arXiv subjects

C. Fasolato

Publications and source records attributed to C. Fasolato.

3 recordsLinked to original sources

arXiv2022

Superradiant Thomson scattering from graphite in the extreme ultraviolet

We study the Thomson scattering from highly oriented pyrolitic graphite excited by the extreme ultraviolet, coherent pulses of FERMI free electron laser (FEL). An apparent nonlinear behavior is observed and fully described in terms of the coherent nature of both exciting FEL beam and scattered radiation, producing an intensity dependent enhancement of the Thomson scattering cross section. The process closely resembles the Dicke's superradiant phenomenon and also triggers the generation of coherent, low-\textit{q} ($<$ 0.3 Å$^{-1}$), low energy phonons. The experimental data and analysis provide quantitative information on the sample characteristics, absorption, scattering factor and coherent phonon energies and populations, and open the route for the investigation of the deep nature of complex materials.

cond-mat.other↗

arXiv2019

DNA-functionalized gold nanoparticle assemblies for Surface Enhanced Raman Scattering

The programmable assembly of DNA strands is a promising tool for building tailored bottom-up nanostructures. Here, we present a plasmonic nanosystem obtained by the base-pairing mediated aggregation of gold nanoparticles (NPs) which are separately functionalized with two different single-stranded DNA chains. Their controlled assembly is mediated by a complementary DNA "bridge" sequence. We monitor the formation of DNA assembled NP aggregates in solution, and we study their Surface Enhanced Raman Scattering (SERS) response by comparison with the single NP constituents. We interpret the revealed SERS signatures in terms of the molecular and NP organization at the nanoscale, demonstrating that the action of the DNA bridge molecule yields regular NP aggregates with controlled interparticle distance and reproducible SERS response. This demonstrates the potential of the present system as a stable, biocompatible, and recyclable SERS sensor.

physics.app-ph↗

arXiv2018

Raman spectroscopy of graphene under ultrafast laser excitation

The equilibrium optical phonons of graphene are well characterized in terms of anharmonicity and electron-phonon interactions, however their non-equilibrium properties in the presence of hot charge carriers are still not fully explored. Here we study the Raman spectrum of graphene under ultrafast laser excitation with 3ps pulses, which trade off between impulsive stimulation and spectral resolution. We localize energy into hot carriers, generating non-equilibrium temperatures in the ~1700-3100K range, far exceeding that of the phonon bath, while simultaneously detecting the Raman response. The linewidth of both G and 2D peaks show an increase as function of the electronic temperature. We explain this as a result of the Dirac cones' broadening and electron-phonon scattering in the highly excited transient regime, important for the emerging field of graphene-based photonics and optoelectronics.

cond-mat.mes-hall↗