Moreover, our observations suggest that this is a universal process, not limited to the active environments associated with galactic nuclei.

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arXiv2013

Deuterated water in the solar-type protostars NGC 1333 IRAS 4A and IRAS 4B

Aims. The aim of this paper is to study deuterated water in the solar-type protostars NGC1333 IRAS4A and IRAS4B, to compare their HDO abundance distribution with other star-forming regions, and to constrain their HDO/H2O ratios. Methods. Using the Herschel/HIFI instrument as well as ground-based telescopes, we observed several HDO lines covering a large excitation range (Eup/k=22-168 K) towards these protostars and an outflow position. Non-LTE radiative transfer codes were then used to determine the HDO abundance profiles in these sources. Results. The HDO fundamental line profiles show a very broad component, tracing the molecular outflows, in addition to a narrower emission component and a narrow absorbing component. In the protostellar envelope of NGC1333 IRAS4A, the HDO inner (T>100 K) and outer (T<100 K) abundances with respect to H2 are estimated at 7.5x10^{-9} and 1.2x10^{-11}, respectively, whereas, in NGC1333 IRAS4B, they are 1.0x10^{-8} and 1.2x10^{-10}, respectively. Similarly to the low-mass protostar IRAS16293-2422, an absorbing outer layer with an enhanced abundance of deuterated water is required to reproduce the absorbing components seen in the fundamental lines at 465 and 894 GHz in both sources. This water-rich layer is probably extended enough to encompass the two sources as well as parts of the outflows. In the outflows emanating from NGC1333 IRAS4A, the HDO column density is estimated at about (2-4)x10^{13} cm^{-2}, leading to an abundance of about (0.7-1.9)x10^{-9}. An HDO/H2O ratio between 7x10^{-4} and 9x10^{-2} is derived in the outflows. In the warm inner regions of these two sources, we estimate the HDO/H2O ratios at about 1x10^{-4}-4x10^{-3}. This ratio seems higher (a few %) in the cold envelope of IRAS4A, whose possible origin is discussed in relation to formation processes of HDO and H2O.

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arXiv2012

The Abundance, Ortho/Para Ratio, and Deuteration of Water in the High-Mass Star Forming Region NGC 6334 I

We present Herschel/HIFI observations of 30 transitions of water isotopologues toward the high-mass star forming region NGC 6334 I. The line profiles of H_2^{16}O, H_2^{17}O, H_2^{18}O, and HDO show a complex pattern of emission and absorption components associated with the embedded hot cores, a lower-density envelope, two outflow components, and several foreground clouds, some associated with the NGC 6334 complex, others seen in projection against the strong continuum background of the source. Our analysis reveals an H2O ortho/para ratio of 3 +/- 0.5 in the foreground clouds, as well as the outflow. The water abundance varies from ~10^{-8} in the foreground clouds and the outer envelope to ~10^{-6} in the hot core. The hot core abundance is two orders of magnitude below the chemical model predictions for dense, warm gas, but within the range of values found in other Herschel/HIFI studies of hot cores and hot corinos. This may be related to the relatively low gas and dust temperature (~100 K), or time dependent effects, resulting in a significant fraction of water molecules still locked up in dust grain mantles. The HDO/H_2O ratio in NGC 6334 I, ~2 10^{-4}, is also relatively low, but within the range found in other high-mass star forming regions.

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arXiv2012

Molecular line survey of the high-mass star-forming region NGC 6334I with Herschel/HIFI and the SMA

We aim at deriving the molecular abundances and temperatures of the hot molecular cores in the high-mass star-forming region NGC 6334I and consequently deriving their physical and astrochemical conditions. In the framework of the Herschel guaranteed time key program CHESS, NGC 6334I is investigated by using HIFI aboard the Herschel Space Observatory. A spectral line survey is carried out in the frequency range 480-1907 GHz, and auxiliary interferometric data from the SMA in the 230 GHz band provide spatial information for disentangling the different physical components contributing to the HIFI spectrum. The spectral lines are identified with the aid of former surveys and spectral line catalogs. The observed spectrum is then compared to a simulated synthetic spectrum with XCLASS, assuming local thermal equilibrium, and best fit parameters are derived using the model optimization package MAGIX. A total of 46 molecules are identified, with 31 isotopologues, resulting in about 4300 emission and absorption lines. High- energy levels of the dominant emitter methanol and vibrationally excited HCN are detected. The number of unidentified lines remains low with 75, or less than 2 percent of the lines detected. The modeling suggests that several spectral features need two or more components to be fitted properly. Other components could be assigned to cold foreground clouds or to outflows, most visible in the SiO emission. A chemical variation between the two embedded hot cores is found, with more N-bearing molecules identified in SMA1 and O-bearing molecules in SMA2. Spectral line surveys give powerful insights into the study of the interstellar medium. Different molecules trace different physical conditions like the inner hot core, the envelope, the outflows or the cold foreground clouds. The derived molecular abundances provide further constraints for astrochemical models.

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arXiv2011

Submillimeter continuum observations of Sagittarius B2 at subarcsecond spatial resolution

We report the first high spatial resolution submillimeter continuum observations of the Sagittarius B2 cloud complex using the Submillimeter Array (SMA). With the subarcsecond resolution provided by the SMA, the two massive star-forming clumps Sgr B2(N) and Sgr B2(M) are resolved into multiple compact sources. In total, twelve submillimeter cores are identified in the Sgr B2(M) region, while only two components are observed in the Sgr B2(N) clump. The gas mass and column density are estimated from the dust continuum emission. We find that most of the cores have gas masses in excess of 100 M$_{\odot}$ and column densities above 10$^{25}$ cm$^{-2}$. The very fragmented appearance of Sgr B2(M), in contrast to the monolithic structure of Sgr B2 (N), suggests that the former is more evolved. The density profile of the Sgr B2(N)-SMA1 core is well fitted by a Plummer density distribution. This would lead one to believe that in the evolutionary sequence of the Sgr B2 cloud complex, a massive star forms first in an homogeneous core, and the rest of the cluster forms subsequently in the then fragmenting structure.

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arXiv2011

TIMASSS: The IRAS16293-2422 Millimeter And Submillimeter Spectral Survey. I. Observations, calibration and analysis of the line kinematics

While unbiased surveys observable from ground-based telescopes have previously been obtained towards several high mass protostars, very little exists on low mass protostars. To fill up this gap, we carried out a complete spectral survey of the bands at 3, 2, 1 and 0.8 mm towards the solar type protostar IRAS16293-2422. The observations covered about 200\,GHz and were obtained with the IRAM-30m and JCMT-15m telescopes. Particular attention was devoted to the inter-calibration of the obtained spectra with previous observations. All the lines detected with more than 3 sigma and free from obvious blending effects were fitted with Gaussians to estimate their basic kinematic properties. More than 4000 lines were detected (with sigma \geq 3) and identified, yielding a line density of approximatively 20 lines per GHz, comparable to previous surveys in massive hot cores. The vast majority (~2/3) of the lines are weak and due to complex organic molecules. The analysis of the profiles of more than 1000 lines belonging 70 species firmly establishes the presence of two distinct velocity components, associated with the two objects, A and B, forming the IRAS16293-2422 binary system. In the source A, the line widths of several species increase with the upper level energy of the transition, a behavior compatible with gas infalling towards a ~1 Mo object. The source B, which does not show this effect, might have a much lower central mass of ~0.1 Mo. The difference in the rest velocities of both objects is consistent with the hypothesis that the source B rotates around the source A. This spectral survey, although obtained with single-dish telescope with a low spatial resolution, allows to separate the emission from 2 different components, thanks to the large number of lines detected. The data of the survey are public and can be retrieved on the web site http://www-laog.obs.ujf-grenoble.fr/heberges/timasss.

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arXiv2011

Herschel observations of Extra-Ordinary Sources: Methanol as a probe of physical conditions in Orion KL

We have examined methanol emission from Orion KL with of the {\em Herschel}/HIFI instrument, and detected two methanol bands centered at 524 GHz and 1061 GHz. The 524 GHz methanol band (observed in HIFI band 1a) is dominated by the isolated $\Delta$J$=$0, K$=-4\rightarrow$-3, v$_t$$=$0 Q branch, and includes 25 E-type and 2 A-type transitions. The 1061 GHz methanol band (observed in HIFI band 4b) is dominated by the $\Delta$J$=$0, K$=7\rightarrow$6, v$_t$$=$0 Q branch transitions which are mostly blended. We have used the isolated E-type v$_t$$=$0 methanol transitions to explore the physical conditions in the molecular gas. With HIFI's high velocity resolution, the methanol emission contributed by different spatial components along the line of sight toward Orion KL (hot core, low velocity flow, and compact ridge) can be distinguished and studied separately. The isolated transitions detected in these bands cover a broad energy range (upper state energy ranging from 80 K to 900 K), which provides a unique probe of the thermal structure in each spatial component. The observations further show that the compact ridge is externally heated. These observations demonstrate the power of methanol lines as probes of the physical conditions in warm regions in close proximity to young stars.

astro-ph.SR↗

arXiv2010

Detection of OH$^+$ and H$_2$O$^+$ towards Orion~KL

We report observations of the reactive molecular ions OH$^+$, H$_2$O$^+$, and H$_3$O$^+$ towards Orion KL with Herschel/HIFI. All three $N=1-0$ fine-structure transitions of OH$^+$ at 909, 971, and 1033GHz and both fine-structure components of the doublet {\it ortho}-H$_2$O$^+$ $1_{11}-0_{00}$ transition at 1115 and 1139GHz were detected; an upper limit was obtained for H$_3$O$^+$. OH$^+$ and H$_2$O$^+$ are observed purely in absorption, showing a narrow component at the source velocity of 9 kms$^{-1}$, and a broad blueshifted absorption similar to that reported recently for HF and {\it para}-H$_{2}^{18}$O, and attributed to the low velocity outflow of Orion KL. We estimate column densities of OH$^+$ and H$_2$O$^+$ for the 9 km s$^{-1}$ component of $9 \pm 3 \times 10^{12}$cm$^{-2}$ and $7 \pm 2 \times 10^{12}$cm$^{-2}$, and those in the outflow of $1.9 \pm 0.7 \times 10^{13}$cm$^{-2}$ and $1.0 \pm 0.3 \times 10^{13}$cm$^{-2}$. Upper limits of $2.4\times 10^{12}$cm$^{-2}$ and $8.7\times 10^{12}$cm$^{-2}$ were derived for the column densities of {\it ortho} and {\it para}-H$_3$O$^+$ from transitions near 985 and 1657GHz. The column densities of the three ions are up to an order of magnitude lower than those obtained from recent observations of W31C and W49N. The comparatively low column densities may be explained by a higher gas density despite the assumption of a very high ionization rate.

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arXiv2010

The methanol lines and hot core of OMC2-FIR4, an intermediate-mass protostar, with Herschel-HIFI

In contrast with numerous studies on the physical and chemical structure of low- and high-mass protostars, much less is known about their intermediate-mass counterparts, a class of objects that could help to elucidate the mechanisms of star formation on both ends of the mass range. We present the first results from a rich HIFI spectral dataset on an intermediate-mass protostar, OMC2-FIR4, obtained in the CHESS (Chemical HErschel SurveyS of star forming regions) key programme. The more than 100 methanol lines detected between 554 and 961 GHz cover a range in upper level energy of 40 to 540 K. Our physical interpretation focusses on the hot core, but likely the cold envelope and shocked regions also play a role in reality, because an analysis of the line profiles suggests the presence of multiple emission components. An upper limit of 10^-6 is placed on the methanol abundance in the hot core, using a population diagram, large-scale source model and other considerations. This value is consistent with abundances previously seen in low-mass hot cores. Furthermore, the highest energy lines at the highest frequencies display asymmetric profiles, which may arise from infall around the hot core.

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arXiv2010

Herschel observations of EXtra-Ordinary Sources (HEXOS): Observations of H2O and its isotopologues towards Orion KL

We report the detection of more than 48 velocity-resolved ground rotational state transitions of H2(16)O, H2(18)O, and H2(17)O - most for the first time - in both emission and absorption toward Orion KL using Herschel/HIFI. We show that a simple fit, constrained to match the known emission and absorption components along the line of sight, is in excellent agreement with the spectral profiles of all the water lines. Using the measured H2(18)O line fluxes, which are less affected by line opacity than their H2(16)O counterparts, and an escape probability method, the column densities of H2(18)O associated with each emission component are derived. We infer total water abundances of 7.4E-5, 1.0E-5, and 1.6E-5 for the plateau, hot core, and extended warm gas, respectively. In the case of the plateau, this value is consistent with previous measures of the Orion-KL water abundance as well as those of other molecular outflows. In the case of the hot core and extended warm gas, these values are somewhat higher than water abundances derived for other quiescent clouds, suggesting that these regions are likely experiencing enhanced water-ice sublimation from (and reduced freeze-out onto) grain surfaces due to the warmer dust in these sources.

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arXiv2010

First detection of ND in the solar-mass protostar IRAS16293-2422

In the past decade, much progress has been made in characterising the processes leading to the enhanced deuterium fractionation observed in the ISM and in particular in the cold, dense parts of star forming regions such as protostellar envelopes. Very high molecular D/H ratios have been found for saturated molecules and ions. However, little is known about the deuterium fractionation in radicals, even though simple radicals often represent an intermediate stage in the formation of more complex, saturated molecules. The imidogen radical NH is such an intermediate species for the ammonia synthesis in the gas phase. Herschel/HIFI represents a unique opportunity to study the deuteration and formation mechanisms of such species, which are not observable from the ground. We searched here for the deuterated radical ND in order to determine the deuterium fractionation of imidogen and constrain the deuteration mechanism of this species. We observed the solar-mass Class 0 protostar IRAS16293-2422 with the heterodyne instrument HIFI as part of the Herschel key programme CHESS (Chemical HErschel Surveys of Star forming regions). The deuterated form of the imidogen radical ND was detected and securely identified with 2 hyperfine component groups of its fundamental transition in absorption against the continuum background emitted from the nascent protostar. The 3 groups of hyperfine components of its hydrogenated counterpart NH were also detected in absorption. We derive a very high deuterium fractionation with an [ND]/[NH] ratio of between 30 and 100%. The deuterium fractionation of imidogen is of the same order of magnitude as that in other molecules, which suggests that an efficient deuterium fractionation mechanism is at play. We discuss two possible formation pathways for ND, by means of either the reaction of N+ with HD, or deuteron/proton exchange with NH.

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arXiv2010

Ortho-to-para ratio of interstellar heavy water

Despite the low elemental deuterium abundance in the Galaxy, enhanced molecular D/H ratios have been found in the environments of low-mass star forming regions, and in particular the Class 0 protostar IRAS 16293-2422. The CHESS (Chemical HErschel Surveys of Star forming regions) Key Program aims at studying the molecular complexity of the interstellar medium. The high sensitivity and spectral resolution of the HIFI instrument provide a unique opportunity to observe the fundamental 1,1,1 - 0,0,0 transition of the ortho-D2O molecule, inaccessible from the ground, and to determine the ortho-to-para D2O ratio. We have detected the fundamental transition of the ortho-D2O molecule at 607.35 GHz towards IRAS 16293-2422. The line is seen in absorption with a line opacity of 0.62 +/- 0.11 (1 sigma). From the previous ground-based observations of the fundamental 1,1,0 - 1,0,1 transition of para-D2O seen in absorption at 316.80 GHz we estimate a line opacity of 0.26 +/- 0.05 (1 sigma). We show that the observed absorption is caused by the cold gas in the envelope of the protostar. Using these new observations, we estimate for the first time the ortho to para D2O ratio to be lower than 2.6 at a 3 sigma level of uncertainty, to be compared with the thermal equilibrium value of 2:1.

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arXiv2010

Herschel observations of EXtra-Ordinary Sources: The Terahertz spectrum of Orion KL seen at high spectral resolution

We present the first high spectral resolution observations of Orion KL in the frequency ranges 1573.4 - 1702.8 GHz (band 6b) and 1788.4 - 1906.8 GHz (band 7b) obtained using the HIFI instrument on board the Herschel Space Observatory. We characterize the main emission lines found in the spectrum, which primarily arise from a range of components associated with Orion KL including the hot core, but also see widespread emission from components associated with molecular outflows traced by H2O, SO2, and OH. We find that the density of observed emission lines is significantly diminished in these bands compared to lower frequency Herschel/HIFI bands.

astro-ph.SR↗

arXiv2010

The distribution of water in the high-mass star-forming region NGC 6334I

We present observations of twelve rotational transitions of H2O-16, H2O-18, and H2O-17 toward the massive star-forming region NGC 6334 I, carried out with Herschel/HIFI as part of the guaranteed time key program Chemical HErschel Surveys of Star forming regions (CHESS). We analyze these observations to obtain insights into physical processes in this region. We identify three main gas components (hot core, cold foreground, and outflow) in NGC 6334 I and derive the physical conditions in these components. The hot core, identified by the emission in highly excited lines, shows a high excitation temperature of 200 K, whereas water in the foreground component is predominantly in the ortho- and para- ground states. The abundance of water varies between 4 10^-5 (outflow) and 10^-8 (cold foreground gas). This variation is most likely due to the freeze-out of water molecules onto dust grains. The H2O-18/H2O-17 abundance ratio is 3.2, which is consistent with the O-18/O-17 ratio determined from CO isotopologues. The ortho/para ratio in water appears to be relatively low 1.6(1) in the cold, quiescent gas, but close to the equilibrium value of three in the warmer outflow material (2.5(0.8)).

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