arXiv subjects

C. Grimaldi

Publications and source records attributed to C. Grimaldi.

At least 19 recordsLinked to original sources

arXiv2024

Technosignatures longevity and Lindy's law

The probability of detecting technosignatures (i.e. evidence of technological activity beyond Earth) increases with their longevity, or the time interval over which they manifest. Therefore, the assumed distribution of longevities has some bearing on the chances of success of technosignature searches, as well as on the inferred age of technosignatures following a first contact. Here, we investigate the possibility that the longevity of technosignatures conforms to the so-called Lindy's law, whereby, at any time, their remaining life expectancy is roughly proportional to their age. We show that, if Lindy's law applies, the general tenet that the first detected technosignature ought to be very long lived may be overruled. We conclude by discussing the number of emitters that had to appear, over the history of the Galaxy, in order for one of them to be detectable today from Earth.

physics.pop-ph↗

arXiv2015

Dimensional effects on the tunneling conductivity of gold-implanted nanocomposite films

We study the dependence of the electrical conductivity on the gold concentration of Au-implanted polymethylmethacrylate (PMMA) and alumina nanocomposite thin films. For Au contents larger than a critical concentration, the conductivity of Au-PMMA and Au-alumina is well described by percolation in two dimensions, indicating that the critical correlation length for percolation is larger than the thickness of the films. Below the critical loading, the conductivity is dominated by tunneling processes between isolated Au particles dispersed in PMMA or alumina continuous matrices. Using an effective medium analysis of the tunneling conductivity, we show that Au-PMMA behaves as a tunneling system in two dimensions, as the film thickness is comparable to the mean Au particle size. On the contrary, the conductivity of Au-alumina films is best described by tunneling in three dimensions, although the film thickness is only a few times larger than the particle size. We interpret the enhancement of the effective dimensionality of Au-alumina films in the tunneling regime as due to the larger film thickness as compared to the mean interparticle distances.

cond-mat.dis-nn↗

arXiv2014

Theory of percolation and tunneling regimes in nanogranular metal films

Nanogranular metal composites, consisting of immiscible metallic and insulating phases deposited on a substrate, are characterized by two distinct electronic transport regimes depending on the relative amount of the metallic phase. At sufficiently large metallic loadings, granular metals behave as percolating systems with a well-defined critical concentration above which macroscopic clusters of physically connected conductive particles span the entire sample. Below the critical loading, granular metal films are in the dielectric regime, where current can flow throughout the composite only via hopping or tunneling processes between isolated nanosized particles or clusters. In this case transport is intrinsically non-percolative in the sense that no critical concentration can be identified for the onset of transport. It is shown here that, although being very different in nature, these two regimes can be described by treating percolation and hopping on equal footing. By considering general features of the microstructure and of the electrical connectedness, the concentration dependence of the dc conductivity of several nanogranular metal films is reproduced to high accuracy within an effective medium approach. In particular, fits to published experimental data enable us to extract the values of microscopic parameters that govern the percolation and tunneling regimes, explaining thus the transport properties observed in nanogranular metal films.

cond-mat.dis-nn↗

arXiv2013

Depletion interaction effects on the tunneling conductivity of nanorod suspensions

We study by simulation and theory how the addition of insulating spherical particles affects the conductivity of fluids of conducting rods, modeled by spherocylinders. The electrical connections are implemented as tunneling processes, leading to a more detailed and realistic description than a discontinuous percolation approach. We find that the spheres enhance the tunneling conductivity for a given concentration of rods and that the enhancement increases with rod concentration into the regime where the conducting network is well established. By reformulating the network of rods using a critical path analysis, we quantify the effect of depletion-induced attraction between the rods due to the spheres. Furthermore, we show that our conductivity data are quantitatively reproduced by an effective medium approximation, which explicitly relates the system tunneling conductance to the structure of the rod-sphere fluid.

cond-mat.soft↗

arXiv2012

Tunneling conductivity in composites of attractive colloids

In conductor-insulator nanocomposites in which conducting fillers are dispersed in an insulating matrix the electrical connectedness is established by interparticle tunneling or hopping processes. These systems are intrinsically non-percolative and a coherent description of the functional dependence of the conductivity $σ$ on the filler properties, and in particular of the conductor-insulator transition, requires going beyond the usual continuum percolation approach by relaxing the constraint of a fixed connectivity distance. In this article we consider dispersions of conducting spherical particles which are connected to all others by tunneling conductances and which are subjected to an effective attractive square well potential. We show that the conductor-insulator transition at low contents $ϕ$ of the conducting fillers does not determine the behavior of $σ$ at larger concentrations, in striking contrast to what is predicted by percolation theory. In particular, we find that at low $ϕ$ the conductivity is governed almost entirely by the stickiness of the attraction, while at larger $ϕ$ values $σ$ depends mainly on the depth of the potential well. As a consequence, by varying the range and depth of the potential while keeping the stickiness fixed, composites with similar conductor-insulator transitions may display conductivity variations of several orders of magnitude at intermediate and large $ϕ$ values. By using a recently developed effective medium theory and the critical path approximation we explain this behavior in terms of dominant tunneling processes which involve interparticle distances spanning different regions of the square-well fluid structure as $ϕ$ is varied. Our predictions could be tested in experiments by changing the potential profile with different depletants in polymer nanocomposites.

cond-mat.dis-nn↗

arXiv2012

Tunneling and percolation transport regimes in segregated composites

We consider the problem of electron transport in segregated conductor-insulator composites in which the conducting particles are connected to all others via tunneling conductances, thus forming a global tunnelingconnected resistor network. Segregation is induced by the presence of large insulating particles, which forbid the much smaller conducting fillers from occupying uniformly the three-dimensional volume of the composite. By considering both colloidal-like and granular-like dispersions of the conducting phase, modeled respectively by dispersions in the continuum and in the lattice, we evaluate by Monte Carlo simulations the effect of segregation on the composite conductivity σ, and show that an effective-medium theory applied to the tunneling network reproduces accurately the Monte Carlo results. The theory clarifies that the main effect of segregation in the continuum is that of reducing the mean interparticle distances, leading to a strong enhancement of the conductivity. In the lattice-segregation case the conductivity enhancement is instead given by the lowering of the percolation thresholds for first and beyond-first nearest neighbors. Our results generalize to segregated composites the tunneling-based description of both the percolation and hopping regimes introduced previously for homogeneous disordered systems.

cond-mat.dis-nn↗

arXiv2010

Transport properties of nonhomogeneous segregated composites

In conductor-insulator composites in which the conducting particles are dispersed in an insulating continuous matrix the electrical connectedness is established by interparticle quantum tunneling. A recent formulation of the transport problem in this kind of composites treats each conducting particle as electrically connected to all others via tunneling conductances to form a global tunneling network. Here, we extend this approach to nonhomogeneous composites with a segregated distribution of the conducting phase. We consider a model of segregation in which large random insulating spherical inclusions forbid small conducting particles to occupy homogeneously the volume of the composite, and allow tunneling between all pairs of the conducting objects. By solving numerically the corresponding tunneling resistor network, we show that the composite conductivity is enhanced by segregation and that it may remain relatively large also for very small values of the conducting filler concentration. We interpret this behavior by a segregation-induced reduction of the interparticle distances, which is confirmed by a critical path approximation applied to the segregated network. Furthermore, we identify an approximate but accurate scaling relation permitting to express the conductivity of a segregated systems in terms of the interparticle distances of a corresponding homogeneous system, and which provides an explicit formula for the conductivity which we apply to experimental data on segregated RuO2-cermet composites.

cond-mat.dis-nn↗

arXiv2010

Percolation-to-hopping crossover in conductor-insulator composites

Here, we show that the conductivity of conductor-insulator composites in which electrons can tunnel from each conducting particle to all others may display both percolation and tunneling (i.e. hopping) regimes depending on few characteristics of the composite. Specifically, we find that the relevant parameters that give rise to one regime or the other are $D/ξ$ (where $D$ is the size of the conducting particles and $ξ$ is the tunneling length) and the specific composite microstructure. For large values of $D/ξ$, percolation arises when the composite microstructure can be modeled as a regular lattice that is fractionally occupied by conducting particle, while the tunneling regime is always obtained for equilibrium distributions of conducting particles in a continuum insulating matrix. As $D/ξ$ decreases the percolating behavior of the conductivity of lattice-like composites gradually crosses over to the tunneling-like regime characterizing particle dispersions in the continuum. For $D/ξ$ values lower than $D/ξ\simeq 5$ the conductivity has tunneling-like behavior independent of the specific microstructure of the composite.

cond-mat.dis-nn↗

arXiv2010

Solution of the tunneling-percolation problem in the nanocomposite regime

We noted that the tunneling-percolation framework is quite well understood at the extreme cases of percolation-like and hopping-like behaviors but that the intermediate regime has not been previously discussed, in spite of its relevance to the intensively studied electrical properties of nanocomposites. Following that we study here the conductivity of dispersions of particle fillers inside an insulating matrix by taking into account explicitly the filler particle shapes and the inter-particle electron tunneling process. We show that the main features of the filler dependencies of the nanocomposite conductivity can be reproduced without introducing any \textit{a priori} imposed cut-off in the inter-particle conductances, as usually done in the percolation-like interpretation of these systems. Furthermore, we demonstrate that our numerical results are fully reproduced by the critical path method, which is generalized here in order to include the particle filler shapes. By exploiting this method, we provide simple analytical formulas for the composite conductivity valid for many regimes of interest. The validity of our formulation is assessed by reinterpreting existing experimental results on nanotube, nanofiber, nanosheet and nanosphere composites and by extracting the characteristic tunneling decay length, which is found to be within the expected range of its values. These results are concluded then to be not only useful for the understanding of the intermediate regime but also for tailoring the electrical properties of nanocomposites.

cond-mat.mtrl-sci↗

arXiv2010

Large polaron formation induced by Rashba spin-orbit coupling

Here the electron-phonon Holstein model with Rashba spin-orbit interaction is studied for a two dimensional square lattice in the adiabatic limit. It is demonstrated that a delocalized electron at zero spin-orbit coupling localizes into a large polaron state as soon as the Rashba term is nonzero. This spin-orbit induced polaron state has localization length inversely proportional to the Rashba coupling $γ$, and it dominates a wide region of the $γ$-$λ$ phase diagram, where $λ$ is the electron-phonon interaction.

cond-mat.str-el↗

arXiv2009

Filler Dependencies of Electrical Conductivity in Nanotube and Nanofiber Composites

We report on a model of polymer nanocomposites with fibrous fillers which explicitly considers the microscopic filler features and replicates the composites as random distributions of particles interconnected via electron tunneling. By exploiting the critical path method, we are able to obtain simple formulas, applicable to most nanotube and nanofiber composites, which allow to infer the overall composite conductivity starting from few parameters like filler volume fraction, size, and aspect-ratio. The validity of our formulation is assessed by reinterpreting existing experimental results and by extracting the characteristic tunneling length, which is mostly found within its expected value range. These results can be used practically to tailor the electrical properties of nanocomposites.

cond-mat.dis-nn↗

arXiv2008

Optimal Percolation of Disordered Segregated Composites

We evaluate the percolation threshold values for a realistic model of continuum segregated systems, where random spherical inclusions forbid the percolating objects, modellized by hard-core spherical particles surrounded by penetrable shells, to occupy large regions inside the composite. We find that the percolation threshold is generally a non-monotonous function of segregation, and that an optimal (i. e., minimum) critical concentration exists well before maximum segregation is reached. We interpret this feature as originating from a competition between reduced available volume effects and enhanced concentrations needed to ensure percolation in the highly segregated regime. The relevance with existing segregated materials is discussed.

cond-mat.dis-nn↗

arXiv2008

Energy levels of a two-dimensional hydrogen atom with spin-orbit Rashba interaction

Electronic bound states around charged impurities in two-dimensional systems with structural inversion asymmetry can be described in terms of a two-dimensional hydrogen atom in the presence of a Rashba spin-orbit interaction. Here, the energy levels of the bound electron are evaluated numerically as a function of the spin-orbit interaction, and analytic expressions for the weak and strong spin-orbit coupling limits are compared with the numerical results. It is found that, besides the level splitting due to the lack of inversion symmetry, the energy levels are lowered for sufficiently strong spin-orbit coupling, indicating that the electron gets more tightly bound to the ion as the spin-orbit interaction increases. Similarities and differences with respect to the two-dimensional Fröhlich polaron with Rashba coupling are discussed.

cond-mat.mes-hall↗

arXiv2008

Weak and strong coupling limits of the two-dimensional Fröhlich polaron with spin-orbit Rashba interaction

The continuous progress in fabricating low-dimensional systems with large spin-orbit couplings has reached a point in which nowadays materials may display spin-orbit splitting energies ranging from a few to hundreds of meV. This situation calls for a better understanding of the interplay between the spin-orbit coupling and other interactions ubiquitously present in solids, in particular when the spin-orbit splitting is comparable in magnitude with characteristic energy scales such as the Fermi energy and the phonon frequency. In this article, the two-dimensional Fröhlich electron-phonon problem is reformulated by introducing the coupling to a spin-orbit Rashba potential, allowing for a description of the spin-orbit effects on the electron-phonon interaction. The ground state of the resulting Fröhlich-Rashba polaron is studied in the weak and strong coupling limits of the electron-phonon interaction for arbitrary values of the spin-orbit splitting. The weak coupling case is studied within the Rayleigh-Schrödinger perturbation theory, while the strong-coupling electron-phonon regime is investigated by means of variational polaron wave functions in the adiabatic limit. It is found that, for both weak and strong coupling polarons, the ground state energy is systematically lowered by the spin-orbit interaction, indicating that the polaronic character is strengthened by the Rashba coupling. It is also shown that, consistently with the lowering of the ground state, the polaron effective mass is enhanced compared to the zero spin-orbit limit. Finally, it is argued that the crossover between weakly and strongly coupled polarons can be shifted by the spin-orbit interaction.

cond-mat.str-el↗

arXiv2007

Electron-phonon interaction and charge carrier mass enhancement in SrTiO3

We report a comprehensive THz, infrared and optical study of Nb doped SrTiO3 as well as DC conductivity and Hall effect measurements. Our THz spectra at 7K show the presence of a very narrow (<2 meV) Drude peak, the spectral weight of which shows approximately a factor of three enhancement of the band mass for all carrier concentrations. The missing spectral weight is regained in a broad 'mid-infrared' band which originates from electron-phonon coupling. We find no evidence of a particularly large electron-phonon coupling that would result in small polaron formation. Analysis of the results yields an electron-phonon coupling parameter of an intermediate strength, $α\approx 4$.

cond-mat.str-el↗

arXiv2007

Electron-phonon effects on spin-orbit split bands of two dimensional systems

The electronic self-energy is studied for a two dimensional electron gas coupled to a spin-orbit Rashba field and interacting with dispersionless phonons. For the case of a momentum independent electron-phonon coupling (Holstein model) we solve numerically the self-consistent non-crossing approximation for the self-energy and calculate the electron mass enhancement $m^*/m$ and the spectral properties. We find that, even for nominal weak electron-phonon interaction, for strong spin-orbit couplings the electrons behave as effectively strongly coupled to the phonons. We interpret this result by a topological change of the Fermi surface occurring at sufficiently strong spin-orbit coupling, which induces a square-root divergence in the electronic density of states at low energies. We provide results for $m^*/m$ and for the density of states of the interacting electrons for several values of the electron filling and of the spin-orbit interaction.

cond-mat.str-el↗

arXiv2006

Topological Change of the Fermi Surface in Low Density Rashba Gases: Application to Superconductivity

Strong spin-orbit coupling can have a profound effect on the electronic structure in a metal or semiconductor, particularly for low electron concentrations. We show how, for small values of the Fermi energy compared to the spin-orbit splitting of Rashba type, a topological change of the Fermi surface leads to an effective reduction of the dimensionality in the electronic density of states. We investigate its consequences on the onset of the superconducting instability. We show, by solving the Eliashberg equations for the critical temperature as a function of spin-orbit coupling and electron density, that the superconducting critical temperature is significantly tuned in this regime by the spin-orbit coupling. We suggest that materials with strong spin-orbit coupling are good candidates for enhanced superconductivity.

cond-mat.mes-hall↗

arXiv2006

Isotope effects in the Hubbard-Holstein model within dynamical mean-field theory

We study the isotope effects arising from the coupling of correlated electrons with dispersionless phonons by considering the Hubbard-Holstein model at half-filling within the dynamical mean-field theory. In particular we calculate the isotope effects on the quasi-particle spectral weight $Z$, the renormalized phonon frequency, and the static charge and spin susceptibilities. In the weakly correlated regime $U/t \lesssim 1.5$, where $U$ is the Hubbard repulsion and $t$ is the bare electron half-bandwidth, the physical properties are qualitatively similar to those characterizing the Holstein model in the absence of Coulomb repulsion, where the bipolaronic binding takes place at large electron-phonon coupling, and it reflects in divergent isotope responses. On the contrary in the strongly correlated regime $U/t \gtrsim 1.5$, where the bipolaronic metal-insulator transition becomes of first order, the isotope effects are bounded, suggesting that the first order transition is likely driven by an electronic mechanism, rather then by a lattice instability. These results point out how the isotope responses are extremely sensitive to phase boundaries and they may be used to characterize the competition between the electron-phonon coupling and the Hubbard repulsion.

cond-mat.str-el↗