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C. Ignacio Sainz-Díaz

Publications and source records attributed to C. Ignacio Sainz-Díaz.

9 recordsLinked to original sources

Self-Organized Pattern Formation in Geological Soft Matter

Geological materials are often seen as the antithesis of soft; rocks are hard. However, during the formation of minerals and rocks, all the systems we shall discuss, indeed geological materials in general, pass through a stage where they are soft. This occurs either because they form at a high temperature - igneous or metamorphic rock - or because they form at a lower temperature but in the presence of water - sedimentary rock. For this reason it is useful to introduce soft-matter concepts into the geological domain. There is a universality in the diverse instances of geological patterns that may be appreciated by looking at the common aspect in their formation of having passed through a stage as soft matter.

physics.geo-ph↗

Self-assembled versus biological pattern formation in geology

Both abiotic self-organization and biological mechanisms have been put forward as the origin of a number of geological patterns. It is important to comprehend the formation mechanisms of such structures both to understand geological self-organization and in order to differentiate them from biological patterns -- fossils and bio-influenced structures -- seen in geological systems. Being able to distinguish the traces of biological activity from geological self-organization is fundamental both for understanding the origin of life on Earth and for the search for life beyond Earth.

nlin.PS↗

A biological hydraulic accumulator: How the squirting cucumber, Ecballium elaterium, squirts its seeds

Seed dispersal is a fundamental process that allows offspring to reach suitable habitats and colonize new environments. While most plants rely on external vectors, some have evolved mechanisms that employ the buildup of liquid pressure in a closed compartment and its explosive release to disperse their seeds. This form of energy storage, reinvented by humans for engineering applications, is termed a hydraulic accumulator. Here we investigated the fluid mechanics involved in dispersal in the squirting cucumber, Ecballium elaterium integrating high-speed videography (up to 10 000 fps), microtomography, and internal pressure sensors. We recorded long-term pressure time series showing that E. elaterium exhibits circadian (24 hour) and ultradian (short-period) rhythms. Remarkably, the measurements revealed a lack of correlation between fruit and stem turgor; while the stem showed strong circadian cycles, the fruit often did not, suggesting isolated physiological processes in different tissues. The fruit's spongy wall tissue stores elastic potential energy as turgor pressure builds to nearly one atmosphere (92-99 kPa). Upon detachment, this energy is rapidly released to expel a turbulent, particle-laden liquid jet. Microtomography revealed that the seeds are packed around a central funiculus, a configuration that optimizes their exit through the basal orifice at velocities of up to 30 m/s. Seeds eventually move faster than the liquid droplets during the later stages of ejection as they shed their liquid coating. This sophisticated mechanism ensures a broad dispersal cone, effectively spreading offspring across space and environmental conditions.

physics.bio-ph↗

Competing structures in a minimal double-well potential model of condensed matter

The microscopic structure of several amorphous substances often reveals complex patterns such as medium- or long-range order, spatial heterogeneity, and even local polycrystallinity. To capture all these features, models usually incorporate a refined description of the particle interaction that includes an ad hoc design of the inside of the system constituents, and use temperature as a control parameter. We show that all these features can emerge from a minimal athermal two-dimensional model where particles interact isotropically by a double-well potential, which includes an excluded volume and a maximum coordination number. The rich variety of structural patterns shown by this simple geometrical model apply to a wide range of real systems including water, silicon, and different amorphous materials.

cond-mat.mtrl-sci↗

Helical microstructures in molluscan biomineralization are a biological example of close packed helices that may form from a colloidal liquid crystal precursor in a twist-bend nematic phase

We demonstrate that nature has produced a close-packed helical twisted filamentous material in the biomineralization of the mollusc. In liquid crystals, twist-bend nematics have been predicted and observed. We present and analyse evidence that the helical biomineral microstructure of mollusc shells may be formed from such a liquid-crystal precursor.

cond-mat.soft↗

Brinicles as a case of inverse chemical gardens

Brinicles are hollow tubes of ice from centimetres to metres in length that form under floating sea ice in the polar oceans when dense, cold brine drains downwards from sea ice into sea water close to its freezing point. When this extremely cold brine leaves the ice it freezes the water it comes into contact with; a hollow tube of ice --- a brinicle --- growing downwards around the plume of descending brine. We show that brinicles can be understood as a form of the self-assembled tubular precipitation structures termed chemical gardens, plant-like structures formed on placing together a soluble metal salt, often in the form of a seed crystal, and an aqueous solution of one of many anions, often silicate. On one hand, in the case of classical chemical gardens, an osmotic pressure difference across a semipermeable precipitation membrane that filters solutions by rejecting the solute leads to an inflow of water and to its rupture. The internal solution, generally being lighter than the external solution, flows up through the break, and as it does so a tube grows upwards by precipitation around the jet of internal solution. Such chemical-garden tubes can grow to many centimetres in length. In the case of brinicles, on the other hand, in floating sea ice we have porous ice in a mushy layer that filters out water, by freezing it, and allows concentrated brine through. Again there is an osmotic pressure difference leading to a continuing ingress of sea water in a siphon pump mechanism that is sustained as long as the ice continues to freeze. Since the brine that is pumped out is denser than the sea water, and descends rather rises, a brinicle is a downwards growing tube of ice; an inverse chemical garden.

nlin.AO↗

Calcium Carbonate Polyamorphism and Its Role in Biomineralization: How Many Amorphous Calcium Carbonates Are There?

Although the polymorphism of calcium carbonate is well known, and its polymorphs-calcite, aragonite, and vaterite-have been highly studied in the context of biomineralization, polyamorphism is a much more recently discovered phenomenon, and the existence of more than one amorphous phase of calcium carbonate in biominerals has only very recently been understood. Here we summarize what is known about polyamorphism in calcium carbonate as well as what is under- stood about the role of amorphous calcium carbonate in biominerals. We show that consideration of the amorphous forms of calcium carbonate within the physical notion of polyamorphism leads to new insights when it comes to the mechanisms by which polymorphic structures can evolve in the first place. This not only has implications for our understanding of biomineralization, but also of the means by which crystallization may be controlled in medical, pharmaceutical, and industrial contexts.

cond-mat.mtrl-sci↗

Crystal growth as an excitable medium

Crystal growth has been widely studied for many years, and, since the pioneering work of Burton, Cabrera and Frank, spirals and target patterns on the crystal surface have been understood as forms of tangential crystal growth mediated by defects and by two-dimensional nucleation. Similar spirals and target patterns are ubiquitous in physical systems describable as excitable media. Here, we demonstrate that this is not merely a superficial resemblance, that the physics of crystal growth can be set within the framework of an excitable medium, and that appreciating this correspondence may prove useful to both fields. Apart from solid crystals, we discuss how our model applies to the biomaterial nacre, formed by layer growth of a biological liquid crystal.

nlin.PS↗

Ice structures, patterns, and processes: A view across the ice-fields

We look ahead from the frontiers of research on ice dynamics in its broadest sense; on the structures of ice, the patterns or morphologies it may assume, and the physical and chemical processes in which it is involved. We highlight open questions in the various fields of ice research in nature; ranging from terrestrial and oceanic ice on Earth, to ice in the atmosphere, to ice on other solar system bodies and in interstellar space.

nlin.PS↗